CA1103108A - Traduction non-disponible - Google Patents

Traduction non-disponible

Info

Publication number: CA1103108A
Authority: CA; Canada
Prior art keywords: weight; group; nitrile; polymer; carbon atoms
Prior art date: 1976-02-17
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA269,951A

Other languages

English (en)

Inventor

Herbert Talsma

William M. Giffen, Jr.

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Standard Oil Co

Original Assignee

Standard Oil Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-02-17

Filing date

1977-01-18

Publication date

1981-06-16

1977-01-18 Application filed by Standard Oil Co filed Critical Standard Oil Co

1981-06-16 Application granted granted Critical

1981-06-16 Publication of CA1103108A publication Critical patent/CA1103108A/fr

Status Expired legal-status Critical Current

Links

238000000576 coating method Methods 0.000 title claims abstract description 44
229920001577 copolymer Polymers 0.000 title abstract description 9
229920000126 latex Polymers 0.000 claims abstract description 40
239000004816 latex Substances 0.000 claims abstract description 39
229910052751 metal Inorganic materials 0.000 claims abstract description 36
239000002184 metal Substances 0.000 claims abstract description 36
239000011248 coating agent Substances 0.000 claims abstract description 30
229920000642 polymer Polymers 0.000 claims description 34
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 30
150000002825 nitriles Chemical class 0.000 claims description 23
239000000178 monomer Substances 0.000 claims description 22
238000006116 polymerization reaction Methods 0.000 claims description 16
238000000034 method Methods 0.000 claims description 14
125000000217 alkyl group Chemical group 0.000 claims description 13
125000004432 carbon atom Chemical group C* 0.000 claims description 13
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 12
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 11
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 10
FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 claims description 10
150000001993 dienes Chemical class 0.000 claims description 9
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
229920001971 elastomer Polymers 0.000 claims description 8
150000002148 esters Chemical class 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 7
229910052739 hydrogen Inorganic materials 0.000 claims description 7
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
229910052736 halogen Inorganic materials 0.000 claims description 6
150000002367 halogens Chemical class 0.000 claims description 6
UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical class CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 claims description 5
OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical class CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 claims description 5
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 5
229920003244 diene elastomer Polymers 0.000 claims description 5
239000004711 α-olefin Substances 0.000 claims description 5
239000000839 emulsion Substances 0.000 claims description 4
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 claims description 4
238000001035 drying Methods 0.000 claims description 2
238000010438 heat treatment Methods 0.000 claims description 2
229910000831 Steel Inorganic materials 0.000 abstract description 21
239000010959 steel Substances 0.000 abstract description 21
229910052782 aluminium Inorganic materials 0.000 abstract description 14
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 14
230000007797 corrosion Effects 0.000 abstract 1
238000005260 corrosion Methods 0.000 abstract 1
239000011117 high nitrile polymer Substances 0.000 abstract 1
238000012360 testing method Methods 0.000 description 21
229940044603 styrene Drugs 0.000 description 9
-1 acrylonitrile Chemical class 0.000 description 7
239000004615 ingredient Substances 0.000 description 7
239000000203 mixture Substances 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
239000007787 solid Substances 0.000 description 6
239000000243 solution Substances 0.000 description 6
238000005452 bending Methods 0.000 description 5
239000007921 spray Substances 0.000 description 5
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
229910052802 copper Inorganic materials 0.000 description 4
239000010949 copper Substances 0.000 description 4
229910000365 copper sulfate Inorganic materials 0.000 description 4
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
229920002554 vinyl polymer Polymers 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
238000003618 dip coating Methods 0.000 description 3
239000012153 distilled water Substances 0.000 description 3
229940117958 vinyl acetate Drugs 0.000 description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000005336 cracking Methods 0.000 description 2
229910001882 dioxygen Inorganic materials 0.000 description 2
239000003995 emulsifying agent Substances 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
239000004519 grease Substances 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
239000002245 particle Substances 0.000 description 2
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
230000000379 polymerizing effect Effects 0.000 description 2
239000005060 rubber Substances 0.000 description 2
238000005507 spraying Methods 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
229920001567 vinyl ester resin Polymers 0.000 description 2
YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
SZTBMYHIYNGYIA-UHFFFAOYSA-M 2-chloroacrylate Chemical compound [O-]C(=O)C(Cl)=C SZTBMYHIYNGYIA-UHFFFAOYSA-M 0.000 description 1
OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
FSGHEPDRMHVUCQ-UHFFFAOYSA-N 2-ethoxyprop-1-ene Chemical compound CCOC(C)=C FSGHEPDRMHVUCQ-UHFFFAOYSA-N 0.000 description 1
DDXZFLFMKZXQOT-UHFFFAOYSA-N 2-fluoroprop-2-enenitrile Chemical compound FC(=C)C#N DDXZFLFMKZXQOT-UHFFFAOYSA-N 0.000 description 1
YOWQWFMSQCOSBA-UHFFFAOYSA-N 2-methoxypropene Chemical compound COC(C)=C YOWQWFMSQCOSBA-UHFFFAOYSA-N 0.000 description 1
TVONJMOVBKMLOM-UHFFFAOYSA-N 2-methylidenebutanenitrile Chemical compound CCC(=C)C#N TVONJMOVBKMLOM-UHFFFAOYSA-N 0.000 description 1
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical class CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
239000002174 Styrene-butadiene Substances 0.000 description 1
229920001893 acrylonitrile styrene Polymers 0.000 description 1
238000013019 agitation Methods 0.000 description 1
229910052783 alkali metal Chemical group 0.000 description 1
150000001340 alkali metals Chemical group 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
235000013361 beverage Nutrition 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical class CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
229920006026 co-polymeric resin Polymers 0.000 description 1
JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 1
230000008021 deposition Effects 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical class CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
238000001914 filtration Methods 0.000 description 1
244000144992 flock Species 0.000 description 1
235000013305 food Nutrition 0.000 description 1
239000007789 gas Substances 0.000 description 1
231100001261 hazardous Toxicity 0.000 description 1
LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical class CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical class CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
AWJZTPWDQYFQPQ-UHFFFAOYSA-N methyl 2-chloroprop-2-enoate Chemical compound COC(=O)C(Cl)=C AWJZTPWDQYFQPQ-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
229960005419 nitrogen Drugs 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
238000013021 overheating Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical class CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 description 1
ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical class CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
239000006223 plastic coating Substances 0.000 description 1
238000012667 polymer degradation Methods 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical class C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical class CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical class CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
238000007761 roller coating Methods 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000011115 styrene butadiene Substances 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
239000000126 substance Substances 0.000 description 1
235000011149 sulphuric acid Nutrition 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
- B05D7/16—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using synthetic lacquers or varnishes
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/18—Homopolymers or copolymers of nitriles
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/04—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to rubbers

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Wood Science & Technology (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Laminated Bodies (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Paints Or Removers (AREA)

CA269,951A 1976-02-17 1977-01-18 Traduction non-disponible Expired CA1103108A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US65884276A	1976-02-17	1976-02-17
US658,842		1991-02-22

Publications (1)

Publication Number	Publication Date
CA1103108A true CA1103108A (fr)	1981-06-16

Family

ID=24642938

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA269,951A Expired CA1103108A (fr)	1976-02-17	1977-01-18	Traduction non-disponible

Country Status (19)

Country	Link
JP (1)	JPS5298741A (fr)
AR (1)	AR217636A1 (fr)
AT (1)	AT374136B (fr)
AU (1)	AU505343B2 (fr)
BE (1)	BE850921A (fr)
BR (1)	BR7700568A (fr)
CA (1)	CA1103108A (fr)
CH (1)	CH625978A5 (fr)
DE (1)	DE2701972A1 (fr)
DK (1)	DK149976C (fr)
FR (1)	FR2341631A1 (fr)
GB (1)	GB1570535A (fr)
IT (1)	IT1074385B (fr)
LU (1)	LU76784A1 (fr)
MX (1)	MX143966A (fr)
NL (1)	NL7701491A (fr)
NO (1)	NO148667C (fr)
SE (1)	SE7701726L (fr)
ZA (1)	ZA77177B (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4379875A (en) *	1980-12-31	1983-04-12	The Standard Oil Company	Coalescing aid for high nitrile copolymer latex coatings

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1333957A (fr) *	1961-07-03	1963-08-02	Bayer Ag	Revêtements et pellicules résistants aux solvants et stables à la chaleur
NL130670C (fr) *	1965-02-15
US3586737A (en) *	1969-02-13	1971-06-22	Standard Oil Co	Impact-resistant rubber-modified olefinic nitrile-acrylic ester polymers
JPS4932793B2 (fr) *	1971-11-13	1974-09-03
JPS4932789A (fr) *	1972-07-25	1974-03-26
JPS5110857A (ja) *	1974-07-16	1976-01-28	Mitsubishi Chem Ind	Nitorirukeikyojugotaisoseibutsu

1977
- 1977-01-13 ZA ZA770177A patent/ZA77177B/xx unknown
- 1977-01-18 CA CA269,951A patent/CA1103108A/fr not_active Expired
- 1977-01-19 DE DE19772701972 patent/DE2701972A1/de not_active Withdrawn
- 1977-01-20 MX MX167764A patent/MX143966A/es unknown
- 1977-01-24 IT IT19578/77A patent/IT1074385B/it active
- 1977-01-26 DK DK032577A patent/DK149976C/da active
- 1977-01-28 BR BR7700568A patent/BR7700568A/pt unknown
- 1977-01-31 BE BE174519A patent/BE850921A/fr not_active IP Right Cessation
- 1977-01-31 AR AR266379A patent/AR217636A1/es active
- 1977-02-02 AT AT0065877A patent/AT374136B/de not_active IP Right Cessation
- 1977-02-04 JP JP1154077A patent/JPS5298741A/ja active Pending
- 1977-02-08 GB GB5093/77A patent/GB1570535A/en not_active Expired
- 1977-02-11 NL NL7701491A patent/NL7701491A/xx not_active Application Discontinuation
- 1977-02-15 CH CH185777A patent/CH625978A5/de not_active IP Right Cessation
- 1977-02-16 SE SE7701726A patent/SE7701726L/xx not_active Application Discontinuation
- 1977-02-16 FR FR7704395A patent/FR2341631A1/fr active Granted
- 1977-02-16 NO NO770501A patent/NO148667C/no unknown
- 1977-02-16 LU LU76784A patent/LU76784A1/xx unknown
- 1977-02-17 AU AU22008/77A patent/AU505343B2/en not_active Expired

Also Published As

Publication number	Publication date
GB1570535A (en)	1980-07-02
CH625978A5 (en)	1981-10-30
AT374136B (de)	1984-03-26
JPS5298741A (en)	1977-08-18
NO770501L (no)	1977-08-18
IT1074385B (it)	1985-04-20
DE2701972A1 (de)	1977-08-18
BE850921A (fr)	1977-05-16
AU505343B2 (en)	1979-11-15
ATA65877A (de)	1983-08-15
FR2341631A1 (fr)	1977-09-16
LU76784A1 (fr)	1978-10-18
ZA77177B (en)	1977-11-30
AR217636A1 (es)	1980-04-15
DK32577A (da)	1977-08-18
SE7701726L (sv)	1977-08-18
NO148667B (no)	1983-08-15
MX143966A (es)	1981-08-11
NL7701491A (nl)	1977-08-19
DK149976C (da)	1987-10-19
FR2341631B1 (fr)	1982-09-10
AU2200877A (en)	1978-08-17
NO148667C (no)	1983-11-23
DK149976B (da)	1986-11-10
BR7700568A (pt)	1977-10-04

Legal Events

Date	Code	Title	Description
1998-06-16	MKEX	Expiry

Publication	Publication Date	Title
EP0629642B1 (fr)	1998-05-06	Composition interpolymère de chlorure de vinylidène en émulsion
EP0037750A2 (fr)	1981-10-14	Copolymères d'acide acrylique ou méthacrylique et compositions aqueuses de revêtement autodéposables les contenant
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