CA1061037A - Methode de production de compositions biodegradables - Google Patents

Methode de production de compositions biodegradables

Info

Publication number: CA1061037A
Authority: CA; Canada
Prior art keywords: auto; oxidative; salt; metal; polyvalent
Prior art date: 1971-09-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA250,163A

Other languages

English (en)

Inventor

James E. Potts

Albert M. Sracic

Stephen W. Cornell

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Union Carbide Corp

Original Assignee

Union Carbide Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1971-09-27

Filing date

1976-04-13

Publication date

1979-08-21

1972-06-28 Priority claimed from US05/267,255 external-priority patent/US3935141A/en

1976-04-13 Application filed by Union Carbide Corp filed Critical Union Carbide Corp

1976-04-13 Priority to CA250,163A priority Critical patent/CA1061037A/fr

1979-08-21 Application granted granted Critical

1979-08-21 Publication of CA1061037A publication Critical patent/CA1061037A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 194
238000000034 method Methods 0.000 title claims abstract description 108
229920000573 polyethylene Polymers 0.000 claims abstract description 134
229910052751 metal Inorganic materials 0.000 claims abstract description 86
239000002184 metal Substances 0.000 claims abstract description 86
239000003963 antioxidant agent Substances 0.000 claims abstract description 62
239000000654 additive Substances 0.000 claims abstract description 60
230000000996 additive effect Effects 0.000 claims abstract description 53
150000003839 salts Chemical class 0.000 claims abstract description 51
230000003078 antioxidant effect Effects 0.000 claims abstract description 45
239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 41
229920000642 polymer Polymers 0.000 claims abstract description 40
238000002156 mixing Methods 0.000 claims abstract description 24
229920006237 degradable polymer Polymers 0.000 claims abstract 3
-1 transition metal salt Chemical class 0.000 claims description 141
239000004743 Polypropylene Substances 0.000 claims description 81
229920001155 polypropylene Polymers 0.000 claims description 74
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 69
229920005989 resin Polymers 0.000 claims description 61
239000011347 resin Substances 0.000 claims description 61
229910017052 cobalt Inorganic materials 0.000 claims description 57
239000010941 cobalt Substances 0.000 claims description 57
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 56
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 45
229910052723 transition metal Inorganic materials 0.000 claims description 29
229910052742 iron Inorganic materials 0.000 claims description 27
239000005977 Ethylene Substances 0.000 claims description 24
150000003624 transition metals Chemical class 0.000 claims description 23
125000005474 octanoate group Chemical group 0.000 claims description 22
229910052799 carbon Inorganic materials 0.000 claims description 21
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 21
150000001721 carbon Chemical group 0.000 claims description 14
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 12
125000005609 naphthenate group Chemical group 0.000 claims description 10
125000004432 carbon atom Chemical group C* 0.000 claims description 9
125000004429 atom Chemical group 0.000 claims description 8
150000002894 organic compounds Chemical class 0.000 claims description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
239000011701 zinc Substances 0.000 claims description 6
229920000233 poly(alkylene oxides) Polymers 0.000 claims description 5
230000027756 respiratory electron transport chain Effects 0.000 claims description 5
239000004711 α-olefin Substances 0.000 claims description 5
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
229920001519 homopolymer Polymers 0.000 claims description 4
238000004519 manufacturing process Methods 0.000 claims description 4
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
229910052725 zinc Inorganic materials 0.000 claims description 4
125000001931 aliphatic group Chemical group 0.000 claims description 3
125000000746 allylic group Chemical group 0.000 claims description 3
125000001743 benzylic group Chemical group 0.000 claims description 3
229920001038 ethylene copolymer Polymers 0.000 claims description 3
150000003384 small molecules Chemical class 0.000 claims description 3
235000021122 unsaturated fatty acids Nutrition 0.000 claims description 3
150000004670 unsaturated fatty acids Chemical class 0.000 claims description 3
230000000593 degrading effect Effects 0.000 claims 4
POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims 2
229920003171 Poly (ethylene oxide) Polymers 0.000 claims 2
150000002739 metals Chemical class 0.000 claims 2
238000005453 pelletization Methods 0.000 claims 2
239000004702 low-density polyethylene Substances 0.000 description 59
229920001684 low density polyethylene Polymers 0.000 description 58
235000006708 antioxidants Nutrition 0.000 description 55
230000006698 induction Effects 0.000 description 43
239000004698 Polyethylene Substances 0.000 description 38
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 37
239000002585 base Substances 0.000 description 35
229910052500 inorganic mineral Inorganic materials 0.000 description 29
239000011707 mineral Substances 0.000 description 29
235000010755 mineral Nutrition 0.000 description 29
MMEDJBFVJUFIDD-UHFFFAOYSA-N 2-[2-(carboxymethyl)phenyl]acetic acid Chemical compound OC(=O)CC1=CC=CC=C1CC(O)=O MMEDJBFVJUFIDD-UHFFFAOYSA-N 0.000 description 28
239000000523 sample Substances 0.000 description 26
239000000243 solution Substances 0.000 description 25
235000015096 spirit Nutrition 0.000 description 23
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 22
238000006731 degradation reaction Methods 0.000 description 21
230000015556 catabolic process Effects 0.000 description 19
238000012360 testing method Methods 0.000 description 19
229940099514 low-density polyethylene Drugs 0.000 description 15
239000002202 Polyethylene glycol Substances 0.000 description 13
230000000694 effects Effects 0.000 description 13
150000002500 ions Chemical class 0.000 description 13
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 11
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
229920001577 copolymer Polymers 0.000 description 10
229920003023 plastic Polymers 0.000 description 10
239000004033 plastic Substances 0.000 description 10
238000013329 compounding Methods 0.000 description 9
230000001590 oxidative effect Effects 0.000 description 9
BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 8
238000005336 cracking Methods 0.000 description 8
239000003381 stabilizer Substances 0.000 description 8
238000003860 storage Methods 0.000 description 8
239000002253 acid Substances 0.000 description 7
150000001868 cobalt Chemical class 0.000 description 7
150000001875 compounds Chemical class 0.000 description 7
GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 7
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 6
QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 6
238000007906 compression Methods 0.000 description 6
230000006835 compression Effects 0.000 description 6
230000007613 environmental effect Effects 0.000 description 6
239000001257 hydrogen Substances 0.000 description 6
229910052739 hydrogen Inorganic materials 0.000 description 6
150000003585 thioureas Chemical class 0.000 description 6
241000518994 Conta Species 0.000 description 5
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
229940011182 cobalt acetate Drugs 0.000 description 5
239000008187 granular material Substances 0.000 description 5
239000000178 monomer Substances 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
239000007787 solid Substances 0.000 description 5
230000006641 stabilisation Effects 0.000 description 5
238000011105 stabilization Methods 0.000 description 5
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
RKBAPHPQTADBIK-UHFFFAOYSA-N cobalt;hexacyanide Chemical compound [Co].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] RKBAPHPQTADBIK-UHFFFAOYSA-N 0.000 description 4
239000013068 control sample Substances 0.000 description 4
OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 4
239000000463 material Substances 0.000 description 4
238000005259 measurement Methods 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
239000006259 organic additive Substances 0.000 description 4
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 4
229920000098 polyolefin Polymers 0.000 description 4
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
229920001897 terpolymer Polymers 0.000 description 4
229920002554 vinyl polymer Polymers 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 3
HQTRGFZLVRBFPT-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)-3-octadecylhenicosane-1,3-diol Chemical compound CCCCCCCCCCCCCCCCCCC(O)(C(CO)(CO)CO)CCCCCCCCCCCCCCCCCC HQTRGFZLVRBFPT-UHFFFAOYSA-N 0.000 description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 3
PRWJPWSKLXYEPD-UHFFFAOYSA-N 4-[4,4-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butan-2-yl]-2-tert-butyl-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(C)CC(C=1C(=CC(O)=C(C=1)C(C)(C)C)C)C1=CC(C(C)(C)C)=C(O)C=C1C PRWJPWSKLXYEPD-UHFFFAOYSA-N 0.000 description 3
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 3
239000003508 Dilauryl thiodipropionate Substances 0.000 description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
AMFIJXSMYBKJQV-UHFFFAOYSA-L cobalt(2+);octadecanoate Chemical compound [Co+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AMFIJXSMYBKJQV-UHFFFAOYSA-L 0.000 description 3
239000000470 constituent Substances 0.000 description 3
235000019304 dilauryl thiodipropionate Nutrition 0.000 description 3
UKRVECBFDMVBPU-UHFFFAOYSA-N ethyl 3-oxoheptanoate Chemical compound CCCCC(=O)CC(=O)OCC UKRVECBFDMVBPU-UHFFFAOYSA-N 0.000 description 3
238000001125 extrusion Methods 0.000 description 3
229920001903 high density polyethylene Polymers 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
FRVCGRDGKAINSV-UHFFFAOYSA-L iron(2+);octadecanoate Chemical compound [Fe+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O FRVCGRDGKAINSV-UHFFFAOYSA-L 0.000 description 3
239000010410 layer Substances 0.000 description 3
239000011572 manganese Substances 0.000 description 3
239000000155 melt Substances 0.000 description 3
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 3
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
239000007800 oxidant agent Substances 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
230000001737 promoting effect Effects 0.000 description 3
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
230000005855 radiation Effects 0.000 description 3
238000009877 rendering Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 3
238000012546 transfer Methods 0.000 description 3
239000011787 zinc oxide Substances 0.000 description 3
CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 3
UAJRSHJHFRVGMG-UHFFFAOYSA-N 1-ethenyl-4-methoxybenzene Chemical compound COC1=CC=C(C=C)C=C1 UAJRSHJHFRVGMG-UHFFFAOYSA-N 0.000 description 2
JLIDVCMBCGBIEY-UHFFFAOYSA-N 1-penten-3-one Chemical compound CCC(=O)C=C JLIDVCMBCGBIEY-UHFFFAOYSA-N 0.000 description 2
YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 2
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
101100069231 Caenorhabditis elegans gkow-1 gene Proteins 0.000 description 2
229910052684 Cerium Inorganic materials 0.000 description 2
229910021556 Chromium(III) chloride Inorganic materials 0.000 description 2
UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 description 2
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Natural products C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 2
238000002835 absorbance Methods 0.000 description 2
230000001133 acceleration Effects 0.000 description 2
125000005907 alkyl ester group Chemical group 0.000 description 2
150000004982 aromatic amines Chemical class 0.000 description 2
UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
239000011575 calcium Substances 0.000 description 2
229910000019 calcium carbonate Inorganic materials 0.000 description 2
229960000359 chromic chloride Drugs 0.000 description 2
QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 2
229920006026 co-polymeric resin Polymers 0.000 description 2
GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 2
FJDJVBXSSLDNJB-LNTINUHCSA-N cobalt;(z)-4-hydroxypent-3-en-2-one Chemical compound [Co].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O FJDJVBXSSLDNJB-LNTINUHCSA-N 0.000 description 2
239000003086 colorant Substances 0.000 description 2
238000000748 compression moulding Methods 0.000 description 2
239000012141 concentrate Substances 0.000 description 2
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
229940076286 cupric acetate Drugs 0.000 description 2
MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 description 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
238000011161 development Methods 0.000 description 2
230000018109 developmental process Effects 0.000 description 2
DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
238000009826 distribution Methods 0.000 description 2
UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 2
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
229920006244 ethylene-ethyl acrylate Polymers 0.000 description 2
229960002089 ferrous chloride Drugs 0.000 description 2
239000008240 homogeneous mixture Substances 0.000 description 2
JCYWCSGERIELPG-UHFFFAOYSA-N imes Chemical class CC1=CC(C)=CC(C)=C1N1C=CN(C=2C(=CC(C)=CC=2C)C)[C]1 JCYWCSGERIELPG-UHFFFAOYSA-N 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
DSSXKBBEJCDMBT-UHFFFAOYSA-M lead(2+);octanoate Chemical compound [Pb+2].CCCCCCCC([O-])=O DSSXKBBEJCDMBT-UHFFFAOYSA-M 0.000 description 2
XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
229910052753 mercury Inorganic materials 0.000 description 2
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230000008859 change Effects 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
FOCAUTSVDIKZOP-UHFFFAOYSA-M chloroacetate Chemical compound [O-]C(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-M 0.000 description 1
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229910052804 chromium Inorganic materials 0.000 description 1
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MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical compound [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 description 1
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230000002596 correlated effect Effects 0.000 description 1
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235000019305 distearyl thiodipropionate Nutrition 0.000 description 1
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125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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230000005865 ionizing radiation Effects 0.000 description 1
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GYCHYNMREWYSKH-UHFFFAOYSA-L iron(ii) bromide Chemical compound [Fe+2].[Br-].[Br-] GYCHYNMREWYSKH-UHFFFAOYSA-L 0.000 description 1
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WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
SZINCDDYCOIOJQ-UHFFFAOYSA-L manganese(2+);octadecanoate Chemical compound [Mn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O SZINCDDYCOIOJQ-UHFFFAOYSA-L 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000002074 melt spinning Methods 0.000 description 1
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230000008018 melting Effects 0.000 description 1
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LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
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WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
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238000003801 milling Methods 0.000 description 1
238000000465 moulding Methods 0.000 description 1
239000002362 mulch Substances 0.000 description 1
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229910052759 nickel Inorganic materials 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
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150000007823 ocimene derivatives Chemical class 0.000 description 1
VRQWWCJWSIOWHG-UHFFFAOYSA-J octadecanoate;zirconium(4+) Chemical compound [Zr+4].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O VRQWWCJWSIOWHG-UHFFFAOYSA-J 0.000 description 1
ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
239000003605 opacifier Substances 0.000 description 1
125000000962 organic group Chemical group 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
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HDBWAWNLGGMZRQ-UHFFFAOYSA-N p-Vinylbiphenyl Chemical compound C1=CC(C=C)=CC=C1C1=CC=CC=C1 HDBWAWNLGGMZRQ-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
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229940059574 pentaerithrityl Drugs 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
229960003330 pentetic acid Drugs 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
229920001568 phenolic resin Polymers 0.000 description 1
150000004986 phenylenediamines Chemical class 0.000 description 1
239000013502 plastic waste Substances 0.000 description 1
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
229920000139 polyethylene terephthalate Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
238000010094 polymer processing Methods 0.000 description 1
229920000306 polymethylpentene Polymers 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
150000003097 polyterpenes Chemical class 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229960001841 potassium permanganate Drugs 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000003244 pro-oxidative effect Effects 0.000 description 1
AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
229920005604 random copolymer Polymers 0.000 description 1
230000000630 rising effect Effects 0.000 description 1
239000011435 rock Substances 0.000 description 1
239000005060 rubber Substances 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
HJHVQCXHVMGZNC-JCJNLNMISA-M sodium;(2z)-2-[(3r,4s,5s,8s,9s,10s,11r,13r,14s,16s)-16-acetyloxy-3,11-dihydroxy-4,8,10,14-tetramethyl-2,3,4,5,6,7,9,11,12,13,15,16-dodecahydro-1h-cyclopenta[a]phenanthren-17-ylidene]-6-methylhept-5-enoate Chemical compound [Na+].O[C@@H]([C@@H]12)C[C@H]3\C(=C(/CCC=C(C)C)C([O-])=O)[C@@H](OC(C)=O)C[C@]3(C)[C@@]2(C)CC[C@@H]2[C@]1(C)CC[C@@H](O)[C@H]2C HJHVQCXHVMGZNC-JCJNLNMISA-M 0.000 description 1
WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 description 1
HUMLQUKVJARKRN-UHFFFAOYSA-M sodium;n,n-dibutylcarbamodithioate Chemical compound [Na+].CCCCN(C([S-])=S)CCCC HUMLQUKVJARKRN-UHFFFAOYSA-M 0.000 description 1
239000002689 soil Substances 0.000 description 1
235000010199 sorbic acid Nutrition 0.000 description 1
239000004334 sorbic acid Substances 0.000 description 1
229940075582 sorbic acid Drugs 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
230000003595 spectral effect Effects 0.000 description 1
238000009987 spinning Methods 0.000 description 1
101150008563 spir gene Proteins 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000001384 succinic acid Substances 0.000 description 1
239000002344 surface layer Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
150000007970 thio esters Chemical class 0.000 description 1
125000003396 thiol group Chemical class [H]S* 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
XJPBRODHZKDRCB-UHFFFAOYSA-N trans-alpha-ocimene Natural products CC(=C)CCC=C(C)C=C XJPBRODHZKDRCB-UHFFFAOYSA-N 0.000 description 1
230000007704 transition Effects 0.000 description 1
238000011282 treatment Methods 0.000 description 1
AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
239000002699 waste material Substances 0.000 description 1
239000011592 zinc chloride Substances 0.000 description 1
235000005074 zinc chloride Nutrition 0.000 description 1
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
229910000368 zinc sulfate Inorganic materials 0.000 description 1
229960001763 zinc sulfate Drugs 0.000 description 1

Landscapes

Processes Of Treating Macromolecular Substances (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA250,163A 1971-09-27 1976-04-13 Methode de production de compositions biodegradables Expired CA1061037A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA250,163A CA1061037A (fr)	1971-09-27	1976-04-13	Methode de production de compositions biodegradables

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US18420671A	1971-09-27	1971-09-27
US05/267,255 US3935141A (en)	1971-09-27	1972-06-28	Environmentally degradable ethylene polymeric compositions
CA150,087A CA1089580A (fr)	1971-09-27	1972-08-24	Produits polymeriques a base d'ethylene qui sont biodegradables
CA250,163A CA1061037A (fr)	1971-09-27	1976-04-13	Methode de production de compositions biodegradables

Publications (1)

Publication Number	Publication Date
CA1061037A true CA1061037A (fr)	1979-08-21

Family

ID=27425617

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA250,163A Expired CA1061037A (fr)	1971-09-27	1976-04-13	Methode de production de compositions biodegradables

Country Status (1)

Country	Link
CA (1)	CA1061037A (fr)

1976
- 1976-04-13 CA CA250,163A patent/CA1061037A/fr not_active Expired

Publication	Publication Date	Title
CA1089580A (fr)	1980-11-11	Produits polymeriques a base d'ethylene qui sont biodegradables
US4067836A (en)	1978-01-10	Environmentally degradable compositions exposed to actinic or ionizing radiation and process
US4540538A (en)	1985-09-10	Anti-block compounds for extrusion of transition metal catalyzed resins
US4412025A (en)	1983-10-25	Anti-block compounds for extrusion of transition metal catalyzed resins
US3825627A (en)	1974-07-23	Ethylene polymer composition having enhanced photodegradability
US4156666A (en)	1979-05-29	Degradable synthetic resin compositions
AU575275B2 (en)	1988-07-21	Photodegrading agent for polymeric compositions
US6197852B1 (en)	2001-03-06	Polyolefin concentrates and composition having improved carbon black dispersion
JP3329458B2 (ja)	2002-09-30	樹脂組成物及び該組成物を用いた成形体
JPWO1993009179A1 (ja)	1993-11-04	樹脂組成物及び該組成物を用いた成形体
US5070129A (en)	1991-12-03	Polyolefin composition containing fluoropolymer
CA1061037A (fr)	1979-08-21	Methode de production de compositions biodegradables
EP0060673B1 (fr)	1986-03-05	Composition de polyoléfines fabriquées par le procédé Ziegler-Natta contenant des agents anti-gel et anti-blocking
US3825626A (en)	1974-07-23	Ethylene polymer composition having enhanced photodegradability
JPH0674348B2 (ja)	1994-09-21	耐候性樹脂組成物
JPH04220446A (ja)	1992-08-11	安定化されたフィルム成形用ポリオレフィン系樹脂組成物
CA2036506C (fr)	1999-02-16	Compositions glissantes, anti-bloquantes et de qualite optique a base de copolymeres d'ethylene de faible cristallinite
JPH07188473A (ja)	1995-07-25	農業用資材
JP2822477B2 (ja)	1998-11-11	熱安定性および耐候性に優れた樹脂組成物
US3755502A (en)	1973-08-28	Blends of polyolefins with isobutene dipentene copolymer and films therefrom
JP4034473B2 (ja)	2008-01-16	押出ラミネート用ポリオレフィン系樹脂材料
JP2962531B2 (ja)	1999-10-12	光崩壊性ポリオレフィン樹脂組成物
EP0565734B1 (fr)	1999-01-27	Composition de resine et piece moulee produite avec ladite resine
JP3424362B2 (ja)	2003-07-07	オレフィン系重合体組成物
JPH06336539A (ja)	1994-12-06	エチレン系樹脂組成物