CA1070088A - Oxydation catalysee d'hydrocarbures halogenes en c2-c4 - Google Patents

Oxydation catalysee d'hydrocarbures halogenes en c2-c4

Info

Publication number: CA1070088A
Authority: CA; Canada
Prior art keywords: catalyst; cobalt; oxide; cobalt oxide; vinyl chloride
Prior art date: 1976-01-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA268,892A

Other languages

English (en)

Inventor

Edward J. Sare

Jerome M. Lavanish

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

PPG Industries Inc

Original Assignee

PPG Industries Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-01-09

Filing date

1976-12-30

Publication date

1980-01-22

1976-11-15 Priority claimed from US05/742,045 external-priority patent/US4065543A/en

1976-12-30 Application filed by PPG Industries Inc filed Critical PPG Industries Inc

1980-01-22 Application granted granted Critical

1980-01-22 Publication of CA1070088A publication Critical patent/CA1070088A/fr

Status Expired legal-status Critical Current

Links

150000008282 halocarbons Chemical class 0.000 title claims abstract description 46
230000003197 catalytic effect Effects 0.000 title abstract description 34
230000003647 oxidation Effects 0.000 title description 10
238000007254 oxidation reaction Methods 0.000 title description 10
239000003054 catalyst Substances 0.000 claims abstract description 187
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims abstract description 122
239000007789 gas Substances 0.000 claims abstract description 111
229910000428 cobalt oxide Inorganic materials 0.000 claims abstract description 108
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 76
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 26
229910052760 oxygen Inorganic materials 0.000 claims abstract description 26
239000001301 oxygen Substances 0.000 claims abstract description 26
-1 vinyl chloride Chemical class 0.000 claims abstract description 11
229930195733 hydrocarbon Natural products 0.000 claims abstract description 10
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 10
238000000034 method Methods 0.000 claims description 69
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 63
230000000694 effects Effects 0.000 claims description 49
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 29
UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(II,III) oxide Inorganic materials [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 claims description 29
229910001868 water Inorganic materials 0.000 claims description 29
238000001035 drying Methods 0.000 claims description 24
LBFUKZWYPLNNJC-UHFFFAOYSA-N cobalt(ii,iii) oxide Chemical compound [Co]=O.O=[Co]O[Co]=O LBFUKZWYPLNNJC-UHFFFAOYSA-N 0.000 claims description 23
230000036571 hydration Effects 0.000 claims description 18
238000006703 hydration reaction Methods 0.000 claims description 18
239000000203 mixture Substances 0.000 claims description 18
UPWOEMHINGJHOB-UHFFFAOYSA-N oxo(oxocobaltiooxy)cobalt Chemical compound O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 claims description 17
UBOXGVDOUJQMTN-UHFFFAOYSA-N 1,1,2-trichloroethane Chemical compound ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 claims description 14
239000012065 filter cake Substances 0.000 claims description 14
IUYLTEAJCNAMJK-UHFFFAOYSA-N cobalt(2+);oxygen(2-) Chemical compound [O-2].[Co+2] IUYLTEAJCNAMJK-UHFFFAOYSA-N 0.000 claims description 13
UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 claims description 12
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 8
150000008280 chlorinated hydrocarbons Chemical class 0.000 claims description 7
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 4
229910052799 carbon Inorganic materials 0.000 claims description 4
239000001569 carbon dioxide Substances 0.000 claims description 4
229910002092 carbon dioxide Inorganic materials 0.000 claims description 4
230000001590 oxidative effect Effects 0.000 claims description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
229910052739 hydrogen Inorganic materials 0.000 claims description 3
239000001257 hydrogen Substances 0.000 claims description 3
VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims description 3
125000001309 chloro group Chemical group Cl* 0.000 claims 1
230000008569 process Effects 0.000 description 29
239000012153 distilled water Substances 0.000 description 24
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
229910017052 cobalt Inorganic materials 0.000 description 19
239000010941 cobalt Substances 0.000 description 19
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 19
239000000047 product Substances 0.000 description 18
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 15
229910052753 mercury Inorganic materials 0.000 description 15
239000002245 particle Substances 0.000 description 15
239000000243 solution Substances 0.000 description 13
229940052308 general anesthetics halogenated hydrocarbons Drugs 0.000 description 12
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
238000002411 thermogravimetry Methods 0.000 description 11
238000002441 X-ray diffraction Methods 0.000 description 10
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 9
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 9
229960002415 trichloroethylene Drugs 0.000 description 9
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 8
229920002554 vinyl polymer Polymers 0.000 description 8
208000016261 weight loss Diseases 0.000 description 8
230000004580 weight loss Effects 0.000 description 8
230000005764 inhibitory process Effects 0.000 description 7
239000008188 pellet Substances 0.000 description 7
239000000376 reactant Substances 0.000 description 7
230000002829 reductive effect Effects 0.000 description 7
235000011121 sodium hydroxide Nutrition 0.000 description 7
MEYVLGVRTYSQHI-UHFFFAOYSA-L cobalt(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Co+2].[O-]S([O-])(=O)=O MEYVLGVRTYSQHI-UHFFFAOYSA-L 0.000 description 6
239000002274 desiccant Substances 0.000 description 6
230000007246 mechanism Effects 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
238000004458 analytical method Methods 0.000 description 5
238000002474 experimental method Methods 0.000 description 5
238000010438 heat treatment Methods 0.000 description 5
229910000041 hydrogen chloride Inorganic materials 0.000 description 5
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 5
239000010410 layer Substances 0.000 description 5
239000004570 mortar (masonry) Substances 0.000 description 5
238000006864 oxidative decomposition reaction Methods 0.000 description 5
238000004611 spectroscopical analysis Methods 0.000 description 5
238000012360 testing method Methods 0.000 description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
DHZSIQDUYCWNSB-UHFFFAOYSA-N chloroethene;1,1-dichloroethene Chemical compound ClC=C.ClC(Cl)=C DHZSIQDUYCWNSB-UHFFFAOYSA-N 0.000 description 4
238000001914 filtration Methods 0.000 description 4
239000000463 material Substances 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
229940110728 nitrogen / oxygen Drugs 0.000 description 4
239000002244 precipitate Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
238000003756 stirring Methods 0.000 description 4
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
238000000441 X-ray spectroscopy Methods 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
239000003518 caustics Substances 0.000 description 3
238000010276 construction Methods 0.000 description 3
230000001419 dependent effect Effects 0.000 description 3
229910001882 dioxygen Inorganic materials 0.000 description 3
238000000921 elemental analysis Methods 0.000 description 3
229910021485 fumed silica Inorganic materials 0.000 description 3
239000007788 liquid Substances 0.000 description 3
229910044991 metal oxide Inorganic materials 0.000 description 3
150000004706 metal oxides Chemical class 0.000 description 3
229910001220 stainless steel Inorganic materials 0.000 description 3
239000010935 stainless steel Substances 0.000 description 3
239000000758 substrate Substances 0.000 description 3
238000005979 thermal decomposition reaction Methods 0.000 description 3
239000002699 waste material Substances 0.000 description 3
PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 description 2
PNLQPWWBHXMFCA-UHFFFAOYSA-N 2-chloroprop-1-ene Chemical compound CC(Cl)=C PNLQPWWBHXMFCA-UHFFFAOYSA-N 0.000 description 2
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 2
CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000003463 adsorbent Substances 0.000 description 2
239000003570 air Substances 0.000 description 2
239000010425 asbestos Substances 0.000 description 2
230000009286 beneficial effect Effects 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000001110 calcium chloride Substances 0.000 description 2
229910001628 calcium chloride Inorganic materials 0.000 description 2
238000001311 chemical methods and process Methods 0.000 description 2
150000001868 cobalt Chemical class 0.000 description 2
KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000007906 compression Methods 0.000 description 2
230000006835 compression Effects 0.000 description 2
239000004035 construction material Substances 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
238000007033 dehydrochlorination reaction Methods 0.000 description 2
CRHLEZORXKQUEI-UHFFFAOYSA-N dialuminum;cobalt(2+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Co+2].[Co+2] CRHLEZORXKQUEI-UHFFFAOYSA-N 0.000 description 2
230000003292 diminished effect Effects 0.000 description 2
125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 2
239000012530 fluid Substances 0.000 description 2
125000005843 halogen group Chemical group 0.000 description 2
229910000039 hydrogen halide Inorganic materials 0.000 description 2
239000012433 hydrogen halide Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
239000012535 impurity Substances 0.000 description 2
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
231100000572 poisoning Toxicity 0.000 description 2
230000000607 poisoning effect Effects 0.000 description 2
230000002035 prolonged effect Effects 0.000 description 2
239000008262 pumice Substances 0.000 description 2
230000009467 reduction Effects 0.000 description 2
230000001105 regulatory effect Effects 0.000 description 2
230000002441 reversible effect Effects 0.000 description 2
229910052895 riebeckite Inorganic materials 0.000 description 2
230000035945 sensitivity Effects 0.000 description 2
229910002027 silica gel Inorganic materials 0.000 description 2
239000000741 silica gel Substances 0.000 description 2
238000005245 sintering Methods 0.000 description 2
238000003860 storage Methods 0.000 description 2
238000005406 washing Methods 0.000 description 2
GHPYJLCQYMAXGG-WCCKRBBISA-N (2R)-2-amino-3-(2-boronoethylsulfanyl)propanoic acid hydrochloride Chemical compound Cl.N[C@@H](CSCCB(O)O)C(O)=O GHPYJLCQYMAXGG-WCCKRBBISA-N 0.000 description 1
OWXJKYNZGFSVRC-NSCUHMNNSA-N (e)-1-chloroprop-1-ene Chemical compound C\C=C\Cl OWXJKYNZGFSVRC-NSCUHMNNSA-N 0.000 description 1
UKDOTCFNLHHKOF-FGRDZWBJSA-N (z)-1-chloroprop-1-ene;(z)-1,2-dichloroethene Chemical group C\C=C/Cl.Cl\C=C/Cl UKDOTCFNLHHKOF-FGRDZWBJSA-N 0.000 description 1
SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
KJDRSWPQXHESDQ-UHFFFAOYSA-N 1,4-dichlorobutane Chemical compound ClCCCCCl KJDRSWPQXHESDQ-UHFFFAOYSA-N 0.000 description 1
IXKYXYVEHROJCV-UHFFFAOYSA-N 1,6-dibromo-1,2,3,3,4,4,5,6,6-nonachlorohex-1-ene Chemical compound ClC(C(Cl)(Cl)Br)C(C(C(=C(Cl)Br)Cl)(Cl)Cl)(Cl)Cl IXKYXYVEHROJCV-UHFFFAOYSA-N 0.000 description 1
CYNYIHKIEHGYOZ-UHFFFAOYSA-N 1-bromopropane Chemical compound CCCBr CYNYIHKIEHGYOZ-UHFFFAOYSA-N 0.000 description 1
SXZSFWHOSHAKMN-UHFFFAOYSA-N 2,3,4,4',5-Pentachlorobiphenyl Chemical compound C1=CC(Cl)=CC=C1C1=CC(Cl)=C(Cl)C(Cl)=C1Cl SXZSFWHOSHAKMN-UHFFFAOYSA-N 0.000 description 1
FALCMQXTWHPRIH-UHFFFAOYSA-N 2,3-dichloroprop-1-ene Chemical compound ClCC(Cl)=C FALCMQXTWHPRIH-UHFFFAOYSA-N 0.000 description 1
229910000619 316 stainless steel Inorganic materials 0.000 description 1
OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
101100191590 Caenorhabditis elegans rpt-2 gene Proteins 0.000 description 1
235000008733 Citrus aurantifolia Nutrition 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
MPCRDALPQLDDFX-UHFFFAOYSA-L Magnesium perchlorate Chemical compound [Mg+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O MPCRDALPQLDDFX-UHFFFAOYSA-L 0.000 description 1
229910000792 Monel Inorganic materials 0.000 description 1
JWOLLWQJKQOEOL-UHFFFAOYSA-N OOOOOOOOOOOOO Chemical compound OOOOOOOOOOOOO JWOLLWQJKQOEOL-UHFFFAOYSA-N 0.000 description 1
ZQTQPYJGMWHXMO-UHFFFAOYSA-N OOOOOOOOOOOOOOOOO Chemical compound OOOOOOOOOOOOOOOOO ZQTQPYJGMWHXMO-UHFFFAOYSA-N 0.000 description 1
239000004734 Polyphenylene sulfide Substances 0.000 description 1
229920013632 Ryton Polymers 0.000 description 1
239000004736 Ryton® Substances 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
235000011941 Tilia x europaea Nutrition 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229940095564 anhydrous calcium sulfate Drugs 0.000 description 1
238000000429 assembly Methods 0.000 description 1
230000000712 assembly Effects 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
230000033228 biological regulation Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
238000007084 catalytic combustion reaction Methods 0.000 description 1
238000003421 catalytic decomposition reaction Methods 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
229910000361 cobalt sulfate Inorganic materials 0.000 description 1
229940044175 cobalt sulfate Drugs 0.000 description 1
FXVNMSSSMOVRTC-UHFFFAOYSA-K cobalt(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[Co+3] FXVNMSSSMOVRTC-UHFFFAOYSA-K 0.000 description 1
229910000335 cobalt(II) sulfate Inorganic materials 0.000 description 1
ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 1
PKSIZOUDEUREFF-UHFFFAOYSA-N cobalt;dihydrate Chemical compound O.O.[Co] PKSIZOUDEUREFF-UHFFFAOYSA-N 0.000 description 1
239000008119 colloidal silica Substances 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
238000010908 decantation Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000005238 degreasing Methods 0.000 description 1
238000007791 dehumidification Methods 0.000 description 1
238000006704 dehydrohalogenation reaction Methods 0.000 description 1
229920006351 engineering plastic Polymers 0.000 description 1
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
239000002360 explosive Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
229910000042 hydrogen bromide Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
238000002955 isolation Methods 0.000 description 1
ULYZAYCEDJDHCC-UHFFFAOYSA-N isopropyl chloride Chemical compound CC(C)Cl ULYZAYCEDJDHCC-UHFFFAOYSA-N 0.000 description 1
239000004571 lime Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000320 mechanical mixture Substances 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
229910001092 metal group alloy Inorganic materials 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910000510 noble metal Inorganic materials 0.000 description 1
150000003891 oxalate salts Chemical class 0.000 description 1
230000036961 partial effect Effects 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920000069 polyphenylene sulfide Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
239000011241 protective layer Substances 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
230000029058 respiratory gaseous exchange Effects 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
238000007789 sealing Methods 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
239000010959 steel Substances 0.000 description 1
239000004575 stone Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
RVUXIPACAZKWHU-UHFFFAOYSA-N sulfuric acid;heptahydrate Chemical compound O.O.O.O.O.O.O.OS(O)(=O)=O RVUXIPACAZKWHU-UHFFFAOYSA-N 0.000 description 1
231100000606 suspected carcinogen Toxicity 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
238000012546 transfer Methods 0.000 description 1
238000009423 ventilation Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B9/00—Component parts for respiratory or breathing apparatus
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8659—Removing halogens or halogen compounds
- B01D53/8662—Organic halogen compounds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665

Landscapes

Engineering & Computer Science (AREA)
Chemical & Material Sciences (AREA)
Environmental & Geological Engineering (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Biomedical Technology (AREA)
Analytical Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Pulmonology (AREA)
General Health & Medical Sciences (AREA)
Business, Economics & Management (AREA)
Emergency Management (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Exhaust Gas Treatment By Means Of Catalyst (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Chemically Coating (AREA)

CA268,892A 1976-01-09 1976-12-30 Oxydation catalysee d'hydrocarbures halogenes en c2-c4 Expired CA1070088A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US64768776A	1976-01-09	1976-01-09
US05/742,045 US4065543A (en)	1976-01-09	1976-11-15	Catalytic oxidation of C2 -C4 halogenated hydrocarbons

Publications (1)

Publication Number	Publication Date
CA1070088A true CA1070088A (fr)	1980-01-22

Family

ID=27095220

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA268,892A Expired CA1070088A (fr)	1976-01-09	1976-12-30	Oxydation catalysee d'hydrocarbures halogenes en c2-c4

Country Status (9)

Country	Link
JP (1)	JPS5287106A (fr)
CA (1)	CA1070088A (fr)
DE (1)	DE2700236C3 (fr)
ES (1)	ES454902A1 (fr)
FR (1)	FR2337707A1 (fr)
GB (1)	GB1543001A (fr)
IT (1)	IT1082502B (fr)
NL (1)	NL7700118A (fr)
NO (1)	NO770055L (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2976041B2 (ja) *	1989-03-06	1999-11-10	工業技術院長	有機ハロゲン化物の除去方法
JP4909473B2 (ja) *	2001-08-31	2012-04-04	三井造船株式会社	排ガス処理触媒
WO2018098450A1 (fr) *	2016-11-28	2018-05-31	Massachusetts Institute Of Technology	Catalyseurs d'oxydation
CN110560063A (zh) *	2019-09-09	2019-12-13	上海纳米技术及应用国家工程研究中心有限公司	高温稳定负载型核壳结构四氧化三钴催化剂及其制备方法和应用
CN112007648A (zh) *	2020-07-29	2020-12-01	合肥皖科凌霄环境科技合伙企业(有限合伙)	一种用于直链烷烃低温催化降解催化剂及其制备方法

1976
- 1976-12-30 CA CA268,892A patent/CA1070088A/fr not_active Expired
1977
- 1977-01-05 DE DE2700236A patent/DE2700236C3/de not_active Expired
- 1977-01-07 NO NO770055A patent/NO770055L/no unknown
- 1977-01-07 NL NL7700118A patent/NL7700118A/xx not_active Application Discontinuation
- 1977-01-07 GB GB454/77A patent/GB1543001A/en not_active Expired
- 1977-01-07 FR FR7700434A patent/FR2337707A1/fr not_active Withdrawn
- 1977-01-07 IT IT67031/77A patent/IT1082502B/it active
- 1977-01-08 JP JP112377A patent/JPS5287106A/ja active Pending
- 1977-01-08 ES ES454902A patent/ES454902A1/es not_active Expired

Also Published As

Publication number	Publication date
DE2700236A1 (de)	1977-07-21
IT1082502B (it)	1985-05-21
ES454902A1 (es)	1977-12-01
NO770055L (no)	1977-07-12
NL7700118A (nl)	1977-07-12
FR2337707A1 (fr)	1977-08-05
DE2700236C3 (de)	1979-01-18
GB1543001A (en)	1979-03-28
JPS5287106A (en)	1977-07-20
DE2700236B2 (de)	1978-05-03

Legal Events

Date	Code	Title	Description
1997-01-22	MKEX	Expiry

Publication	Publication Date	Title
CA1071846A (fr)	1980-02-19	Oxydation catalytique du chlorure de vinyle
US4059677A (en)	1977-11-22	Catalytic oxidation of C2 -C4 halogenated hydrocarbons
EP0033424B1 (fr)	1988-05-11	Elimination de soufre et/ou composés de soufre de courants industriels en utilisant des spinelles d'alumine métalliques
Windawi et al.	1993	Catalytic destruction of halogenated volatile organic compounds
Agarwal et al.	1992	Catalyst deactivation during deep oxidation of chlorohydrocarbons
US4855276A (en)	1989-08-08	Solid filtration medium incorporating alumina and carbon
AU600076B2 (en)	1990-08-02	A process for regenerating a monofunctional large-pore zeolite catalyst having high selectivity for paraffin dehydrocyclization
Oliveira et al.	2008	Catalytic oxidation of aromatic VOCs with Cr or Pd-impregnated Al-pillared bentonite: Byproduct formation and deactivation studies
MXPA02005142A (es)	2002-11-07	Un proceso para la conversion de etileno en cloruro de vinilo, y composiciones catalizadoras novedosas utiles para este proceso.
RU1836312C (ru)	1993-08-23	Способ снижени содержани ненасыщенных примесей в насыщенных фторгалогенуглеродах
CA1075881A (fr)	1980-04-22	Oxydation catalysee des hydrocarbures halogenes en c2,c4
US4059675A (en)	1977-11-22	Decomposition of halogenated organic compounds
CA1066876A (fr)	1979-11-27	Decomposition de composes organiques halogenes
JP4392862B2 (ja)	2010-01-06	溶液から塩素酸イオンを除去するための方法
US4421533A (en)	1983-12-20	Method of removing ozone and composition therefor
JPH10504636A (ja)	1998-05-06	クロム触媒および触媒酸化法
CA1070088A (fr)	1980-01-22	Oxydation catalysee d'hydrocarbures halogenes en c2-c4
KR100376899B1 (ko)	2003-03-19	가스로부터 금속 카르보닐 및 수분의 제거 방법 및 장치
US4065543A (en)	1977-12-27	Catalytic oxidation of C2 -C4 halogenated hydrocarbons
Soares et al.	2016	Oxidation of mixtures of ethyl acetate and butyl acetate over cryptomelane and the effect of water vapor
JP2935524B2 (ja)	1999-08-16	選択的吸着による弗化スルフリルの精製方法
GB2054544A (en)	1981-02-18	Method for purifying boron trichloride
JPS6241488B2 (fr)	1987-09-03
AU769603B2 (en)	2004-01-29	Guard bed containing lead compounds upstream of a bed of copper-containing catalyst to prevent its contamination by chlorine and sulphur contaminants
US6589494B1 (en)	2003-07-08	Process for eliminating halogen-containing compounds contained in a gas or liquid using an adsorbent composition based on at least one metallic element