CA1141076A - Composition vulcanisable aux ultraviolets, contenant u n sel de bis-(aryl)iodonium et un fluide intermediaire de silicone a base de copolymere de polydialkyl et d' alkyl epoxy siloxane, a liaison epoxy pre-transversale et fonction dialkyl epoxy, groupes terminaux - Google Patents

Composition vulcanisable aux ultraviolets, contenant u n sel de bis-(aryl)iodonium et un fluide intermediaire de silicone a base de copolymere de polydialkyl et d' alkyl epoxy siloxane, a liaison epoxy pre-transversale et fonction dialkyl epoxy, groupes terminaux

Info

Publication number: CA1141076A
Authority: CA; Canada
Prior art keywords: epoxy; silicone; epoxy functional; approximately; bis
Prior art date: 1980-11-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000365247A

Other languages

English (en)

Inventor

Richard P. Eckberg

Ronald W. Larochelle

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

General Electric Co

Original Assignee

General Electric Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-11-21

Filing date

1980-11-21

Publication date

1983-02-08

1980-11-21 Application filed by General Electric Co filed Critical General Electric Co

1980-11-21 Priority to CA000365247A priority Critical patent/CA1141076A/fr

1983-02-08 Application granted granted Critical

1983-02-08 Publication of CA1141076A publication Critical patent/CA1141076A/fr

Status Expired legal-status Critical Current

Links

239000004593 Epoxy Substances 0.000 title claims abstract description 117
239000012530 fluid Substances 0.000 title claims abstract description 86
239000000203 mixture Substances 0.000 title claims abstract description 80
229920001296 polysiloxane Polymers 0.000 title claims description 107
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical class I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 title claims description 9
229920001577 copolymer Polymers 0.000 title claims description 7
239000000758 substrate Substances 0.000 claims abstract description 39
239000004447 silicone coating Substances 0.000 claims abstract description 31
230000005855 radiation Effects 0.000 claims abstract description 14
-1 polysiloxane copolymer Polymers 0.000 claims description 61
238000000576 coating method Methods 0.000 claims description 39
238000000034 method Methods 0.000 claims description 25
239000000123 paper Substances 0.000 claims description 23
239000011248 coating agent Substances 0.000 claims description 20
230000008569 process Effects 0.000 claims description 18
238000001723 curing Methods 0.000 claims description 13
229910017048 AsF6 Inorganic materials 0.000 claims description 6
239000004698 Polyethylene Substances 0.000 claims description 6
229920000573 polyethylene Polymers 0.000 claims description 6
125000000217 alkyl group Chemical group 0.000 claims description 5
125000001188 haloalkyl group Chemical group 0.000 claims description 4
239000004743 Polypropylene Substances 0.000 claims description 3
AENNXXRRACDJAY-UHFFFAOYSA-N bis(2-dodecylphenyl)iodanium Chemical class CCCCCCCCCCCCC1=CC=CC=C1[I+]C1=CC=CC=C1CCCCCCCCCCCC AENNXXRRACDJAY-UHFFFAOYSA-N 0.000 claims description 3
239000011521 glass Substances 0.000 claims description 3
229910052751 metal Inorganic materials 0.000 claims description 3
239000002184 metal Substances 0.000 claims description 3
229920001155 polypropylene Polymers 0.000 claims description 3
YSXJIDHYEFYSON-UHFFFAOYSA-N bis(4-dodecylphenyl)iodanium Chemical class C1=CC(CCCCCCCCCCCC)=CC=C1[I+]C1=CC=C(CCCCCCCCCCCC)C=C1 YSXJIDHYEFYSON-UHFFFAOYSA-N 0.000 claims description 2
239000011888 foil Substances 0.000 claims description 2
238000002156 mixing Methods 0.000 claims description 2
229920006267 polyester film Polymers 0.000 claims description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
230000001737 promoting effect Effects 0.000 claims 1
DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 claims 1
230000001464 adherent effect Effects 0.000 abstract description 12
238000009877 rendering Methods 0.000 abstract description 3
IDZFFYHOAKUWGY-UHFFFAOYSA-N 1,2-didodecyl-3-iodobenzene Chemical class CCCCCCCCCCCCC1=CC=CC(I)=C1CCCCCCCCCCCC IDZFFYHOAKUWGY-UHFFFAOYSA-N 0.000 abstract 1
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 42
239000003054 catalyst Substances 0.000 description 25
239000002904 solvent Substances 0.000 description 20
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 19
239000000853 adhesive Substances 0.000 description 18
230000001070 adhesive effect Effects 0.000 description 18
239000000047 product Substances 0.000 description 17
229920002554 vinyl polymer Polymers 0.000 description 17
238000004132 cross linking Methods 0.000 description 15
239000011541 reaction mixture Substances 0.000 description 15
238000012360 testing method Methods 0.000 description 15
239000000463 material Substances 0.000 description 14
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
150000003839 salts Chemical class 0.000 description 14
SLJFKNONPLNAPF-UHFFFAOYSA-N 3-Vinyl-7-oxabicyclo[4.1.0]heptane Chemical compound C1C(C=C)CCC2OC21 SLJFKNONPLNAPF-UHFFFAOYSA-N 0.000 description 12
230000015572 biosynthetic process Effects 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 11
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 10
239000000243 solution Substances 0.000 description 10
238000003786 synthesis reaction Methods 0.000 description 10
239000004205 dimethyl polysiloxane Substances 0.000 description 9
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 9
239000002243 precursor Substances 0.000 description 9
239000001257 hydrogen Substances 0.000 description 8
229910052739 hydrogen Inorganic materials 0.000 description 8
238000006459 hydrosilylation reaction Methods 0.000 description 8
239000003999 initiator Substances 0.000 description 8
239000003795 chemical substances by application Substances 0.000 description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
229920002799 BoPET Polymers 0.000 description 6
239000005041 Mylar™ Substances 0.000 description 6
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 6
229910052697 platinum Inorganic materials 0.000 description 6
229920001843 polymethylhydrosiloxane Polymers 0.000 description 6
238000003756 stirring Methods 0.000 description 6
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 5
239000008199 coating composition Substances 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 5
230000005012 migration Effects 0.000 description 5
238000013508 migration Methods 0.000 description 5
150000002924 oxiranes Chemical group 0.000 description 5
238000010992 reflux Methods 0.000 description 5
239000007787 solid Substances 0.000 description 5
239000002253 acid Substances 0.000 description 4
239000012298 atmosphere Substances 0.000 description 4
125000005520 diaryliodonium group Chemical group 0.000 description 4
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
239000003504 photosensitizing agent Substances 0.000 description 4
DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 4
MCVUKOYZUCWLQQ-UHFFFAOYSA-N tridecylbenzene Chemical class CCCCCCCCCCCCCC1=CC=CC=C1 MCVUKOYZUCWLQQ-UHFFFAOYSA-N 0.000 description 4
WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
229960000583 acetic acid Drugs 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
125000002091 cationic group Chemical group 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 3
239000010408 film Substances 0.000 description 3
239000012467 final product Substances 0.000 description 3
239000012362 glacial acetic acid Substances 0.000 description 3
239000002655 kraft paper Substances 0.000 description 3
238000005259 measurement Methods 0.000 description 3
230000007246 mechanism Effects 0.000 description 3
KWKAKUADMBZCLK-UHFFFAOYSA-N methyl heptene Natural products CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 3
239000002516 radical scavenger Substances 0.000 description 3
229910001220 stainless steel Inorganic materials 0.000 description 3
239000010935 stainless steel Substances 0.000 description 3
VMAWODUEPLAHOE-UHFFFAOYSA-N 2,4,6,8-tetrakis(ethenyl)-2,4,6,8-tetramethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C=C[Si]1(C)O[Si](C)(C=C)O[Si](C)(C=C)O[Si](C)(C=C)O1 VMAWODUEPLAHOE-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
CVKMDAZAUGXUFX-UHFFFAOYSA-N C1C2(C=C)CCC1C1C2O1 Chemical compound C1C2(C=C)CCC1C1C2O1 CVKMDAZAUGXUFX-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
GXBYFVGCMPJVJX-UHFFFAOYSA-N Epoxybutene Chemical compound C=CC1CO1 GXBYFVGCMPJVJX-UHFFFAOYSA-N 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
239000003522 acrylic cement Substances 0.000 description 2
238000013006 addition curing Methods 0.000 description 2
239000000654 additive Substances 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
239000002390 adhesive tape Substances 0.000 description 2
230000032683 aging Effects 0.000 description 2
125000000746 allylic group Chemical group 0.000 description 2
238000000151 deposition Methods 0.000 description 2
230000008021 deposition Effects 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
230000000977 initiatory effect Effects 0.000 description 2
229920001684 low density polyethylene Polymers 0.000 description 2
239000004702 low-density polyethylene Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
229910052753 mercury Inorganic materials 0.000 description 2
239000003495 polar organic solvent Substances 0.000 description 2
239000010970 precious metal Substances 0.000 description 2
238000011084 recovery Methods 0.000 description 2
229920006268 silicone film Polymers 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000006467 substitution reaction Methods 0.000 description 2
239000001117 sulphuric acid Substances 0.000 description 2
235000011149 sulphuric acid Nutrition 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
YHPVLCAYDLBZOA-UHFFFAOYSA-N 1-decyl-2-ethylbenzene Chemical compound CCCCCCCCCCC1=CC=CC=C1CC YHPVLCAYDLBZOA-UHFFFAOYSA-N 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
WZJUBBHODHNQPW-UHFFFAOYSA-N 2,4,6,8-tetramethyl-1,3,5,7,2$l^{3},4$l^{3},6$l^{3},8$l^{3}-tetraoxatetrasilocane Chemical compound C[Si]1O[Si](C)O[Si](C)O[Si](C)O1 WZJUBBHODHNQPW-UHFFFAOYSA-N 0.000 description 1
STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical group CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
229920000298 Cellophane Polymers 0.000 description 1
238000005727 Friedel-Crafts reaction Methods 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
239000006087 Silane Coupling Agent Substances 0.000 description 1
238000007259 addition reaction Methods 0.000 description 1
239000002318 adhesion promoter Substances 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
238000013459 approach Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229920005601 base polymer Polymers 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
230000033228 biological regulation Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
RBHJBMIOOPYDBQ-UHFFFAOYSA-N carbon dioxide;propan-2-one Chemical compound O=C=O.CC(C)=O RBHJBMIOOPYDBQ-UHFFFAOYSA-N 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
230000008859 change Effects 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000001066 destructive effect Effects 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
BITPLIXHRASDQB-UHFFFAOYSA-N ethenyl-[ethenyl(dimethyl)silyl]oxy-dimethylsilane Chemical compound C=C[Si](C)(C)O[Si](C)(C)C=C BITPLIXHRASDQB-UHFFFAOYSA-N 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000000284 extract Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000013505 freshwater Substances 0.000 description 1
238000001879 gelation Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
230000005764 inhibitory process Effects 0.000 description 1
MGFYSGNNHQQTJW-UHFFFAOYSA-N iodonium Chemical compound [IH2+] MGFYSGNNHQQTJW-UHFFFAOYSA-N 0.000 description 1
229910052741 iridium Inorganic materials 0.000 description 1
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
125000005358 mercaptoalkyl group Chemical group 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
235000019645 odor Nutrition 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
229910052762 osmium Inorganic materials 0.000 description 1
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
238000000016 photochemical curing Methods 0.000 description 1
JLKDVMWYMMLWTI-UHFFFAOYSA-M potassium iodate Chemical compound [K+].[O-]I(=O)=O JLKDVMWYMMLWTI-UHFFFAOYSA-M 0.000 description 1
239000001230 potassium iodate Substances 0.000 description 1
229940093930 potassium iodate Drugs 0.000 description 1
235000006666 potassium iodate Nutrition 0.000 description 1
238000010944 pre-mature reactiony Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000003847 radiation curing Methods 0.000 description 1
238000012429 release testing Methods 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
238000007142 ring opening reaction Methods 0.000 description 1
230000000630 rising effect Effects 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
239000002002 slurry Substances 0.000 description 1
WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
229910000342 sodium bisulfate Inorganic materials 0.000 description 1
239000011877 solvent mixture Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000012258 stirred mixture Substances 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
239000010409 thin film Substances 0.000 description 1
238000012546 transfer Methods 0.000 description 1
238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
XBEADGFTLHRJRB-UHFFFAOYSA-N undecylbenzene Chemical class CCCCCCCCCCCC1=CC=CC=C1 XBEADGFTLHRJRB-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1

Landscapes

Silicon Polymers (AREA)
Epoxy Resins (AREA)

CA000365247A 1980-11-21 1980-11-21 Composition vulcanisable aux ultraviolets, contenant u n sel de bis-(aryl)iodonium et un fluide intermediaire de silicone a base de copolymere de polydialkyl et d' alkyl epoxy siloxane, a liaison epoxy pre-transversale et fonction dialkyl epoxy, groupes terminaux Expired CA1141076A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000365247A CA1141076A (fr)	1980-11-21	1980-11-21	Composition vulcanisable aux ultraviolets, contenant u n sel de bis-(aryl)iodonium et un fluide intermediaire de silicone a base de copolymere de polydialkyl et d' alkyl epoxy siloxane, a liaison epoxy pre-transversale et fonction dialkyl epoxy, groupes terminaux

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000365247A CA1141076A (fr)	1980-11-21	1980-11-21	Composition vulcanisable aux ultraviolets, contenant u n sel de bis-(aryl)iodonium et un fluide intermediaire de silicone a base de copolymere de polydialkyl et d' alkyl epoxy siloxane, a liaison epoxy pre-transversale et fonction dialkyl epoxy, groupes terminaux

Publications (1)

Publication Number	Publication Date
CA1141076A true CA1141076A (fr)	1983-02-08

Family

ID=4118521

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000365247A Expired CA1141076A (fr)	1980-11-21	1980-11-21	Composition vulcanisable aux ultraviolets, contenant u n sel de bis-(aryl)iodonium et un fluide intermediaire de silicone a base de copolymere de polydialkyl et d' alkyl epoxy siloxane, a liaison epoxy pre-transversale et fonction dialkyl epoxy, groupes terminaux

Country Status (1)

Country	Link
CA (1)	CA1141076A (fr)

1980
- 1980-11-21 CA CA000365247A patent/CA1141076A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2000-02-08	MKEX	Expiry

Publication	Publication Date	Title
US4279717A (en)	1981-07-21	Ultraviolet curable epoxy silicone coating compositions
US4421904A (en)	1983-12-20	Ultraviolet curable silicone coating compositions
US5814679A (en)	1998-09-29	Premium release photo-curable silicone compositions
US4370358A (en)	1983-01-25	Ultraviolet curable silicone adhesives
JP2653693B2 (ja)	1997-09-17	シリコーン剥離層含有複合構造体
US5397813A (en)	1995-03-14	Premium release UV curable epoxysilicone compositions
CA1218494A (fr)	1987-02-24	Compositions de silicium a dispersion temporisee durcies aux ultraviolets
US4340647A (en)	1982-07-20	Vinyl gum cure accelerators for addition-cure silicone
US5332797A (en)	1994-07-26	Silicone release compositions
EP0103639B1 (fr)	1987-01-07	Accelerateurs de durcissement en resine de vinyle pour silicone durci par condensation
US4830924A (en)	1989-05-16	Modified silicone release coating compositions
US5721290A (en)	1998-02-24	Oxo-acid modified epoxy silicone compositions
JPS60228561A (ja)	1985-11-13	硬化可能なオルガノポリシロキサン組成物及びその使用方法
USRE31727E (en)	1984-11-06	Vinyl gum cure accelerators for addition-cure silicone
EP1697474A2 (fr)	2006-09-06	Nouvelles formations de revetement de silicone photodurcissable de longue conservation
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