CA1051250A - Sensibilisation spectrale de complexes a metal de transition - Google Patents

Sensibilisation spectrale de complexes a metal de transition

Info

Publication number: CA1051250A
Authority: CA; Canada
Prior art keywords: radiation; cobalt; iii; complex; sensitive element
Prior art date: 1974-04-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA221,818A

Other languages

English (en)

Other versions

CA221818S (en

Inventor

Daniel S. Daniel

Albert T. Brault

Glenn R. Wilkes

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eastman Kodak Co

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-04-15

Filing date

1975-03-11

Publication date

1979-03-27

1975-03-11 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1979-03-27 Application granted granted Critical

1979-03-27 Publication of CA1051250A publication Critical patent/CA1051250A/fr

Status Expired legal-status Critical Current

Links

230000003595 spectral effect Effects 0.000 title claims abstract description 118
206010070834 Sensitisation Diseases 0.000 title description 4
230000008313 sensitization Effects 0.000 title description 4
229910052723 transition metal Inorganic materials 0.000 title description 2
150000003624 transition metals Chemical class 0.000 title description 2
230000005855 radiation Effects 0.000 claims abstract description 256
229910017052 cobalt Inorganic materials 0.000 claims abstract description 161
239000010941 cobalt Substances 0.000 claims abstract description 161
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 159
239000003446 ligand Substances 0.000 claims abstract description 61
230000009467 reduction Effects 0.000 claims abstract description 59
230000005283 ground state Effects 0.000 claims abstract description 40
230000003647 oxidation Effects 0.000 claims abstract description 28
238000007254 oxidation reaction Methods 0.000 claims abstract description 28
150000001450 anions Chemical class 0.000 claims abstract description 19
JAWGVVJVYSANRY-UHFFFAOYSA-N cobalt(3+) Chemical compound [Co+3] JAWGVVJVYSANRY-UHFFFAOYSA-N 0.000 claims abstract description 18
-1 azido, thiocyanato Chemical group 0.000 claims description 78
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 64
238000000576 coating method Methods 0.000 claims description 64
238000006722 reduction reaction Methods 0.000 claims description 58
239000000975 dye Substances 0.000 claims description 53
150000001875 compounds Chemical class 0.000 claims description 51
239000011248 coating agent Substances 0.000 claims description 47
238000000034 method Methods 0.000 claims description 35
229910021529 ammonia Inorganic materials 0.000 claims description 31
125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 claims description 27
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 claims description 24
230000008569 process Effects 0.000 claims description 19
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 18
125000002091 cationic group Chemical group 0.000 claims description 18
238000010438 heat treatment Methods 0.000 claims description 15
230000003287 optical effect Effects 0.000 claims description 15
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 14
VMGAPWLDMVPYIA-HIDZBRGKSA-N n'-amino-n-iminomethanimidamide Chemical compound N\N=C\N=N VMGAPWLDMVPYIA-HIDZBRGKSA-N 0.000 claims description 14
BOLDJAUMGUJJKM-LSDHHAIUSA-N renifolin D Natural products CC(=C)[C@@H]1Cc2c(O)c(O)ccc2[C@H]1CC(=O)c3ccc(O)cc3O BOLDJAUMGUJJKM-LSDHHAIUSA-N 0.000 claims description 14
UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 14
239000000203 mixture Substances 0.000 claims description 13
125000000217 alkyl group Chemical group 0.000 claims description 11
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 11
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 10
QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 claims description 9
230000005670 electromagnetic radiation Effects 0.000 claims description 9
YUKQRDCYNOVPGJ-UHFFFAOYSA-N thioacetamide Chemical compound CC(N)=S YUKQRDCYNOVPGJ-UHFFFAOYSA-N 0.000 claims description 9
159000000000 sodium salts Chemical class 0.000 claims description 8
DLFVBJFMPXGRIB-UHFFFAOYSA-N thioacetamide Natural products CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims description 8
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 7
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
239000002253 acid Substances 0.000 claims description 7
239000002585 base Substances 0.000 claims description 7
239000012954 diazonium Substances 0.000 claims description 7
150000001989 diazonium salts Chemical group 0.000 claims description 7
150000007857 hydrazones Chemical class 0.000 claims description 7
UJKPHYRXOLRVJJ-MLSVHJFASA-N CC(O)C1=C(C)/C2=C/C3=N/C(=C\C4=C(CCC(O)=O)C(C)=C(N4)/C=C4\N=C(\C=C\1/N\2)C(C)=C4C(C)O)/C(CCC(O)=O)=C3C Chemical group CC(O)C1=C(C)/C2=C/C3=N/C(=C\C4=C(CCC(O)=O)C(C)=C(N4)/C=C4\N=C(\C=C\1/N\2)C(C)=C4C(C)O)/C(CCC(O)=O)=C3C UJKPHYRXOLRVJJ-MLSVHJFASA-N 0.000 claims description 6
125000003118 aryl group Chemical group 0.000 claims description 6
125000004432 carbon atom Chemical group C* 0.000 claims description 6
125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 claims description 6
229960003569 hematoporphyrin Drugs 0.000 claims description 6
DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 claims description 6
229910052757 nitrogen Inorganic materials 0.000 claims description 6
125000005504 styryl group Chemical group 0.000 claims description 6
238000012546 transfer Methods 0.000 claims description 6
239000011230 binding agent Substances 0.000 claims description 5
239000000298 carbocyanine Substances 0.000 claims description 5
239000002738 chelating agent Substances 0.000 claims description 5
GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 claims description 5
AEOCXXJPGCBFJA-UHFFFAOYSA-N ethionamide Chemical compound CCC1=CC(C(N)=S)=CC=N1 AEOCXXJPGCBFJA-UHFFFAOYSA-N 0.000 claims description 5
QWYZFXLSWMXLDM-UHFFFAOYSA-M pinacyanol iodide Chemical compound [I-].C1=CC2=CC=CC=C2N(CC)C1=CC=CC1=CC=C(C=CC=C2)C2=[N+]1CC QWYZFXLSWMXLDM-UHFFFAOYSA-M 0.000 claims description 5
VZVHUBYZGAUXLX-UHFFFAOYSA-N azane;azanide;cobalt(3+) Chemical compound N.N.N.[NH2-].[NH2-].[NH2-].[Co+3] VZVHUBYZGAUXLX-UHFFFAOYSA-N 0.000 claims description 4
125000000751 azo group Chemical group [*]N=N[*] 0.000 claims description 4
230000001747 exhibiting effect Effects 0.000 claims description 4
125000001624 naphthyl group Chemical group 0.000 claims description 4
150000003839 salts Chemical class 0.000 claims description 4
ZFYDGPJXMYCXNV-UHFFFAOYSA-M 1-ethyl-2-[5-(1-ethylquinolin-1-ium-2-yl)penta-2,4-dienylidene]quinoline;iodide Chemical compound [I-].C1=CC2=CC=CC=C2N(CC)C1=CC=CC=CC1=CC=C(C=CC=C2)C2=[N+]1CC ZFYDGPJXMYCXNV-UHFFFAOYSA-M 0.000 claims description 3
CCOLQVLHZWALHZ-UHFFFAOYSA-N 2-[5-(3-methyl-1,3-benzoxazol-2-ylidene)-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]acetic acid Chemical compound O1C2=CC=CC=C2N(C)C1=C1SC(=S)N(CC(O)=O)C1=O CCOLQVLHZWALHZ-UHFFFAOYSA-N 0.000 claims description 3
239000002262 Schiff base Substances 0.000 claims description 3
150000004753 Schiff bases Chemical class 0.000 claims description 3
125000002877 alkyl aryl group Chemical group 0.000 claims description 3
125000000129 anionic group Chemical group 0.000 claims description 3
OAEGRYMCJYIXQT-UHFFFAOYSA-N dithiooxamide Chemical compound NC(=S)C(N)=S OAEGRYMCJYIXQT-UHFFFAOYSA-N 0.000 claims description 3
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 3
VWDLPATYDZFCES-UHFFFAOYSA-N 4-[4-[(2,4-dinitrophenyl)methylidene]quinolin-1-yl]butane-1-sulfonic acid Chemical compound C12=CC=CC=C2N(CCCCS(=O)(=O)O)C=CC1=CC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O VWDLPATYDZFCES-UHFFFAOYSA-N 0.000 claims description 2
230000015572 biosynthetic process Effects 0.000 claims description 2
235000021286 stilbenes Nutrition 0.000 claims description 2
229940012017 ethylenediamine Drugs 0.000 claims 7
LNKNWPNGZMWPFA-UHFFFAOYSA-N 2-[5-[1-(3-methyl-1,3-thiazolidin-2-ylidene)propan-2-ylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]acetic acid Chemical compound CN1CCSC1=CC(C)=C1C(=O)N(CC(O)=O)C(=S)S1 LNKNWPNGZMWPFA-UHFFFAOYSA-N 0.000 claims 2
NVXMOCINNAPHSD-UHFFFAOYSA-N 2-[5-[2-(3-ethyl-1,3-benzothiazol-2-ylidene)ethylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]acetic acid Chemical compound S1C2=CC=CC=C2N(CC)C1=CC=C1SC(=S)N(CC(O)=O)C1=O NVXMOCINNAPHSD-UHFFFAOYSA-N 0.000 claims 2
QWFJNAHLMKUKHA-UHFFFAOYSA-N 2-[5-[2-(3-ethyl-1,3-benzoxazol-2-ylidene)ethylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]acetic acid Chemical compound O1C2=CC=CC=C2N(CC)C1=CC=C1SC(=S)N(CC(O)=O)C1=O QWFJNAHLMKUKHA-UHFFFAOYSA-N 0.000 claims 2
KJXKJGBRCAUHMN-UHFFFAOYSA-N 3-ethyl-5-[2-(3-ethyl-1,3-benzothiazol-2-ylidene)ethylidene]-2-sulfanylidene-1,3-thiazolidin-4-one Chemical compound O=C1N(CC)C(=S)SC1=CC=C1N(CC)C2=CC=CC=C2S1 KJXKJGBRCAUHMN-UHFFFAOYSA-N 0.000 claims 2
JAFSZVFUWRLSPS-UHFFFAOYSA-N 3-ethyl-5-[2-(3-ethyl-1,3-benzoxazol-2-ylidene)ethylidene]-1-phenyl-2-sulfanylideneimidazolidin-4-one Chemical compound O1C2=CC=CC=C2N(CC)C1=CC=C1C(=O)N(CC)C(=S)N1C1=CC=CC=C1 JAFSZVFUWRLSPS-UHFFFAOYSA-N 0.000 claims 2
YAORVROFPFPJJU-UHFFFAOYSA-N 3-ethyl-5-[2-(3-ethyl-1,3-benzoxazol-2-ylidene)ethylidene]-2-sulfanylidene-1,3-thiazolidin-4-one Chemical compound O=C1N(CC)C(=S)SC1=CC=C1N(CC)C2=CC=CC=C2O1 YAORVROFPFPJJU-UHFFFAOYSA-N 0.000 claims 2
VFUBECKRASDZKT-UHFFFAOYSA-N 4-[4-[1-(1-ethylbenzo[e][1,3]benzothiazol-2-ylidene)propan-2-ylidene]-3-methyl-5-oxopyrazol-1-yl]benzenesulfonic acid Chemical compound S1C2=CC=C3C=CC=CC3=C2N(CC)C1=CC(C)=C(C1=O)C(C)=NN1C1=CC=C(S(O)(=O)=O)C=C1 VFUBECKRASDZKT-UHFFFAOYSA-N 0.000 claims 2
BGUFNHOQYFNSKN-UHFFFAOYSA-N 4-[4-[1-(3-ethyl-1,3-benzothiazol-2-ylidene)propan-2-ylidene]-3-methyl-5-oxopyrazol-1-yl]benzenesulfonic acid Chemical compound S1C2=CC=CC=C2N(CC)C1=CC(C)=C(C1=O)C(C)=NN1C1=CC=C(S(O)(=O)=O)C=C1 BGUFNHOQYFNSKN-UHFFFAOYSA-N 0.000 claims 2
BOMGUORSURCISS-UHFFFAOYSA-N 5-[2-(3-ethyl-1,3-benzothiazol-2-ylidene)ethylidene]-2-(n-phenylanilino)-1,3-thiazol-4-one Chemical compound S1C2=CC=CC=C2N(CC)C1=CC=C(C(N=1)=O)SC=1N(C=1C=CC=CC=1)C1=CC=CC=C1 BOMGUORSURCISS-UHFFFAOYSA-N 0.000 claims 2
ITFOFRBMZFRAFD-UHFFFAOYSA-N 5-[2-(3-ethyl-1,3-benzoxazol-2-ylidene)ethylidene]-2-(n-phenylanilino)-1,3-thiazol-4-one Chemical compound O1C2=CC=CC=C2N(CC)C1=CC=C(C(N=1)=O)SC=1N(C=1C=CC=CC=1)C1=CC=CC=C1 ITFOFRBMZFRAFD-UHFFFAOYSA-N 0.000 claims 2
FERGHJGMKGXSGF-UHFFFAOYSA-N 5-[4-(3-ethyl-1,3-benzothiazol-2-ylidene)but-2-enylidene]-3-heptyl-1-phenyl-2-sulfanylideneimidazolidin-4-one Chemical compound C(C)N1C(SC2=C1C=CC=C2)=CC=CC=C2C(N(C(N2C2=CC=CC=C2)=S)CCCCCCC)=O FERGHJGMKGXSGF-UHFFFAOYSA-N 0.000 claims 2
IREUENUIFYGOGL-UHFFFAOYSA-M sodium;4-[4-(3-ethyl-4-oxo-2-sulfanylidene-1,3-thiazolidin-5-ylidene)pyridin-1-yl]butane-1-sulfonate Chemical compound [Na+].O=C1N(CC)C(=S)SC1=C1C=CN(CCCCS([O-])(=O)=O)C=C1 IREUENUIFYGOGL-UHFFFAOYSA-M 0.000 claims 2
XKWQNWOHLZAFPS-UHFFFAOYSA-N 1,1',3,3'-tetraethyl-5,5',6,6'-tetrachloroimidacarbocyanine Chemical compound CCN1C2=CC(Cl)=C(Cl)C=C2N(CC)C1=CC=CC1=[N+](CC)C2=CC(Cl)=C(Cl)C=C2N1CC XKWQNWOHLZAFPS-UHFFFAOYSA-N 0.000 claims 1
125000000143 2-carboxyethyl group Chemical group [H]OC(=O)C([H])([H])C([H])([H])* 0.000 claims 1
ZTGKHKPZSMMHNM-UHFFFAOYSA-N 3-(2-phenylethenyl)benzene-1,2-disulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC(C=CC=2C=CC=CC=2)=C1S(O)(=O)=O ZTGKHKPZSMMHNM-UHFFFAOYSA-N 0.000 claims 1
QASPZJKUSLIXOS-UHFFFAOYSA-L S(C#N)[Co+]Cl.C(CN)N.C(CN)N Chemical compound S(C#N)[Co+]Cl.C(CN)N.C(CN)N QASPZJKUSLIXOS-UHFFFAOYSA-L 0.000 claims 1
PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 claims 1
125000005263 alkylenediamine group Chemical group 0.000 claims 1
BZRRQSJJPUGBAA-UHFFFAOYSA-L cobalt(ii) bromide Chemical compound Br[Co]Br BZRRQSJJPUGBAA-UHFFFAOYSA-L 0.000 claims 1
125000001475 halogen functional group Chemical group 0.000 claims 1
PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 claims 1
239000010410 layer Substances 0.000 description 191
231100000489 sensitizer Toxicity 0.000 description 103
239000000243 solution Substances 0.000 description 37
229920000159 gelatin Polymers 0.000 description 34
239000008273 gelatin Substances 0.000 description 34
108010010803 Gelatin Proteins 0.000 description 33
235000019322 gelatine Nutrition 0.000 description 33
235000011852 gelatine desserts Nutrition 0.000 description 33
238000003384 imaging method Methods 0.000 description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
229910052709 silver Inorganic materials 0.000 description 16
239000004332 silver Substances 0.000 description 16
239000002904 solvent Substances 0.000 description 16
238000012545 processing Methods 0.000 description 15
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
238000000926 separation method Methods 0.000 description 12
125000001424 substituent group Chemical group 0.000 description 12
239000007795 chemical reaction product Substances 0.000 description 11
238000012360 testing method Methods 0.000 description 10
150000003556 thioamides Chemical class 0.000 description 10
238000001429 visible spectrum Methods 0.000 description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
230000004044 response Effects 0.000 description 9
238000005259 measurement Methods 0.000 description 8
INPLXZPZQSLHBR-UHFFFAOYSA-N cobalt(2+);sulfide Chemical compound [S-2].[Co+2] INPLXZPZQSLHBR-UHFFFAOYSA-N 0.000 description 7
239000000463 material Substances 0.000 description 7
229920000642 polymer Polymers 0.000 description 7
239000010453 quartz Substances 0.000 description 7
230000035945 sensitivity Effects 0.000 description 7
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
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239000007864 aqueous solution Substances 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 6
QSQUFRGBXGXOHF-UHFFFAOYSA-N cobalt(iii) nitrate Chemical compound [Co].O[N+]([O-])=O.O[N+]([O-])=O.O[N+]([O-])=O QSQUFRGBXGXOHF-UHFFFAOYSA-N 0.000 description 6
238000010586 diagram Methods 0.000 description 6
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238000010521 absorption reaction Methods 0.000 description 5
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229910052740 iodine Inorganic materials 0.000 description 5
239000011630 iodine Substances 0.000 description 5
150000002500 ions Chemical class 0.000 description 5
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 5
239000000376 reactant Substances 0.000 description 5
229910000029 sodium carbonate Inorganic materials 0.000 description 5
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150000001412 amines Chemical class 0.000 description 4
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KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
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229910002651 NO3 Inorganic materials 0.000 description 3
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BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
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125000002252 acyl group Chemical group 0.000 description 3
230000004075 alteration Effects 0.000 description 3
WVCXSPJPERKPJS-UHFFFAOYSA-L azane;dichloropalladium;hydrate Chemical compound N.N.N.N.O.Cl[Pd]Cl WVCXSPJPERKPJS-UHFFFAOYSA-L 0.000 description 3
239000000987 azo dye Substances 0.000 description 3
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GTKRFUAGOKINCA-UHFFFAOYSA-M chlorosilver;silver Chemical compound [Ag].[Ag]Cl GTKRFUAGOKINCA-UHFFFAOYSA-M 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
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235000020679 tap water Nutrition 0.000 description 1
239000012085 test solution Substances 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
150000003557 thiazoles Chemical class 0.000 description 1
150000003549 thiazolines Chemical class 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
125000003396 thiol group Chemical class [H]S* 0.000 description 1
150000003585 thioureas Chemical class 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
239000011135 tin Substances 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
150000004654 triazenes Chemical class 0.000 description 1
IEKWPPTXWFKANS-UHFFFAOYSA-K trichlorocobalt Chemical compound Cl[Co](Cl)Cl IEKWPPTXWFKANS-UHFFFAOYSA-K 0.000 description 1
125000004205 trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 1
125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
239000001018 xanthene dye Substances 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/67—Compositions containing cobalt salts or cobalt compounds as photosensitive substances

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)

CA221,818A 1974-04-15 1975-03-11 Sensibilisation spectrale de complexes a metal de transition Expired CA1051250A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US46117174A	1974-04-15	1974-04-15

Publications (1)

Publication Number	Publication Date
CA1051250A true CA1051250A (fr)	1979-03-27

Family

ID=23831484

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA221,818A Expired CA1051250A (fr)	1974-04-15	1975-03-11	Sensibilisation spectrale de complexes a metal de transition

Country Status (4)

Country	Link
JP (1)	JPS5410856B2 (fr)
CA (1)	CA1051250A (fr)
FR (1)	FR2267570B1 (fr)
GB (1)	GB1496944A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5476755A (en) *	1993-11-19	1995-12-19	Konica Corporation	Image forming element and image forming method
US5698363A (en) *	1995-07-10	1997-12-16	Konica Corporation	Image forming method

1975
- 1975-03-11 CA CA221,818A patent/CA1051250A/fr not_active Expired
- 1975-04-14 FR FR7511497A patent/FR2267570B1/fr not_active Expired
- 1975-04-15 JP JP4575675A patent/JPS5410856B2/ja not_active Expired
- 1975-04-15 GB GB1549675A patent/GB1496944A/en not_active Expired

Also Published As

Publication number	Publication date
DE2516174B2 (de)	1977-01-27
FR2267570A1 (fr)	1975-11-07
FR2267570B1 (fr)	1977-04-15
JPS5410856B2 (fr)	1979-05-10
JPS50139723A (fr)	1975-11-08
DE2516174A1 (de)	1975-10-23
GB1496944A (en)	1978-01-05

Publication	Publication Date	Title
US4075019A (en)	1978-02-21	High gain cobalt(III)complex composition and element
US4045221A (en)	1977-08-30	Process of amplifying image in image recording layer by releasing reactant from image forming layer containing cobalt(III)complex
CH642182A5 (fr)	1984-03-30	Produit photographique comprenant un reseau de micro-cellules et procede pour sa preparation.
US4201588A (en)	1980-05-06	Radiation sensitive co(III)complex photoreduction element with image recording layer
US4284704A (en)	1981-08-18	Photographic elements with incorporated hydrogen source photoreductant and tetrazolium salt
US4273860A (en)	1981-06-16	Inhibition of image formation utilizing cobalt(III) complexes
US3384484A (en)	1968-05-21	Silver halide photographic materials containing organic hydrazone compounds
CA1051250A (fr)	1979-03-27	Sensibilisation spectrale de complexes a metal de transition
US4243737A (en)	1981-01-06	Image forming composition and elements with Co(III) complex, conjugated π bonding compounds and photoreductant
US4171221A (en)	1979-10-16	High gain Co(III)complex imaging
EP0003263B1 (fr)	1982-09-29	Méthode pour l'obtention d'une image et élément pour la formation d'une image par inhibition à base de complexes de cobalt (III)
US3954468A (en)	1976-05-04	Radiation process for producing colored photopolymer systems
US3503741A (en)	1970-03-31	Silver-dye-bleach process utilizing formazan dyes
US3446619A (en)	1969-05-27	Radiation sensitive silver-dye complexes
US4124392A (en)	1978-11-07	Cobalt complex amplification imaging system with blocked dye precursor
US4195998A (en)	1980-04-01	CO(III) Complex containing radiation sensitive element with diazo recording layer
US4324852A (en)	1982-04-13	Transition metal photoreduction systems and processes
US4334005A (en)	1982-06-08	Transition metal photoreduction systems and processes
EP0120601B1 (fr)	1988-10-19	Formation d'images par oxydation
US4314019A (en)	1982-02-02	Transition metal photoreduction systems and processes
US4294912A (en)	1981-10-13	Thermally responsive cobalt(III) complex imaging compositions having lowered activation temperatures
US4057427A (en)	1977-11-08	Peroxide redox amplification imaging using manganese catalyst images
CA1051706A (fr)	1979-04-03	Systemes et processus de photoreduction par metal de transition
US3881930A (en)	1975-05-06	2H-benzimidazole photoreductive imaging
JPS6332177B2 (fr)	1988-06-28