CA1059690A - Methode d'extraction de l'halogenure de vinyle - Google Patents

Methode d'extraction de l'halogenure de vinyle

Info

Publication number: CA1059690A
Authority: CA; Canada
Prior art keywords: process according; alkane; polymer; polymerization; pressure
Prior art date: 1974-12-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA241,929A

Other languages

English (en)

Other versions

CA241929S (en

Inventor

Lester Weintraub

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Pantasote Co

Original Assignee

Pantasote Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-12-19

Filing date

1975-12-17

Publication date

1979-07-31

1975-12-17 Application filed by Pantasote Co filed Critical Pantasote Co

1979-07-31 Application granted granted Critical

1979-07-31 Publication of CA1059690A publication Critical patent/CA1059690A/fr

Status Expired legal-status Critical Current

Links

-1 Vinyl halide Chemical class 0.000 title claims abstract description 44
229920002554 vinyl polymer Polymers 0.000 title claims abstract description 43
238000000034 method Methods 0.000 title claims abstract description 28
229920000642 polymer Polymers 0.000 claims abstract description 49
150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 36
229920001577 copolymer Polymers 0.000 claims abstract description 7
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 28
239000000178 monomer Substances 0.000 claims description 21
238000006116 polymerization reaction Methods 0.000 claims description 21
239000000203 mixture Substances 0.000 claims description 16
229920001519 homopolymer Polymers 0.000 claims description 9
AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical group CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims description 8
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 8
238000010438 heat treatment Methods 0.000 claims description 7
125000004432 carbon atom Chemical group C* 0.000 claims description 6
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 claims description 5
238000010557 suspension polymerization reaction Methods 0.000 claims description 5
238000013022 venting Methods 0.000 claims description 4
239000007787 solid Substances 0.000 claims description 3
238000012662 bulk polymerization Methods 0.000 claims description 2
238000010528 free radical solution polymerization reaction Methods 0.000 claims description 2
239000000725 suspension Substances 0.000 claims description 2
229920001567 vinyl ester resin Polymers 0.000 claims description 2
239000007795 chemical reaction product Substances 0.000 claims 2
150000001924 cycloalkanes Chemical class 0.000 abstract description 3
238000002156 mixing Methods 0.000 description 15
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 12
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 11
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
235000012970 cakes Nutrition 0.000 description 6
239000002002 slurry Substances 0.000 description 6
235000021463 dry cake Nutrition 0.000 description 5
150000002500 ions Chemical class 0.000 description 5
239000004800 polyvinyl chloride Substances 0.000 description 5
229920005989 resin Polymers 0.000 description 5
239000011347 resin Substances 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 4
229920000915 polyvinyl chloride Polymers 0.000 description 4
239000004808 2-ethylhexylester Substances 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
KRADHMIOFJQKEZ-UHFFFAOYSA-N Tri-2-ethylhexyl trimellitate Chemical compound CCCCC(CC)COC(=O)C1=CC=C(C(=O)OCC(CC)CCCC)C(C(=O)OCC(CC)CCCC)=C1 KRADHMIOFJQKEZ-UHFFFAOYSA-N 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
239000000084 colloidal system Substances 0.000 description 3
JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 3
238000001035 drying Methods 0.000 description 3
NUHSROFQTUXZQQ-UHFFFAOYSA-N isopentenyl diphosphate Chemical compound CC(=C)CCO[P@](O)(=O)OP(O)(O)=O NUHSROFQTUXZQQ-UHFFFAOYSA-N 0.000 description 3
229920000126 latex Polymers 0.000 description 3
108010010803 Gelatin Proteins 0.000 description 2
229920003091 Methocel™ Polymers 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
230000002411 adverse Effects 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
229920000159 gelatin Polymers 0.000 description 2
239000008273 gelatin Substances 0.000 description 2
235000019322 gelatine Nutrition 0.000 description 2
235000011852 gelatine desserts Nutrition 0.000 description 2
239000003999 initiator Substances 0.000 description 2
239000004816 latex Substances 0.000 description 2
235000019645 odor Nutrition 0.000 description 2
230000001681 protective effect Effects 0.000 description 2
239000000243 solution Substances 0.000 description 2
BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 1
239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
229910000003 Lead carbonate Inorganic materials 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
239000000872 buffer Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000012933 diacyl peroxide Substances 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
235000010981 methylcellulose Nutrition 0.000 description 1
239000002245 particle Substances 0.000 description 1
125000005634 peroxydicarbonate group Chemical group 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920000233 poly(alkylene oxides) Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000011084 recovery Methods 0.000 description 1
239000004576 sand Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
235000012424 soybean oil Nutrition 0.000 description 1
239000003549 soybean oil Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
235000012976 tarts Nutrition 0.000 description 1
230000007704 transition Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/001—Removal of residual monomers by physical means
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CA241,929A 1974-12-19 1975-12-17 Methode d'extraction de l'halogenure de vinyle Expired CA1059690A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US53442074A	1974-12-19	1974-12-19

Publications (1)

Publication Number	Publication Date
CA1059690A true CA1059690A (fr)	1979-07-31

Family

ID=24129948

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA241,929A Expired CA1059690A (fr)	1974-12-19	1975-12-17	Methode d'extraction de l'halogenure de vinyle

Country Status (4)

Country	Link
JP (1)	JPS5855966B2 (fr)
CA (1)	CA1059690A (fr)
FR (1)	FR2295045A1 (fr)
GB (1)	GB1530609A (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5362196A (en) *	1976-11-16	1978-06-03	Matsushita Electric Ind Co Ltd	Etching electrolyte for ferrite
DE2701147C2 (de) *	1977-01-13	1987-01-02	Wacker-Chemie GmbH, 8000 München	Verfahren zur Herstellung von Vinylchlorid-Copolymerisaten mit niedrigem Restmonomergehalt
IT1263955B (it) *	1993-02-23	1996-09-05	Ausimont Spa	Processo di (co) polimerizzazione radicalica di monomeri olefinici fluorurati
CN114478882B (zh) *	2020-10-28	2023-06-16	中国石油化工股份有限公司	一种pvc树脂的制备方法
CN114478883A (zh) *	2020-10-28	2022-05-13	中国石油化工股份有限公司	一种高孔隙率低皮膜hpvc树脂制备方法

1975
- 1975-12-16 FR FR7538514A patent/FR2295045A1/fr active Granted
- 1975-12-17 CA CA241,929A patent/CA1059690A/fr not_active Expired
- 1975-12-18 GB GB5181375A patent/GB1530609A/en not_active Expired
- 1975-12-19 JP JP15173375A patent/JPS5855966B2/ja not_active Expired

Also Published As

Publication number	Publication date
JPS5188590A (en)	1976-08-03
GB1530609A (en)	1978-11-01
JPS5855966B2 (ja)	1983-12-13
FR2295045B1 (fr)	1980-07-25
FR2295045A1 (fr)	1976-07-16

Publication	Publication Date	Title
US4272424A (en)	1981-06-09	Process for the preparation of vinyl chloride-based resins
US5087678A (en)	1992-02-11	Method for reducing foaming in a vinyl chloride polymerization reactor
US5232991A (en)	1993-08-03	Preparation of an impact-resistant polyacrylate/vinyl chloride graft copolymer
EP0705847A2 (fr)	1996-04-10	Agent de suspension pour la polymérisation d'un composé vinylique en suspension
JPS584933B2 (ja)	1983-01-28	可塑化塩化ビニリデン↓−塩化ビニル系共重合体の製造法
US4098978A (en)	1978-07-04	Process for emulsion polymerization of vinylidene halides and product thereof
US4246385A (en)	1981-01-20	Process for reducing content of unreacted vinyl halide in vinyl halide polymers
CA1039888A (fr)	1978-10-03	Procede de production de copolymeres avec greffes de chlorure de polyvinyle
EP0129700A2 (fr)	1985-01-02	Grains fins de chlorure de polyvinyle et procédé pour sa préparation
CA1109199A (fr)	1981-09-15	Procede de polymerisation par inversion pour la production de resines vinyliques
JPS5855966B2 (ja)	1983-12-13	ハロゲンカビニルノストリツピングホウホウ
EP0118631B1 (fr)	1988-06-01	Procédé de production de polymères de chlorure de vinyle
US4229569A (en)	1980-10-21	Process for the removal of vinyl chloride from aqueous slurries of vinyl chloride polymers
JPH0150322B2 (fr)	1989-10-30
JP3584591B2 (ja)	2004-11-04	塩化ビニル系重合体の製造方法
US5665836A (en)	1997-09-09	Method of preparing vinyl chloride polymers and copolymers of improved antistatic performance
JP2528892B2 (ja)	1996-08-28	塩化ビニル系化合物の懸濁重合用分散安定剤
JPH09302003A (ja)	1997-11-25	塩化ビニル系単量体の重合方法
US4107419A (en)	1978-08-15	Alpha halo substituted asymmetrical diacyl peroxides in co-initiator systems
US2616882A (en)	1952-11-04	Shortstopping vinyl chloride polymerizations with vinyl pyridines
CA1178747A (fr)	1984-11-27	Procede ameliore pour polymeres d'halogenures vinyliques
RU2070209C1 (ru)	1996-12-10	Способ получения привитого сополимера винилхлорида
US2616880A (en)	1952-11-04	Shortstopping vinyl chloride polymerizations with conjugated trienic terpenes
US3063977A (en)	1962-11-13	Process for producing copolymers of polyvinylchloride
US4963592A (en)	1990-10-16	Super porous low molecular weight vinyl halide resins