CA1120000A - Extraction du titane par voie electrolytique - Google Patents

Extraction du titane par voie electrolytique

Info

Publication number: CA1120000A
Authority: CA; Canada
Prior art keywords: diaphragm; cathode; anode; cell; titanium
Prior art date: 1978-04-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000301820A

Other languages

English (en)

Inventor

David R. Johnson

Paul R. Juckniess

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-04-24

Filing date

1978-04-24

Publication date

1982-03-16

1978-04-24 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1978-04-24 Priority to CA000301820A priority Critical patent/CA1120000A/fr

1982-03-16 Application granted granted Critical

1982-03-16 Publication of CA1120000A publication Critical patent/CA1120000A/fr

Status Expired legal-status Critical Current

Links

229910052719 titanium Inorganic materials 0.000 title claims abstract description 52
239000010936 titanium Substances 0.000 title claims abstract description 52
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 46
238000000034 method Methods 0.000 title claims abstract description 31
238000005363 electrowinning Methods 0.000 title description 4
229910052751 metal Inorganic materials 0.000 claims abstract description 31
239000002184 metal Substances 0.000 claims abstract description 31
150000003839 salts Chemical class 0.000 claims abstract description 18
239000007789 gas Substances 0.000 claims abstract description 17
150000003609 titanium compounds Chemical class 0.000 claims abstract description 11
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 35
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 17
229910052759 nickel Inorganic materials 0.000 claims description 16
239000010941 cobalt Substances 0.000 claims description 14
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 14
229910017052 cobalt Inorganic materials 0.000 claims description 13
239000000758 substrate Substances 0.000 claims description 13
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
239000011148 porous material Substances 0.000 claims description 10
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 7
239000011248 coating agent Substances 0.000 claims description 7
238000000576 coating method Methods 0.000 claims description 7
239000000203 mixture Substances 0.000 claims description 7
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
229910052742 iron Inorganic materials 0.000 claims description 6
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 6
150000002739 metals Chemical class 0.000 claims description 4
235000011164 potassium chloride Nutrition 0.000 claims description 4
229910052786 argon Inorganic materials 0.000 claims description 3
238000005868 electrolysis reaction Methods 0.000 claims description 3
239000001103 potassium chloride Substances 0.000 claims description 3
229910045601 alloy Inorganic materials 0.000 claims description 2
239000000956 alloy Substances 0.000 claims description 2
239000000374 eutectic mixture Substances 0.000 claims description 2
230000005496 eutectics Effects 0.000 claims description 2
230000008018 melting Effects 0.000 claims description 2
238000002844 melting Methods 0.000 claims description 2
229910000531 Co alloy Inorganic materials 0.000 claims 1
229910000640 Fe alloy Inorganic materials 0.000 claims 1
229910000990 Ni alloy Inorganic materials 0.000 claims 1
239000003792 electrolyte Substances 0.000 abstract description 16
239000012298 atmosphere Substances 0.000 abstract description 11
150000001875 compounds Chemical class 0.000 abstract description 3
238000011109 contamination Methods 0.000 abstract description 2
210000000188 diaphragm Anatomy 0.000 description 103
239000000243 solution Substances 0.000 description 27
238000000151 deposition Methods 0.000 description 17
230000008021 deposition Effects 0.000 description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 14
238000012360 testing method Methods 0.000 description 12
-1 titanium Chemical class 0.000 description 12
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 10
239000000460 chlorine Substances 0.000 description 10
229910052801 chlorine Inorganic materials 0.000 description 10
229940075397 calomel Drugs 0.000 description 9
ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 9
239000011780 sodium chloride Substances 0.000 description 7
150000004820 halides Chemical class 0.000 description 6
238000003780 insertion Methods 0.000 description 6
230000037431 insertion Effects 0.000 description 6
239000000463 material Substances 0.000 description 6
239000003570 air Substances 0.000 description 5
HCQWRNRRURULEY-UHFFFAOYSA-L lithium;potassium;dichloride Chemical compound [Li+].[Cl-].[Cl-].[K+] HCQWRNRRURULEY-UHFFFAOYSA-L 0.000 description 5
239000010802 sludge Substances 0.000 description 5
239000007787 solid Substances 0.000 description 5
LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 4
238000007747 plating Methods 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
GTKRFUAGOKINCA-UHFFFAOYSA-M chlorosilver;silver Chemical compound [Ag].[Ag]Cl GTKRFUAGOKINCA-UHFFFAOYSA-M 0.000 description 3
239000002131 composite material Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
229910001209 Low-carbon steel Inorganic materials 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
229910000831 Steel Inorganic materials 0.000 description 2
230000001464 adherent effect Effects 0.000 description 2
239000003513 alkali Substances 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
230000004888 barrier function Effects 0.000 description 2
229910052793 cadmium Inorganic materials 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000000919 ceramic Substances 0.000 description 2
238000004320 controlled atmosphere Methods 0.000 description 2
230000001276 controlling effect Effects 0.000 description 2
235000019589 hardness Nutrition 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
238000005259 measurement Methods 0.000 description 2
230000001681 protective effect Effects 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
239000010959 steel Substances 0.000 description 2
229910000975 Carbon steel Inorganic materials 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
UOACKFBJUYNSLK-XRKIENNPSA-N Estradiol Cypionate Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H](C4=CC=C(O)C=C4CC3)CC[C@@]21C)C(=O)CCC1CCCC1 UOACKFBJUYNSLK-XRKIENNPSA-N 0.000 description 1
241001149900 Fusconaia subrotunda Species 0.000 description 1
229910020549 KCl—NaCl Inorganic materials 0.000 description 1
229910013618 LiCl—KCl Inorganic materials 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
KUGRPPRAQNPSQD-UHFFFAOYSA-N OOOOO Chemical compound OOOOO KUGRPPRAQNPSQD-UHFFFAOYSA-N 0.000 description 1
MOMWFXLCFJOAFX-UHFFFAOYSA-N OOOOOOOO Chemical compound OOOOOOOO MOMWFXLCFJOAFX-UHFFFAOYSA-N 0.000 description 1
229910021607 Silver chloride Inorganic materials 0.000 description 1
229910010062 TiCl3 Inorganic materials 0.000 description 1
229910003074 TiCl4 Inorganic materials 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910001508 alkali metal halide Inorganic materials 0.000 description 1
229910001615 alkaline earth metal halide Inorganic materials 0.000 description 1
239000012080 ambient air Substances 0.000 description 1
239000010405 anode material Substances 0.000 description 1
238000004364 calculation method Methods 0.000 description 1
UBAZGMLMVVQSCD-UHFFFAOYSA-N carbon dioxide;molecular oxygen Chemical compound O=O.O=C=O UBAZGMLMVVQSCD-UHFFFAOYSA-N 0.000 description 1
229910010293 ceramic material Inorganic materials 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000011247 coating layer Substances 0.000 description 1
229940000425 combination drug Drugs 0.000 description 1
238000004891 communication Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000002950 deficient Effects 0.000 description 1
238000013461 design Methods 0.000 description 1
238000005553 drilling Methods 0.000 description 1
230000005611 electricity Effects 0.000 description 1
239000008151 electrolyte solution Substances 0.000 description 1
238000005530 etching Methods 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
239000010439 graphite Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
238000005065 mining Methods 0.000 description 1
238000012544 monitoring process Methods 0.000 description 1
150000004767 nitrides Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
238000004080 punching Methods 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
239000011833 salt mixture Substances 0.000 description 1
238000007790 scraping Methods 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
OGFYIDCVDSATDC-UHFFFAOYSA-N silver silver Chemical compound [Ag].[Ag] OGFYIDCVDSATDC-UHFFFAOYSA-N 0.000 description 1
238000005245 sintering Methods 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
WRWQVSOJXAVREP-UHFFFAOYSA-J tetrachlorotitanium hydrochloride Chemical compound Cl.[Cl-].[Cl-].[Cl-].[Cl-].[Ti+4] WRWQVSOJXAVREP-UHFFFAOYSA-J 0.000 description 1
150000003608 titanium Chemical class 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
239000002699 waste material Substances 0.000 description 1
238000009941 weaving Methods 0.000 description 1

Landscapes

Electrolytic Production Of Metals (AREA)

CA000301820A 1978-04-24 1978-04-24 Extraction du titane par voie electrolytique Expired CA1120000A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000301820A CA1120000A (fr)	1978-04-24	1978-04-24	Extraction du titane par voie electrolytique

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000301820A CA1120000A (fr)	1978-04-24	1978-04-24	Extraction du titane par voie electrolytique

Publications (1)

Publication Number	Publication Date
CA1120000A true CA1120000A (fr)	1982-03-16

Family

ID=4111320

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000301820A Expired CA1120000A (fr)	1978-04-24	1978-04-24	Extraction du titane par voie electrolytique

Country Status (1)

Country	Link
CA (1)	CA1120000A (fr)

1978
- 1978-04-24 CA CA000301820A patent/CA1120000A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1999-03-16	MKEX	Expiry

Publication	Publication Date	Title
CA1068645A (fr)	1979-12-25	Cathodes d'electrolyse enduites d'un melange vaporise et lixivie de nickel et de cobalt
CN101328592B (zh)	2010-12-08	导电的金刚石电极结构和用于含氟材料的电解合成的方法
CA1072916A (fr)	1980-03-04	Cathodes pour electrolyse a revetement vaporise de bioxyde de cobalt et de zirconium
CA2339092A1 (fr)	2000-02-10	Cellules d'extraction electrolytique de l'aluminium avec anodes a base de metal aux dimensions stables
CA2492215A1 (fr)	2004-01-22	Cellule electrolytique pour production d'aluminium a partir d'alumine
US2848397A (en)	1958-08-19	Electrolytic production of metallic titanium
CA2544702A1 (fr)	2005-05-19	Production electrolytique d'aluminium
US4167468A (en)	1979-09-11	Apparatus for electrowinning multivalent metals
US2908619A (en)	1959-10-13	Production of titanium
US2975111A (en)	1961-03-14	Production of titanium
Barhoun et al.	1992	Electrodeposition of niobium from fluoroniobate K2NbF7 solutions in fused NaCl-KCl
US4165262A (en)	1979-08-21	Method of electrowinning titanium
US4118291A (en)	1978-10-03	Method of electrowinning titanium
FI61726C (fi)	1982-09-10	Sintrad kiselkarbid-ventil-metallborid-kolanod foer elektrokemiska processer
CA1120000A (fr)	1982-03-16	Extraction du titane par voie electrolytique
JPS5834553B2 (ja)	1983-07-27	Ｚ↓ｒ又はＨ↓ｆ生成用電解槽
US4116801A (en)	1978-09-26	Apparatus for electrowinning multivalent metals
US4219401A (en)	1980-08-26	Metal electrowinning feed cathode
CA1062202A (fr)	1979-09-11	Cathodes recouvertes de rhenium
EP0104759B1 (fr)	1986-05-07	Electrode de condensateur poreuse en tantale et sa production
US3082159A (en)	1963-03-19	Production of titanium
US20030173227A1 (en)	2003-09-18	Electrolytic cell for producing aluminum employing planar anodes
Schwarz et al.	1995	Electrorefining of aluminium scrap from chloride melts
CA1112605A (fr)	1981-11-17	Dispositif d'extraction electrolylique de metaux multivalents
US4483752A (en)	1984-11-20	Valve metal electrodeposition onto graphite