CA1086433A - Flottation de charbon oxyde grace a une emulsion du type latex de polyacrylate de sodium - Google Patents

Flottation de charbon oxyde grace a une emulsion du type latex de polyacrylate de sodium

Info

Publication number: CA1086433A
Authority: CA; Canada
Prior art keywords: coal; sodium polyacrylate; water; emulsion; oil
Prior art date: 1977-06-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA284,075A

Other languages

English (en)

Inventor

Robert E. Finch

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ChampionX LLC

Original Assignee

Nalco Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-06-20

Filing date

1977-08-04

Publication date

1980-09-23

1977-08-04 Application filed by Nalco Chemical Co filed Critical Nalco Chemical Co

1980-09-23 Application granted granted Critical

1980-09-23 Publication of CA1086433A publication Critical patent/CA1086433A/fr

Status Expired legal-status Critical Current

Links

239000003245 coal Substances 0.000 title claims abstract description 86
229920001495 poly(sodium acrylate) polymer Polymers 0.000 title claims abstract description 37
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 title claims abstract description 37
239000000839 emulsion Substances 0.000 title claims abstract description 28
238000005188 flotation Methods 0.000 title claims abstract description 21
239000004816 latex Substances 0.000 title abstract description 22
229920000126 latex Polymers 0.000 title abstract description 22
238000000034 method Methods 0.000 claims abstract description 19
239000002245 particle Substances 0.000 claims abstract description 13
239000003795 chemical substances by application Substances 0.000 claims abstract description 12
238000009291 froth flotation Methods 0.000 claims abstract description 10
239000007762 w/o emulsion Substances 0.000 claims abstract description 10
239000002904 solvent Substances 0.000 claims abstract description 5
230000002209 hydrophobic effect Effects 0.000 claims abstract description 4
239000003381 stabilizer Substances 0.000 claims abstract description 4
239000003995 emulsifying agent Substances 0.000 claims abstract description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
239000012190 activator Substances 0.000 claims description 7
239000007788 liquid Substances 0.000 claims description 4
239000004094 surface-active agent Substances 0.000 claims description 4
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
239000008346 aqueous phase Substances 0.000 claims description 3
239000007764 o/w emulsion Substances 0.000 claims description 2
230000000087 stabilizing effect Effects 0.000 claims description 2
229920000642 polymer Polymers 0.000 abstract description 15
239000000203 mixture Substances 0.000 abstract description 9
ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 abstract description 4
239000001593 sorbitan monooleate Substances 0.000 abstract description 4
229940035049 sorbitan monooleate Drugs 0.000 abstract description 4
235000011069 sorbitan monooleate Nutrition 0.000 abstract description 4
229920002367 Polyisobutene Polymers 0.000 abstract description 2
CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 abstract description 2
125000003118 aryl group Chemical group 0.000 abstract description 2
239000012188 paraffin wax Substances 0.000 abstract description 2
238000011084 recovery Methods 0.000 description 16
241000196324 Embryophyta Species 0.000 description 11
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
-1 depressants Substances 0.000 description 6
239000001301 oxygen Substances 0.000 description 6
229910052760 oxygen Inorganic materials 0.000 description 6
239000007787 solid Substances 0.000 description 6
WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 5
NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 4
125000000129 anionic group Chemical group 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000000178 monomer Substances 0.000 description 4
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
239000000295 fuel oil Substances 0.000 description 3
229910052500 inorganic mineral Inorganic materials 0.000 description 3
239000011707 mineral Substances 0.000 description 3
235000010755 mineral Nutrition 0.000 description 3
229920002401 polyacrylamide Polymers 0.000 description 3
229920000058 polyacrylate Polymers 0.000 description 3
229940070721 polyacrylate Drugs 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000002002 slurry Substances 0.000 description 3
239000007858 starting material Substances 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
230000002939 deleterious effect Effects 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
239000003607 modifier Substances 0.000 description 2
239000003921 oil Substances 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
230000002085 persistent effect Effects 0.000 description 2
239000012071 phase Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 description 2
210000003462 vein Anatomy 0.000 description 2
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
WHRZCXAVMTUTDD-UHFFFAOYSA-N 1h-furo[2,3-d]pyrimidin-2-one Chemical compound N1C(=O)N=C2OC=CC2=C1 WHRZCXAVMTUTDD-UHFFFAOYSA-N 0.000 description 1
QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
239000004908 Emulsion polymer Substances 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
235000006173 Larrea tridentata Nutrition 0.000 description 1
244000073231 Larrea tridentata Species 0.000 description 1
101100114416 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) con-10 gene Proteins 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
150000008051 alkyl sulfates Chemical class 0.000 description 1
RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
239000003830 anthracite Substances 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000004939 coking Methods 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
230000001143 conditioned effect Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
229960002126 creosote Drugs 0.000 description 1
150000001896 cresols Chemical class 0.000 description 1
238000011161 development Methods 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
230000005484 gravity Effects 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000003999 initiator Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000003077 lignite Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
238000011017 operating method Methods 0.000 description 1
239000010665 pine oil Substances 0.000 description 1
229920002239 polyacrylonitrile Polymers 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
238000012545 processing Methods 0.000 description 1
150000003242 quaternary ammonium salts Chemical class 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000000344 soap Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
235000011121 sodium hydroxide Nutrition 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
230000002269 spontaneous effect Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000013519 translation Methods 0.000 description 1
230000014616 translation Effects 0.000 description 1
GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
239000002699 waste material Substances 0.000 description 1
229920003169 water-soluble polymer Polymers 0.000 description 1
239000012991 xanthate Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/016—Macromolecular compounds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/007—Modifying reagents for adjusting pH or conductivity
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
- B03D2203/08—Coal ores, fly ash or soot

Landscapes

Compositions Of Macromolecular Compounds (AREA)
Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Solid Fuels And Fuel-Associated Substances (AREA)

CA284,075A 1977-06-20 1977-08-04 Flottation de charbon oxyde grace a une emulsion du type latex de polyacrylate de sodium Expired CA1086433A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US80777077A	1977-06-20	1977-06-20
US807,770		1977-06-20

Publications (1)

Publication Number	Publication Date
CA1086433A true CA1086433A (fr)	1980-09-23

Family

ID=25197143

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA284,075A Expired CA1086433A (fr)	1977-06-20	1977-08-04	Flottation de charbon oxyde grace a une emulsion du type latex de polyacrylate de sodium

Country Status (8)

Country	Link
AU (1)	AU2872577A (fr)
CA (1)	CA1086433A (fr)
DE (1)	DE2740548C2 (fr)
ES (1)	ES468380A1 (fr)
FR (1)	FR2400960A1 (fr)
GB (1)	GB1593805A (fr)
GR (1)	GR67247B (fr)
ZA (1)	ZA775107B (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB2171929B (en) *	1985-03-08	1988-09-01	Cargo Fleet Chemical Co	Improvements relating to particle separation
CN111468305A (zh) *	2020-05-26	2020-07-31	河南天鸿选矿科技有限公司	一种钛铁矿浮选捕收剂
CN115846056B (zh) *	2022-11-10	2024-07-05	山西大学	一种低阶煤浮选用w/o型微乳液捕收剂及其制备与应用

1977
- 1977-08-04 CA CA284,075A patent/CA1086433A/fr not_active Expired
- 1977-08-23 ZA ZA00775107A patent/ZA775107B/xx unknown
- 1977-09-06 DE DE2740548A patent/DE2740548C2/de not_active Expired
- 1977-09-12 AU AU28725/77A patent/AU2872577A/en not_active Expired
- 1977-09-16 FR FR7728042A patent/FR2400960A1/fr active Granted
1978
- 1978-03-08 GR GR55651A patent/GR67247B/el unknown
- 1978-03-30 ES ES468380A patent/ES468380A1/es not_active Expired
- 1978-04-07 GB GB13775/78A patent/GB1593805A/en not_active Expired

Also Published As

Publication number	Publication date
AU2872577A (en)	1978-09-21
GB1593805A (en)	1981-07-22
DE2740548C2 (de)	1979-03-15
ZA775107B (en)	1978-09-27
GR67247B (fr)	1981-06-25
ES468380A1 (es)	1978-12-16
FR2400960B1 (fr)	1981-11-13
FR2400960A1 (fr)	1979-03-23
DE2740548B1 (de)	1978-07-06

Legal Events

Date	Code	Title	Description
1997-09-23	MKEX	Expiry

Publication	Publication Date	Title
EP0662865B1 (fr)	1997-04-02	Procede de flottation de charbon
US4222862A (en)	1980-09-16	Flotation of oxidized coal with a latex emulsion of sodium polyacrylate used as a promoter
US3807557A (en)	1974-04-30	Flotation of pyrite from coal
US4857221A (en)	1989-08-15	Recovering coal fines
US3925200A (en)	1975-12-09	Method for separation of mixture of plastics
GB2072700A (en)	1981-10-07	Flotation of coal with latex emulsions of hydrocarbon oil
EP0164237B1 (fr)	1991-03-06	Polyorganosiloxanes comme collecteurs dans la préparation des fines de charbon par flottation avec formation d'écume
US4162966A (en)	1979-07-31	Flotation of deep mined coal with water-in-oil emulsions of sodium polyacrylate
EP0163480B1 (fr)	1991-10-02	Silicone-glycols comme collecteurs dans la préparation des fines de charbon par flottation avec formation d'écume
US4268379A (en)	1981-05-19	Selective flocculation for increased coal recovery by froth flotation
US5304317A (en)	1994-04-19	Froth flotation of fine particles
CA1086433A (fr)	1980-09-23	Flottation de charbon oxyde grace a une emulsion du type latex de polyacrylate de sodium
EP0246105B1 (fr)	1992-03-18	Extraction des fines de charbon
CA1084638A (fr)	1980-08-26	Rendement accru en charbon oxyde des operations de concentration par flottation
US4363724A (en)	1982-12-14	Use of C8-34 alpha olefin sulfonates to improve and enhance the flotation and collection process used for barite
US4770767A (en)	1988-09-13	Method for the froth flotation of coal
AU612487B2 (en)	1991-07-11	Pyrite depressants useful in the separation of pyrite from coal
US4157296A (en)	1979-06-05	Flotation process for fluoride minerals
EP0339856B1 (fr)	1994-12-28	Agents déprimants de la pyrite utilisables pour la séparation de la pyrite et du charbon
US4211642A (en)	1980-07-08	Beneficiation of coal and metallic and non-metallic ores by froth flotation process using polyhydroxy alkyl xanthate depressants
CA1112378A (fr)	1981-11-10	Flottation du charbon extrait en profondeur dans des emulsions d'eau dans l'huile de polyacrylate de sodium
AU646329B2 (en)	1994-02-17	Froth flotation of fine coal or mineral particles
SU1457939A1 (ru)	1989-02-15	Способ флотации окисленных олов нных руд
JPS6211628B2 (fr)	1987-03-13
SU1036390A1 (ru)	1983-08-23	Вспениватель дл флотации полиметаллических руд