CA1099250A - Traduction non-disponible - Google Patents

Traduction non-disponible

Info

Publication number: CA1099250A
Authority: CA; Canada
Prior art keywords: catalyst; group; rare earth; inert support; grams
Prior art date: 1976-10-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA288,657A

Other languages

English (en)

Inventor

Wilfrid G. Shaw

James F. White

Michael D. Applequist

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Standard Oil Co

Original Assignee

Standard Oil Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-10-19

Filing date

1977-10-13

Publication date

1981-04-14

1976-10-19 Priority claimed from US05/733,735 external-priority patent/US4085065A/en

1976-10-19 Priority claimed from US05/733,737 external-priority patent/US4075123A/en

1976-10-19 Priority claimed from US05/733,738 external-priority patent/US4075124A/en

1977-10-13 Application filed by Standard Oil Co filed Critical Standard Oil Co

1981-04-14 Application granted granted Critical

1981-04-14 Publication of CA1099250A publication Critical patent/CA1099250A/fr

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 17
238000002360 preparation method Methods 0.000 title abstract description 18
239000002253 acid Substances 0.000 title abstract description 3
150000007513 acids Chemical class 0.000 title abstract 2
150000001299 aldehydes Chemical class 0.000 title abstract 2
239000000203 mixture Substances 0.000 claims abstract description 32
229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 32
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims abstract description 22
STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 claims abstract description 18
229910052802 copper Inorganic materials 0.000 claims abstract description 17
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 16
229910052782 aluminium Inorganic materials 0.000 claims abstract description 14
229910052793 cadmium Inorganic materials 0.000 claims abstract description 14
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 13
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 13
229910052716 thallium Inorganic materials 0.000 claims abstract description 12
230000003647 oxidation Effects 0.000 claims abstract description 11
238000007254 oxidation reaction Methods 0.000 claims abstract description 11
229910003202 NH4 Inorganic materials 0.000 claims abstract description 10
229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 10
150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 10
229910052737 gold Inorganic materials 0.000 claims abstract description 9
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims abstract description 8
229910001882 dioxygen Inorganic materials 0.000 claims abstract description 8
229910052732 germanium Inorganic materials 0.000 claims abstract description 8
229910052697 platinum Inorganic materials 0.000 claims abstract description 8
229910052702 rhenium Inorganic materials 0.000 claims abstract description 8
229910052707 ruthenium Inorganic materials 0.000 claims abstract description 8
229910052759 nickel Inorganic materials 0.000 claims abstract description 7
229910052763 palladium Inorganic materials 0.000 claims abstract description 7
229910052758 niobium Inorganic materials 0.000 claims abstract description 6
239000012808 vapor phase Substances 0.000 claims abstract description 6
229910052725 zinc Inorganic materials 0.000 claims abstract description 6
229910052770 Uranium Inorganic materials 0.000 claims abstract description 5
229910052733 gallium Inorganic materials 0.000 claims abstract description 5
229910052703 rhodium Inorganic materials 0.000 claims abstract description 5
229910052776 Thorium Inorganic materials 0.000 claims abstract description 4
229910052738 indium Inorganic materials 0.000 claims abstract description 4
229910052745 lead Inorganic materials 0.000 claims abstract description 3
229910052719 titanium Inorganic materials 0.000 claims abstract 6
229910052801 chlorine Inorganic materials 0.000 claims abstract 3
239000003054 catalyst Substances 0.000 claims description 172
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 32
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
239000010949 copper Substances 0.000 claims description 16
239000000463 material Substances 0.000 claims description 14
238000006243 chemical reaction Methods 0.000 claims description 13
150000002910 rare earth metals Chemical group 0.000 claims description 12
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 10
239000000377 silicon dioxide Substances 0.000 claims description 10
239000010931 gold Substances 0.000 claims description 7
229910052684 Cerium Inorganic materials 0.000 claims description 6
239000010955 niobium Substances 0.000 claims description 6
239000002245 particle Substances 0.000 claims description 6
229910052709 silver Inorganic materials 0.000 claims description 6
239000010936 titanium Substances 0.000 claims description 6
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
239000011248 coating agent Substances 0.000 claims description 5
238000000576 coating method Methods 0.000 claims description 5
239000011701 zinc Substances 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 4
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical group [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 4
239000010948 rhodium Substances 0.000 claims description 4
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 4
229910010271 silicon carbide Inorganic materials 0.000 claims description 4
239000004332 silver Substances 0.000 claims description 4
229910052691 Erbium Inorganic materials 0.000 claims description 3
229910052779 Neodymium Inorganic materials 0.000 claims description 3
229910052777 Praseodymium Inorganic materials 0.000 claims description 3
UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical group [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 3
229910052746 lanthanum Inorganic materials 0.000 claims description 3
BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims description 3
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 2
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical group [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 2
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical group [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 2
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical group [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical group [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
229940044194 cadmium Drugs 0.000 claims 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical group [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical group [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical group [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims 1
230000003197 catalytic effect Effects 0.000 abstract description 7
229910052785 arsenic Inorganic materials 0.000 abstract description 5
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract description 5
229910052698 phosphorus Inorganic materials 0.000 abstract description 5
239000011574 phosphorus Substances 0.000 abstract description 5
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract description 4
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 4
229910052750 molybdenum Inorganic materials 0.000 abstract description 4
239000011733 molybdenum Substances 0.000 abstract description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 3
229910052760 oxygen Inorganic materials 0.000 abstract description 3
239000001301 oxygen Substances 0.000 abstract description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 23
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
235000011007 phosphoric acid Nutrition 0.000 description 12
229910000147 aluminium phosphate Inorganic materials 0.000 description 11
XPVHUBFHKQQSDA-UHFFFAOYSA-N ammonium arsenate Chemical compound [NH4+].[NH4+].O[As]([O-])([O-])=O XPVHUBFHKQQSDA-UHFFFAOYSA-N 0.000 description 11
229960004838 phosphoric acid Drugs 0.000 description 11
-1 ~rl Inorganic materials 0.000 description 11
NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 10
IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 10
239000000047 product Substances 0.000 description 10
239000012153 distilled water Substances 0.000 description 8
QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 7
150000001875 compounds Chemical class 0.000 description 7
OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 7
CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 7
229940071536 silver acetate Drugs 0.000 description 7
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 6
ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 6
238000001354 calcination Methods 0.000 description 6
230000000052 comparative effect Effects 0.000 description 6
239000002002 slurry Substances 0.000 description 6
239000004246 zinc acetate Substances 0.000 description 6
APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 4
239000011609 ammonium molybdate Substances 0.000 description 4
229940010552 ammonium molybdate Drugs 0.000 description 4
235000018660 ammonium molybdate Nutrition 0.000 description 4
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 4
YHBDIEWMOMLKOO-UHFFFAOYSA-I pentachloroniobium Chemical compound Cl[Nb](Cl)(Cl)(Cl)Cl YHBDIEWMOMLKOO-UHFFFAOYSA-I 0.000 description 4
239000000843 powder Substances 0.000 description 4
239000002244 precipitate Substances 0.000 description 4
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 4
241001279686 Allium moly Species 0.000 description 3
239000011149 active material Substances 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
VGBWDOLBWVJTRZ-UHFFFAOYSA-K cerium(3+);triacetate Chemical compound [Ce+3].CC([O-])=O.CC([O-])=O.CC([O-])=O VGBWDOLBWVJTRZ-UHFFFAOYSA-K 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
235000016768 molybdenum Nutrition 0.000 description 3
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
229910019614 (NH4)6 Mo7 O24.4H2 O Inorganic materials 0.000 description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
FIXLYHHVMHXSCP-UHFFFAOYSA-H azane;dihydroxy(dioxo)molybdenum;trioxomolybdenum;tetrahydrate Chemical compound N.N.N.N.N.N.O.O.O.O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O FIXLYHHVMHXSCP-UHFFFAOYSA-H 0.000 description 2
FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 2
229940046892 lead acetate Drugs 0.000 description 2
DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 description 2
CAYKLJBSARHIDI-UHFFFAOYSA-K trichloroalumane;hydrate Chemical compound O.Cl[Al](Cl)Cl CAYKLJBSARHIDI-UHFFFAOYSA-K 0.000 description 2
238000009736 wetting Methods 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
COQLPRJCUIATTQ-UHFFFAOYSA-N Uranyl acetate Chemical compound O.O.O=[U]=O.CC(O)=O.CC(O)=O COQLPRJCUIATTQ-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
238000009835 boiling Methods 0.000 description 1
YZYDPPZYDIRSJT-UHFFFAOYSA-K boron phosphate Chemical compound [B+3].[O-]P([O-])([O-])=O YZYDPPZYDIRSJT-UHFFFAOYSA-K 0.000 description 1
229910000149 boron phosphate Inorganic materials 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
LHQLJMJLROMYRN-UHFFFAOYSA-L cadmium acetate Chemical compound [Cd+2].CC([O-])=O.CC([O-])=O LHQLJMJLROMYRN-UHFFFAOYSA-L 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical group [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
238000000975 co-precipitation Methods 0.000 description 1
AJNVQOSZGJRYEI-UHFFFAOYSA-N digallium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ga+3].[Ga+3] AJNVQOSZGJRYEI-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
229910001195 gallium oxide Inorganic materials 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
239000005078 molybdenum compound Substances 0.000 description 1
150000002752 molybdenum compounds Chemical class 0.000 description 1
PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium oxide Inorganic materials [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
150000003018 phosphorus compounds Chemical class 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
SVOOVMQUISJERI-UHFFFAOYSA-K rhodium(3+);triacetate Chemical compound [Rh+3].CC([O-])=O.CC([O-])=O.CC([O-])=O SVOOVMQUISJERI-UHFFFAOYSA-K 0.000 description 1
YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
HQOJMTATBXYHNR-UHFFFAOYSA-M thallium(I) acetate Chemical compound [Tl+].CC([O-])=O HQOJMTATBXYHNR-UHFFFAOYSA-M 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
229940048102 triphosphoric acid Drugs 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8873—Zinc, cadmium or mercury
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
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- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
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- B01J27/14—Phosphorus; Compounds thereof
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- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

CA288,657A 1976-10-19 1977-10-13 Traduction non-disponible Expired CA1099250A (fr)

Applications Claiming Priority (6)

Application Number	Priority Date	Filing Date	Title
US733,737		1976-10-19
US05/733,735 US4085065A (en)	1976-10-19	1976-10-19	Process for the preparation of unsaturated acids from unsaturated aldehydes
US733,735		1976-10-19
US05/733,737 US4075123A (en)	1976-10-19	1976-10-19	Process for the preparation of unsaturated acids from unsaturated aldehydes
US05/733,738 US4075124A (en)	1976-10-19	1976-10-19	Process for the preparation of unsaturated acids from unsaturated aldehydes
US733,738		1991-07-23

Publications (1)

Publication Number	Publication Date
CA1099250A true CA1099250A (fr)	1981-04-14

Family

ID=27419180

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA288,657A Expired CA1099250A (fr)	1976-10-19	1977-10-13	Traduction non-disponible

Country Status (15)

Country	Link
JP (1)	JPS5351194A (fr)
BG (2)	BG40648A3 (fr)
BR (1)	BR7706924A (fr)
CA (1)	CA1099250A (fr)
DD (1)	DD133431A5 (fr)
DE (2)	DE2760323C2 (fr)
ES (5)	ES472474A1 (fr)
FR (1)	FR2371229A1 (fr)
GB (1)	GB1575334A (fr)
IN (1)	IN147123B (fr)
IT (1)	IT1088096B (fr)
NL (1)	NL7711377A (fr)
NO (6)	NO773568L (fr)
PT (1)	PT67146B (fr)
RO (1)	RO81263B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5811416B2 (ja) *	1978-12-13	1983-03-02	日本化薬株式会社	メタクリル酸の製造法
FR2521565B1 (fr) *	1982-02-17	1985-07-05	Dior Sa Parfums Christian	Melange pulverulent de constituants lipidiques et de constituants hydrophobes, procede pour le preparer, phases lamellaires lipidiques hydratees et procede de fabrication, compositions pharmaceutiques ou cosmetiques comportant des phases lamellaires lipidiques hydratees
JPH0791212B2 (ja) *	1988-07-11	1995-10-04	三菱レイヨン株式会社	メタクリル酸の製造法
US10882801B2 (en)	2016-01-04	2021-01-05	Saudi Arabian Oil Company	Methods for gas phase oxidative desulphurization of hydrocarbons using CuZnAl catalysts promoted with group VIB metal oxides

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5529061B2 (fr) *	1973-08-16	1980-07-31

1977
- 1977-09-24 IN IN250/DEL/77A patent/IN147123B/en unknown
- 1977-10-10 IT IT28433/77A patent/IT1088096B/it active
- 1977-10-12 PT PT67146A patent/PT67146B/pt unknown
- 1977-10-13 CA CA288,657A patent/CA1099250A/fr not_active Expired
- 1977-10-13 DE DE2760323A patent/DE2760323C2/de not_active Expired
- 1977-10-13 DE DE2746135A patent/DE2746135C2/de not_active Expired
- 1977-10-17 GB GB43047/77A patent/GB1575334A/en not_active Expired
- 1977-10-17 FR FR7731167A patent/FR2371229A1/fr active Granted
- 1977-10-17 NL NL7711377A patent/NL7711377A/xx not_active Application Discontinuation
- 1977-10-17 BR BR7706924A patent/BR7706924A/pt unknown
- 1977-10-18 DD DD77201574A patent/DD133431A5/xx unknown
- 1977-10-18 RO RO91875A patent/RO81263B/ro unknown
- 1977-10-18 BG BG037602A patent/BG40648A3/xx unknown
- 1977-10-18 JP JP12564277A patent/JPS5351194A/ja active Granted
- 1977-10-18 BG BG041246A patent/BG40476A3/xx unknown
- 1977-10-18 NO NO773568A patent/NO773568L/no unknown
1978
- 1978-08-10 ES ES472474A patent/ES472474A1/es not_active Expired
- 1978-08-10 ES ES472476A patent/ES472476A1/es not_active Expired
- 1978-08-10 ES ES472473A patent/ES472473A1/es not_active Expired
- 1978-08-10 ES ES472475A patent/ES472475A1/es not_active Expired
- 1978-08-10 ES ES472472A patent/ES472472A1/es not_active Expired
- 1978-11-15 NO NO783835A patent/NO783835L/no unknown
- 1978-11-15 NO NO783833A patent/NO783833L/no unknown
- 1978-11-15 NO NO783837A patent/NO783837L/no unknown
- 1978-11-15 NO NO783834A patent/NO783834L/no unknown
- 1978-11-15 NO NO783836A patent/NO783836L/no unknown

Also Published As

Publication number	Publication date
DD133431A5 (de)	1979-01-03
ES472476A1 (es)	1979-04-16
NO783837L (no)	1978-04-20
IT1088096B (it)	1985-06-04
NL7711377A (nl)	1978-04-21
DE2746135C2 (de)	1987-02-26
NO783836L (no)	1978-04-20
NO783833L (no)	1978-04-20
BG40476A3 (en)	1986-12-15
RO81263B (ro)	1983-02-28
DE2746135A1 (de)	1978-04-27
NO773568L (no)	1978-04-20
BG40648A3 (en)	1986-01-15
NO783834L (no)	1978-04-20
BR7706924A (pt)	1978-06-27
ES472472A1 (es)	1979-04-01
RO81263A (fr)	1983-02-15
GB1575334A (en)	1980-09-17
PT67146A (en)	1977-11-01
ES472474A1 (es)	1979-04-01
JPS5351194A (en)	1978-05-10
ES472475A1 (es)	1979-04-01
DE2760323C2 (fr)	1989-07-20
ES472473A1 (es)	1979-04-01
JPS6211618B2 (fr)	1987-03-13
FR2371229B1 (fr)	1984-03-09
NO783835L (no)	1978-04-20
PT67146B (en)	1979-03-19
FR2371229A1 (fr)	1978-06-16
IN147123B (fr)	1979-11-17

Legal Events

Date	Code	Title	Description
1998-04-14	MKEX	Expiry

Publication	Publication Date	Title
EP0427508B1 (fr)	1995-02-01	Méthode pour la préparation de l'acide acrylique
US3875220A (en)	1975-04-01	Process for the preparation of methacrylic acid from methacrolein
US4017423A (en)	1977-04-12	Process for the preparation of unsaturated acids from unsaturated aldehydes
EP0010429B1 (fr)	1983-05-11	Procédé de préparation d'un catalyseur d'oxydation contenant un anion molybdate
EP0288217B1 (fr)	1993-03-17	Procédé d'ammoxydation et composition catalytique appropriée
EP2117706A1 (fr)	2009-11-18	Catalyseur pour l'oxydation d'aldéhydes saturés et insaturés en acide carboxylique insaturé, procédé de marquage et son procédé d'utilisation
EP0288218B1 (fr)	1993-06-30	Procédé d'ammoxydation et composition catalytique appropriée
EP0027351A1 (fr)	1981-04-22	Catalyseurs d'oxydation et procédé de préparation de la méthacroléine par oxydation en phase vapeur
US4085065A (en)	1978-04-18	Process for the preparation of unsaturated acids from unsaturated aldehydes
US4219484A (en)	1980-08-26	Production of maleic anhydride from four-carbon hydrocarbons using catalysts prepared by water reflux techniques
US4075123A (en)	1978-02-21	Process for the preparation of unsaturated acids from unsaturated aldehydes
EP0146099B1 (fr)	1990-03-21	Procédé de préparation d'acide acrylique par oxidation de l'acroléine ainsi qu'un nouveau catalyseur pour ledit procédé
US4075124A (en)	1978-02-21	Process for the preparation of unsaturated acids from unsaturated aldehydes
US4596784A (en)	1986-06-24	Catalyst compositions and their use for the preparation of unsaturated carboxylic acids
CA1089432A (fr)	1980-11-11	Procede pour la preparation d'un catalyseur destine a l'oxydation en phase vapeur d'aldehydes insatures en acides correspondants
US4257921A (en)	1981-03-24	Catalyst for the oxidation of butene
GB1575334A (en)	1980-09-17	Process for the preparation of unsaturated acids from unsaturated aldehydes and catalyst for use in this process
JP3328340B2 (ja)	2002-09-24	アクロレインまたはアクリル酸の製造法、およびそれに使用する触媒
US4443555A (en)	1984-04-17	Method for the preparation of high activity phosphomolybdic acid based catalysts
CA1117930A (fr)	1982-02-09	Synthese d'ester maleique
US4219671A (en)	1980-08-26	Oxidation of butene to acetic acid
US4093635A (en)	1978-06-06	Preparation of maleic anhydride from four-carbon hydrocarbons
CA1191828A (fr)	1985-08-13	Methode de preparation de catalyseurs a base d'acide phosphomolybdique hautement actifs
JP2623008B2 (ja)	1997-06-25	メタクロレイン及びメタクリル酸の製造法
KR800000672B1 (ko)	1980-07-14	불포화산 제조용 촉매 조성물