CA1114151A - Obtention de ceramiques de dioxyde de titane polycristallin - Google Patents

Obtention de ceramiques de dioxyde de titane polycristallin

Info

Publication number: CA1114151A
Authority: CA; Canada
Prior art keywords: metal species; slurry; titanium dioxide; powder; rutile
Prior art date: 1976-02-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA356,359A

Other languages

English (en)

Inventor

Owen W. Johnson

Gerald R. Miller

Paul S. Beutler

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Ford Motor Co

Original Assignee

Ford Motor Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-02-18

Filing date

1980-07-16

Publication date

1981-12-15

1977-02-17 Priority claimed from CA272,017A external-priority patent/CA1099092A/fr

1980-07-16 Application filed by Ford Motor Co filed Critical Ford Motor Co

1980-07-16 Priority to CA356,359A priority Critical patent/CA1114151A/fr

1981-12-15 Application granted granted Critical

1981-12-15 Publication of CA1114151A publication Critical patent/CA1114151A/fr

Status Expired legal-status Critical Current

Links

GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 114
239000000919 ceramic Substances 0.000 title claims abstract description 54
239000004408 titanium dioxide Substances 0.000 title claims abstract description 36
238000004519 manufacturing process Methods 0.000 title claims description 5
229910052751 metal Inorganic materials 0.000 claims abstract description 53
239000002184 metal Substances 0.000 claims abstract description 53
239000000843 powder Substances 0.000 claims abstract description 40
239000002002 slurry Substances 0.000 claims abstract description 31
238000005245 sintering Methods 0.000 claims abstract description 18
238000010438 heat treatment Methods 0.000 claims abstract description 16
239000001301 oxygen Substances 0.000 claims abstract description 11
229910052760 oxygen Inorganic materials 0.000 claims abstract description 11
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 10
238000001035 drying Methods 0.000 claims abstract description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
239000000203 mixture Substances 0.000 claims abstract description 7
-1 aliphatic alcohols Chemical class 0.000 claims abstract description 6
238000001704 evaporation Methods 0.000 claims abstract description 5
230000008020 evaporation Effects 0.000 claims abstract description 5
150000003839 salts Chemical class 0.000 claims abstract description 5
238000000137 annealing Methods 0.000 claims abstract description 4
OHZZTXYKLXZFSZ-UHFFFAOYSA-I manganese(3+) 5,10,15-tris(1-methylpyridin-1-ium-4-yl)-20-(1-methylpyridin-4-ylidene)porphyrin-22-ide pentachloride Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Mn+3].C1=CN(C)C=CC1=C1C(C=C2)=NC2=C(C=2C=C[N+](C)=CC=2)C([N-]2)=CC=C2C(C=2C=C[N+](C)=CC=2)=C(C=C2)N=C2C(C=2C=C[N+](C)=CC=2)=C2N=C1C=C2 OHZZTXYKLXZFSZ-UHFFFAOYSA-I 0.000 claims abstract description 4
239000002904 solvent Substances 0.000 claims abstract description 3
229910052715 tantalum Inorganic materials 0.000 claims description 47
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 46
238000000034 method Methods 0.000 claims description 37
229910052758 niobium Inorganic materials 0.000 claims description 30
239000010955 niobium Substances 0.000 claims description 30
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 28
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 21
239000000463 material Substances 0.000 claims description 13
230000035939 shock Effects 0.000 claims description 6
238000000265 homogenisation Methods 0.000 claims description 5
230000009972 noncorrosive effect Effects 0.000 claims description 5
150000001875 compounds Chemical class 0.000 claims description 2
230000001747 exhibiting effect Effects 0.000 claims description 2
SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 2
229960004132 diethyl ether Drugs 0.000 claims 2
238000007792 addition Methods 0.000 description 13
239000012535 impurity Substances 0.000 description 9
235000010215 titanium dioxide Nutrition 0.000 description 9
229910002370 SrTiO3 Inorganic materials 0.000 description 7
238000012545 processing Methods 0.000 description 7
241000894007 species Species 0.000 description 7
238000009834 vaporization Methods 0.000 description 7
230000008016 vaporization Effects 0.000 description 7
239000011230 binding agent Substances 0.000 description 6
125000002091 cationic group Chemical group 0.000 description 6
230000007797 corrosion Effects 0.000 description 6
238000005260 corrosion Methods 0.000 description 6
229910002971 CaTiO3 Inorganic materials 0.000 description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
238000009826 distribution Methods 0.000 description 5
150000002500 ions Chemical class 0.000 description 5
230000003647 oxidation Effects 0.000 description 5
238000007254 oxidation reaction Methods 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
239000000654 additive Substances 0.000 description 4
239000003570 air Substances 0.000 description 4
238000001816 cooling Methods 0.000 description 4
235000019441 ethanol Nutrition 0.000 description 4
ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Inorganic materials O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 description 4
URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 4
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 description 4
230000000996 additive effect Effects 0.000 description 3
239000011449 brick Substances 0.000 description 3
238000005524 ceramic coating Methods 0.000 description 3
239000011248 coating agent Substances 0.000 description 3
238000000576 coating method Methods 0.000 description 3
239000013078 crystal Substances 0.000 description 3
239000002019 doping agent Substances 0.000 description 3
229910052742 iron Inorganic materials 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
239000011812 mixed powder Substances 0.000 description 3
YHBDIEWMOMLKOO-UHFFFAOYSA-I pentachloroniobium Chemical compound Cl[Nb](Cl)(Cl)(Cl)Cl YHBDIEWMOMLKOO-UHFFFAOYSA-I 0.000 description 3
239000005077 polysulfide Substances 0.000 description 3
229920001021 polysulfide Polymers 0.000 description 3
150000008117 polysulfides Polymers 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
238000003756 stirring Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
OEIMLTQPLAGXMX-UHFFFAOYSA-I tantalum(v) chloride Chemical compound Cl[Ta](Cl)(Cl)(Cl)Cl OEIMLTQPLAGXMX-UHFFFAOYSA-I 0.000 description 3
238000012360 testing method Methods 0.000 description 3
238000005303 weighing Methods 0.000 description 3
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
239000004372 Polyvinyl alcohol Substances 0.000 description 2
239000012080 ambient air Substances 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
WEUCVIBPSSMHJG-UHFFFAOYSA-N calcium titanate Chemical compound [O-2].[O-2].[O-2].[Ca+2].[Ti+4] WEUCVIBPSSMHJG-UHFFFAOYSA-N 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
229910001873 dinitrogen Inorganic materials 0.000 description 2
230000002706 hydrostatic effect Effects 0.000 description 2
239000007788 liquid Substances 0.000 description 2
229910052574 oxide ceramic Inorganic materials 0.000 description 2
239000011224 oxide ceramic Substances 0.000 description 2
BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 2
239000008188 pellet Substances 0.000 description 2
238000013001 point bending Methods 0.000 description 2
229920002451 polyvinyl alcohol Polymers 0.000 description 2
239000005297 pyrex Substances 0.000 description 2
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
229910010271 silicon carbide Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 description 2
DNXHEGUUPJUMQT-UHFFFAOYSA-N (+)-estrone Natural products OC1=CC=C2C3CCC(C)(C(CC4)=O)C4C3CCC2=C1 DNXHEGUUPJUMQT-UHFFFAOYSA-N 0.000 description 1
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
241000370685 Arge Species 0.000 description 1
241000582342 Carria Species 0.000 description 1
FVIGODVHAVLZOO-UHFFFAOYSA-N Dixanthogen Chemical compound CCOC(=S)SSC(=S)OCC FVIGODVHAVLZOO-UHFFFAOYSA-N 0.000 description 1
240000002989 Euphorbia neriifolia Species 0.000 description 1
244000228957 Ferula foetida Species 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
101100409194 Rattus norvegicus Ppargc1b gene Proteins 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
238000007743 anodising Methods 0.000 description 1
JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
229910002113 barium titanate Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000003518 caustics Substances 0.000 description 1
229910010293 ceramic material Inorganic materials 0.000 description 1
238000004814 ceramic processing Methods 0.000 description 1
239000002800 charge carrier Substances 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
239000000470 constituent Substances 0.000 description 1
231100000069 corrosive reaction Toxicity 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
238000000280 densification Methods 0.000 description 1
238000001739 density measurement Methods 0.000 description 1
238000001514 detection method Methods 0.000 description 1
238000011161 development Methods 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
229960002377 dixanthogen Drugs 0.000 description 1
230000005684 electric field Effects 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
239000003966 growth inhibitor Substances 0.000 description 1
238000007654 immersion Methods 0.000 description 1
230000007774 longterm Effects 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
239000011268 mixed slurry Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000004570 mortar (masonry) Substances 0.000 description 1
150000002822 niobium compounds Chemical class 0.000 description 1
229910000484 niobium oxide Inorganic materials 0.000 description 1
239000000615 nonconductor Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
AOLPZAHRYHXPLR-UHFFFAOYSA-I pentafluoroniobium Chemical compound F[Nb](F)(F)(F)F AOLPZAHRYHXPLR-UHFFFAOYSA-I 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
238000003825 pressing Methods 0.000 description 1
238000003672 processing method Methods 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
229910001925 ruthenium oxide Inorganic materials 0.000 description 1
WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
229910052979 sodium sulfide Inorganic materials 0.000 description 1
GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
238000004901 spalling Methods 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
229910001936 tantalum oxide Inorganic materials 0.000 description 1
238000005382 thermal cycling Methods 0.000 description 1
HLCHESOMJVGDSJ-UHFFFAOYSA-N thiq Chemical compound C1=CC(Cl)=CC=C1CC(C(=O)N1CCC(CN2N=CN=C2)(CC1)C1CCCCC1)NC(=O)C1NCC2=CC=CC=C2C1 HLCHESOMJVGDSJ-UHFFFAOYSA-N 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
230000004584 weight gain Effects 0.000 description 1
235000019786 weight gain Nutrition 0.000 description 1

Landscapes

Compositions Of Oxide Ceramics (AREA)

CA356,359A 1976-02-18 1980-07-16 Obtention de ceramiques de dioxyde de titane polycristallin Expired CA1114151A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA356,359A CA1114151A (fr)	1976-02-18	1980-07-16	Obtention de ceramiques de dioxyde de titane polycristallin

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US65897576A	1976-02-18	1976-02-18
US658,975		1976-02-18
CA272,017A CA1099092A (fr)	1976-02-18	1977-02-17	Collecteur ou accumulateur de courant materiau a conductivite amelioree et non corrodable
CA356,359A CA1114151A (fr)	1976-02-18	1980-07-16	Obtention de ceramiques de dioxyde de titane polycristallin

Publications (1)

Publication Number	Publication Date
CA1114151A true CA1114151A (fr)	1981-12-15

Family

ID=27164914

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA356,359A Expired CA1114151A (fr)	1976-02-18	1980-07-16	Obtention de ceramiques de dioxyde de titane polycristallin

Country Status (1)

Country	Link
CA (1)	CA1114151A (fr)

1980
- 1980-07-16 CA CA356,359A patent/CA1114151A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1998-12-15	MKEX	Expiry

Publication	Publication Date	Title
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