CA1031370A - Procede pour l'isomerisation de methyl-2 butenenitrile-3 en pentenenitrile lineaire - Google Patents

Procede pour l'isomerisation de methyl-2 butenenitrile-3 en pentenenitrile lineaire

Info

Publication number
CA1031370A
CA1031370A CA210,299A CA210299A CA1031370A CA 1031370 A CA1031370 A CA 1031370A CA 210299 A CA210299 A CA 210299A CA 1031370 A CA1031370 A CA 1031370A
Authority
CA
Canada
Prior art keywords
butenenitrile
isomerization
methyl
linear pentenenitrile
pentenenitrile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA210,299A
Other languages
English (en)
Other versions
CA210299S (en
Inventor
Peter E. Tomlinson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Application granted granted Critical
Publication of CA1031370A publication Critical patent/CA1031370A/fr
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CA210,299A 1973-10-02 1974-09-30 Procede pour l'isomerisation de methyl-2 butenenitrile-3 en pentenenitrile lineaire Expired CA1031370A (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US00402905A US3852329A (en) 1973-10-02 1973-10-02 Process for isomerization of 2-methyl-3-butene-nitrile to a linear pentenenitrile

Publications (1)

Publication Number Publication Date
CA1031370A true CA1031370A (fr) 1978-05-16

Family

ID=23593759

Family Applications (1)

Application Number Title Priority Date Filing Date
CA210,299A Expired CA1031370A (fr) 1973-10-02 1974-09-30 Procede pour l'isomerisation de methyl-2 butenenitrile-3 en pentenenitrile lineaire

Country Status (9)

Country Link
US (1) US3852329A (fr)
JP (1) JPS5821911B2 (fr)
BE (1) BE820586A (fr)
CA (1) CA1031370A (fr)
DE (1) DE2446854C2 (fr)
FR (1) FR2246540B1 (fr)
GB (1) GB1432926A (fr)
IT (1) IT1022539B (fr)
NL (1) NL185342C (fr)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1979000193A1 (fr) * 1977-10-11 1979-04-19 Ici Ltd Nitriles organiques
US4298546A (en) * 1980-08-05 1981-11-03 E. I. Du Pont De Nemours And Company Isomerization of 2-methyl-3-butenenitrile
EP0101450A4 (fr) * 1982-02-17 1984-07-06 Commw Scient Ind Res Org Catalyseurs d'oligomerisation et d'isomerisation d'olefines.
FR2710909B1 (fr) * 1993-10-08 1995-12-15 Rhone Poulenc Chimie Procédé d'isomérisation du méthyl-2 butène-3 nitrile.
CA2177135C (fr) * 1993-11-23 2005-04-26 Wilson Tam Procedes et compositions de catalyseurs pour hydrocyanuration de mono-olefines
BR9507460A (pt) 1994-04-14 1997-09-02 Du Pont Processo para hidrocianação e composição de precursor de catalisador
TW315370B (fr) * 1994-10-07 1997-09-11 Du Pont
US5512696A (en) * 1995-07-21 1996-04-30 E. I. Du Pont De Nemours And Company Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
US5440067A (en) * 1994-11-18 1995-08-08 E. I. Dupont De Nemours And Company Catalyzed gas phase isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
US5821378A (en) * 1995-01-27 1998-10-13 E. I. Du Pont De Nemours And Company Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
IN187044B (fr) * 1995-01-27 2002-01-05 Du Pont
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854892B1 (fr) 2003-05-12 2005-06-24 Rhodia Polyamide Intermediates Procede de fabrication de dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
DE102004004684A1 (de) * 2004-01-29 2005-08-18 Basf Ag Verfahren zur Hydrocyanierung
WO2007109005A2 (fr) 2006-03-17 2007-09-27 Invista Technologies S.A R.L. Procédé pour purifier des triorganophosphites grâce au traitement à l'aide d'un adjuvant basique
US7709674B2 (en) 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
ES2542430T3 (es) 2010-07-07 2015-08-05 Invista Technologies S.À.R.L. Proceso para hacer nitrilos
JP2014530221A (ja) 2011-10-07 2014-11-17 インヴィスタテクノロジーズ エスアエルエル ニトリルの作製方法
US10759741B2 (en) 2013-07-17 2020-09-01 Invista North America S.A R.L. Separating a solvent from a nickel catalyst by distillation

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3536748A (en) * 1965-11-23 1970-10-27 Du Pont Catalytic isomerization of 2-methyl-3-butenenitrile to linear pentenenitriles
US3526654A (en) * 1968-05-17 1970-09-01 Du Pont Isomerization of 2-pentenenitrile to 3-pentenenitrile
NL7002580A (fr) * 1969-03-03 1970-09-07
NL7017965A (fr) * 1969-12-17 1971-06-21
US3676481A (en) * 1970-06-29 1972-07-11 Du Pont Catalytic isomerization of 2-methyl-3-butenenitrile to linear pentenenitriles in the presence of certain metal salt and/or tri(hydrocarbyl)boron promoters
US3852328A (en) * 1973-09-26 1974-12-03 Du Pont Catalytic isomerization of 2-methyl-3-butenenitrile to a linear pentenenitrile

Also Published As

Publication number Publication date
BE820586A (fr) 1975-04-01
NL7412971A (nl) 1975-04-04
NL185342C (nl) 1990-03-16
US3852329A (en) 1974-12-03
JPS5821911B2 (ja) 1983-05-04
DE2446854A1 (de) 1975-04-10
DE2446854C2 (de) 1985-06-20
FR2246540A1 (fr) 1975-05-02
FR2246540B1 (fr) 1978-11-24
JPS5059327A (fr) 1975-05-22
IT1022539B (it) 1978-04-20
NL185342B (nl) 1989-10-16
GB1432926A (en) 1976-04-22

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