CA1074509A - Materiaux de renforcement des pneus en polyester fluore - Google Patents
Materiaux de renforcement des pneus en polyester fluoreInfo
- Publication number
- CA1074509A CA1074509A CA236,503A CA236503A CA1074509A CA 1074509 A CA1074509 A CA 1074509A CA 236503 A CA236503 A CA 236503A CA 1074509 A CA1074509 A CA 1074509A
- Authority
- CA
- Canada
- Prior art keywords
- polyester
- fluorination
- fluorine
- fabric
- cord
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 66
- 230000002787 reinforcement Effects 0.000 title claims description 27
- 239000000463 material Substances 0.000 title claims description 25
- 239000004744 fabric Substances 0.000 claims abstract description 24
- 239000005060 rubber Substances 0.000 claims abstract description 14
- 229920001971 elastomer Polymers 0.000 claims abstract description 13
- 238000003682 fluorination reaction Methods 0.000 claims description 48
- 229910052731 fluorine Inorganic materials 0.000 claims description 32
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 30
- 239000011737 fluorine Substances 0.000 claims description 30
- 238000011282 treatment Methods 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 21
- 239000001301 oxygen Substances 0.000 claims description 17
- 229910052760 oxygen Inorganic materials 0.000 claims description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 14
- 239000007789 gas Substances 0.000 claims description 11
- 239000004816 latex Substances 0.000 claims description 9
- 229920000126 latex Polymers 0.000 claims description 9
- 239000002318 adhesion promoter Substances 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 230000006872 improvement Effects 0.000 claims description 3
- DGXAGETVRDOQFP-UHFFFAOYSA-N 2,6-dihydroxybenzaldehyde Chemical group OC1=CC=CC(O)=C1C=O DGXAGETVRDOQFP-UHFFFAOYSA-N 0.000 claims 2
- 239000000203 mixture Substances 0.000 description 25
- 239000000835 fiber Substances 0.000 description 21
- 150000007942 carboxylates Chemical group 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000009472 formulation Methods 0.000 description 7
- 239000012159 carrier gas Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 5
- 239000002344 surface layer Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000006473 carboxylation reaction Methods 0.000 description 3
- 238000005660 chlorination reaction Methods 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 239000012495 reaction gas Substances 0.000 description 3
- 238000010058 rubber compounding Methods 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000021523 carboxylation Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BUZICZZQJDLXJN-UHFFFAOYSA-N 3-azaniumyl-4-hydroxybutanoate Chemical compound OCC(N)CC(O)=O BUZICZZQJDLXJN-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical group F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 229910000792 Monel Inorganic materials 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000012668 chain scission Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/126—Halogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Reinforced Plastic Materials (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/531,854 US4009304A (en) | 1971-09-30 | 1974-12-12 | Fluorinated polyester tire reinforcement materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1074509A true CA1074509A (fr) | 1980-04-01 |
Family
ID=24119332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA236,503A Expired CA1074509A (fr) | 1974-12-12 | 1975-09-26 | Materiaux de renforcement des pneus en polyester fluore |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5171386A (fr) |
| BE (1) | BE836360A (fr) |
| CA (1) | CA1074509A (fr) |
| DE (1) | DE2546426A1 (fr) |
| FR (1) | FR2294206A1 (fr) |
| GB (1) | GB1501954A (fr) |
| NL (1) | NL7514370A (fr) |
| SE (1) | SE7510920L (fr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4105179A1 (de) * | 1991-02-20 | 1992-08-27 | Ahlbrandt System Gmbh | Verfahren zur behandlung von gegenstaenden mit einem fluor enthaltenden gas sowie vorrichtung zu seiner durchfuehrung |
| JP4638995B2 (ja) * | 2001-03-30 | 2011-02-23 | 株式会社クラレ | 成形体およびその製造方法 |
| US8440047B2 (en) | 2007-05-23 | 2013-05-14 | Fenner U.S., Inc. | Method for producing a stretch resistant belt |
-
1975
- 1975-09-26 CA CA236,503A patent/CA1074509A/fr not_active Expired
- 1975-09-30 SE SE7510920A patent/SE7510920L/xx not_active Application Discontinuation
- 1975-10-08 JP JP12082875A patent/JPS5171386A/ja active Pending
- 1975-10-13 GB GB4186275A patent/GB1501954A/en not_active Expired
- 1975-10-16 DE DE19752546426 patent/DE2546426A1/de active Pending
- 1975-11-24 FR FR7535777A patent/FR2294206A1/fr active Granted
- 1975-12-08 BE BE2054700A patent/BE836360A/fr unknown
- 1975-12-09 NL NL7514370A patent/NL7514370A/xx not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| FR2294206B1 (fr) | 1979-03-16 |
| JPS5171386A (ja) | 1976-06-21 |
| BE836360A (fr) | 1976-04-01 |
| DE2546426A1 (de) | 1976-06-16 |
| SE7510920L (sv) | 1976-06-14 |
| GB1501954A (en) | 1978-02-22 |
| NL7514370A (nl) | 1976-06-15 |
| FR2294206A1 (fr) | 1976-07-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4009304A (en) | Fluorinated polyester tire reinforcement materials | |
| EP2151520B1 (fr) | Elément de renforcement du caoutchouc et produit en caoutchouc l'utilisant | |
| CA2638611A1 (fr) | Agent de traitement aqueux permettant de renforcer des fibres | |
| KR20170085882A (ko) | 폴리에스테르 섬유, 이의 제조방법 및 이를 포함하는 타이어 코드 | |
| JP4565537B2 (ja) | ゴム補強用ポリエステル繊維コードの製造方法 | |
| CA1074509A (fr) | Materiaux de renforcement des pneus en polyester fluore | |
| CA2245609A1 (fr) | Fil de renforcement en carbone, multi-filament, enduit | |
| JP3201330B2 (ja) | ゴム補強用コードおよびその処理剤 | |
| EP0937740B1 (fr) | Corde pour renforcer un caoutchouc et matériaux de traitement de cette corde | |
| US7267843B2 (en) | Textile fabric and yarn composed of synthetic fibers, preparation thereof and use thereof | |
| JP3379142B2 (ja) | ナイロン66ゴム補強用コード | |
| US5154975A (en) | Liquid composition for glass fiber impregnation | |
| US3930095A (en) | Composite of rubber bonded to glass fibers | |
| US3716396A (en) | Process for producing polyesters of improved rubber adhesion and product | |
| US5236742A (en) | Liquid composition for glass fiber impregnation | |
| US3272676A (en) | Method of effecting the adhesion of polyester materials to rubbers | |
| US3284278A (en) | Process for the adhesive bodying of olefin copolymers to synthetic and natural fibers and shaped articles obtained therefrom | |
| JPS595601B2 (ja) | 合成樹脂及び合成繊維の弗素化及びスルホ弗素化 | |
| JP4465514B2 (ja) | ポリエステル繊維コードの処理方法 | |
| JPWO2006051873A1 (ja) | ゴム補強用コードおよびその製造方法ならびにそれを用いたゴム製品 | |
| US3955033A (en) | Adhesion of glass fibers to rubber | |
| JP3030999B2 (ja) | ゴム補強用ポリエステル繊維の処理方法 | |
| JP2894798B2 (ja) | ゴム補強用ガラス繊維の処理剤 | |
| KR20030093950A (ko) | 직물용 함침 및 결합제 | |
| JP3360605B2 (ja) | ゴム補強用コードおよびその処理剤 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |