CA1042020A - Combustion catalytique a basse temperature sur lit fluidise d'hydrocarbures chlores effluents - Google Patents

Combustion catalytique a basse temperature sur lit fluidise d'hydrocarbures chlores effluents

Info

Publication number: CA1042020A
Authority: CA; Canada
Prior art keywords: ethylene; catalyst; range; weight; chlorinated
Prior art date: 1974-07-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA226,042A

Other languages

English (en)

Other versions

CA226042S (fr

Inventor

Ronald M. Kovach

Henry J. Essig

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Goodrich Corp

Original Assignee

BF Goodrich Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-07-22

Filing date

1975-05-01

Publication date

1978-11-07

1975-05-01 Application filed by BF Goodrich Corp filed Critical BF Goodrich Corp

1978-11-07 Application granted granted Critical

1978-11-07 Publication of CA1042020A publication Critical patent/CA1042020A/fr

Status Expired legal-status Critical Current

Links

239000002699 waste material Substances 0.000 title abstract description 28
239000012530 fluid Substances 0.000 title abstract description 11
238000007084 catalytic combustion reaction Methods 0.000 title abstract description 7
239000003054 catalyst Substances 0.000 claims abstract description 46
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 31
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 25
229910000041 hydrogen chloride Inorganic materials 0.000 claims abstract description 25
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims abstract description 25
239000000460 chlorine Substances 0.000 claims abstract description 23
229910052801 chlorine Inorganic materials 0.000 claims abstract description 23
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 22
238000002485 combustion reaction Methods 0.000 claims abstract description 21
239000006227 byproduct Substances 0.000 claims abstract description 20
239000000377 silicon dioxide Substances 0.000 claims abstract description 20
239000000463 material Substances 0.000 claims abstract description 18
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 14
229910052681 coesite Inorganic materials 0.000 claims abstract description 11
229910052906 cristobalite Inorganic materials 0.000 claims abstract description 11
235000012239 silicon dioxide Nutrition 0.000 claims abstract description 11
229910052682 stishovite Inorganic materials 0.000 claims abstract description 11
229910052905 tridymite Inorganic materials 0.000 claims abstract description 11
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 7
229910052593 corundum Inorganic materials 0.000 claims abstract description 6
239000000203 mixture Substances 0.000 claims abstract description 6
229910001845 yogo sapphire Inorganic materials 0.000 claims abstract description 6
238000000034 method Methods 0.000 claims description 52
230000008569 process Effects 0.000 claims description 46
239000005977 Ethylene Substances 0.000 claims description 15
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 14
239000000567 combustion gas Substances 0.000 claims description 13
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
229910052760 oxygen Inorganic materials 0.000 claims description 11
239000001301 oxygen Substances 0.000 claims description 11
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical group ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 10
238000005660 chlorination reaction Methods 0.000 claims description 4
238000004064 recycling Methods 0.000 claims 1
238000006243 chemical reaction Methods 0.000 abstract description 13
239000007789 gas Substances 0.000 abstract description 11
238000004519 manufacturing process Methods 0.000 abstract description 7
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
229910001868 water Inorganic materials 0.000 abstract description 4
229910002090 carbon oxide Inorganic materials 0.000 abstract description 3
150000001875 compounds Chemical class 0.000 abstract description 2
229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
239000012433 hydrogen halide Substances 0.000 abstract 1
229940060038 chlorine Drugs 0.000 description 20
235000017168 chlorine Nutrition 0.000 description 19
230000003197 catalytic effect Effects 0.000 description 9
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
229910052799 carbon Inorganic materials 0.000 description 7
239000000047 product Substances 0.000 description 7
230000015572 biosynthetic process Effects 0.000 description 6
238000003786 synthesis reaction Methods 0.000 description 6
-1 ethyl- - Chemical class 0.000 description 5
239000002245 particle Substances 0.000 description 5
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
239000002904 solvent Substances 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
229910002092 carbon dioxide Inorganic materials 0.000 description 3
238000005336 cracking Methods 0.000 description 3
238000005243 fluidization Methods 0.000 description 3
239000011261 inert gas Substances 0.000 description 3
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
235000013980 iron oxide Nutrition 0.000 description 3
VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 3
238000011084 recovery Methods 0.000 description 3
QVLAWKAXOMEXPM-UHFFFAOYSA-N 1,1,1,2-tetrachloroethane Chemical class ClCC(Cl)(Cl)Cl QVLAWKAXOMEXPM-UHFFFAOYSA-N 0.000 description 2
UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical class CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 2
SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
RWNKSTSCBHKHTB-UHFFFAOYSA-N Hexachloro-1,3-butadiene Chemical compound ClC(Cl)=C(Cl)C(Cl)=C(Cl)Cl RWNKSTSCBHKHTB-UHFFFAOYSA-N 0.000 description 2
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 2
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical class ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
238000007792 addition Methods 0.000 description 2
230000002411 adverse Effects 0.000 description 2
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
229960003750 ethyl chloride Drugs 0.000 description 2
230000035611 feeding Effects 0.000 description 2
239000000446 fuel Substances 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000012535 impurity Substances 0.000 description 2
NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical class Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical class CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
238000001311 chemical methods and process Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
HRYZWHHZPQKTII-ZDOIIHCHSA-N chloroethane Chemical class [13CH3][13CH2]Cl HRYZWHHZPQKTII-ZDOIIHCHSA-N 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000007033 dehydrochlorination reaction Methods 0.000 description 1
238000013461 design Methods 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
OYFJQPXVCSSHAI-QFPUQLAESA-N enalapril maleate Chemical compound OC(=O)\C=C/C(O)=O.C([C@@H](C(=O)OCC)N[C@@H](C)C(=O)N1[C@@H](CCC1)C(O)=O)CC1=CC=CC=C1 OYFJQPXVCSSHAI-QFPUQLAESA-N 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
230000009931 harmful effect Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical class ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
238000007038 hydrochlorination reaction Methods 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
239000002440 industrial waste Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000010808 liquid waste Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910001510 metal chloride Inorganic materials 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000000178 monomer Substances 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000008707 rearrangement Effects 0.000 description 1
238000007670 refining Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229910052814 silicon oxide Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
238000004448 titration Methods 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
238000009834 vaporization Methods 0.000 description 1
230000008016 vaporization Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/395—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to a chemical modification of at least one compound

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
General Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Exhaust Gas Treatment By Means Of Catalyst (AREA)
Catalysts (AREA)

CA226,042A 1974-07-22 1975-05-01 Combustion catalytique a basse temperature sur lit fluidise d'hydrocarbures chlores effluents Expired CA1042020A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US49079474A	1974-07-22	1974-07-22

Publications (1)

Publication Number	Publication Date
CA1042020A true CA1042020A (fr)	1978-11-07

Family

ID=23949500

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA226,042A Expired CA1042020A (fr)	1974-07-22	1975-05-01	Combustion catalytique a basse temperature sur lit fluidise d'hydrocarbures chlores effluents

Country Status (10)

Country	Link
JP (1)	JPS6012326B2 (fr)
BE (1)	BE831590A (fr)
CA (1)	CA1042020A (fr)
DE (1)	DE2532075A1 (fr)
ES (1)	ES439003A1 (fr)
FR (1)	FR2279701A1 (fr)
GB (1)	GB1505869A (fr)
IT (1)	IT1036389B (fr)
NL (1)	NL7506866A (fr)
SE (1)	SE425309B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1120956A (fr) *	1977-09-07	1982-03-30	William Q. Beard, Jr.	Procede de fabrication du perchloroethylene par oxychloration catalytique
JPS5962515U (ja) *	1982-10-19	1984-04-24	株式会社中嶋製作所	養鶏用体重測定器

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3453073A (en) *	1967-03-31	1969-07-01	Air Reduction	Hydrogen chloride recovery process
GB1430568A (en) *	1973-05-14	1976-03-31	Mitsubihsi Chemical Ind Ltd	Method of decomposing halohydrocarbons

1975
- 1975-05-01 CA CA226,042A patent/CA1042020A/fr not_active Expired
- 1975-05-23 GB GB22477/75A patent/GB1505869A/en not_active Expired
- 1975-06-10 NL NL7506866A patent/NL7506866A/xx not_active Application Discontinuation
- 1975-06-11 JP JP50069780A patent/JPS6012326B2/ja not_active Expired
- 1975-06-27 IT IT68661/75A patent/IT1036389B/it active
- 1975-06-30 ES ES439003A patent/ES439003A1/es not_active Expired
- 1975-07-01 FR FR7520641A patent/FR2279701A1/fr active Granted
- 1975-07-17 DE DE19752532075 patent/DE2532075A1/de not_active Withdrawn
- 1975-07-21 SE SE7508289A patent/SE425309B/xx unknown
- 1975-07-22 BE BE158483A patent/BE831590A/fr not_active IP Right Cessation

Also Published As

Publication number	Publication date
JPS5113708A (en)	1976-02-03
GB1505869A (en)	1978-03-30
DE2532075A1 (de)	1976-02-05
NL7506866A (nl)	1976-01-26
AU8080575A (en)	1976-11-11
JPS6012326B2 (ja)	1985-04-01
ES439003A1 (es)	1977-02-16
BE831590A (fr)	1975-11-17
IT1036389B (it)	1979-10-30
SE425309B (sv)	1982-09-20
SE7508289L (sv)	1976-01-23
FR2279701B1 (fr)	1980-05-30
FR2279701A1 (fr)	1976-02-20

Publication	Publication Date	Title
US4169862A (en)	1979-10-02	Low temperature catalytic combustion of chlorohydrocarbons
AU738446B2 (en)	2001-09-20	Production of one or more useful products from lesser value halogenated materials
US5292703A (en)	1994-03-08	Catalyst and process for oxychlorination of ethylene to EDC
US3496242A (en)	1970-02-17	Oxychlorination of mixed hydrocarbons
US4435379A (en)	1984-03-06	Process for treating chlorinated hydrocarbons
US3453073A (en)	1969-07-01	Hydrogen chloride recovery process
CA1039316A (fr)	1978-09-26	Combustion catalytique a basse temperature d'hydrocarbure chlores
JP3001976B2 (ja)	2000-01-24	オキシクロリネーション方法
CA1052826A (fr)	1979-04-17	Combustion a basse temperature, sur lit fluidifie, d'un ecoulement d'hydrocarbures chlores de rebut
US3907912A (en)	1975-09-23	Fluid bed oxychlorination of ethylene
US3527819A (en)	1970-09-08	Oxychlorination process for preparing trichloroethylene and tetrachloroethylene
US4485081A (en)	1984-11-27	Hydrogen chloride recovery process
US3345422A (en)	1967-10-03	Control of oxychlorination reactions
CA1047540A (fr)	1979-01-30	Procede pour la fabrication de derives chlores de l'ethylene, base sur la combustion catalytique de sous-produits de rebut
CA1042924A (fr)	1978-11-21	Combustion catalytique a basse temperature d'hydrocarbures chlores
US5763710A (en)	1998-06-09	Oxychlorination process
JPS6012326B2 (ja)	1985-04-01	エチレンの塩素化誘導体の製造方法
US3295921A (en)	1967-01-03	Production of halides
SU424345A3 (ru)	1974-04-15	Способ получения трихлорэтилена
US4436673A (en)	1984-03-13	Fluid bed process for preparing phenylphosphonous dichloride
US3444252A (en)	1969-05-13	Manufacture of chlorinated hydrocarbons
CA1210923A (fr)	1986-09-09	Traitement des hydrocarbures chlores
NO752592L (fr)	1976-01-23
CA1154463A (fr)	1983-09-27	Reacteur et methode d'oxychloration de l'ethylene
GB865939A (en)	1961-04-26	Process for the production of chlorides from oxides