CA1074509A - Materiaux de renforcement des pneus en polyester fluore - Google Patents

Materiaux de renforcement des pneus en polyester fluore

Info

Publication number: CA1074509A
Authority: CA; Canada
Prior art keywords: polyester; fluorination; fluorine; fabric; cord
Prior art date: 1974-12-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA236,503A

Other languages

English (en)

Other versions

CA236503S (en

Inventor

Dale D. Dixon

William M. Smith (Jr.)

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Air Products and Chemicals Inc

Original Assignee

Air Products and Chemicals Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-12-12

Filing date

1975-09-26

Publication date

1980-04-01

1974-12-12 Priority claimed from US05/531,854 external-priority patent/US4009304A/en

1975-09-26 Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc

1980-04-01 Application granted granted Critical

1980-04-01 Publication of CA1074509A publication Critical patent/CA1074509A/fr

Status Expired legal-status Critical Current

Links

229920000728 polyester Polymers 0.000 title claims abstract description 66
230000002787 reinforcement Effects 0.000 title claims description 27
239000000463 material Substances 0.000 title claims description 25
239000004744 fabric Substances 0.000 claims abstract description 24
239000005060 rubber Substances 0.000 claims abstract description 14
229920001971 elastomer Polymers 0.000 claims abstract description 13
238000003682 fluorination reaction Methods 0.000 claims description 48
229910052731 fluorine Inorganic materials 0.000 claims description 32
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 30
239000011737 fluorine Substances 0.000 claims description 30
238000011282 treatment Methods 0.000 claims description 24
238000000034 method Methods 0.000 claims description 21
239000001301 oxygen Substances 0.000 claims description 17
229910052760 oxygen Inorganic materials 0.000 claims description 17
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 16
230000008569 process Effects 0.000 claims description 14
239000007789 gas Substances 0.000 claims description 11
239000004816 latex Substances 0.000 claims description 9
229920000126 latex Polymers 0.000 claims description 9
239000002318 adhesion promoter Substances 0.000 claims description 6
150000002148 esters Chemical class 0.000 claims description 5
239000011248 coating agent Substances 0.000 claims description 3
238000000576 coating method Methods 0.000 claims description 3
230000006872 improvement Effects 0.000 claims description 3
DGXAGETVRDOQFP-UHFFFAOYSA-N 2,6-dihydroxybenzaldehyde Chemical group OC1=CC=CC(O)=C1C=O DGXAGETVRDOQFP-UHFFFAOYSA-N 0.000 claims 2
239000000203 mixture Substances 0.000 description 25
239000000835 fiber Substances 0.000 description 21
150000007942 carboxylates Chemical group 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
238000012360 testing method Methods 0.000 description 8
238000009472 formulation Methods 0.000 description 7
239000012159 carrier gas Substances 0.000 description 6
238000005259 measurement Methods 0.000 description 5
239000002344 surface layer Substances 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 4
230000035484 reaction time Effects 0.000 description 4
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
239000000853 adhesive Substances 0.000 description 3
230000001070 adhesive effect Effects 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
238000006473 carboxylation reaction Methods 0.000 description 3
238000005660 chlorination reaction Methods 0.000 description 3
125000001153 fluoro group Chemical group F* 0.000 description 3
239000012948 isocyanate Substances 0.000 description 3
150000002513 isocyanates Chemical class 0.000 description 3
239000012495 reaction gas Substances 0.000 description 3
238000010058 rubber compounding Methods 0.000 description 3
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
239000004677 Nylon Substances 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
230000002411 adverse Effects 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
230000021523 carboxylation Effects 0.000 description 2
238000009792 diffusion process Methods 0.000 description 2
239000012153 distilled water Substances 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000010410 layer Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
229920001778 nylon Polymers 0.000 description 2
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000005406 washing Methods 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
BUZICZZQJDLXJN-UHFFFAOYSA-N 3-azaniumyl-4-hydroxybutanoate Chemical compound OCC(N)CC(O)=O BUZICZZQJDLXJN-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
229920013683 Celanese Polymers 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical group F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
238000004566 IR spectroscopy Methods 0.000 description 1
229910000792 Monel Inorganic materials 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
230000004913 activation Effects 0.000 description 1
238000004026 adhesive bonding Methods 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
238000013459 approach Methods 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
230000005540 biological transmission Effects 0.000 description 1
238000012668 chain scission Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000001186 cumulative effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
230000008034 disappearance Effects 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
239000008246 gaseous mixture Substances 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229920002521 macromolecule Polymers 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
238000013508 migration Methods 0.000 description 1
230000005012 migration Effects 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
238000000465 moulding Methods 0.000 description 1
229920003052 natural elastomer Polymers 0.000 description 1
229920001194 natural rubber Polymers 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
230000035515 penetration Effects 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
238000012545 processing Methods 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
239000002356 single layer Substances 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
238000004448 titration Methods 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/126—Halogenation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Polymers & Plastics (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Materials Engineering (AREA)
Manufacturing & Machinery (AREA)
General Chemical & Material Sciences (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Reinforced Plastic Materials (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
Treatments Of Macromolecular Shaped Articles (AREA)
Lining Or Joining Of Plastics Or The Like (AREA)

CA236,503A 1974-12-12 1975-09-26 Materiaux de renforcement des pneus en polyester fluore Expired CA1074509A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US05/531,854 US4009304A (en)	1971-09-30	1974-12-12	Fluorinated polyester tire reinforcement materials

Publications (1)

Publication Number	Publication Date
CA1074509A true CA1074509A (fr)	1980-04-01

Family

ID=24119332

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA236,503A Expired CA1074509A (fr)	1974-12-12	1975-09-26	Materiaux de renforcement des pneus en polyester fluore

Country Status (8)

Country	Link
JP (1)	JPS5171386A (fr)
BE (1)	BE836360A (fr)
CA (1)	CA1074509A (fr)
DE (1)	DE2546426A1 (fr)
FR (1)	FR2294206A1 (fr)
GB (1)	GB1501954A (fr)
NL (1)	NL7514370A (fr)
SE (1)	SE7510920L (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4105179A1 (de) *	1991-02-20	1992-08-27	Ahlbrandt System Gmbh	Verfahren zur behandlung von gegenstaenden mit einem fluor enthaltenden gas sowie vorrichtung zu seiner durchfuehrung
JP4638995B2 (ja) *	2001-03-30	2011-02-23	株式会社クラレ	成形体およびその製造方法
US8440047B2 (en)	2007-05-23	2013-05-14	Fenner U.S., Inc.	Method for producing a stretch resistant belt

1975
- 1975-09-26 CA CA236,503A patent/CA1074509A/fr not_active Expired
- 1975-09-30 SE SE7510920A patent/SE7510920L/xx not_active Application Discontinuation
- 1975-10-08 JP JP12082875A patent/JPS5171386A/ja active Pending
- 1975-10-13 GB GB4186275A patent/GB1501954A/en not_active Expired
- 1975-10-16 DE DE19752546426 patent/DE2546426A1/de active Pending
- 1975-11-24 FR FR7535777A patent/FR2294206A1/fr active Granted
- 1975-12-08 BE BE2054700A patent/BE836360A/fr unknown
- 1975-12-09 NL NL7514370A patent/NL7514370A/xx not_active Application Discontinuation

Also Published As

Publication number	Publication date
FR2294206B1 (fr)	1979-03-16
SE7510920L (sv)	1976-06-14
DE2546426A1 (de)	1976-06-16
GB1501954A (en)	1978-02-22
FR2294206A1 (fr)	1976-07-09
JPS5171386A (ja)	1976-06-21
BE836360A (fr)	1976-04-01
NL7514370A (nl)	1976-06-15

Legal Events

Date	Code	Title	Description
1997-04-01	MKEX	Expiry

Publication	Publication Date	Title
US4009304A (en)	1977-02-22	Fluorinated polyester tire reinforcement materials
US8222328B2 (en)	2012-07-17	Reinforcing sheet for reinforcing toothed belt, and toothed belt and method for production thereof
EP2151520B1 (fr)	2013-09-18	Elément de renforcement du caoutchouc et produit en caoutchouc l'utilisant
JP4565537B2 (ja)	2010-10-20	ゴム補強用ポリエステル繊維コードの製造方法
CA1074509A (fr)	1980-04-01	Materiaux de renforcement des pneus en polyester fluore
CA2245609A1 (fr)	1999-03-12	Fil de renforcement en carbone, multi-filament, enduit
JP3201330B2 (ja)	2001-08-20	ゴム補強用コードおよびその処理剤
US7267843B2 (en)	2007-09-11	Textile fabric and yarn composed of synthetic fibers, preparation thereof and use thereof
CA2471447C (fr)	2012-02-21	Fibre pour renforcer des produits a base de caoutchouc
JP3379142B2 (ja)	2003-02-17	ナイロン６６ゴム補強用コード
US5154975A (en)	1992-10-13	Liquid composition for glass fiber impregnation
US3930095A (en)	1975-12-30	Composite of rubber bonded to glass fibers
US3716396A (en)	1973-02-13	Process for producing polyesters of improved rubber adhesion and product
US4246144A (en)	1981-01-20	Modified phenolic aldehyde resin to produce an improved adhesive coating and method of making same
US5236742A (en)	1993-08-17	Liquid composition for glass fiber impregnation
US3272676A (en)	1966-09-13	Method of effecting the adhesion of polyester materials to rubbers
US3284278A (en)	1966-11-08	Process for the adhesive bodying of olefin copolymers to synthetic and natural fibers and shaped articles obtained therefrom
JPS595601B2 (ja)	1984-02-06	合成樹脂及び合成繊維の弗素化及びスルホ弗素化
EP0084453B1 (fr)	1989-10-25	Procédé pour renforcer du caoutchouc avec des fibres
US4238595A (en)	1980-12-09	Modified phenolic aldehyde resin to produce an improved adhesive coating and method of making same
JP4465514B2 (ja)	2010-05-19	ポリエステル繊維コードの処理方法
JPWO2006051873A1 (ja)	2008-08-07	ゴム補強用コードおよびその製造方法ならびにそれを用いたゴム製品
CA2428327A1 (fr)	2003-12-03	Agent d'impregnation et de liage pour textiles
JP3360605B2 (ja)	2002-12-24	ゴム補強用コードおよびその処理剤
Yilmaz	2009	Investigation into the effects of accelerated aging conditions on adhesion of Resorcinol–Formaldehyde–Latex treated synthetic cords