CA1120793A - Phosphites encapsules - Google Patents

Phosphites encapsules

Info

Publication number: CA1120793A
Authority: CA; Canada
Prior art keywords: wax; mixture; organic phosphite; pentaerythritol diphosphite; phosphite composition
Prior art date: 1977-12-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000317667A

Other languages

English (en)

Inventor

Ved K. Sahajpal

Jacques Delaere

Zigmunt K. Kromolicki

Mattheus R. Settels

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

GE Chemicals Inc

Original Assignee

Borg Warner Chemicals Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-12-23

Filing date

1978-12-11

Publication date

1982-03-30

1978-12-11 Application filed by Borg Warner Chemicals Inc filed Critical Borg Warner Chemicals Inc

1982-03-30 Application granted granted Critical

1982-03-30 Publication of CA1120793A publication Critical patent/CA1120793A/fr

Status Expired legal-status Critical Current

Links

AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 title abstract description 7
GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 claims abstract description 15
230000007062 hydrolysis Effects 0.000 claims abstract description 7
238000006460 hydrolysis reaction Methods 0.000 claims abstract description 7
150000002148 esters Chemical class 0.000 claims abstract description 4
238000002844 melting Methods 0.000 claims abstract description 4
230000008018 melting Effects 0.000 claims abstract description 4
239000003208 petroleum Substances 0.000 claims abstract description 4
239000000203 mixture Substances 0.000 claims description 40
239000001993 wax Substances 0.000 claims description 25
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 22
125000003003 spiro group Chemical group 0.000 claims description 12
239000002904 solvent Substances 0.000 claims description 11
UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 claims description 10
-1 glycerol ester Chemical class 0.000 claims description 7
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
125000000217 alkyl group Chemical group 0.000 claims description 6
239000007788 liquid Substances 0.000 claims description 6
238000000034 method Methods 0.000 claims description 6
ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 3
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
238000009835 boiling Methods 0.000 claims description 2
230000008020 evaporation Effects 0.000 claims description 2
238000001704 evaporation Methods 0.000 claims description 2
239000012170 montan wax Substances 0.000 claims description 2
125000001931 aliphatic group Chemical group 0.000 claims 1
239000012178 vegetable wax Substances 0.000 claims 1
229920000642 polymer Polymers 0.000 abstract description 14
239000000654 additive Substances 0.000 abstract description 5
230000000087 stabilizing effect Effects 0.000 abstract description 5
239000011248 coating agent Substances 0.000 abstract description 2
238000000576 coating method Methods 0.000 abstract description 2
230000000996 additive effect Effects 0.000 abstract 1
238000000354 decomposition reaction Methods 0.000 abstract 1
238000003801 milling Methods 0.000 abstract 1
238000012360 testing method Methods 0.000 description 11
PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 6
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
230000006866 deterioration Effects 0.000 description 3
230000003301 hydrolyzing effect Effects 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
239000000047 product Substances 0.000 description 3
WAOPGHCXGUXHKF-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)-1,1-diphenylpropane-1,3-diol dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.C1(=CC=CC=C1)C(O)(C(CO)(CO)CO)C1=CC=CC=C1 WAOPGHCXGUXHKF-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
235000010290 biphenyl Nutrition 0.000 description 2
239000004305 biphenyl Substances 0.000 description 2
239000004203 carnauba wax Substances 0.000 description 2
239000012530 fluid Substances 0.000 description 2
239000012760 heat stabilizer Substances 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
SSZBUIDZHHWXNJ-UHFFFAOYSA-N palmityl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC SSZBUIDZHHWXNJ-UHFFFAOYSA-N 0.000 description 2
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
239000000376 reactant Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000013112 stability test Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
229920001169 thermoplastic Polymers 0.000 description 2
DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
YGPLZBDXFXBLMZ-UHFFFAOYSA-N 1,1-dichloro-2,2-bis(hydroxymethyl)propane-1,3-diol dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)C(O)(Cl)Cl YGPLZBDXFXBLMZ-UHFFFAOYSA-N 0.000 description 1
239000004386 Erythritol Substances 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
239000004166 Lanolin Substances 0.000 description 1
235000004431 Linum usitatissimum Nutrition 0.000 description 1
240000006240 Linum usitatissimum Species 0.000 description 1
240000005125 Myrtus communis Species 0.000 description 1
235000013418 Myrtus communis Nutrition 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
240000000111 Saccharum officinarum Species 0.000 description 1
235000007201 Saccharum officinarum Nutrition 0.000 description 1
SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
239000012179 bayberry wax Substances 0.000 description 1
235000013871 bee wax Nutrition 0.000 description 1
239000012166 beeswax Substances 0.000 description 1
125000006267 biphenyl group Chemical group 0.000 description 1
230000000903 blocking effect Effects 0.000 description 1
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
239000008116 calcium stearate Substances 0.000 description 1
235000013539 calcium stearate Nutrition 0.000 description 1
239000004204 candelilla wax Substances 0.000 description 1
235000013868 candelilla wax Nutrition 0.000 description 1
229940073532 candelilla wax Drugs 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
235000013869 carnauba wax Nutrition 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
230000000875 corresponding effect Effects 0.000 description 1
125000003963 dichloro group Chemical group Cl* 0.000 description 1
HBLUTSPORGTSEC-UHFFFAOYSA-N dioctadecoxy-sulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound CCCCCCCCCCCCCCCCCCOP(S)(=S)OCCCCCCCCCCCCCCCCCC HBLUTSPORGTSEC-UHFFFAOYSA-N 0.000 description 1
238000005538 encapsulation Methods 0.000 description 1
229940009714 erythritol Drugs 0.000 description 1
239000012467 final product Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
239000008240 homogeneous mixture Substances 0.000 description 1
238000000265 homogenisation Methods 0.000 description 1
239000012182 japan wax Substances 0.000 description 1
229940119170 jojoba wax Drugs 0.000 description 1
235000019388 lanolin Nutrition 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000002156 mixing Methods 0.000 description 1
GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
239000012186 ozocerite Substances 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
235000019809 paraffin wax Nutrition 0.000 description 1
239000012187 peat wax Substances 0.000 description 1
235000019271 petrolatum Nutrition 0.000 description 1
150000008301 phosphite esters Chemical class 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000012176 shellac wax Substances 0.000 description 1
235000012424 soybean oil Nutrition 0.000 description 1
UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/527—Cyclic esters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
- C08L91/08—Mineral waxes

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Compositions Of Macromolecular Compounds (AREA)
Paints Or Removers (AREA)
Anti-Oxidant Or Stabilizer Compositions (AREA)
Fats And Perfumes (AREA)

CA000317667A 1977-12-23 1978-12-11 Phosphites encapsules Expired CA1120793A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US86382377A	1977-12-23	1977-12-23
US863,823		1977-12-23

Publications (1)

Publication Number	Publication Date
CA1120793A true CA1120793A (fr)	1982-03-30

Family

ID=25341864

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000317667A Expired CA1120793A (fr)	1977-12-23	1978-12-11	Phosphites encapsules

Country Status (5)

Country	Link
JP (1)	JPS5499151A (fr)
CA (1)	CA1120793A (fr)
DE (1)	DE2855351C3 (fr)
FR (1)	FR2423508A1 (fr)
GB (1)	GB2010859B (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
KR20130090787A (ko) *	2010-05-21	2013-08-14	티코나 엘엘씨	안정화제를 포함하는 고온 중합체 합금

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL234660A (fr) *	1958-06-09
US3205250A (en) *	1961-11-20	1965-09-07	Hooker Chemical Corp	3, 9-alkoxy and 3, 9-chloropropyl-2, 4, 8, 10-tetraoxa-3, 9-phosphospiro (6, 6) hendeanes
GB1243421A (en) *	1969-01-01	1971-08-18	Ass Lead Mfg Ltd	Improvements in coated additives for synthetic resins
US3888752A (en) *	1973-11-28	1975-06-10	Gen Motors Corp	Phosphite ester antioxidants in radiation cured styrene butadiene elastomers
JPS5137136A (ja) *	1974-09-25	1976-03-29	Adeka Argus Chemical Co Ltd	Jukihosufuaitososeibutsu
GB1555773A (en) *	1975-07-25	1979-11-14	Lucas Industries Ltd	Motors vehicle
DE2753136B2 (de) *	1977-11-29	1981-04-02	Hoechst Ag, 6000 Frankfurt	Feste Phosphorigsäureester-Zubereitungen mit verbesserter Stabilisatorwirkung in Kunststoffen

1978
- 1978-12-11 CA CA000317667A patent/CA1120793A/fr not_active Expired
- 1978-12-20 GB GB7849245A patent/GB2010859B/en not_active Expired
- 1978-12-21 DE DE2855351A patent/DE2855351C3/de not_active Expired
- 1978-12-22 FR FR7836201A patent/FR2423508A1/fr active Granted
- 1978-12-23 JP JP15908478A patent/JPS5499151A/ja active Granted

Also Published As

Publication number	Publication date
DE2855351A1 (de)	1979-07-05
GB2010859B (en)	1982-08-18
FR2423508A1 (fr)	1979-11-16
JPS5499151A (en)	1979-08-04
GB2010859A (en)	1979-07-04
FR2423508B1 (fr)	1983-10-28
DE2855351B2 (de)	1980-06-26
DE2855351C3 (de)	1981-02-26
JPS6138210B2 (fr)	1986-08-28

Legal Events

Date	Code	Title	Description
1999-03-30	MKEX	Expiry

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EP0768993B1 (fr)	1998-08-19	Composition agricole et agent de traitement destines a reduire l'hygroscopicite et la formation de poussiere dans des engrais
JPH09500669A (ja)	1997-01-21	砂および／または土の表面を固化するための選択したポリ酢酸ビニル分散液の使用
US4299885A (en)	1981-11-10	Encapsulated phosphites
US4898616A (en)	1990-02-06	Aqueous additive systems, methods and polymeric particles
HUT72433A (en)	1996-04-29	Amin stabilized amorphous composition phosphite and procedure for making this
JP2018502033A (ja)	2018-01-25	吸湿性及び粉塵形成を低減するための微粒子状肥料用コンディショニング剤
US4960644A (en)	1990-10-02	Aqueous additive systems, methods and polymeric particles
CA2120018C (fr)	1997-12-23	Additifs sous forme solides, dispersables dans des milieux aqueux et methode pour les preparer
CA1120793A (fr)	1982-03-30	Phosphites encapsules
US5346941A (en)	1994-09-13	Powder for the modification of thermoplastic resins
AU9040891A (en)	1992-07-08	Primarily solid concentrate which contains a biocide
JPH0368638A (ja)	1991-03-25	安定化されたホスファイト組成物
US2413491A (en)	1946-12-31	Coated hygroscopic salts
US2779744A (en)	1957-01-29	Polystyrene phonograph record composition and method of making same
US4518732A (en)	1985-05-21	Solid stabilizer composition
CA1113706A (fr)	1981-12-08	Preparations soildes 'ester d'acide phosphorique resistant a l'hydrolyse et ayant un meilleur effet de stabilisation des matieres plastiques
CA1041076A (fr)	1978-10-24	Compose friable et methode de fabrication
EP0565966B1 (fr)	1996-11-06	Procédé de traitement de polyoléfine en forme de particules, particules traitées obtenues et méthode pour l'utilisation de celles-ci
CA3190221A1 (fr)	2022-03-03	Agent de conditionnement pour engrais particulaire
US2680691A (en)	1954-06-08	Transparent flame-resistant cellulose acetate butyrate
US2367663A (en)	1945-01-23	Insulating tape
US2292518A (en)	1942-08-11	Coated paper
WO2001083401A1 (fr)	2001-11-08	Carnallite a taux reduit d'absorption d'humidite et son procede d'obtention
JPH10102033A (ja)	1998-04-21	液状アルミニウム石鹸組成物、該組成物を含有するゲル化剤及びゲル化方法
US2682477A (en)	1954-06-29	Glycol and polypentaerythritol composition