CA1057231A - Nouveau procede de chromage - Google Patents

Nouveau procede de chromage

Info

Publication number: CA1057231A
Authority: CA; Canada
Prior art keywords: chromium; ions; fluoride; aluminum; electroplating
Prior art date: 1973-08-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA207,707A

Other languages

English (en)

Other versions

CA207707S (en

Inventor

Hyman Chessin

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

M&T Chemicals Inc

Original Assignee

M&T Chemicals Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-08-30

Filing date

1974-08-23

Publication date

1979-06-26

1974-08-23 Application filed by M&T Chemicals Inc filed Critical M&T Chemicals Inc

1979-06-26 Application granted granted Critical

1979-06-26 Publication of CA1057231A publication Critical patent/CA1057231A/fr

Status Expired legal-status Critical Current

Links

VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title claims abstract description 62
229910052804 chromium Inorganic materials 0.000 title claims abstract description 61
239000011651 chromium Substances 0.000 title claims abstract description 61
238000007747 plating Methods 0.000 title claims abstract description 37
238000000034 method Methods 0.000 title claims abstract description 16
229910052782 aluminium Inorganic materials 0.000 claims abstract description 46
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract description 44
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 42
229910052751 metal Inorganic materials 0.000 claims abstract description 25
239000002184 metal Substances 0.000 claims abstract description 25
238000009713 electroplating Methods 0.000 claims abstract description 22
-1 aluminum ions Chemical class 0.000 claims abstract description 21
239000000203 mixture Substances 0.000 claims abstract description 21
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 14
230000002378 acidificating effect Effects 0.000 claims abstract description 10
150000001845 chromium compounds Chemical class 0.000 claims abstract description 6
229910001430 chromium ion Inorganic materials 0.000 claims abstract description 6
JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 claims abstract description 6
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 19
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims description 19
229910000838 Al alloy Inorganic materials 0.000 claims description 3
229910001220 stainless steel Inorganic materials 0.000 claims description 3
239000010935 stainless steel Substances 0.000 claims 1
KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminium flouride Chemical compound F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 abstract description 8
229910001610 cryolite Inorganic materials 0.000 abstract description 2
239000007790 solid phase Substances 0.000 abstract 1
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 27
239000000243 solution Substances 0.000 description 17
239000003054 catalyst Substances 0.000 description 14
238000012360 testing method Methods 0.000 description 9
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 8
150000002222 fluorine compounds Chemical class 0.000 description 7
239000002253 acid Substances 0.000 description 6
150000002500 ions Chemical class 0.000 description 6
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 4
229910004074 SiF6 Inorganic materials 0.000 description 4
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
230000000694 effects Effects 0.000 description 3
INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
230000004580 weight loss Effects 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
239000012153 distilled water Substances 0.000 description 2
239000012535 impurity Substances 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Substances 0.000 description 2
NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
239000000047 product Substances 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
239000010963 304 stainless steel Substances 0.000 description 1
229910004725 CaSiF6 Inorganic materials 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
229910003638 H2SiF6 Inorganic materials 0.000 description 1
229910004883 Na2SiF6 Inorganic materials 0.000 description 1
101100396546 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) tif-6 gene Proteins 0.000 description 1
229910000978 Pb alloy Inorganic materials 0.000 description 1
229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
241000769223 Thenea Species 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000004913 activation Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
229940070337 ammonium silicofluoride Drugs 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
239000011260 aqueous acid Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
239000001996 bearing alloy Substances 0.000 description 1
210000001217 buttock Anatomy 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
229910001634 calcium fluoride Inorganic materials 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
229910052923 celestite Inorganic materials 0.000 description 1
QCCDYNYSHILRDG-UHFFFAOYSA-K cerium(3+);trifluoride Chemical compound [F-].[F-].[F-].[Ce+3] QCCDYNYSHILRDG-UHFFFAOYSA-K 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
230000000536 complexating effect Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000004512 die casting Methods 0.000 description 1
238000007865 diluting Methods 0.000 description 1
238000004070 electrodeposition Methods 0.000 description 1
238000005530 etching Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000004744 fabric Substances 0.000 description 1
150000004673 fluoride salts Chemical class 0.000 description 1
238000007654 immersion Methods 0.000 description 1
238000007689 inspection Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
238000002161 passivation Methods 0.000 description 1
235000003270 potassium fluoride Nutrition 0.000 description 1
239000011698 potassium fluoride Substances 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
235000013024 sodium fluoride Nutrition 0.000 description 1
239000011775 sodium fluoride Substances 0.000 description 1
229910001495 sodium tetrafluoroborate Inorganic materials 0.000 description 1
239000010959 steel Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
235000011149 sulphuric acid Nutrition 0.000 description 1
208000024891 symptom Diseases 0.000 description 1
RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
SWURHZJFFJEBEE-UHFFFAOYSA-J tetrafluorocerium Chemical compound F[Ce](F)(F)F SWURHZJFFJEBEE-UHFFFAOYSA-J 0.000 description 1
ZEFWRWWINDLIIV-UHFFFAOYSA-N tetrafluorosilane;dihydrofluoride Chemical compound F.F.F[Si](F)(F)F ZEFWRWWINDLIIV-UHFFFAOYSA-N 0.000 description 1
238000004448 titration Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/04—Electroplating: Baths therefor from solutions of chromium

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Electroplating And Plating Baths Therefor (AREA)
Chemical Treatment Of Metals (AREA)
Electroplating Methods And Accessories (AREA)

CA207,707A 1973-08-30 1974-08-23 Nouveau procede de chromage Expired CA1057231A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US39307273A	1973-08-30	1973-08-30

Publications (1)

Publication Number	Publication Date
CA1057231A true CA1057231A (fr)	1979-06-26

Family

ID=23553161

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA207,707A Expired CA1057231A (fr)	1973-08-30	1974-08-23	Nouveau procede de chromage

Country Status (11)

Country	Link
JP (1)	JPS5728753B2 (fr)
BE (1)	BE815301A (fr)
CA (1)	CA1057231A (fr)
DE (1)	DE2422076A1 (fr)
ES (1)	ES426214A1 (fr)
FR (1)	FR2242489B1 (fr)
GB (1)	GB1459569A (fr)
IT (1)	IT1018226B (fr)
NL (1)	NL7411574A (fr)
SE (1)	SE7409083L (fr)
ZA (1)	ZA744725B (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP1507026A1 (fr) *	2003-08-14	2005-02-16	Enthone Inc.	Methode pour l'inertisation selective ou complète des pièces à travailler et des parties d'installation par dépôt non-reactif

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US303114A (en) *		1884-08-05		Car-brake

1974
- 1974-05-07 DE DE2422076A patent/DE2422076A1/de not_active Ceased
- 1974-05-11 ES ES74426214A patent/ES426214A1/es not_active Expired
- 1974-05-16 JP JP5495974A patent/JPS5728753B2/ja not_active Expired
- 1974-05-16 FR FR7417071A patent/FR2242489B1/fr not_active Expired
- 1974-05-20 BE BE144547A patent/BE815301A/fr not_active IP Right Cessation
- 1974-06-25 GB GB2818474A patent/GB1459569A/en not_active Expired
- 1974-07-10 SE SE7409083A patent/SE7409083L/xx unknown
- 1974-07-24 ZA ZA00744725A patent/ZA744725B/xx unknown
- 1974-08-23 CA CA207,707A patent/CA1057231A/fr not_active Expired
- 1974-08-26 IT IT9555/74A patent/IT1018226B/it active
- 1974-08-30 NL NL7411574A patent/NL7411574A/xx not_active Application Discontinuation

Also Published As

Publication number	Publication date
ZA744725B (en)	1975-12-31
NL7411574A (nl)	1975-03-04
ES426214A1 (es)	1976-11-16
JPS5728753B2 (fr)	1982-06-18
FR2242489B1 (fr)	1979-02-16
FR2242489A1 (fr)	1975-03-28
JPS5072837A (fr)	1975-06-16
SE7409083L (fr)	1975-03-03
GB1459569A (en)	1976-12-22
DE2422076A1 (de)	1975-04-10
BE815301A (fr)	1974-09-16
IT1018226B (it)	1977-09-30

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EP0747510B1 (fr)	2000-04-19	Revêtement d'oxyde de chrome à partir d'une solution de chrome trivalent
US3954574A (en)	1976-05-04	Trivalent chromium electroplating baths and electroplating therefrom
AU2004202524A1 (en)	2004-12-23	Method of surface treating metal and metal surface treated thereby
KR100197145B1 (ko)	1999-06-15	금속표면의 인산아연 처리방법
Dubpernell	2013	Electrodeposition of chromium from chromic acid solutions
CA1105873A (fr)	1981-07-28	Bain trivalent de chromage
JPH05287549A (ja)	1993-11-02	カチオン型電着塗装のための金属表面のリン酸亜鉛処理方法
EP2787102B1 (fr)	2017-05-17	Supplément et procédé de production de tôle en acier traitée en surface
CA1057231A (fr)	1979-06-26	Nouveau procede de chromage
CA2881081A1 (fr)	2014-02-13	Liquide de traitement de surface metallique, procede de traitement de surface des bases metalliques et base metallique obtenue par un procede de traitement de surface des bases metalliques
JPS5887291A (ja)	1983-05-25	クロム電気メツキ液
US3654101A (en)	1972-04-04	Novel chromium plating compositions and processes
US4422908A (en)	1983-12-27	Zinc plating
ES2969188T3 (es)	2024-05-16	Procedimiento para la deposición galvánica de revestimientos de aleaciones de cinc-níquel a partir de un baño de aleación de cinc-níquel alcalino con degradación reducida de aditivos
CN105102686B (zh)	2017-03-08	具有经改良腐蚀抗性的功能铬层
USRE29749E (en)	1978-08-29	Trivalent chromium electroplating baths and electroplating therefrom
RU2219293C1 (ru)	2003-12-20	Электролит меднения
Davies et al.	1952	Complex Fluorides for the Deposition of Tin and Tin Alloys
US20030010627A1 (en)	2003-01-16	Metal surface-treating method
AU2020205312B2 (en)	2025-05-01	Functional chromium alloy plating from trivalent chromium electrolytes
EP0088192A1 (fr)	1983-09-14	Contrôle d'évolution de gaz d'anode dans un bain de placage à base de chrome trivalent
RU2840543C1 (ru)	2025-05-26	Электролит для электроосаждения олово-цинковых покрытий
US2131427A (en)	1938-09-27	Process of electrolytically depositing iron and nickel alloy
US2802779A (en)	1957-08-13	Electrodeposition of nickel and nickel alloys
US2787589A (en)	1957-04-02	Chromium plating