CA1106308A - Procede d'extraction d'impuretes d'alkyles de plomb dans des hydrocarbures liquides - Google Patents

Procede d'extraction d'impuretes d'alkyles de plomb dans des hydrocarbures liquides

Info

Publication number: CA1106308A
Authority: CA; Canada
Prior art keywords: process according; silica; sorbent; alumina; lead
Prior art date: 1976-12-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA290,563A

Other languages

English (en)

Inventor

Costandi A. Audeh

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-12-27

Filing date

1977-11-09

Publication date

1981-08-04

1977-11-09 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1981-08-04 Application granted granted Critical

1981-08-04 Publication of CA1106308A publication Critical patent/CA1106308A/fr

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 35
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 26
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 26
239000007788 liquid Substances 0.000 title claims abstract description 13
125000000217 alkyl group Chemical group 0.000 title claims abstract description 9
239000012535 impurity Substances 0.000 title abstract description 6
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 13
239000000356 contaminant Substances 0.000 claims abstract description 12
239000007787 solid Substances 0.000 claims abstract description 4
239000002594 sorbent Substances 0.000 claims description 36
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 31
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 27
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 24
229910000041 hydrogen chloride Inorganic materials 0.000 claims description 24
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
239000010457 zeolite Substances 0.000 claims description 14
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 12
239000000377 silicon dioxide Substances 0.000 claims description 12
229910021536 Zeolite Inorganic materials 0.000 claims description 9
239000011148 porous material Substances 0.000 claims description 7
239000003054 catalyst Substances 0.000 claims description 6
239000000446 fuel Substances 0.000 claims description 6
239000003502 gasoline Substances 0.000 claims description 6
229910000323 aluminium silicate Inorganic materials 0.000 claims description 5
229910001570 bauxite Inorganic materials 0.000 claims description 4
239000004927 clay Substances 0.000 claims description 4
229910052680 mordenite Inorganic materials 0.000 claims description 3
239000011959 amorphous silica alumina Substances 0.000 claims description 2
239000011324 bead Substances 0.000 claims description 2
238000005336 cracking Methods 0.000 claims description 2
239000002274 desiccant Substances 0.000 claims description 2
239000011159 matrix material Substances 0.000 claims 1
238000011109 contamination Methods 0.000 description 12
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
239000000203 mixture Substances 0.000 description 8
239000007789 gas Substances 0.000 description 7
239000000047 product Substances 0.000 description 6
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
229910052786 argon Inorganic materials 0.000 description 4
-1 silica-thoria Inorganic materials 0.000 description 4
238000010998 test method Methods 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
238000010521 absorption reaction Methods 0.000 description 3
238000009835 boiling Methods 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
239000000463 material Substances 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
239000000523 sample Substances 0.000 description 3
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000008186 active pharmaceutical agent Substances 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
QTMDXZNDVAMKGV-UHFFFAOYSA-L copper(ii) bromide Chemical compound [Cu+2].[Br-].[Br-] QTMDXZNDVAMKGV-UHFFFAOYSA-L 0.000 description 2
239000010779 crude oil Substances 0.000 description 2
239000011521 glass Substances 0.000 description 2
230000005484 gravity Effects 0.000 description 2
150000002611 lead compounds Chemical class 0.000 description 2
238000011068 loading method Methods 0.000 description 2
239000000741 silica gel Substances 0.000 description 2
229910002027 silica gel Inorganic materials 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
238000011282 treatment Methods 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
239000005995 Aluminium silicate Substances 0.000 description 1
229910021590 Copper(II) bromide Inorganic materials 0.000 description 1
238000002835 absorbance Methods 0.000 description 1
238000010306 acid treatment Methods 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
238000010923 batch production Methods 0.000 description 1
238000001354 calcination Methods 0.000 description 1
238000011088 calibration curve Methods 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
238000007385 chemical modification Methods 0.000 description 1
229910052570 clay Inorganic materials 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
229960003280 cupric chloride Drugs 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
229910001649 dickite Inorganic materials 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
239000010771 distillate fuel oil Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
230000001050 lubricating effect Effects 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000011707 mineral Substances 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
235000010446 mineral oil Nutrition 0.000 description 1
125000005609 naphthenate group Chemical group 0.000 description 1
239000003921 oil Substances 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
238000002407 reforming Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical group CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 description 1
125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
XOOGZRUBTYCLHG-UHFFFAOYSA-N tetramethyllead Chemical compound C[Pb](C)(C)C XOOGZRUBTYCLHG-UHFFFAOYSA-N 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Treatment Of Liquids With Adsorbents In General (AREA)

CA290,563A 1976-12-27 1977-11-09 Procede d'extraction d'impuretes d'alkyles de plomb dans des hydrocarbures liquides Expired CA1106308A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US75446176A	1976-12-27	1976-12-27
US754,461		1976-12-27

Publications (1)

Publication Number	Publication Date
CA1106308A true CA1106308A (fr)	1981-08-04

Family

ID=25034892

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA290,563A Expired CA1106308A (fr)	1976-12-27	1977-11-09	Procede d'extraction d'impuretes d'alkyles de plomb dans des hydrocarbures liquides

Country Status (13)

Country	Link
JP (1)	JPS5382805A (fr)
AU (1)	AU515118B2 (fr)
BE (1)	BE861604A (fr)
CA (1)	CA1106308A (fr)
DE (1)	DE2756222A1 (fr)
ES (1)	ES465271A1 (fr)
FR (1)	FR2375316A1 (fr)
GB (1)	GB1582996A (fr)
IT (1)	IT1089122B (fr)
NL (1)	NL7714295A (fr)
NO (1)	NO774325L (fr)
NZ (1)	NZ185798A (fr)
ZA (1)	ZA777104B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5622386A (en) *	1979-07-31	1981-03-02	Nippon Oil Co Ltd	Mineral oil refining
JP3537581B2 (ja) *	1996-03-04	2004-06-14	クラレケミカル株式会社	水銀吸着剤

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2368261A (en) *	1943-04-16	1945-01-30	Jr Frederick E Neef	Method of removing dye and tetraethyl lead from gasoline
US2745793A (en) *	1953-02-02	1956-05-15	Sun Oil Co	Deleading gasoline
US3998725A (en) *	1975-04-30	1976-12-21	Exxon Research And Engineering Company	Method of removing alkyl lead compounds from liquid hydrocarbon fuels

1977
- 1977-11-09 CA CA290,563A patent/CA1106308A/fr not_active Expired
- 1977-11-24 AU AU30802/77A patent/AU515118B2/en not_active Expired
- 1977-11-28 NZ NZ185798A patent/NZ185798A/xx unknown
- 1977-11-29 ZA ZA00777104A patent/ZA777104B/xx unknown
- 1977-12-05 FR FR7736506A patent/FR2375316A1/fr not_active Withdrawn
- 1977-12-05 GB GB50501/77A patent/GB1582996A/en not_active Expired
- 1977-12-07 BE BE183254A patent/BE861604A/fr unknown
- 1977-12-15 NO NO774325A patent/NO774325L/no unknown
- 1977-12-16 DE DE19772756222 patent/DE2756222A1/de not_active Withdrawn
- 1977-12-21 ES ES465271A patent/ES465271A1/es not_active Expired
- 1977-12-22 NL NL7714295A patent/NL7714295A/xx not_active Application Discontinuation
- 1977-12-23 IT IT31251/77A patent/IT1089122B/it active
- 1977-12-27 JP JP15661477A patent/JPS5382805A/ja active Pending

Also Published As

Publication number	Publication date
DE2756222A1 (de)	1978-06-29
GB1582996A (en)	1981-01-21
FR2375316A1 (fr)	1978-07-21
JPS5382805A (en)	1978-07-21
NL7714295A (nl)	1978-06-29
IT1089122B (it)	1985-06-18
BE861604A (fr)	1978-06-07
ZA777104B (en)	1979-07-25
AU3080277A (en)	1979-05-31
NZ185798A (en)	1980-09-12
AU515118B2 (en)	1981-03-19
ES465271A1 (es)	1978-09-16
NO774325L (no)	1978-06-28

Legal Events

Date	Code	Title	Description
1998-08-04	MKEX	Expiry

Publication	Publication Date	Title
KR100608474B1 (ko)	2006-08-09	아세틸렌계 물질의 흡착 및 흡착제의 재생에 의한 올레핀 정제 방법
US5107060A (en)	1992-04-21	Thermal cracking of mercury-containing hydrocarbon
CA2008611A1 (fr)	1990-08-01	Methode pour eliminer le mercure dans les hydrocarbures par adsorption reactive a haute temprature
US5106507A (en)	1992-04-21	Method for recovering hydrocarbon contaminants from wastewater
US8551328B2 (en)	2013-10-08	Organic chloride adsorbent
JPS6141952B2 (fr)	1986-09-18
US6107535A (en)	2000-08-22	Process for removing nitrogenated and sulfurated contaminants from hydrocarbon streams
US4645587A (en)	1987-02-24	Process for removing silicon compounds from hydrocarbon streams
EP3442683B1 (fr)	2023-03-15	Procédé chimique de réduction de soufre d'hydrocarbures
US4137154A (en)	1979-01-30	Process for the removal of nitrogen compounds from various organic media
KR20000076130A (ko)	2000-12-26	아세틸렌계 화합물의 흡착에 의한 올레핀의 정제 및 흡착제의 재생
US8354019B2 (en)	2013-01-15	Process for reducing benzene content of hydrocarbon stream using microporous carbon adsorbent
US10689583B2 (en)	2020-06-23	Process for removing sulfur compounds from hydrocarbon streams
CA1106308A (fr)	1981-08-04	Procede d'extraction d'impuretes d'alkyles de plomb dans des hydrocarbures liquides
US4424120A (en)	1984-01-03	Process for removal of alkyl lead impurities from liquid hydrocarbons
US2999861A (en)	1961-09-12	Segregation of organic nitrogen compounds
US3121756A (en)	1964-02-18	Separatory process using modified montmorillonites
US4424119A (en)	1984-01-03	Process for removal of alkyl lead impurities from liquid hydrocarbons
US7435337B2 (en)	2008-10-14	Use of caesium-exchanged faujasite type zeolites for intense desulphurization of a gasoline cut
US4120782A (en)	1978-10-17	Method for improving the treating capacity of a clay sorbent
US5834392A (en)	1998-11-10	Nitrile selective adsorbent
CA1132122A (fr)	1982-09-21	Methode de fractionnement catalytique d'hydrocarbures, et catalyseur pour la mise en oeuvre de ladite methode
US2270058A (en)	1942-01-13	Refining of mineral oils
US20040065618A1 (en)	2004-04-08	Purification process
KR20100011953A (ko)	2010-02-03	트리에틸포스페이트(ｔｅｐｏ)로부터 미량의 비소 불순물을 제거하는 방법