CA1070896A - Gels polymeriques, hydrophiles d'echange ionique - Google Patents

Gels polymeriques, hydrophiles d'echange ionique

Info

Publication number: CA1070896A
Authority: CA; Canada
Prior art keywords: groups; ionogenous; group; alkylene; parts
Prior art date: 1975-02-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA219,478A

Other languages

English (en)

Other versions

CA219478S (en

Inventor

Jiri Coupek

Otakar Mikes

Petr Strop

Miroslava Krivakova

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Czech Academy of Sciences CAS

Original Assignee

Czech Academy of Sciences CAS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-02-06

Filing date

1975-02-06

Publication date

1980-01-29

1975-02-06 Application filed by Czech Academy of Sciences CAS filed Critical Czech Academy of Sciences CAS

1975-02-06 Priority to CA219,478A priority Critical patent/CA1070896A/fr

1980-01-29 Application granted granted Critical

1980-01-29 Publication of CA1070896A publication Critical patent/CA1070896A/fr

Status Expired legal-status Critical Current

Links

238000005342 ion exchange Methods 0.000 title claims abstract description 13
238000000034 method Methods 0.000 title claims abstract description 10
238000002360 preparation method Methods 0.000 title claims abstract description 9
239000000499 gel Substances 0.000 title description 4
239000000178 monomer Substances 0.000 claims abstract description 28
239000000463 material Substances 0.000 claims abstract description 12
-1 methacryloyl groups Chemical group 0.000 claims abstract description 12
239000010695 polyglycol Substances 0.000 claims abstract description 12
238000007334 copolymerization reaction Methods 0.000 claims abstract description 10
229920000151 polyglycol Polymers 0.000 claims abstract description 10
150000001875 compounds Chemical class 0.000 claims abstract description 9
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims abstract description 8
125000002947 alkylene group Chemical group 0.000 claims abstract description 8
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 6
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 6
239000000725 suspension Substances 0.000 claims abstract description 6
125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 5
125000000217 alkyl group Chemical group 0.000 claims abstract description 4
239000003431 cross linking reagent Substances 0.000 claims abstract description 4
239000003381 stabilizer Substances 0.000 claims abstract description 4
125000004386 diacrylate group Chemical group 0.000 claims abstract description 3
HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 claims description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 8
SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 claims description 6
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
150000001252 acrylic acid derivatives Chemical class 0.000 claims description 4
239000007864 aqueous solution Substances 0.000 claims description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
239000000203 mixture Substances 0.000 claims description 4
150000003926 acrylamides Chemical class 0.000 claims description 3
125000003368 amide group Chemical group 0.000 claims description 3
239000002612 dispersion medium Substances 0.000 claims description 3
239000001257 hydrogen Substances 0.000 claims description 3
229910052739 hydrogen Inorganic materials 0.000 claims description 3
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
150000002734 metacrylic acid derivatives Chemical class 0.000 claims description 3
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical class CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 3
230000008961 swelling Effects 0.000 claims description 3
229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims 1
238000002955 isolation Methods 0.000 abstract description 4
238000013375 chromatographic separation Methods 0.000 abstract description 3
125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 abstract 1
150000001408 amides Chemical class 0.000 abstract 1
125000004103 aminoalkyl group Chemical group 0.000 abstract 1
238000004132 cross linking Methods 0.000 abstract 1
239000006185 dispersion Substances 0.000 abstract 1
229940116441 divinylbenzene Drugs 0.000 abstract 1
229920001522 polyglycol ester Polymers 0.000 abstract 1
150000002500 ions Chemical class 0.000 description 21
239000002245 particle Substances 0.000 description 9
229920000642 polymer Polymers 0.000 description 7
239000001913 cellulose Substances 0.000 description 5
229920002678 cellulose Polymers 0.000 description 5
238000001179 sorption measurement Methods 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 3
239000012634 fragment Substances 0.000 description 3
238000004811 liquid chromatography Methods 0.000 description 3
229920002521 macromolecule Polymers 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
102000039446 nucleic acids Human genes 0.000 description 3
108020004707 nucleic acids Proteins 0.000 description 3
150000007523 nucleic acids Chemical class 0.000 description 3
108090000623 proteins and genes Proteins 0.000 description 3
102000004169 proteins and genes Human genes 0.000 description 3
239000000126 substance Substances 0.000 description 3
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
102000004190 Enzymes Human genes 0.000 description 2
108090000790 Enzymes Proteins 0.000 description 2
WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
230000008859 change Effects 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
239000000835 fiber Substances 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
229940063559 methacrylic acid Drugs 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
229920001184 polypeptide Polymers 0.000 description 2
239000011148 porous material Substances 0.000 description 2
102000004196 processed proteins & peptides Human genes 0.000 description 2
108090000765 processed proteins & peptides Proteins 0.000 description 2
238000005406 washing Methods 0.000 description 2
OLQFXOWPTQTLDP-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCO OLQFXOWPTQTLDP-UHFFFAOYSA-N 0.000 description 1
XNQDKIWPZVPVQD-UHFFFAOYSA-N 2-(2-methylprop-2-enoylamino)ethanesulfonic acid Chemical compound CC(=C)C(=O)NCCS(O)(=O)=O XNQDKIWPZVPVQD-UHFFFAOYSA-N 0.000 description 1
PRAMZQXXPOLCIY-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethanesulfonic acid Chemical compound CC(=C)C(=O)OCCS(O)(=O)=O PRAMZQXXPOLCIY-UHFFFAOYSA-N 0.000 description 1
JVIPLYCGEZUBIO-UHFFFAOYSA-N 2-(4-fluorophenyl)-1,3-dioxoisoindole-5-carboxylic acid Chemical compound O=C1C2=CC(C(=O)O)=CC=C2C(=O)N1C1=CC=C(F)C=C1 JVIPLYCGEZUBIO-UHFFFAOYSA-N 0.000 description 1
QHVBLSNVXDSMEB-UHFFFAOYSA-N 2-(diethylamino)ethyl prop-2-enoate Chemical compound CCN(CC)CCOC(=O)C=C QHVBLSNVXDSMEB-UHFFFAOYSA-N 0.000 description 1
JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
229940095095 2-hydroxyethyl acrylate Drugs 0.000 description 1
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
229920002307 Dextran Polymers 0.000 description 1
229920001425 Diethylaminoethyl cellulose Polymers 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
229910052776 Thorium Inorganic materials 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
229920001807 Urea-formaldehyde Polymers 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
MZVQCMJNVPIDEA-UHFFFAOYSA-N [CH2]CN(CC)CC Chemical group [CH2]CN(CC)CC MZVQCMJNVPIDEA-UHFFFAOYSA-N 0.000 description 1
VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
238000005903 acid hydrolysis reaction Methods 0.000 description 1
238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
244000052616 bacterial pathogen Species 0.000 description 1
230000008901 benefit Effects 0.000 description 1
229920001222 biopolymer Polymers 0.000 description 1
125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
239000013043 chemical agent Substances 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
239000003245 coal Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000003795 desorption Methods 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000004744 fabric Substances 0.000 description 1
239000011888 foil Substances 0.000 description 1
SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000004676 glycans Polymers 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
239000003999 initiator Substances 0.000 description 1
229910001410 inorganic ion Inorganic materials 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
239000012528 membrane Substances 0.000 description 1
230000003340 mental effect Effects 0.000 description 1
SNVLJLYUUXKWOJ-UHFFFAOYSA-N methylidenecarbene Chemical compound C=[C] SNVLJLYUUXKWOJ-UHFFFAOYSA-N 0.000 description 1
244000005700 microbiome Species 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
229920005615 natural polymer Polymers 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
238000012856 packing Methods 0.000 description 1
101150093826 par1 gene Proteins 0.000 description 1
230000035515 penetration Effects 0.000 description 1
229920001568 phenolic resin Polymers 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
150000004804 polysaccharides Polymers 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
230000008569 process Effects 0.000 description 1
238000010526 radical polymerization reaction Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
239000000243 solution Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
229920006027 ternary co-polymer Polymers 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000010936 titanium Substances 0.000 description 1
239000010457 zeolite Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Landscapes

Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CA219,478A 1975-02-06 1975-02-06 Gels polymeriques, hydrophiles d'echange ionique Expired CA1070896A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA219,478A CA1070896A (fr)	1975-02-06	1975-02-06	Gels polymeriques, hydrophiles d'echange ionique

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA219,478A CA1070896A (fr)	1975-02-06	1975-02-06	Gels polymeriques, hydrophiles d'echange ionique

Publications (1)

Publication Number	Publication Date
CA1070896A true CA1070896A (fr)	1980-01-29

Family

ID=4102222

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA219,478A Expired CA1070896A (fr)	1975-02-06	1975-02-06	Gels polymeriques, hydrophiles d'echange ionique

Country Status (1)

Country	Link
CA (1)	CA1070896A (fr)

1975
- 1975-02-06 CA CA219,478A patent/CA1070896A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1997-01-29	MKEX	Expiry

Publication	Publication Date	Title
US4139684A (en)	1979-02-13	Method for preparation of hydrophilic polymeric ion exchanging gels
US4828710A (en)	1989-05-09	Method for the extraction of water from macromolecular solutions
DE69502396T2 (de)	1998-11-26	Polymere adsorbentien mit erhöhter adsorptionskapizität und kinetik und verfahren zu ihrer herstellung
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US7582684B2 (en)	2009-09-01	Macroporous ion exchange resins
JPH0577453B2 (fr)	1993-10-26
US6323249B1 (en)	2001-11-27	Macroporous resins having large pores but with high crush strength
BR8303410A (pt)	1984-02-07	Processo de semeadura para a fabricacao de particulas de copolimero de permuta ionica,reticulada e de particulas de poliestireno reticulada,contas de copolimero,resina de permuta,ionica e processo de remocao de ions de um meio fluido
JPS5833018B2 (ja)	1983-07-16	シンスイセイジユウゴウタイマトリツクスオユウスルリヨウセイイオンコウカンタイノセイゾウホウホウ
US4443366A (en)	1984-04-17	Gel chromatography material
CA1144700A (fr)	1983-04-12	Grands grains de resines echangeuses d'ions, et methode de preparation
JPH01254247A (ja)	1989-10-11	複合化分離剤及びその製造法
US5196527A (en)	1993-03-23	Porous ion-exchanged fine cellulose particles, method for production thereof, and affinity carrier
EP1000660B1 (fr)	2005-03-02	Méthode de préparation d'échangeurs anioniques monodispersés sous forme de gel
US3226380A (en)	1965-12-28	Polyhydroxy materials containing ionexchange groups and non-ionic substituents and their method of preparation
JPH0426321B2 (fr)	1992-05-07
US4238569A (en)	1980-12-09	Preparation of hydrophilic material for gel chromatography
RU2002111890A (ru)	2003-11-10	Способ получения гелеобразных катионитов и их применение в способах обработки и очистки
CA1070896A (fr)	1980-01-29	Gels polymeriques, hydrophiles d'echange ionique
EP0377046A1 (fr)	1990-07-11	Particules fines de cellulose poreuse echangeuse d'ions, procede pour leur production, et porteur d'affinite
DE3427441C2 (fr)	1989-01-26
CA1279307C (fr)	1991-01-22	Materiau composite extra-moleculaire
US4132844A (en)	1979-01-02	Treatment of acrylamide polymer gel
DE2162508A1 (de)	1972-06-29	Verfahren zur Herstellung vernetzter poröser Mischpolymerisate