CA1108107A - Catalyseur de craquage a resistance amelioree a l'empoisonnement par des elements metalliques - Google Patents

Catalyseur de craquage a resistance amelioree a l'empoisonnement par des elements metalliques

Info

Publication number: CA1108107A
Authority: CA; Canada
Prior art keywords: catalyst; silica; alumina; cracking; colloidal dispersion
Prior art date: 1977-02-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA291,954A

Other languages

English (en)

Inventor

Arthur W. Chester

William A. Stover

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-02-16

Filing date

1977-11-29

Publication date

1981-09-01

1977-11-29 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1981-09-01 Application granted granted Critical

1981-09-01 Publication of CA1108107A publication Critical patent/CA1108107A/fr

Status Expired legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 75
229910052751 metal Inorganic materials 0.000 title claims abstract description 31
239000002184 metal Substances 0.000 title claims abstract description 31
238000005336 cracking Methods 0.000 title claims abstract description 28
150000002739 metals Chemical class 0.000 title claims abstract description 14
231100000572 poisoning Toxicity 0.000 title claims abstract description 4
230000000607 poisoning effect Effects 0.000 title claims abstract description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 55
239000000377 silicon dioxide Substances 0.000 claims abstract description 25
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 22
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 12
239000010457 zeolite Substances 0.000 claims abstract description 9
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 8
238000000034 method Methods 0.000 claims description 14
239000002245 particle Substances 0.000 claims description 14
239000011159 matrix material Substances 0.000 claims description 10
238000001246 colloidal dispersion Methods 0.000 claims description 9
230000015572 biosynthetic process Effects 0.000 claims description 6
229910000323 aluminium silicate Inorganic materials 0.000 claims description 4
239000002131 composite material Substances 0.000 claims description 4
239000000356 contaminant Substances 0.000 claims description 4
229910052809 inorganic oxide Inorganic materials 0.000 claims description 3
238000004523 catalytic cracking Methods 0.000 claims description 2
239000012530 fluid Substances 0.000 claims description 2
239000004215 Carbon black (E152) Substances 0.000 claims 1
229930195733 hydrocarbon Natural products 0.000 claims 1
150000002430 hydrocarbons Chemical class 0.000 claims 1
238000002360 preparation method Methods 0.000 claims 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 1
239000000203 mixture Substances 0.000 abstract description 6
230000000694 effects Effects 0.000 description 13
239000000571 coke Substances 0.000 description 12
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
206010027439 Metal poisoning Diseases 0.000 description 10
229910052739 hydrogen Inorganic materials 0.000 description 10
239000001257 hydrogen Substances 0.000 description 10
229910052681 coesite Inorganic materials 0.000 description 7
229910052906 cristobalite Inorganic materials 0.000 description 7
239000007789 gas Substances 0.000 description 7
229910052759 nickel Inorganic materials 0.000 description 7
235000012239 silicon dioxide Nutrition 0.000 description 7
229910052682 stishovite Inorganic materials 0.000 description 7
229910052905 tridymite Inorganic materials 0.000 description 7
229910052720 vanadium Inorganic materials 0.000 description 7
239000011734 sodium Substances 0.000 description 6
239000008119 colloidal silica Substances 0.000 description 5
229910052761 rare earth metal Inorganic materials 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
238000001035 drying Methods 0.000 description 4
239000000499 gel Substances 0.000 description 4
239000011148 porous material Substances 0.000 description 4
239000000047 product Substances 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
-1 boria Chemical compound 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
238000009826 distribution Methods 0.000 description 3
238000010348 incorporation Methods 0.000 description 3
239000012263 liquid product Substances 0.000 description 3
239000002574 poison Substances 0.000 description 3
231100000614 poison Toxicity 0.000 description 3
150000002910 rare earth metals Chemical class 0.000 description 3
239000002002 slurry Substances 0.000 description 3
238000001694 spray drying Methods 0.000 description 3
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
239000004115 Sodium Silicate Substances 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
230000005484 gravity Effects 0.000 description 2
239000000017 hydrogel Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
229910052911 sodium silicate Inorganic materials 0.000 description 2
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
239000007921 spray Substances 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
238000012360 testing method Methods 0.000 description 2
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
239000008096 xylene Substances 0.000 description 2
SYQQWGGBOQFINV-FBWHQHKGSA-N 4-[2-[(2s,8s,9s,10r,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-3-oxo-1,2,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-2-yl]ethoxy]-4-oxobutanoic acid Chemical compound C1CC2=CC(=O)[C@H](CCOC(=O)CCC(O)=O)C[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 SYQQWGGBOQFINV-FBWHQHKGSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
239000008186 active pharmaceutical agent Substances 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 1
150000001463 antimony compounds Chemical class 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
238000001354 calcination Methods 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000004927 clay Substances 0.000 description 1
239000012084 conversion product Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
230000002939 deleterious effect Effects 0.000 description 1
238000000151 deposition Methods 0.000 description 1
238000011161 development Methods 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
238000000265 homogenisation Methods 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
150000002697 manganese compounds Chemical class 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
229910052914 metal silicate Inorganic materials 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
229910052680 mordenite Inorganic materials 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
230000009290 primary effect Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
239000003870 refractory metal Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000010025 steaming Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Crystallography & Structural Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

CA291,954A 1977-02-16 1977-11-29 Catalyseur de craquage a resistance amelioree a l'empoisonnement par des elements metalliques Expired CA1108107A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US76924477A	1977-02-16	1977-02-16
US769,244		1977-02-16

Publications (1)

Publication Number	Publication Date
CA1108107A true CA1108107A (fr)	1981-09-01

Family

ID=25084906

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA291,954A Expired CA1108107A (fr)	1977-02-16	1977-11-29	Catalyseur de craquage a resistance amelioree a l'empoisonnement par des elements metalliques

Country Status (7)

Country	Link
JP (1)	JPS53100985A (fr)
AU (1)	AU515612B2 (fr)
BR (1)	BR7800895A (fr)
CA (1)	CA1108107A (fr)
DE (1)	DE2756220A1 (fr)
GB (1)	GB1585711A (fr)
NL (1)	NL7801693A (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1133879A (fr) *	1979-03-19	1982-10-19	Jerome F. Mayer	Catalyseur convertisseur d'hydrocarbures, et procede faisant appel audit catalyseur
US4326993A (en) *	1979-12-17	1982-04-27	Mobil Oil Corporation	Novel cracking catalysts and catalyst supports
SE438449B (sv) *	1980-06-30	1985-04-22	Katalistiks International Bv	Krackningskatalysator for krackning av kolveten i en med fluidiserad katalysatorbedd arbetande reaktor
JPS6121191A (ja) *	1984-07-09	1986-01-29	ガルフ・リサ−チ・エンド・デベロツプメント・コンパニ−	新規な接触分解組成物およびこれを用いる高金属含有量の供給材料を接触分解する方法
CA1329580C (fr) *	1987-12-28	1994-05-17	Pochen Chu	Obtention de catalyseurs pour le craquage de bases d'hydrocarbures lourds

1977
- 1977-11-29 CA CA291,954A patent/CA1108107A/fr not_active Expired
- 1977-12-06 AU AU31265/77A patent/AU515612B2/en not_active Expired
- 1977-12-16 DE DE19772756220 patent/DE2756220A1/de not_active Withdrawn
1978
- 1978-01-03 GB GB4778A patent/GB1585711A/en not_active Expired
- 1978-01-31 JP JP899978A patent/JPS53100985A/ja active Pending
- 1978-02-15 NL NL7801693A patent/NL7801693A/xx not_active Application Discontinuation
- 1978-02-15 BR BR7800895A patent/BR7800895A/pt unknown

Also Published As

Publication number	Publication date
AU3126577A (en)	1979-06-14
JPS53100985A (en)	1978-09-02
AU515612B2 (en)	1981-04-16
DE2756220A1 (de)	1978-08-17
BR7800895A (pt)	1979-01-02
GB1585711A (en)	1981-03-11
NL7801693A (nl)	1978-08-18

Legal Events

Date	Code	Title	Description
1998-09-01	MKEX	Expiry

Publication	Publication Date	Title
US4198320A (en)	1980-04-15	Cracking catalyst with improved resistance to poisoning by metals
CA2057738C (fr)	2003-08-19	Compositions catalytiques
CA1155104A (fr)	1983-10-11	Supports de catalyseurs, et catalyseurs de fractionnement qui les renferment
US3210267A (en)	1965-10-05	Catalytic cracking of hydrocarbons with the use of a crystalline zeolite catalyst containing rare earths and a porous matrix
US4442223A (en)	1984-04-10	Catalyst and catalyst support compositions
US4137152A (en)	1979-01-30	Selective high conversion cracking process
US3459680A (en)	1969-08-05	Crystalline zeolite composite for catalytic hydrocarbon conversion
EP0083163A1 (fr)	1983-07-06	Catalyseur pour la conversion d'hydrocarbures lourds et procédés utilisant un tel catalyseur
US5001097A (en)	1991-03-19	Hydrocarbon conversion with octane-enhancing catalysts
US4880787A (en)	1989-11-14	Cracking catalyst
US5997729A (en)	1999-12-07	Catalytic cracking catalyst and method for cracking a heavy oil
US5037531A (en)	1991-08-06	Catalytic cracking process
CA1216835A (fr)	1987-01-20	Catalyseurs de conversion d'hydrocarbures
US3686121A (en)	1972-08-22	Hydrocarbon conversion catalyst
AU601466B2 (en)	1990-09-13	A cracking catalyst and the preparation and use thereof
US5001096A (en)	1991-03-19	Metal passivating agents
US5160601A (en)	1992-11-03	Hydrocarbon conversion with octane-enhancing catalysts
JPS60193543A (ja)	1985-10-02	炭化水素接触分解用触媒組成物の製造法
GB1585711A (en)	1981-03-11	Cracking catalyst with resistance to poisoning by metals
JP4394992B2 (ja)	2010-01-06	ガソリンのオクタン価及び／又は低級オレフィン増加用触媒組成物及びそれを使用した炭化水素の流動接触分解方法
AU617395B2 (en)	1991-11-28	Catalytic cracking catalysts
JP3527036B2 (ja)	2004-05-17	炭化水素接触分解用触媒組成物の製造方法
US3459679A (en)	1969-08-05	Catalyst prepared by steaming alkali metal aluminosilicate in a matrix with polyvalent metal salt
SK149296A3 (en)	1997-08-06	A catalyst or catalyst additive, method of their preparation and their use for cracking mineral oil fractions
CA1242983A (fr)	1988-10-11	Procede de craquage catalytique zsm-5 utilisant des cristaux zsm-5 de grande taille