CA1052826A - Combustion a basse temperature, sur lit fluidifie, d'un ecoulement d'hydrocarbures chlores de rebut - Google Patents

Combustion a basse temperature, sur lit fluidifie, d'un ecoulement d'hydrocarbures chlores de rebut

Info

Publication number: CA1052826A
Authority: CA; Canada
Prior art keywords: ethylene; range; chlorinated; stream; fluid bed
Prior art date: 1975-02-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA227,653A

Other languages

English (en)

Other versions

CA227653S (en

Inventor

Henry J. Essig

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Goodrich Corp

Original Assignee

BF Goodrich Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-02-19

Filing date

1975-05-23

Publication date

1979-04-17

1975-05-23 Application filed by BF Goodrich Corp filed Critical BF Goodrich Corp

1979-04-17 Application granted granted Critical

1979-04-17 Publication of CA1052826A publication Critical patent/CA1052826A/fr

Status Expired legal-status Critical Current

Links

239000002699 waste material Substances 0.000 title abstract description 26
239000012530 fluid Substances 0.000 title abstract description 12
238000007084 catalytic combustion reaction Methods 0.000 title abstract description 8
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 36
239000003054 catalyst Substances 0.000 claims abstract description 35
239000000460 chlorine Substances 0.000 claims abstract description 22
229910052801 chlorine Inorganic materials 0.000 claims abstract description 22
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 21
239000006227 byproduct Substances 0.000 claims abstract description 20
238000002485 combustion reaction Methods 0.000 claims abstract description 20
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 19
229910000041 hydrogen chloride Inorganic materials 0.000 claims abstract description 19
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims abstract description 19
239000000463 material Substances 0.000 claims abstract description 18
239000000377 silicon dioxide Substances 0.000 claims abstract description 17
239000007789 gas Substances 0.000 claims abstract description 12
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 11
239000000203 mixture Substances 0.000 claims abstract description 8
238000000034 method Methods 0.000 claims description 51
230000008569 process Effects 0.000 claims description 48
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 21
239000005977 Ethylene Substances 0.000 claims description 18
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical group ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 13
239000001301 oxygen Substances 0.000 claims description 13
229910052760 oxygen Inorganic materials 0.000 claims description 13
239000000567 combustion gas Substances 0.000 claims description 12
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
229910052799 carbon Inorganic materials 0.000 claims description 8
239000002245 particle Substances 0.000 claims description 6
238000012935 Averaging Methods 0.000 claims description 2
239000011148 porous material Substances 0.000 claims description 2
208000036366 Sensation of pressure Diseases 0.000 claims 5
238000004064 recycling Methods 0.000 claims 2
238000006243 chemical reaction Methods 0.000 abstract description 10
238000004519 manufacturing process Methods 0.000 abstract description 7
229910052681 coesite Inorganic materials 0.000 abstract description 4
229910052906 cristobalite Inorganic materials 0.000 abstract description 4
229910052682 stishovite Inorganic materials 0.000 abstract description 4
229910052905 tridymite Inorganic materials 0.000 abstract description 4
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 3
229910002090 carbon oxide Inorganic materials 0.000 abstract description 3
235000012239 silicon dioxide Nutrition 0.000 abstract description 3
150000001875 compounds Chemical class 0.000 abstract description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
229910001868 water Inorganic materials 0.000 abstract description 2
229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
239000012433 hydrogen halide Substances 0.000 abstract 1
229940060038 chlorine Drugs 0.000 description 18
235000017168 chlorine Nutrition 0.000 description 17
229940093470 ethylene Drugs 0.000 description 15
230000003197 catalytic effect Effects 0.000 description 9
230000015572 biosynthetic process Effects 0.000 description 6
239000000047 product Substances 0.000 description 6
238000003786 synthesis reaction Methods 0.000 description 6
238000005336 cracking Methods 0.000 description 4
239000002904 solvent Substances 0.000 description 4
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 3
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical class ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 3
238000005660 chlorination reaction Methods 0.000 description 3
238000005243 fluidization Methods 0.000 description 3
239000011261 inert gas Substances 0.000 description 3
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
235000013980 iron oxide Nutrition 0.000 description 3
VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 3
229950011008 tetrachloroethylene Drugs 0.000 description 3
QVLAWKAXOMEXPM-UHFFFAOYSA-N 1,1,1,2-tetrachloroethane Chemical class ClCC(Cl)(Cl)Cl QVLAWKAXOMEXPM-UHFFFAOYSA-N 0.000 description 2
UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical class CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 2
SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical class CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
RWNKSTSCBHKHTB-UHFFFAOYSA-N Hexachloro-1,3-butadiene Chemical compound ClC(Cl)=C(Cl)C(Cl)=C(Cl)Cl RWNKSTSCBHKHTB-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
238000007792 addition Methods 0.000 description 2
230000002411 adverse Effects 0.000 description 2
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
229960003750 ethyl chloride Drugs 0.000 description 2
230000035611 feeding Effects 0.000 description 2
239000000446 fuel Substances 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000012535 impurity Substances 0.000 description 2
NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical class Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
238000011084 recovery Methods 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
-1 vinylidene halides Chemical class 0.000 description 2
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
238000001311 chemical methods and process Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
HRYZWHHZPQKTII-ZDOIIHCHSA-N chloroethane Chemical class [13CH3][13CH2]Cl HRYZWHHZPQKTII-ZDOIIHCHSA-N 0.000 description 1
KFUSEUYYWQURPO-UPHRSURJSA-N cis-1,2-dichloroethene Chemical group Cl\C=C/Cl KFUSEUYYWQURPO-UPHRSURJSA-N 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000007033 dehydrochlorination reaction Methods 0.000 description 1
238000013461 design Methods 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
230000009931 harmful effect Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical class ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
239000002440 industrial waste Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000010808 liquid waste Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
230000003340 mental effect Effects 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
229910001510 metal chloride Inorganic materials 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000000178 monomer Substances 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000008707 rearrangement Effects 0.000 description 1
238000007670 refining Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
238000004448 titration Methods 0.000 description 1
KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical group Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 description 1
229960002415 trichloroethylene Drugs 0.000 description 1
UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
238000009834 vaporization Methods 0.000 description 1
230000008016 vaporization Effects 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/395—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to a chemical modification of at least one compound

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
General Chemical & Material Sciences (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CA227,653A 1975-02-19 1975-05-23 Combustion a basse temperature, sur lit fluidifie, d'un ecoulement d'hydrocarbures chlores de rebut Expired CA1052826A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US55112575A	1975-02-19	1975-02-19

Publications (1)

Publication Number	Publication Date
CA1052826A true CA1052826A (fr)	1979-04-17

Family

ID=24199977

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA227,653A Expired CA1052826A (fr)	1975-02-19	1975-05-23	Combustion a basse temperature, sur lit fluidifie, d'un ecoulement d'hydrocarbures chlores de rebut

Country Status (2)

Country	Link
BE (1)	BE831593A (fr)
CA (1)	CA1052826A (fr)

1975
- 1975-05-23 CA CA227,653A patent/CA1052826A/fr not_active Expired
- 1975-07-22 BE BE158486A patent/BE831593A/fr unknown

Also Published As

Publication number	Publication date
BE831593A (fr)	1975-11-17

Publication	Publication Date	Title
US4169862A (en)	1979-10-02	Low temperature catalytic combustion of chlorohydrocarbons
AU2007263778B2 (en)	2012-02-02	Process for the manufacture of 1,2-dichloroethane
AU2007263775B2 (en)	2012-02-02	Process for the manufacture of 1,2-dichloroethane
US5663465A (en)	1997-09-02	By-product recycling in oxychlorination process
US5099084A (en)	1992-03-24	Process for the chlorination of methane
JP2008525379A (ja)	2008-07-17	１，２−ジクロロエタンの製造方法
US3989807A (en)	1976-11-02	Low temperature catalytic oxidation of chlorinated compounds to recover chlorine values using chromium-impregnated supported catalysts
EP0159366A1 (fr)	1985-10-30	Procédé pour transformer des hydrocarbures chlorinés et des oxydes de métaux en oxydes de carbone et en chlorures de métaux
US4230668A (en)	1980-10-28	Process and apparatus for producing halogenated unsaturated hydrocarbons
US4031149A (en)	1977-06-21	Low temperature catalytic combustion of chlorohydrocarbons
US4351819A (en)	1982-09-28	Recovery of chlorine values in integrated process for oxychlorination and combustion of chlorinated hydrocarbons
US3642918A (en)	1972-02-15	Production of perchloroethylene and trichloroethylene utilizing oxychlorination reaction
AU680937B2 (en)	1997-08-14	Oxychlorination process
CA1042020A (fr)	1978-11-07	Combustion catalytique a basse temperature sur lit fluidise d'hydrocarbures chlores effluents
US4485081A (en)	1984-11-27	Hydrogen chloride recovery process
US3557229A (en)	1971-01-19	Oxychlorination of ethane to vinyl chloride
CA1042924A (fr)	1978-11-21	Combustion catalytique a basse temperature d'hydrocarbures chlores
US5705720A (en)	1998-01-06	Continuous process for cracking 1,2-dichloroethane
CA1047540A (fr)	1979-01-30	Procede pour la fabrication de derives chlores de l'ethylene, base sur la combustion catalytique de sous-produits de rebut
US2725412A (en)	1955-11-29	Chlorination of 1, 1-dichloroethane
EP0007064B1 (fr)	1983-01-19	Purification de dichlorure d'éthylène
NO752592L (fr)	1976-01-23
CA1109853A (fr)	1981-09-29	Catalyseur et procede pour la production de vcm
CA1117984A (fr)	1982-02-09	Chloration en phase vapeur du 1,1-dichloroethane
Smolyan et al.	1960	Developments in the chlorination of saturated hydrocarbons