CA1089797A - Lit en fibres electrolytiques pour la recuperation du mercure et autres ions metalliques lourds - Google Patents

Lit en fibres electrolytiques pour la recuperation du mercure et autres ions metalliques lourds

Info

Publication number: CA1089797A
Authority: CA; Canada
Prior art keywords: cathode; anode; mercury; bed; chamber
Prior art date: 1975-08-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA258,443A

Other languages

English (en)

Inventor

Edward N. Balko

Shyam D. Argade

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF Corp

Original Assignee

BASF Wyandotte Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-08-29

Filing date

1976-08-04

Publication date

1980-11-18

1976-08-04 Application filed by BASF Wyandotte Corp filed Critical BASF Wyandotte Corp

1980-11-18 Application granted granted Critical

1980-11-18 Publication of CA1089797A publication Critical patent/CA1089797A/fr

Status Expired legal-status Critical Current

Links

QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title claims abstract description 37
229910052753 mercury Inorganic materials 0.000 title claims abstract description 32
150000002500 ions Chemical class 0.000 title description 4
238000011084 recovery Methods 0.000 title description 3
229910001385 heavy metal Inorganic materials 0.000 title description 2
239000000835 fiber Substances 0.000 claims abstract description 34
239000007788 liquid Substances 0.000 claims abstract description 28
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 20
239000000243 solution Substances 0.000 claims abstract description 17
238000000034 method Methods 0.000 claims abstract description 14
239000011780 sodium chloride Substances 0.000 claims abstract description 10
239000008151 electrolyte solution Substances 0.000 claims abstract description 4
238000004064 recycling Methods 0.000 claims abstract description 3
229940008718 metallic mercury Drugs 0.000 claims description 3
238000010405 reoxidation reaction Methods 0.000 claims 1
239000012267 brine Substances 0.000 abstract 1
238000011109 contamination Methods 0.000 abstract 1
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract 1
229910052751 metal Inorganic materials 0.000 description 21
239000002184 metal Substances 0.000 description 21
210000004027 cell Anatomy 0.000 description 16
210000005056 cell body Anatomy 0.000 description 10
239000004020 conductor Substances 0.000 description 7
229910021645 metal ion Inorganic materials 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000007789 gas Substances 0.000 description 6
239000000463 material Substances 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 4
-1 mercury ions Chemical class 0.000 description 4
150000002739 metals Chemical class 0.000 description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
239000004743 Polypropylene Substances 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
239000003792 electrolyte Substances 0.000 description 3
239000002245 particle Substances 0.000 description 3
229920001155 polypropylene Polymers 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
229920001971 elastomer Polymers 0.000 description 2
239000011521 glass Substances 0.000 description 2
239000012535 impurity Substances 0.000 description 2
239000012528 membrane Substances 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
229910052709 silver Inorganic materials 0.000 description 2
239000004332 silver Substances 0.000 description 2
235000011121 sodium hydroxide Nutrition 0.000 description 2
125000006850 spacer group Chemical group 0.000 description 2
229910021654 trace metal Inorganic materials 0.000 description 2
239000011800 void material Substances 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
241000100287 Membras Species 0.000 description 1
229920000914 Metallic fiber Polymers 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
238000013019 agitation Methods 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical class [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical class [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
239000010406 cathode material Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
230000005465 channeling Effects 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000010276 construction Methods 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
230000008021 deposition Effects 0.000 description 1
239000002657 fibrous material Substances 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000010931 gold Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000012811 non-conductive material Substances 0.000 description 1
LMAZKPOSWVOFGY-FBAUPLQOSA-N orine Natural products CO[C@H]1C[C@H](O[C@H]2CC[C@]3(C)[C@H]4C[C@@H](OC(=O)C=Cc5ccccc5)[C@]6(C)[C@@](O)(CC[C@]6(O)[C@]4(O)CC=C3C2)[C@H](C)OC(=O)C=Cc7ccccc7)O[C@H](C)[C@H]1O LMAZKPOSWVOFGY-FBAUPLQOSA-N 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
239000005373 porous glass Substances 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
239000012047 saturated solution Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
229910052718 tin Chemical class 0.000 description 1
239000002699 waste material Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/14—Purification
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F1/46114—Electrodes in particulate form or with conductive and/or non conductive particles between them
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4676—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electroreduction
- C02F1/4678—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electroreduction of metals
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Water Supply & Treatment (AREA)
Hydrology & Water Resources (AREA)
Environmental & Geological Engineering (AREA)
Life Sciences & Earth Sciences (AREA)
General Chemical & Material Sciences (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Metallurgy (AREA)
Electrolytic Production Of Metals (AREA)
Water Treatment By Electricity Or Magnetism (AREA)
Electrodes For Compound Or Non-Metal Manufacture (AREA)

CA258,443A 1975-08-29 1976-08-04 Lit en fibres electrolytiques pour la recuperation du mercure et autres ions metalliques lourds Expired CA1089797A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US60887575A	1975-08-29	1975-08-29
US608,875		1975-08-29

Publications (1)

Publication Number	Publication Date
CA1089797A true CA1089797A (fr)	1980-11-18

Family

ID=24438423

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA258,443A Expired CA1089797A (fr)	1975-08-29	1976-08-04	Lit en fibres electrolytiques pour la recuperation du mercure et autres ions metalliques lourds

Country Status (7)

Country	Link
JP (1)	JPS5230270A (fr)
BE (1)	BE845288A (fr)
CA (1)	CA1089797A (fr)
DE (1)	DE2637936A1 (fr)
FR (1)	FR2322216A1 (fr)
IT (1)	IT1066147B (fr)
NL (1)	NL7609586A (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5458687A (en) *	1977-10-20	1979-05-11	Nippon Zeon Co Ltd	Manufacture of material separator of hollow fiber type
JPS5483623A (en) *	1977-12-15	1979-07-03	Agency Of Ind Science & Technol	Separating method for mercury from acidic aqueous solution
US4244795A (en) *	1978-05-24	1981-01-13	Akzo N.V.	Process and apparatus for electrolytically removing metal ions from a solution thereof
JPH0671532B2 (ja) *	1989-09-18	1994-09-14	東レ株式会社	流体分離モジュール及びその製造方法
GB9908345D0 (en) *	1999-04-12	1999-06-09	Ea Tech Ltd	A process for the recovery of mercury from aqueous solutions and an electrochemical cell therfor

1976
- 1976-08-04 CA CA258,443A patent/CA1089797A/fr not_active Expired
- 1976-08-18 BE BE169894A patent/BE845288A/fr unknown
- 1976-08-23 FR FR7625468A patent/FR2322216A1/fr active Granted
- 1976-08-23 IT IT5098576A patent/IT1066147B/it active
- 1976-08-23 DE DE19762637936 patent/DE2637936A1/de active Pending
- 1976-08-27 NL NL7609586A patent/NL7609586A/xx not_active Application Discontinuation
- 1976-08-30 JP JP10273276A patent/JPS5230270A/ja active Pending

Also Published As

Publication number	Publication date
BE845288A (fr)	1976-12-16
FR2322216B3 (fr)	1979-05-18
DE2637936A1 (de)	1977-03-03
FR2322216A1 (fr)	1977-03-25
NL7609586A (nl)	1977-03-02
JPS5230270A (en)	1977-03-07
IT1066147B (it)	1985-03-04

Legal Events

Date	Code	Title	Description
1997-11-18	MKEX	Expiry

Publication	Publication Date	Title
US3981787A (en)	1976-09-21	Electrochemical circulating bed cell
CA2229661C (fr)	2000-10-24	Procede d'extraction electrolytyque de zinc intense bien qu'a rendement energetique eleve sur des lits particulaires mobiles
EP0171478B1 (fr)	1990-03-28	Procédé et cellule électrolytique employant un lit fluidisé
EP0309389A2 (fr)	1989-03-29	Dispositif électrolytique pour la récupération de métaux précieux
US3730864A (en)	1973-05-01	Decreasing the phenolic content of liquids by an electrochemical technique
US3650925A (en)	1972-03-21	Recovery of metals from solution
Van der Heiden et al.	1978	Fluidized bed electrolysis for removal or recovery of metals from dilute solutions
CA1087131A (fr)	1980-10-07	Extraction electrolytique d'ions de metaux lourds contenus dans des solutions aqueuses
US4208258A (en)	1980-06-17	Method for the recovery of mercury and other heavy metal ions from a liquid stream
US3899404A (en)	1975-08-12	Method of removing mercury from an aqueous solution
CN118007193B (zh)	2024-10-18	一种硫代硫酸盐电化学浸出-回收一体化短流程提取贵金属的方法
CN1277269A (zh)	2000-12-20	电解方法
EP0008410B1 (fr)	1983-03-30	Procédé de traitement d'eaux residuaires contenant de l'acide chromique
US4115222A (en)	1978-09-19	Method for electrolytic winning of lead
CA1122561A (fr)	1982-04-27	Decomposition de l'amalgame derive de l'electrolyse et de la polarisation anodique du mercure
US4204937A (en)	1980-05-27	Novel electrolytic amalgam denuder apparatus
US3262871A (en)	1966-07-26	Preparation of phosphine
GB1598306A (en)	1981-09-16	Electrolytic method and apparatus
US3109789A (en)	1963-11-05	Preparation of phosphine
JPS5873783A (ja)	1983-05-04	水素アノ−ドで塊状の亜鉛を電解抽出する方法
JPH032959B2 (fr)	1991-01-17
CA1122923A (fr)	1982-05-04	Denudeur electrolytique pour decomposer un amalgame et debarasser le mercure de ses impuretes
FI71027C (fi)	1986-10-27	Foerfarande foer reglering av en elektrolytutfaellningsprocessfoer metaller
US1209835A (en)	1916-12-26	Process of treating materials electrolytically.
DE2637936A1 (de)	1977-03-03	Verfahren zur elektrolytischen entfernung von schwermetallionen