CA1048689A - Copolyesters retardant la propagation de la flamme - Google Patents

Copolyesters retardant la propagation de la flamme

Info

Publication number: CA1048689A
Authority: CA; Canada
Prior art keywords: composition; weight; polycondensation; esterification; percent
Prior art date: 1973-12-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA74214473A

Other languages

English (en)

Other versions

CA214473S (en

Inventor

Douglas D. Callander

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Goodyear Tire and Rubber Co

Original Assignee

Goodyear Tire and Rubber Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-12-21

Filing date

1974-11-22

Publication date

1979-02-13

1974-11-22 Application filed by Goodyear Tire and Rubber Co filed Critical Goodyear Tire and Rubber Co

1979-02-13 Application granted granted Critical

1979-02-13 Publication of CA1048689A publication Critical patent/CA1048689A/fr

Status Expired legal-status Critical Current

Links

229920001634 Copolyester Polymers 0.000 title claims abstract description 50
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 19
239000003063 flame retardant Substances 0.000 title claims description 19
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 50
238000006068 polycondensation reaction Methods 0.000 claims abstract description 44
239000000203 mixture Substances 0.000 claims abstract description 31
-1 diol compound Chemical class 0.000 claims abstract description 28
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 26
238000000034 method Methods 0.000 claims abstract description 26
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 13
239000001294 propane Substances 0.000 claims abstract description 13
125000005907 alkyl ester group Chemical group 0.000 claims abstract description 12
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 12
150000002009 diols Chemical class 0.000 claims description 31
239000000463 material Substances 0.000 claims description 21
238000005809 transesterification reaction Methods 0.000 claims description 18
230000002195 synergetic effect Effects 0.000 claims description 16
238000005886 esterification reaction Methods 0.000 claims description 14
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 13
230000032050 esterification Effects 0.000 claims description 13
WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 claims description 10
230000004048 modification Effects 0.000 claims description 9
238000012986 modification Methods 0.000 claims description 9
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 8
229910052787 antimony Inorganic materials 0.000 claims description 8
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 8
239000000460 chlorine Substances 0.000 claims description 7
229910052801 chlorine Inorganic materials 0.000 claims description 7
150000001463 antimony compounds Chemical class 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
125000001246 bromo group Chemical group Br* 0.000 claims description 4
150000003606 tin compounds Chemical class 0.000 claims description 4
229910052725 zinc Inorganic materials 0.000 claims description 4
239000011701 zinc Substances 0.000 claims description 4
229910052783 alkali metal Inorganic materials 0.000 claims description 3
150000003254 radicals Chemical class 0.000 claims 4
239000004744 fabric Substances 0.000 description 13
239000002253 acid Substances 0.000 description 10
125000005843 halogen group Chemical group 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 8
229920000642 polymer Polymers 0.000 description 8
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 7
150000002334 glycols Chemical class 0.000 description 7
229920000728 polyester Polymers 0.000 description 7
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
150000001991 dicarboxylic acids Chemical class 0.000 description 6
239000001301 oxygen Substances 0.000 description 6
229910052760 oxygen Inorganic materials 0.000 description 6
229910052736 halogen Inorganic materials 0.000 description 5
150000002367 halogens Chemical class 0.000 description 5
230000035484 reaction time Effects 0.000 description 5
239000000126 substance Substances 0.000 description 5
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
239000003054 catalyst Substances 0.000 description 4
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 4
HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 4
229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 3
125000001309 chloro group Chemical group Cl* 0.000 description 3
230000000694 effects Effects 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
229940071125 manganese acetate Drugs 0.000 description 3
UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 3
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
229910052753 mercury Inorganic materials 0.000 description 3
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
238000012360 testing method Methods 0.000 description 3
PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 2
ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
239000003513 alkali Substances 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
239000004305 biphenyl Substances 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
VEIOBOXBGYWJIT-UHFFFAOYSA-N cyclohexane;methanol Chemical compound OC.OC.C1CCCCC1 VEIOBOXBGYWJIT-UHFFFAOYSA-N 0.000 description 2
FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 2
125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
239000000539 dimer Substances 0.000 description 2
239000000835 fiber Substances 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
239000011572 manganese Substances 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
229920000139 polyethylene terephthalate Polymers 0.000 description 2
239000005020 polyethylene terephthalate Substances 0.000 description 2
229920005989 resin Polymers 0.000 description 2
239000011347 resin Substances 0.000 description 2
229920002994 synthetic fiber Polymers 0.000 description 2
239000012209 synthetic fiber Substances 0.000 description 2
239000004753 textile Substances 0.000 description 2
239000011787 zinc oxide Substances 0.000 description 2
QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 1
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
OQFSYHWITGFERZ-UHFFFAOYSA-N 2-bromoethanesulfonic acid Chemical compound OS(=O)(=O)CCBr OQFSYHWITGFERZ-UHFFFAOYSA-N 0.000 description 1
CARJPEPCULYFFP-UHFFFAOYSA-N 5-Sulfo-1,3-benzenedicarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(S(O)(=O)=O)=C1 CARJPEPCULYFFP-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
229910000410 antimony oxide Inorganic materials 0.000 description 1
CZJCMXPZSYNVLP-UHFFFAOYSA-N antimony zinc Chemical compound [Zn].[Sb] CZJCMXPZSYNVLP-UHFFFAOYSA-N 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000002585 base Substances 0.000 description 1
235000010290 biphenyl Nutrition 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
BTVWZWFKMIUSGS-UHFFFAOYSA-N dimethylethyleneglycol Natural products CC(C)(O)CO BTVWZWFKMIUSGS-UHFFFAOYSA-N 0.000 description 1
238000004044 disperse dyeing Methods 0.000 description 1
GTZOYNFRVVHLDZ-UHFFFAOYSA-N dodecane-1,1-diol Chemical compound CCCCCCCCCCCC(O)O GTZOYNFRVVHLDZ-UHFFFAOYSA-N 0.000 description 1
238000004043 dyeing Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
239000011521 glass Substances 0.000 description 1
XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
229940045996 isethionic acid Drugs 0.000 description 1
229940046892 lead acetate Drugs 0.000 description 1
HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 1
YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
238000000465 moulding Methods 0.000 description 1
WPUMVKJOWWJPRK-UHFFFAOYSA-N naphthalene-2,7-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=CC2=CC(C(=O)O)=CC=C21 WPUMVKJOWWJPRK-UHFFFAOYSA-N 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
238000010525 oxidative degradation reaction Methods 0.000 description 1
VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
150000002926 oxygen Chemical class 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920001515 polyalkylene glycol Polymers 0.000 description 1
229920001225 polyester resin Polymers 0.000 description 1
239000004645 polyester resin Substances 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920005594 polymer fiber Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
BKIKRRUKWYJTEU-UHFFFAOYSA-N propane terephthalic acid Chemical compound CCC.OC(=O)c1ccc(cc1)C(O)=O BKIKRRUKWYJTEU-UHFFFAOYSA-N 0.000 description 1
230000000630 rising effect Effects 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000009987 spinning Methods 0.000 description 1
238000004381 surface treatment Methods 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
239000004246 zinc acetate Substances 0.000 description 1
150000003752 zinc compounds Chemical class 0.000 description 1

Landscapes

Polyesters Or Polycarbonates (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA74214473A 1973-12-21 1974-11-22 Copolyesters retardant la propagation de la flamme Expired CA1048689A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US42719173A	1973-12-21	1973-12-21

Publications (1)

Publication Number	Publication Date
CA1048689A true CA1048689A (fr)	1979-02-13

Family

ID=23693845

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA74214473A Expired CA1048689A (fr)	1973-12-21	1974-11-22	Copolyesters retardant la propagation de la flamme

Country Status (6)

Country	Link
AR (1)	AR205913A1 (fr)
AU (1)	AU6749974A (fr)
BR (1)	BR7410605D0 (fr)
CA (1)	CA1048689A (fr)
FI (1)	FI367074A7 (fr)
IN (1)	IN140895B (fr)

1974
- 1974-01-01 AR AR25692874A patent/AR205913A1/es active
- 1974-04-03 AU AU67499/74A patent/AU6749974A/en not_active Expired
- 1974-11-22 CA CA74214473A patent/CA1048689A/fr not_active Expired
- 1974-11-26 IN IN2630/CAL/74A patent/IN140895B/en unknown
- 1974-12-18 FI FI3670/74A patent/FI367074A7/fi unknown
- 1974-12-19 BR BR1060574A patent/BR7410605D0/pt unknown

Also Published As

Publication number	Publication date
AU6749974A (en)	1974-07-25
FI367074A7 (fr)	1975-06-22
AR205913A1 (es)	1976-06-15
IN140895B (fr)	1977-01-01
BR7410605D0 (pt)	1975-09-02

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JP4571910B2 (ja)	2010-10-27	エステル変性ジカルボキシレートポリマー
US4377682A (en)	1983-03-22	Copolyesters
KR100404666B1 (ko)	2004-05-20	방염성 폴리에스테르 공중합체
US3909489A (en)	1975-09-30	Polyesters and copolyesters having improved flame retardancy
IE920015A1 (en)	1992-07-15	Flame resistant, low pilling polyester fiber
JPH05230345A (ja)	1993-09-07	耐炎性ポリエステル
US3883611A (en)	1975-05-13	Copolyester(ethylene terephthalate/tetramethylene dibromoterephthalate) a new block polymer
CA1048689A (fr)	1979-02-13	Copolyesters retardant la propagation de la flamme
JP2001172823A (ja)	2001-06-26	難燃性ポリエステル繊維及びその製造方法
KR100449383B1 (ko)	2004-11-26	난연성 폴리에스테르 섬유의 제조방법
JPH04359016A (ja)	1992-12-11	改質ポリエステルの製造方法
US4043981A (en)	1977-08-23	Copolyesters derived from ethoxylated 3,5-dibromo-4-hydroxybenzoic acid
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US3904707A (en)	1975-09-09	Flame retardant polyester compositions
US3887523A (en)	1975-06-03	Fiber-forming copolyester compositions from brominated ethoxylated hydroquinone
JPH01103650A (ja)	1989-04-20	改質ポリエステル組成物
CA1059676A (fr)	1979-07-31	Composes de polyester retardateurs de combustion
US3057827A (en)	1962-10-09	Sulfinate containing polyesters dyeable with basic dyes
JPH0563506B2 (fr)	1993-09-10
US3758442A (en)	1973-09-11	Ocess for preparation thereof and articles thereof novel polyetheresters of hydroxyalkoxyl diphenyl-4-carboxylic acid pr
US3833542A (en)	1974-09-03	Manufacture of thermally stabilized polyethylene terephthalate
JP2795741B2 (ja)	1998-09-10	ポリエステルブロック共重合体
US3817934A (en)	1974-06-18	Sulfodicarboxylic acid caprolactam reaction product modified polyesters
KR930011322B1 (ko)	1993-11-30	난연성 폴리에스테르 섬유의 제조방법
US3692741A (en)	1972-09-19	Metal 2,5-dimethoxy cinnamic salts as catalysts-optical brighteners for polyester resins