CA1105499A - Methode de deposition d'une couche de carbures en melange a la surface d'un article en alliage ferreux, et matiere de traitement connexe - Google Patents

Methode de deposition d'une couche de carbures en melange a la surface d'un article en alliage ferreux, et matiere de traitement connexe

Info

Publication number: CA1105499A
Authority: CA; Canada
Prior art keywords: weight; oxide; percent; chromium; niobium
Prior art date: 1977-07-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA306,923A

Other languages

English (en)

Inventor

Noboru Komatsu

Tohru Arai

Hironori Fujita

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Toyota Central R&D Labs Inc

Original Assignee

Toyota Central R&D Labs Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-07-07

Filing date

1978-07-06

Publication date

1981-07-21

1977-07-07 Priority claimed from JP8041177A external-priority patent/JPS5416342A/ja

1977-08-11 Priority claimed from JP9557177A external-priority patent/JPS5429847A/ja

1978-07-06 Application filed by Toyota Central R&D Labs Inc filed Critical Toyota Central R&D Labs Inc

1981-07-21 Application granted granted Critical

1981-07-21 Publication of CA1105499A publication Critical patent/CA1105499A/fr

Status Expired legal-status Critical Current

Links

229910045601 alloy Inorganic materials 0.000 title claims abstract description 80
239000000956 alloy Substances 0.000 title claims abstract description 80
238000000034 method Methods 0.000 title claims abstract description 29
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title claims description 12
239000000463 material Substances 0.000 title abstract description 16
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 85
239000011651 chromium Substances 0.000 claims abstract description 83
239000002184 metal Substances 0.000 claims abstract description 81
229910052751 metal Inorganic materials 0.000 claims abstract description 80
229910052804 chromium Inorganic materials 0.000 claims abstract description 77
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 35
229910052799 carbon Inorganic materials 0.000 claims abstract description 18
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 17
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 9
239000004327 boric acid Substances 0.000 claims abstract description 9
239000010410 layer Substances 0.000 claims description 97
239000000843 powder Substances 0.000 claims description 74
239000000203 mixture Substances 0.000 claims description 61
239000010955 niobium Substances 0.000 claims description 42
229910052758 niobium Inorganic materials 0.000 claims description 35
229910052720 vanadium Inorganic materials 0.000 claims description 32
229910000628 Ferrovanadium Inorganic materials 0.000 claims description 29
PNXOJQQRXBVKEX-UHFFFAOYSA-N iron vanadium Chemical compound [V].[Fe] PNXOJQQRXBVKEX-UHFFFAOYSA-N 0.000 claims description 29
239000002344 surface layer Substances 0.000 claims description 28
QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 25
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 25
229910052715 tantalum Inorganic materials 0.000 claims description 24
229910000592 Ferroniobium Inorganic materials 0.000 claims description 23
229910021538 borax Inorganic materials 0.000 claims description 23
ZFGFKQDDQUAJQP-UHFFFAOYSA-N iron niobium Chemical compound [Fe].[Fe].[Nb] ZFGFKQDDQUAJQP-UHFFFAOYSA-N 0.000 claims description 23
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 23
235000010339 sodium tetraborate Nutrition 0.000 claims description 23
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 16
BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims description 12
239000002245 particle Substances 0.000 claims description 12
229910001936 tantalum oxide Inorganic materials 0.000 claims description 12
229910001935 vanadium oxide Inorganic materials 0.000 claims description 9
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims description 7
229910000484 niobium oxide Inorganic materials 0.000 claims description 7
URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 claims description 7
230000000737 periodic effect Effects 0.000 claims description 7
-1 alkali-metal borate Chemical class 0.000 claims description 5
229910000851 Alloy steel Inorganic materials 0.000 claims description 2
229910000975 Carbon steel Inorganic materials 0.000 claims description 2
229910052783 alkali metal Inorganic materials 0.000 claims description 2
239000010962 carbon steel Substances 0.000 claims description 2
229940045605 vanadium Drugs 0.000 claims 14
229910000604 Ferrochrome Inorganic materials 0.000 claims 2
WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 claims 2
BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical group [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims 2
229910000599 Cr alloy Inorganic materials 0.000 claims 1
239000011203 carbon fibre reinforced carbon Substances 0.000 claims 1
239000000788 chromium alloy Substances 0.000 claims 1
229920000136 polysorbate Polymers 0.000 claims 1
238000007254 oxidation reaction Methods 0.000 abstract description 7
230000003647 oxidation Effects 0.000 abstract description 6
230000007797 corrosion Effects 0.000 abstract description 5
238000005260 corrosion Methods 0.000 abstract description 5
238000007598 dipping method Methods 0.000 abstract description 5
150000002739 metals Chemical class 0.000 abstract description 5
238000010438 heat treatment Methods 0.000 abstract description 2
229940107218 chromium Drugs 0.000 description 52
235000012721 chromium Nutrition 0.000 description 52
239000004328 sodium tetraborate Substances 0.000 description 21
238000009740 moulding (composite fabrication) Methods 0.000 description 18
150000001875 compounds Chemical class 0.000 description 14
GVEHJMMRQRRJPM-UHFFFAOYSA-N chromium(2+);methanidylidynechromium Chemical compound [Cr+2].[Cr]#[C-].[Cr]#[C-] GVEHJMMRQRRJPM-UHFFFAOYSA-N 0.000 description 12
229910003470 tongbaite Inorganic materials 0.000 description 12
UNASZPQZIFZUSI-UHFFFAOYSA-N methylidyneniobium Chemical compound [Nb]#C UNASZPQZIFZUSI-UHFFFAOYSA-N 0.000 description 11
INZDTEICWPZYJM-UHFFFAOYSA-N 1-(chloromethyl)-4-[4-(chloromethyl)phenyl]benzene Chemical compound C1=CC(CCl)=CC=C1C1=CC=C(CCl)C=C1 INZDTEICWPZYJM-UHFFFAOYSA-N 0.000 description 8
230000015572 biosynthetic process Effects 0.000 description 8
238000005755 formation reaction Methods 0.000 description 8
230000007547 defect Effects 0.000 description 7
ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Chemical compound O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 description 7
238000006722 reduction reaction Methods 0.000 description 7
229910001315 Tool steel Inorganic materials 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
229910000423 chromium oxide Inorganic materials 0.000 description 6
238000011282 treatment Methods 0.000 description 6
239000003638 chemical reducing agent Substances 0.000 description 5
229940124024 weight reducing agent Drugs 0.000 description 5
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 4
238000002441 X-ray diffraction Methods 0.000 description 4
230000007423 decrease Effects 0.000 description 4
230000000694 effects Effects 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
238000001000 micrograph Methods 0.000 description 4
230000001603 reducing effect Effects 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
239000011575 calcium Substances 0.000 description 3
238000004090 dissolution Methods 0.000 description 3
229910000640 Fe alloy Inorganic materials 0.000 description 2
229910001257 Nb alloy Inorganic materials 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
150000001642 boronic acid derivatives Chemical class 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
GETQUXSKPMRGCK-UHFFFAOYSA-N chromium;methane Chemical compound C.C.C.[Cr].[Cr].[Cr].[Cr].[Cr].[Cr].[Cr] GETQUXSKPMRGCK-UHFFFAOYSA-N 0.000 description 2
238000005336 cracking Methods 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
238000009826 distribution Methods 0.000 description 2
238000005242 forging Methods 0.000 description 2
238000007496 glass forming Methods 0.000 description 2
239000002075 main ingredient Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 2
229910052710 silicon Inorganic materials 0.000 description 2
239000010703 silicon Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
229910003468 tantalcarbide Inorganic materials 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
229910001021 Ferroalloy Inorganic materials 0.000 description 1
241001527806 Iti Species 0.000 description 1
206010037660 Pyrexia Diseases 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
229910000756 V alloy Inorganic materials 0.000 description 1
241000765309 Vanadis Species 0.000 description 1
239000000654 additive Substances 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
235000010210 aluminium Nutrition 0.000 description 1
239000002585 base Substances 0.000 description 1
238000005266 casting Methods 0.000 description 1
229910052729 chemical element Inorganic materials 0.000 description 1
238000005254 chromizing Methods 0.000 description 1
229940000425 combination drug Drugs 0.000 description 1
230000002301 combined effect Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
239000002923 metal particle Substances 0.000 description 1
VOVZXURTCKPRDQ-CQSZACIVSA-N n-[4-[chloro(difluoro)methoxy]phenyl]-6-[(3r)-3-hydroxypyrrolidin-1-yl]-5-(1h-pyrazol-5-yl)pyridine-3-carboxamide Chemical compound C1[C@H](O)CCN1C1=NC=C(C(=O)NC=2C=CC(OC(F)(F)Cl)=CC=2)C=C1C1=CC=NN1 VOVZXURTCKPRDQ-CQSZACIVSA-N 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
230000036647 reaction Effects 0.000 description 1
239000010959 steel Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000010936 titanium Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/18—Solid state diffusion of only metal elements or silicon into metallic material surfaces using liquids, e.g. salt baths, liquid suspensions
- C23C10/26—Solid state diffusion of only metal elements or silicon into metallic material surfaces using liquids, e.g. salt baths, liquid suspensions more than one element being diffused

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Manufacture Of Alloys Or Alloy Compounds (AREA)
Other Surface Treatments For Metallic Materials (AREA)
Chemically Coating (AREA)
Carbon And Carbon Compounds (AREA)
Chemical Treatment Of Metals (AREA)

CA306,923A 1977-07-07 1978-07-06 Methode de deposition d'une couche de carbures en melange a la surface d'un article en alliage ferreux, et matiere de traitement connexe Expired CA1105499A (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
JP80411/1977		1977-07-07
JP8041177A JPS5416342A (en)	1977-07-07	1977-07-07	Method of forming composite carbide layer of 5a group elements on steel alloy surface
JP95571/1977		1977-08-11
JP9557177A JPS5429847A (en)	1977-08-11	1977-08-11	Method of forming composite carbide layer of chromium and one or more of 5a group elements on surface of iron alloy

Publications (1)

Publication Number	Publication Date
CA1105499A true CA1105499A (fr)	1981-07-21

Family

ID=26421423

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA306,923A Expired CA1105499A (fr)	1977-07-07	1978-07-06	Methode de deposition d'une couche de carbures en melange a la surface d'un article en alliage ferreux, et matiere de traitement connexe

Country Status (5)

Country	Link
CA (1)	CA1105499A (fr)
CH (1)	CH639427A5 (fr)
DE (1)	DE2829976C2 (fr)
FR (1)	FR2396809A1 (fr)
GB (1)	GB2000814B (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1179242A (fr) *	1980-06-17	1984-12-11	Norimasa Uchida	Methode de traitement de surfaces
JPS57171624A (en) *	1981-04-14	1982-10-22	Toyota Central Res & Dev Lab Inc	Production of cutlery
JPS59190355A (ja) *	1983-04-08	1984-10-29	Toyota Central Res & Dev Lab Inc	鉄合金材料の表面硬化処理方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE341795C (de) *	1918-11-07	1921-10-08	Richard Walter	Verfahren zur Herstellung von Bor enthaltenden Metallen und Legierungen
JPS5137893B2 (fr) *	1973-04-12	1976-10-19
JPS519688B2 (fr) *	1973-04-12	1976-03-29

1978
- 1978-06-27 GB GB7828059A patent/GB2000814B/en not_active Expired
- 1978-07-04 FR FR7819893A patent/FR2396809A1/fr active Granted
- 1978-07-06 CA CA306,923A patent/CA1105499A/fr not_active Expired
- 1978-07-06 CH CH739178A patent/CH639427A5/de not_active IP Right Cessation
- 1978-07-07 DE DE19782829976 patent/DE2829976C2/de not_active Expired

Also Published As

Publication number	Publication date
FR2396809B1 (fr)	1983-08-19
GB2000814A (en)	1979-01-17
DE2829976C2 (de)	1985-06-20
FR2396809A1 (fr)	1979-02-02
CH639427A5 (de)	1983-11-15
GB2000814B (en)	1982-03-17
DE2829976A1 (de)	1979-01-18

Legal Events

Date	Code	Title	Description
1998-07-21	MKEX	Expiry

Publication	Publication Date	Title
Ei-Mahallawy et al.	1997	Analysis of coating layer formedon steel strips during aluminising by hot dipping in Al-Si baths
US3811961A (en)	1974-05-21	Boridized steel-bonded carbides
US4230751A (en)	1980-10-28	Treating composition, forming a mixed-carbide layer of Va-Group elements and of chromium on a ferrous-alloy surface and resulting product
US4158578A (en)	1979-06-19	Method for forming a carbide layer of a Va-Group element of the periodic table or chromium on the surface of a ferrous alloy article
CN101326309B (zh)	2012-05-09	热喷涂布辊
JPS6153443B2 (fr)	1986-11-18
EP0252479B1 (fr)	1990-10-17	Procédé pour le traitement de surfaces et matériaux employés pour ce traitement
US3719518A (en)	1973-03-06	Process of forming a carbide layer of vanadium, niobium or tantalum upon a steel surface
US4202705A (en)	1980-05-13	Treating bath, forming a mixed carbide layer of Va-Group elements on a ferrous alloy surface and resulting product
CA1105499A (fr)	1981-07-21	Methode de deposition d'une couche de carbures en melange a la surface d'un article en alliage ferreux, et matiere de traitement connexe
US3869319A (en)	1975-03-04	Wear resistant deposited steel
US3922405A (en)	1975-11-25	Method for forming of a carbide layer of a V-a group element of the periodic table on the surface of an iron, ferrous alloy or cemented carbide article
US4168162A (en)	1979-09-18	Infiltrating powder composition
KR910001357B1 (ko)	1991-03-04	내마모층을 형성하는 방법
JPS63147882A (ja)	1988-06-20	表面処理方法
US4077108A (en)	1978-03-07	Process for producing dense machinable alloys from particulate scrap
EP0063386B1 (fr)	1985-08-28	Procédé pour la formation d'une couche de carbure sur la surface d'un objet en alliage de fer ou d'un carbure cimenté
Hui et al.	1996	A study of wear resistance of a new brush-plated alloy Ni-Fe-WS
Shankar et al.	2002	Die soldering: Effect of process parameters and alloy characteristics on soldering in the pressure die casting process
CA1304658C (fr)	1992-07-07	Methode de traitement superficiel d'un objet en fer ou en alliage de fer
CA1111673A (fr)	1981-11-03	Piece metallique coulee a couche superficielle cementee, et methode de fabrication connexe
US3874909A (en)	1975-04-01	Method for forming a carbide layer on the surface of an iron or ferrous alloy article
CA1052317A (fr)	1979-04-10	Electrodeposition d'un carbure du groupe va sur un article en fer, en alliage ferreux ou en carbure cemente
US5118341A (en)	1992-06-02	Machinable powder metallurgical parts and method
EP0212435A2 (fr)	1987-03-04	Procédé pour la fabrication d'alliages métalliques durs, résistants à l'usure et/ou à la corrosion ainsi que les alliages métalliques fabriqués selon ce procédé