CA1106347A - Fabrication d'un catalyseur de conversion d'hydro- carbures - Google Patents

Fabrication d'un catalyseur de conversion d'hydro- carbures

Info

Publication number: CA1106347A
Authority: CA; Canada
Prior art keywords: zeolite; mixing; slurry; clay; sol
Prior art date: 1977-07-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA304,551A

Other languages

English (en)

Inventor

Theodore V. Flaherty, Jr.

Richard J. Nozemack

Hanson L. Guidry

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

WR Grace and Co

Original Assignee

WR Grace and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-07-12

Filing date

1978-05-31

Publication date

1981-08-04

1977-07-12 Priority claimed from US05/814,819 external-priority patent/US4126579A/en

1978-05-31 Application filed by WR Grace and Co filed Critical WR Grace and Co

1981-08-04 Application granted granted Critical

1981-08-04 Publication of CA1106347A publication Critical patent/CA1106347A/fr

Status Expired legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 33
239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 7
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 7
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 7
238000004519 manufacturing process Methods 0.000 title claims abstract description 7
238000006243 chemical reaction Methods 0.000 title claims abstract description 6
239000010457 zeolite Substances 0.000 claims abstract description 28
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 27
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 26
239000002002 slurry Substances 0.000 claims abstract description 26
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 25
239000002245 particle Substances 0.000 claims abstract description 24
238000002156 mixing Methods 0.000 claims abstract description 21
239000000203 mixture Substances 0.000 claims abstract description 14
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 11
230000002378 acidificating effect Effects 0.000 claims abstract description 7
238000005507 spraying Methods 0.000 claims abstract description 7
239000000741 silica gel Substances 0.000 claims abstract description 4
229910002027 silica gel Inorganic materials 0.000 claims abstract description 4
238000000034 method Methods 0.000 claims description 23
239000004927 clay Substances 0.000 claims description 19
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
239000002253 acid Substances 0.000 claims description 13
239000004115 Sodium Silicate Substances 0.000 claims description 12
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 12
229910052911 sodium silicate Inorganic materials 0.000 claims description 12
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
238000001035 drying Methods 0.000 claims description 8
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 5
229910000323 aluminium silicate Inorganic materials 0.000 claims description 4
238000005406 washing Methods 0.000 claims description 4
239000000376 reactant Substances 0.000 claims description 3
150000003839 salts Chemical class 0.000 claims description 3
150000007513 acids Chemical class 0.000 claims description 2
239000011230 binding agent Substances 0.000 claims description 2
239000000047 product Substances 0.000 description 14
239000007921 spray Substances 0.000 description 14
239000000243 solution Substances 0.000 description 11
239000000377 silicon dioxide Substances 0.000 description 10
239000004005 microsphere Substances 0.000 description 9
239000003570 air Substances 0.000 description 8
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 6
239000011148 porous material Substances 0.000 description 6
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000000499 gel Substances 0.000 description 4
239000000017 hydrogel Substances 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
229910052761 rare earth metal Inorganic materials 0.000 description 4
150000002910 rare earth metals Chemical class 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
239000011734 sodium Substances 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
238000000889 atomisation Methods 0.000 description 3
239000012013 faujasite Substances 0.000 description 3
238000012986 modification Methods 0.000 description 3
230000004048 modification Effects 0.000 description 3
239000007787 solid Substances 0.000 description 3
238000001694 spray drying Methods 0.000 description 3
229910052681 coesite Inorganic materials 0.000 description 2
229910052906 cristobalite Inorganic materials 0.000 description 2
239000007789 gas Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
229910052682 stishovite Inorganic materials 0.000 description 2
229910052905 tridymite Inorganic materials 0.000 description 2
239000003039 volatile agent Substances 0.000 description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
241000282326 Felis catus Species 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
229940037003 alum Drugs 0.000 description 1
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
239000012080 ambient air Substances 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
239000011959 amorphous silica alumina Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000004523 catalytic cracking Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000005336 cracking Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000011369 resultant mixture Substances 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
229910001388 sodium aluminate Inorganic materials 0.000 description 1
238000009718 spray deposition Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/32—Freeze drying, i.e. lyophilisation
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Crystallography & Structural Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Chemical & Material Sciences (AREA)
Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)

CA304,551A 1977-07-12 1978-05-31 Fabrication d'un catalyseur de conversion d'hydro- carbures Expired CA1106347A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US05/814,819 US4126579A (en)	1977-03-22	1977-07-12	Hydrocarbon conversion catalyst manufacture
US814,819		1977-07-12

Publications (1)

Publication Number	Publication Date
CA1106347A true CA1106347A (fr)	1981-08-04

Family

ID=25216081

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA304,551A Expired CA1106347A (fr)	1977-07-12	1978-05-31	Fabrication d'un catalyseur de conversion d'hydro- carbures

Country Status (7)

Country	Link
JP (1)	JPS5440292A (fr)
CA (1)	CA1106347A (fr)
DE (1)	DE2829477A1 (fr)
FR (1)	FR2397230A1 (fr)
GB (1)	GB2000986B (fr)
MX (1)	MX151212A (fr)
NL (1)	NL7807455A (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4548912A (en) *	1980-04-14	1985-10-22	Ashland Oil, Inc.	Microspherical catalysts
JPH0817944B2 (ja) *	1986-12-29	1996-02-28	東ソー株式会社	液相有機反応用ゼオライト触媒成形体
GB2331071A (en) *	1997-11-11	1999-05-12	Solvay	Manufacture of micro spherical zeolite containing catalyst particles
KR20090039742A (ko) *	2006-07-06	2009-04-22	더블유.알. 그레이스 앤드 캄파니-콘.	알루미늄 설페이트 결합 촉매

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1074496A (en) *	1964-02-10	1967-07-05	Grace W R & Co	Improved hydrocarbon cracking catalysts
GB1231826A (fr) *	1967-07-31	1971-05-12
JPS5422953B1 (fr) *	1969-01-02	1979-08-10
DE1953518A1 (de) *	1969-10-24	1971-05-06	Basf Ag	Verfahren zur Herstellung von Mischoxiden,die Eisen- und/oder Nickeloxide als Hauptkomponente enthalten
US3867308A (en) *	1973-12-10	1975-02-18	Grace W R & Co	Process for preparing a petroleum cracking catalyst
US3957689A (en) *	1974-08-02	1976-05-18	W. R. Grace & Co.	Process for preparing an attrition resistant zeolite hydrocarbon conversion catalyst

1978
- 1978-05-31 CA CA304,551A patent/CA1106347A/fr not_active Expired
- 1978-07-05 DE DE19782829477 patent/DE2829477A1/de not_active Withdrawn
- 1978-07-06 GB GB7829081A patent/GB2000986B/en not_active Expired
- 1978-07-11 FR FR7820647A patent/FR2397230A1/fr not_active Withdrawn
- 1978-07-11 MX MX174130A patent/MX151212A/es unknown
- 1978-07-11 JP JP8366178A patent/JPS5440292A/ja active Pending
- 1978-07-11 NL NL7807455A patent/NL7807455A/xx not_active Application Discontinuation

Also Published As

Publication number	Publication date
FR2397230A1 (fr)	1979-02-09
NL7807455A (nl)	1979-01-16
MX151212A (es)	1984-10-11
JPS5440292A (en)	1979-03-29
GB2000986B (en)	1982-04-15
DE2829477A1 (de)	1979-01-25
GB2000986A (en)	1979-01-24

Legal Events

Date	Code	Title	Description
1998-08-04	MKEX	Expiry

Publication	Publication Date	Title
CA1038364A (fr)	1978-09-12	Methode de preparation d'un catalyseur de raffinage du petrole
US4086187A (en)	1978-04-25	Attrition resistant zeolitic catalyst
US3957689A (en)	1976-05-18	Process for preparing an attrition resistant zeolite hydrocarbon conversion catalyst
US4126579A (en)	1978-11-21	Hydrocarbon conversion catalyst manufacture
US3140249A (en)	1964-07-07	Catalytic cracking of hydrocarbons with a crystalline zeolite catalyst composite
US5051385A (en)	1991-09-24	Monodispersed mesoporous catalyst matrices and FCC catalysts thereof
CA1071610A (en)	1980-02-12	Copolymerized silica hydrosol bound cracking catalyst
US4493902A (en)	1985-01-15	Fluid catalytic cracking catalyst comprising microspheres containing more than about 40 percent by weight Y-faujasite and methods for making
US3210267A (en)	1965-10-05	Catalytic cracking of hydrocarbons with the use of a crystalline zeolite catalyst containing rare earths and a porous matrix
Coustel et al.	1994	Improved stability of MCM-41 through textural control
KR101110092B1 (ko)	2012-03-08	오일 고흡수성 무정형 실리카 입자
US3459680A (en)	1969-08-05	Crystalline zeolite composite for catalytic hydrocarbon conversion
US4332699A (en)	1982-06-01	Catalyst preparation
JPS6214947A (ja)	1987-01-23	触媒の製法
US3506594A (en)	1970-04-14	Microspherical zeolitic molecular sieve composite catalyst and preparation thereof
US20020160192A1 (en)	2002-10-31	Attrition resistant inorganic microspheroidal particles
US5547564A (en)	1996-08-20	Catalytic Cracking
EP0209793A1 (fr)	1987-01-28	Catalyseur de craquage
MXPA03002474A (es)	2003-07-14	Catalizadores para la destilacion fraccionada estructuralmente mejorados.
GB2112368A (en)	1983-07-20	Alumina spheroids useful as a catalyst support
JPH0930809A (ja)	1997-02-04	シリカゲルの製造方法
CA1123813A (fr)	1982-05-18	Poudres d'aluminosilicate
JPH04310239A (ja)	1992-11-02	外皮を被覆されたｆｃｃ触媒
CA1106347A (fr)	1981-08-04	Fabrication d'un catalyseur de conversion d'hydro- carbures
JPH09507790A (ja)	1997-08-12	流動ベッドでメチルアミンを製造するための摩耗耐性をもったゼオライト触媒