CA1081196A - Production d'hydrocarbures et catalyseur - Google Patents

Production d'hydrocarbures et catalyseur

Info

Publication number: CA1081196A
Authority: CA; Canada
Prior art keywords: catalyst; hydrocarbons; zeolite; silica; iron
Prior art date: 1975-08-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA256,743A

Other languages

English (en)

Inventor

Charles M. Bartish

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Air Products and Chemicals Inc

Original Assignee

Air Products and Chemicals Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-08-14

Filing date

1976-07-12

Publication date

1980-07-08

1975-08-14 Priority claimed from US05/604,633 external-priority patent/US4131568A/en

1976-07-12 Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc

1980-07-08 Application granted granted Critical

1980-07-08 Publication of CA1081196A publication Critical patent/CA1081196A/fr

Status Expired legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 65
150000002430 hydrocarbons Chemical class 0.000 title abstract description 59
229930195733 hydrocarbon Natural products 0.000 title abstract description 58
238000000034 method Methods 0.000 title abstract description 15
239000010457 zeolite Substances 0.000 claims abstract description 54
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 50
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 48
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 44
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 34
229910052742 iron Inorganic materials 0.000 claims abstract description 22
239000000203 mixture Substances 0.000 claims abstract description 22
239000010949 copper Substances 0.000 claims abstract description 20
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 19
229910052802 copper Inorganic materials 0.000 claims abstract description 19
229910052680 mordenite Inorganic materials 0.000 claims description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
238000006243 chemical reaction Methods 0.000 abstract description 26
239000003502 gasoline Substances 0.000 abstract description 18
239000002283 diesel fuel Substances 0.000 abstract description 15
239000007788 liquid Substances 0.000 abstract description 11
239000004215 Carbon black (E152) Substances 0.000 abstract description 8
230000002194 synthesizing effect Effects 0.000 abstract description 6
230000003197 catalytic effect Effects 0.000 abstract description 5
208000036366 Sensation of pressure Diseases 0.000 abstract 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 31
229910002091 carbon monoxide Inorganic materials 0.000 description 25
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 23
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 21
IYRDVAUFQZOLSB-UHFFFAOYSA-N copper iron Chemical compound [Fe].[Cu] IYRDVAUFQZOLSB-UHFFFAOYSA-N 0.000 description 17
230000015572 biosynthetic process Effects 0.000 description 16
239000001257 hydrogen Substances 0.000 description 16
229910052739 hydrogen Inorganic materials 0.000 description 16
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 15
239000007789 gas Substances 0.000 description 9
239000000377 silicon dioxide Substances 0.000 description 9
238000003786 synthesis reaction Methods 0.000 description 8
239000000047 product Substances 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
239000003921 oil Substances 0.000 description 6
150000001336 alkenes Chemical class 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
239000000446 fuel Substances 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
239000001993 wax Substances 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 3
150000001879 copper Chemical class 0.000 description 3
238000009740 moulding (composite fabrication) Methods 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
239000011734 sodium Substances 0.000 description 3
229910000029 sodium carbonate Inorganic materials 0.000 description 3
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
150000001299 aldehydes Chemical class 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000003245 coal Substances 0.000 description 2
239000012153 distilled water Substances 0.000 description 2
238000009826 distribution Methods 0.000 description 2
229940096405 magnesium cation Drugs 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
239000012188 paraffin wax Substances 0.000 description 2
235000019809 paraffin wax Nutrition 0.000 description 2
239000002245 particle Substances 0.000 description 2
235000019271 petrolatum Nutrition 0.000 description 2
-1 postassium Chemical compound 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
230000001376 precipitating effect Effects 0.000 description 2
230000001105 regulatory effect Effects 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
229910000608 Fe(NO3)3.9H2O Inorganic materials 0.000 description 1
229910002549 Fe–Cu Inorganic materials 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
229910052908 analcime Inorganic materials 0.000 description 1
238000001354 calcination Methods 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
238000005336 cracking Methods 0.000 description 1
239000010779 crude oil Substances 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000012013 faujasite Substances 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
229910001657 ferrierite group Inorganic materials 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
229910052909 inorganic silicate Inorganic materials 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229910052674 natrolite Inorganic materials 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
239000006069 physical mixture Substances 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
235000015320 potassium carbonate Nutrition 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
229910001388 sodium aluminate Inorganic materials 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
- B01J29/14—Iron group metals or copper
- B01J29/146—Y-type faujasite
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
- B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
- B01J29/24—Iron group metals or copper
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
- C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
- C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0455—Reaction conditions
- C07C1/046—Numerical values of parameters
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/72—Copper
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- C07C2529/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
- C07C2529/14—Iron group metals or copper
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
- C07C2529/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
- C07C2529/24—Iron group metals or copper
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Crystallography & Structural Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA256,743A 1975-08-14 1976-07-12 Production d'hydrocarbures et catalyseur Expired CA1081196A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US05/604,633 US4131568A (en)	1975-08-14	1975-08-14	Catalytic synthesis of low molecular weight hydrocarbons
US64431375A	1975-12-24	1975-12-24

Publications (1)

Publication Number	Publication Date
CA1081196A true CA1081196A (fr)	1980-07-08

Family

ID=27084707

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA256,743A Expired CA1081196A (fr)	1975-08-14	1976-07-12	Production d'hydrocarbures et catalyseur

Country Status (4)

Country	Link
CA (1)	CA1081196A (fr)
DE (1)	DE2636282A1 (fr)
FR (1)	FR2320923A1 (fr)
GB (1)	GB1547247A (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL7711350A (nl) *	1977-10-17	1979-04-19	Shell Int Research	Werkwijze voor de bereiding van koolwaterstoffen.
FR2538266B2 (fr) *	1982-01-14	1986-12-05	Azote & Prod Chim	Catalyseurs de conversion du gaz de synthese
DE3360034D1 (en) *	1982-01-14	1985-02-07	Azote & Prod Chim	Synthesis gas conversion catalysts
FR2529099B2 (fr) *	1982-06-25	1986-03-21	Azote & Prod Chim	Catalyseurs de conversion du gaz de synthese
FR2519563B1 (fr) *	1982-01-14	1986-01-10	Azote & Prod Chim	Catalyseurs de conversion du gaz de synthese
JPS6023330A (ja) *	1983-07-15	1985-02-05	Daido Sanso Kk	炭化水素の製造方法
EP0154063A1 (fr) *	1984-03-01	1985-09-11	The Standard Oil Company	Catalyseur silicalite modifié, sa préparation et procédé pour son utilisation
US5344849A (en) *	1990-10-31	1994-09-06	Canada Chemical Corporation	Catalytic process for the production of hydrocarbons

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL73958C (fr) *		1900-01-01
DE1061306B (de) *	1952-03-17	1959-07-16	Ruhrchemie Ag	Verfahren und Vorrichtung zur Kohlenoxydhydrierung unter Verwendung kupferhaltiger Eisen-Sinterkatalysatoren

1976
- 1976-07-12 CA CA256,743A patent/CA1081196A/fr not_active Expired
- 1976-08-03 GB GB32320/76A patent/GB1547247A/en not_active Expired
- 1976-08-11 FR FR7625266A patent/FR2320923A1/fr active Granted
- 1976-08-12 DE DE19762636282 patent/DE2636282A1/de not_active Withdrawn

Also Published As

Publication number	Publication date
GB1547247A (en)	1979-06-06
FR2320923B1 (fr)	1980-06-20
FR2320923A1 (fr)	1977-03-11
DE2636282A1 (de)	1977-02-24

Legal Events

Date	Code	Title	Description
1997-07-08	MKEX	Expiry

Publication	Publication Date	Title
EP0020141B1 (fr)	1982-08-11	Conversion du gaz de synthèse en mélanges d'hydrocarbures en utilisant deux réacteurs
US5504118A (en)	1996-04-02	Process for the production of hydrocarbons
US4131568A (en)	1978-12-26	Catalytic synthesis of low molecular weight hydrocarbons
US5621155A (en)	1997-04-15	Process for the production of hydrocarbons
US5543437A (en)	1996-08-06	Process for the production of hydrocarbons
US4423265A (en)	1983-12-27	Process for snygas conversions to liquid hydrocarbon products
US5645613A (en)	1997-07-08	Process for the production of hydrocarbons
US2686195A (en)	1954-08-10	Hydrocarbon synthesis
JPS5839131B2 (ja)	1983-08-27	ゴウセイガスオタンカスイソコンゴウブツヘテンカスルホウホウ
EP4046710A1 (fr)	2022-08-24	Catalyseur à base de fer coeur-coquille utilisé pour la production directe d'hydrocarbures aromatiques à partir de gaz de synthèse, et son procédé de préparation et son application
WO1995020558A1 (fr)	1995-08-03	Procede pour la production d'hydrocarbures
GB2099716A (en)	1982-12-15	Fischer-tropsch catalyst for the production of hydrocarbons from synthesis gas
EP0188530A1 (fr)	1986-07-30	Conversion amelioree de gaz de synthese en carburants liquides pour moteurs.
US4443561A (en)	1984-04-17	Process for the preparation of organic compounds
US5126377A (en)	1992-06-30	Catalyst for conversion of synthesis gas into hydrocarbons
US4340503A (en)	1982-07-20	Catalyst for converting synthesis gas to light olefins
US4617288A (en)	1986-10-14	Low nitrogen iron-containing Fischer-Tropsch catalyst for conversion of synthesis gas and process for preparing the catalyst
US4906671A (en)	1990-03-06	Fischer-tropsch process
CA1081196A (fr)	1980-07-08	Production d'hydrocarbures et catalyseur
US4595702A (en)	1986-06-17	Conversion of synthesis gas to liquid hydrocarbons
US4659743A (en)	1987-04-21	Process and catalyst for converting synthesis gas to liquid hydrocarbon mixture
GB2169919A (en)	1986-07-23	Process for the preparation of hydrocarbons
Dry	1989	Commercial conversion of carbon monoxide to fuels and chemicals
US2735862A (en)	1956-02-21	Synthesis of hydrocarbons with iron-cobalt catalyst
CA1175862A (fr)	1984-10-09	Conversion de produits de synthese fisher-tropsch en benzene, xylene et toluene