CA1137025A - Methode de separation du trityum en presence dans les decharges d'eau lourde - Google Patents
Methode de separation du trityum en presence dans les decharges d'eau lourdeInfo
- Publication number
- CA1137025A CA1137025A CA000354954A CA354954A CA1137025A CA 1137025 A CA1137025 A CA 1137025A CA 000354954 A CA000354954 A CA 000354954A CA 354954 A CA354954 A CA 354954A CA 1137025 A CA1137025 A CA 1137025A
- Authority
- CA
- Canada
- Prior art keywords
- tritium
- column
- heavy water
- stream
- liquid heavy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 title claims abstract description 76
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 title claims abstract description 39
- 229910052722 tritium Inorganic materials 0.000 title claims abstract description 39
- 239000007788 liquid Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 25
- 238000000605 extraction Methods 0.000 title claims abstract description 10
- 239000007789 gas Substances 0.000 claims abstract description 25
- 229910052805 deuterium Inorganic materials 0.000 claims abstract description 17
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 claims abstract description 16
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 8
- 230000000155 isotopic effect Effects 0.000 claims abstract description 3
- 239000002699 waste material Substances 0.000 claims abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000001301 oxygen Substances 0.000 claims abstract 2
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 2
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 abstract description 12
- 241000720974 Protium Species 0.000 abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 9
- 230000003197 catalytic effect Effects 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004243 E-number Substances 0.000 description 1
- 235000019227 E-number Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241001058146 Erium Species 0.000 description 1
- 241001430696 Protis Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 238000005372 isotope separation Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D59/00—Separation of different isotopes of the same chemical element
- B01D59/22—Separation by extracting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D59/00—Separation of different isotopes of the same chemical element
- B01D59/28—Separation by chemical exchange
- B01D59/32—Separation by chemical exchange by exchange between fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D59/00—Separation of different isotopes of the same chemical element
- B01D59/38—Separation by electrochemical methods
- B01D59/40—Separation by electrochemical methods by electrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D59/00—Separation of different isotopes of the same chemical element
- B01D59/50—Separation involving two or more processes covered by different groups selected from groups B01D59/02, B01D59/10, B01D59/20, B01D59/22, B01D59/28, B01D59/34, B01D59/36, B01D59/38, B01D59/44
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B4/00—Hydrogen isotopes; Inorganic compounds thereof prepared by isotope exchange, e.g. NH3 + D2 → NH2D + HD
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000354954A CA1137025A (fr) | 1980-06-13 | 1980-06-13 | Methode de separation du trityum en presence dans les decharges d'eau lourde |
| RO104139A RO82100B (ro) | 1980-06-13 | 1981-04-26 | Procedeu pentru extractia tritiului din apa grea |
| KR1019810001504A KR840000967B1 (ko) | 1980-06-13 | 1981-05-01 | 액체 중수(重水)흐름으로부터 프로튬(Protium)과 삼중수소를 동시에 추출하는 방법 |
| DE19813122498 DE3122498A1 (de) | 1980-06-13 | 1981-06-05 | Verfahren zum extrahieren von tritium aus einem fluessigen schwerwasserstrom |
| CH3757/81A CH647480A5 (fr) | 1980-06-13 | 1981-06-09 | Procede d'extraction de tritium d'un courant d'eau lourde liquide. |
| JP9068281A JPS5727119A (en) | 1980-06-13 | 1981-06-12 | Method of extracting tritium from heavy water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000354954A CA1137025A (fr) | 1980-06-13 | 1980-06-13 | Methode de separation du trityum en presence dans les decharges d'eau lourde |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1137025A true CA1137025A (fr) | 1982-12-07 |
Family
ID=4117288
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000354954A Expired CA1137025A (fr) | 1980-06-13 | 1980-06-13 | Methode de separation du trityum en presence dans les decharges d'eau lourde |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS5727119A (fr) |
| KR (1) | KR840000967B1 (fr) |
| CA (1) | CA1137025A (fr) |
| CH (1) | CH647480A5 (fr) |
| DE (1) | DE3122498A1 (fr) |
| RO (1) | RO82100B (fr) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995015807A1 (fr) * | 1993-12-06 | 1995-06-15 | Atomic Energy Of Canada Limited | Usine geographiquement dispersee d'extraction du tritium |
| US6190531B1 (en) | 1999-07-27 | 2001-02-20 | University Of North Carolina | Concentration and removal of tritium and/or deuterium from water contaminated with tritium and/or deuterium |
| US10381121B2 (en) | 2013-11-13 | 2019-08-13 | Savannah River Nuclear Solutions, Llc | Decontamination of tritiated water |
| US11058994B2 (en) | 2019-01-18 | 2021-07-13 | Savannah River National Solutions, LLC | Tritium cleanup system and method |
| CN118767675A (zh) * | 2024-08-13 | 2024-10-15 | 天津市津南区一畔新能源有限公司 | 反应堆的氚水提纯装置 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102721371B1 (ko) * | 2024-08-05 | 2024-10-25 | 주식회사 에이젠코어 | 복수의 모듈을 포함하는 중수소의 제조장치 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1526867A (fr) * | 1966-08-09 | 1968-05-31 | Commissariat Energie Atomique | Perfectionnements apportés aux moyens pour retirer le protonium et le tritium de l'eau lourde |
-
1980
- 1980-06-13 CA CA000354954A patent/CA1137025A/fr not_active Expired
-
1981
- 1981-04-26 RO RO104139A patent/RO82100B/ro unknown
- 1981-05-01 KR KR1019810001504A patent/KR840000967B1/ko not_active Expired
- 1981-06-05 DE DE19813122498 patent/DE3122498A1/de not_active Ceased
- 1981-06-09 CH CH3757/81A patent/CH647480A5/fr not_active IP Right Cessation
- 1981-06-12 JP JP9068281A patent/JPS5727119A/ja active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995015807A1 (fr) * | 1993-12-06 | 1995-06-15 | Atomic Energy Of Canada Limited | Usine geographiquement dispersee d'extraction du tritium |
| US6190531B1 (en) | 1999-07-27 | 2001-02-20 | University Of North Carolina | Concentration and removal of tritium and/or deuterium from water contaminated with tritium and/or deuterium |
| US10381121B2 (en) | 2013-11-13 | 2019-08-13 | Savannah River Nuclear Solutions, Llc | Decontamination of tritiated water |
| US11087897B2 (en) | 2013-11-13 | 2021-08-10 | Savannah River Nuclear Solutions, Llc | Decontamination of tritiated water |
| US11058994B2 (en) | 2019-01-18 | 2021-07-13 | Savannah River National Solutions, LLC | Tritium cleanup system and method |
| CN118767675A (zh) * | 2024-08-13 | 2024-10-15 | 天津市津南区一畔新能源有限公司 | 反应堆的氚水提纯装置 |
| CN118767675B (zh) * | 2024-08-13 | 2025-09-26 | 天津市津南区一畔新能源有限公司 | 反应堆的氚水提纯装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3122498A1 (de) | 1982-06-03 |
| CH647480A5 (fr) | 1985-01-31 |
| RO82100A (fr) | 1984-01-14 |
| JPS5727119A (en) | 1982-02-13 |
| KR840000967B1 (ko) | 1984-07-02 |
| KR830005892A (ko) | 1983-09-14 |
| RO82100B (ro) | 1984-01-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |