CA1045832A - Extraction et separation des metaux par un liquide echangeur de cations - Google Patents

Extraction et separation des metaux par un liquide echangeur de cations

Info

Publication number: CA1045832A
Authority: CA; Canada
Prior art keywords: zinc; iron; metal; organic; aqueous
Prior art date: 1974-05-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA294,634A

Other languages

English (en)

Inventor

Gunnar Thorsen

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-05-30

Filing date

1978-01-10

Publication date

1979-01-09

1978-01-10 Application filed by Individual filed Critical Individual

1979-01-09 Application granted granted Critical

1979-01-09 Publication of CA1045832A publication Critical patent/CA1045832A/fr

Status Expired legal-status Critical Current

Links

229910052751 metal Inorganic materials 0.000 title claims abstract description 111
239000002184 metal Substances 0.000 title claims abstract description 111
238000000034 method Methods 0.000 title claims abstract description 73
230000008569 process Effects 0.000 title claims abstract description 68
150000002739 metals Chemical class 0.000 title claims abstract description 47
150000001768 cations Chemical class 0.000 title claims abstract description 34
238000000605 extraction Methods 0.000 title claims abstract description 29
238000000926 separation method Methods 0.000 title abstract description 15
239000007788 liquid Substances 0.000 title description 16
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 123
229910052742 iron Inorganic materials 0.000 claims abstract description 59
239000012074 organic phase Substances 0.000 claims abstract description 53
239000000243 solution Substances 0.000 claims abstract description 47
239000002994 raw material Substances 0.000 claims abstract description 36
238000002386 leaching Methods 0.000 claims abstract description 30
239000002253 acid Substances 0.000 claims abstract description 28
239000007864 aqueous solution Substances 0.000 claims abstract description 18
229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 17
239000011707 mineral Substances 0.000 claims abstract description 17
239000007791 liquid phase Substances 0.000 claims abstract description 14
150000001735 carboxylic acids Chemical class 0.000 claims abstract description 9
239000012266 salt solution Substances 0.000 claims abstract description 8
239000000463 material Substances 0.000 claims abstract description 7
239000003960 organic solvent Substances 0.000 claims abstract description 7
-1 alkyl phosphoric acids Chemical class 0.000 claims abstract description 4
235000011007 phosphoric acid Nutrition 0.000 claims abstract description 4
239000011701 zinc Substances 0.000 claims description 70
229910052725 zinc Inorganic materials 0.000 claims description 62
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 60
239000010949 copper Substances 0.000 claims description 18
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 16
229910052802 copper Inorganic materials 0.000 claims description 16
235000010755 mineral Nutrition 0.000 claims description 16
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 15
239000011686 zinc sulphate Substances 0.000 claims description 15
235000009529 zinc sulphate Nutrition 0.000 claims description 15
239000007787 solid Substances 0.000 claims description 13
238000004519 manufacturing process Methods 0.000 claims description 12
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 11
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 11
229910021653 sulphate ion Inorganic materials 0.000 claims description 11
239000001117 sulphuric acid Substances 0.000 claims description 11
235000011149 sulphuric acid Nutrition 0.000 claims description 11
239000000203 mixture Substances 0.000 claims description 9
150000003839 salts Chemical class 0.000 claims description 9
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 8
239000012141 concentrate Substances 0.000 claims description 8
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 7
235000014692 zinc oxide Nutrition 0.000 claims description 7
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 6
229910044991 metal oxide Inorganic materials 0.000 claims description 6
150000004706 metal oxides Chemical class 0.000 claims description 6
238000005868 electrolysis reaction Methods 0.000 claims description 5
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
239000004291 sulphur dioxide Substances 0.000 claims description 4
235000010269 sulphur dioxide Nutrition 0.000 claims description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 3
229910017052 cobalt Inorganic materials 0.000 claims description 3
239000010941 cobalt Substances 0.000 claims description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 3
229910000041 hydrogen chloride Inorganic materials 0.000 claims description 3
239000010814 metallic waste Substances 0.000 claims description 3
229910052759 nickel Inorganic materials 0.000 claims description 3
238000000746 purification Methods 0.000 claims description 3
239000001569 carbon dioxide Substances 0.000 claims description 2
229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
239000002699 waste material Substances 0.000 claims description 2
150000003751 zinc Chemical class 0.000 claims description 2
239000005083 Zinc sulfide Substances 0.000 claims 2
239000007789 gas Substances 0.000 claims 2
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
241000283986 Lepus Species 0.000 claims 1
229910052799 carbon Inorganic materials 0.000 claims 1
BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 claims 1
239000008151 electrolyte solution Substances 0.000 claims 1
229940021013 electrolyte solution Drugs 0.000 claims 1
150000002505 iron Chemical class 0.000 claims 1
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims 1
235000013980 iron oxide Nutrition 0.000 claims 1
VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims 1
239000008346 aqueous phase Substances 0.000 abstract description 20
238000000622 liquid--liquid extraction Methods 0.000 abstract description 16
238000000638 solvent extraction Methods 0.000 abstract description 16
239000003513 alkali Substances 0.000 abstract description 6
229910021645 metal ion Inorganic materials 0.000 description 13
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 12
150000004696 coordination complex Chemical class 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
238000011084 recovery Methods 0.000 description 7
150000002892 organic cations Chemical class 0.000 description 6
238000003756 stirring Methods 0.000 description 6
239000011787 zinc oxide Substances 0.000 description 6
238000000151 deposition Methods 0.000 description 5
229910052935 jarosite Inorganic materials 0.000 description 5
150000007524 organic acids Chemical class 0.000 description 5
239000000047 product Substances 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 4
125000002091 cationic group Chemical group 0.000 description 4
230000008021 deposition Effects 0.000 description 4
238000005755 formation reaction Methods 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
239000005569 Iron sulphate Substances 0.000 description 3
150000003818 basic metals Chemical class 0.000 description 3
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 3
125000002524 organometallic group Chemical group 0.000 description 3
239000012071 phase Substances 0.000 description 3
238000005554 pickling Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
235000008733 Citrus aurantifolia Nutrition 0.000 description 2
235000011941 Tilia x europaea Nutrition 0.000 description 2
229910052728 basic metal Inorganic materials 0.000 description 2
238000010586 diagram Methods 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
229910052602 gypsum Inorganic materials 0.000 description 2
239000010440 gypsum Substances 0.000 description 2
239000004571 lime Substances 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
230000000135 prohibitive effect Effects 0.000 description 2
239000011343 solid material Substances 0.000 description 2
239000007790 solid phase Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
238000010306 acid treatment Methods 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
230000009918 complex formation Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000012065 filter cake Substances 0.000 description 1
239000007792 gaseous phase Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
125000005608 naphthenic acid group Chemical group 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
229960004838 phosphoric acid Drugs 0.000 description 1
NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
229910052683 pyrite Inorganic materials 0.000 description 1
239000011028 pyrite Substances 0.000 description 1
238000007670 refining Methods 0.000 description 1
239000013049 sediment Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
238000004381 surface treatment Methods 0.000 description 1
230000007704 transition Effects 0.000 description 1
SYOKIDBDQMKNDQ-XWTIBIIYSA-N vildagliptin Chemical compound C1C(O)(C2)CC(C3)CC1CC32NCC(=O)N1CCC[C@H]1C#N SYOKIDBDQMKNDQ-XWTIBIIYSA-N 0.000 description 1
239000002351 wastewater Substances 0.000 description 1
UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
229940007718 zinc hydroxide Drugs 0.000 description 1
229910021511 zinc hydroxide Inorganic materials 0.000 description 1
229910000859 α-Fe Inorganic materials 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling

Landscapes

Manufacture And Refinement Of Metals (AREA)
Electrolytic Production Of Metals (AREA)

CA294,634A 1974-05-30 1978-01-10 Extraction et separation des metaux par un liquide echangeur de cations Expired CA1045832A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA201,300A CA1040436A (fr)	1974-05-30	1974-05-30	Methode d'extraction et de separation de metaux a l'aide d'echangeurs de cations liquides

Publications (1)

Publication Number	Publication Date
CA1045832A true CA1045832A (fr)	1979-01-09

Family

ID=4100249

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
CA201,300A Expired CA1040436A (fr)	1974-05-30	1974-05-30	Methode d'extraction et de separation de metaux a l'aide d'echangeurs de cations liquides
CA294,634A Expired CA1045832A (fr)	1974-05-30	1978-01-10	Extraction et separation des metaux par un liquide echangeur de cations

Family Applications Before (1)

Application Number	Title	Priority Date	Filing Date
CA201,300A Expired CA1040436A (fr)	1974-05-30	1974-05-30	Methode d'extraction et de separation de metaux a l'aide d'echangeurs de cations liquides

Country Status (1)

Country	Link
CA (2)	CA1040436A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN116219172B (zh) *	2023-02-16	2026-02-17	武汉工程大学	一种生物吸附破络协同回收冶金污泥中铜的方法

1974
- 1974-05-30 CA CA201,300A patent/CA1040436A/fr not_active Expired
1978
- 1978-01-10 CA CA294,634A patent/CA1045832A/fr not_active Expired

Also Published As

Publication number	Publication date
CA1040436A (fr)	1978-10-17

Publication	Publication Date	Title
US4288304A (en)	1981-09-08	Hydrometallurgical process for treatment of sulphur ores
CA2912332C (fr)	2017-12-05	Procede de recuperation de metaux
CA1119817A (fr)	1982-03-16	Methode de separation du cuivre metallique
US5078786A (en)	1992-01-07	Process for recovering metal values from jarosite solids
JPH04501584A (ja)	1992-03-19	有価金属の電解溶液から不純物元素を除去する方法
US3251646A (en)	1966-05-17	Process for the recovery or purification of metals by liquid-liquid extraction
US4023964A (en)	1977-05-17	Method of obtaining copper from copper-bearing ores
US4162294A (en)	1979-07-24	Process for working up nonferrous metal hydroxide sludge waste
Amer et al.	1995	The recovery of zinc from the leach liquors of the CENIM-LNETI process by solvent extraction with di (-2-ethylhexyl) phosphoric acid
US4008134A (en)	1977-02-15	Extraction and separation of metals from solids using liquid cation exchangers
KR20240019147A (ko)	2024-02-14	고순도 니켈 및 코발트 화합물 생산
US4220627A (en)	1980-09-02	Process for the treatment of raw materials containing arsenic and metal
EP1805335B1 (fr)	2014-11-05	Procede de preparation d'une solution contenant un agent d'extraction organique charge de nickel
JPS5929092B2 (ja)	1984-07-18	水溶液から亜鉛および銅を分離する方法
US3923976A (en)	1975-12-02	Process for recovery of zinc from solutions that contain it as a result of extraction with solvents for their adaptation to electrolysis
US3869360A (en)	1975-03-04	Reduction method for separating metal values from ocean floor nodule ore
US4778520A (en)	1988-10-18	Process for leaching zinc from partially desulfurized zinc concentrates by sulfuric acid
DE1952751B2 (de)	1971-04-08	Verfahren zur hydrometallurgischen verhuettung von schwefel haltigen nickelkonzentraten
US4200504A (en)	1980-04-29	Extraction and separation of metals from solids using liquid cation exchangers
US3870060A (en)	1975-03-11	Method of removing monovalent inorganic acids from an aqueous solution containing metal salts of the acids
CA1045832A (fr)	1979-01-09	Extraction et separation des metaux par un liquide echangeur de cations
Van der Zeeuw	1977	Purification of zinc calcine leach solutions by exchange extraction with the zinc salt of “versatic” acid
AU631902B2 (en)	1992-12-10	Method for the recovery of zinc, copper and lead of oxidized and/or sulfurized ores and materials
EP4623117A1 (fr)	2025-10-01	Procédé d'extraction de manganèse
US4173520A (en)	1979-11-06	Hydrometallurgical method for treating nickel mattes