CA1044824A - Determination de la teneur globale en ions - Google Patents
Determination de la teneur globale en ionsInfo
- Publication number
- CA1044824A CA1044824A CA229,430A CA229430A CA1044824A CA 1044824 A CA1044824 A CA 1044824A CA 229430 A CA229430 A CA 229430A CA 1044824 A CA1044824 A CA 1044824A
- Authority
- CA
- Canada
- Prior art keywords
- ion
- exchange resin
- column
- ion exchange
- sample solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005342 ion exchange Methods 0.000 claims abstract description 46
- 239000000523 sample Substances 0.000 claims abstract description 41
- 238000000034 method Methods 0.000 claims abstract description 27
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000012488 sample solution Substances 0.000 claims abstract description 26
- 150000002500 ions Chemical class 0.000 claims abstract description 25
- 150000001450 anions Chemical class 0.000 claims abstract description 20
- 239000003957 anion exchange resin Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 150000001768 cations Chemical group 0.000 claims description 21
- 239000003729 cation exchange resin Substances 0.000 claims description 20
- 239000011347 resin Substances 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 18
- 239000000243 solution Substances 0.000 claims description 16
- 238000002347 injection Methods 0.000 claims description 14
- 239000007924 injection Substances 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 5
- 238000010828 elution Methods 0.000 claims description 5
- 229910001415 sodium ion Inorganic materials 0.000 claims description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical group [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 229910001416 lithium ion Inorganic materials 0.000 claims description 2
- 238000004445 quantitative analysis Methods 0.000 claims description 2
- 239000003456 ion exchange resin Substances 0.000 abstract description 12
- 229920003303 ion-exchange polymer Polymers 0.000 abstract description 12
- 125000002091 cationic group Chemical group 0.000 abstract description 3
- -1 alkali metal cation Chemical class 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000002352 surface water Substances 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000012492 regenerant Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000013375 chromatographic separation Methods 0.000 description 2
- 239000012468 concentrated sample Substances 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229910001414 potassium ion Inorganic materials 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000003109 Karl Fischer titration Methods 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 229940023913 cation exchange resins Drugs 0.000 description 1
- 230000005465 channeling Effects 0.000 description 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Treatment Of Liquids With Adsorbents In General (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA229,430A CA1044824A (fr) | 1975-06-16 | 1975-06-16 | Determination de la teneur globale en ions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA229,430A CA1044824A (fr) | 1975-06-16 | 1975-06-16 | Determination de la teneur globale en ions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1044824A true CA1044824A (fr) | 1978-12-19 |
Family
ID=4103355
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA229,430A Expired CA1044824A (fr) | 1975-06-16 | 1975-06-16 | Determination de la teneur globale en ions |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1044824A (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108490036A (zh) * | 2018-03-14 | 2018-09-04 | 上海外高桥造船有限公司 | 一种水中盐分的测定方法 |
-
1975
- 1975-06-16 CA CA229,430A patent/CA1044824A/fr not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108490036A (zh) * | 2018-03-14 | 2018-09-04 | 上海外高桥造船有限公司 | 一种水中盐分的测定方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3925019A (en) | Chromatographic analysis of ionic species | |
| US3920397A (en) | Apparatus and method for quantitative analysis of ionic species by liquid column chromatography | |
| US3926559A (en) | Method and apparatus for quantitative chromatographic analysis of cationic species | |
| CA1042988A (fr) | Chromatographe a ion double par colonnes paralleles | |
| US3897213A (en) | Automated quantitative analysis of ionic species | |
| Longbottom et al. | Gas chromatographic determination of methyl mercury in fish, sediment, and water | |
| US5175110A (en) | Analysis of ions present at low concentrations in solutions containing other ions | |
| JPS62223668A (ja) | イオンクロマトグラフイ方法および装置 | |
| US4849110A (en) | Method and apparatus for liquid chromatography | |
| US3918906A (en) | Determining total ionic content | |
| US20030037589A1 (en) | Method of calibration using analytical apparatus for measurement of low concentration constituent | |
| US4672042A (en) | Method of and apparatus for chromatographic analysis | |
| Fairman et al. | Flow injection-mini-column technique with ICP-AES detection for the isolation and preconcentration of the fast reactive aluminium fraction in waters | |
| US3915642A (en) | Quantitative analysis of single ion species | |
| CA1044824A (fr) | Determination de la teneur globale en ions | |
| US4732686A (en) | Weak eluant ion chromatography | |
| US3920398A (en) | Method for chromatographic analysis of organic acids or their carboxylate salts | |
| Hemmings et al. | The speciation of arsenic (V) and arsenic (III), by ion-exclusion chromatography, in solutions containing iron and sulphuric acid | |
| RU2184382C1 (ru) | Способ определения стронция-90 в твердых образцах | |
| JPS6353509B2 (fr) | ||
| Böhme et al. | Trace analysis of bromate and bromide with ion chromatography on coated reversed phase materials | |
| Barnard et al. | The Interaction of Hair Fibers with Alkali Bromide Solutions | |
| CA1038510A (fr) | Analyse quantitative, automatique des especes ioniques | |
| US4396718A (en) | Field test method for estimation of concentration of organic materials in water | |
| Routson et al. | A Column Cation-Exchange-Capacity Procedure for Low-Exchange-Capacity Sands |