CA1151726A - Electrodes de cellule alcaline et methode de fabrication - Google Patents

Electrodes de cellule alcaline et methode de fabrication

Info

Publication number: CA1151726A
Authority: CA; Canada
Prior art keywords: mixture; depolarizer; silicate; additive; combination
Prior art date: 1981-05-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000378435A

Other languages

English (en)

Inventor

Gerard M. Healy

Eleanor J. Rossler

Marion Wiacek

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Duracell Inc USA

Original Assignee

Duracell International Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-05-27

Filing date

1981-05-27

Publication date

1983-08-09

1981-05-27 Application filed by Duracell International Inc filed Critical Duracell International Inc

1981-05-27 Priority to CA000378435A priority Critical patent/CA1151726A/fr

1983-08-09 Application granted granted Critical

1983-08-09 Publication of CA1151726A publication Critical patent/CA1151726A/fr

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 12
239000000203 mixture Substances 0.000 claims abstract description 85
239000000654 additive Substances 0.000 claims abstract description 30
230000000996 additive effect Effects 0.000 claims abstract description 30
239000003792 electrolyte Substances 0.000 claims abstract description 29
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 26
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 19
239000011701 zinc Substances 0.000 claims abstract description 19
229910052725 zinc Inorganic materials 0.000 claims abstract description 17
239000003921 oil Substances 0.000 claims abstract description 16
239000003995 emulsifying agent Substances 0.000 claims abstract description 15
239000007788 liquid Substances 0.000 claims abstract description 15
229920005573 silicon-containing polymer Polymers 0.000 claims abstract description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims abstract description 14
229910052914 metal silicate Inorganic materials 0.000 claims abstract description 11
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims abstract description 10
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
239000012670 alkaline solution Substances 0.000 claims abstract description 8
229910044991 metal oxide Inorganic materials 0.000 claims abstract description 8
150000004706 metal oxides Chemical class 0.000 claims abstract description 8
239000006229 carbon black Substances 0.000 claims abstract description 7
229910002804 graphite Inorganic materials 0.000 claims abstract description 7
239000010439 graphite Substances 0.000 claims abstract description 7
238000005056 compaction Methods 0.000 claims abstract description 6
229910052793 cadmium Inorganic materials 0.000 claims abstract description 4
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims abstract description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
229910052751 metal Inorganic materials 0.000 claims description 10
239000002184 metal Substances 0.000 claims description 10
239000002904 solvent Substances 0.000 claims description 10
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 7
150000001875 compounds Chemical class 0.000 claims description 7
AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 claims description 3
229910021383 artificial graphite Inorganic materials 0.000 claims description 2
238000000889 atomisation Methods 0.000 claims description 2
229910021382 natural graphite Inorganic materials 0.000 claims description 2
239000000378 calcium silicate Substances 0.000 claims 2
229910052918 calcium silicate Inorganic materials 0.000 claims 2
OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims 2
HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims 2
239000000391 magnesium silicate Substances 0.000 claims 2
229910052919 magnesium silicate Inorganic materials 0.000 claims 2
235000019792 magnesium silicate Nutrition 0.000 claims 2
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 2
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims 2
229910052753 mercury Inorganic materials 0.000 claims 2
229910052709 silver Inorganic materials 0.000 claims 2
239000004332 silver Substances 0.000 claims 2
239000008188 pellet Substances 0.000 abstract description 59
239000000839 emulsion Substances 0.000 abstract description 19
229920001296 polysiloxane Polymers 0.000 abstract description 17
238000004519 manufacturing process Methods 0.000 abstract description 15
210000004027 cell Anatomy 0.000 description 84
239000007789 gas Substances 0.000 description 9
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 6
239000000470 constituent Substances 0.000 description 6
229910052739 hydrogen Inorganic materials 0.000 description 6
239000001257 hydrogen Substances 0.000 description 6
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
238000001125 extrusion Methods 0.000 description 4
239000004615 ingredient Substances 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
230000027455 binding Effects 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
239000011575 calcium Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000008151 electrolyte solution Substances 0.000 description 3
229940021013 electrolyte solution Drugs 0.000 description 3
229910052749 magnesium Inorganic materials 0.000 description 3
239000011777 magnesium Substances 0.000 description 3
230000035515 penetration Effects 0.000 description 3
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
229910052910 alkali metal silicate Inorganic materials 0.000 description 2
239000010405 anode material Substances 0.000 description 2
238000013459 approach Methods 0.000 description 2
210000003850 cellular structure Anatomy 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
230000006866 deterioration Effects 0.000 description 2
239000003349 gelling agent Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
239000007787 solid Substances 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
229960001296 zinc oxide Drugs 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
230000008275 binding mechanism Effects 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
239000004020 conductor Substances 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000004744 fabric Substances 0.000 description 1
239000011152 fibreglass Substances 0.000 description 1
239000004519 grease Substances 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
238000007654 immersion Methods 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000002120 nanofilm Substances 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
OTCVAHKKMMUFAY-UHFFFAOYSA-N oxosilver Chemical class [Ag]=O OTCVAHKKMMUFAY-UHFFFAOYSA-N 0.000 description 1
239000003973 paint Substances 0.000 description 1
238000005498 polishing Methods 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
239000003223 protective agent Substances 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
-1 silicate ions Chemical class 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
229910001923 silver oxide Inorganic materials 0.000 description 1
239000010959 steel Substances 0.000 description 1
210000000352 storage cell Anatomy 0.000 description 1
239000000725 suspension Substances 0.000 description 1
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1

Landscapes

Battery Electrode And Active Subsutance (AREA)

CA000378435A 1981-05-27 1981-05-27 Electrodes de cellule alcaline et methode de fabrication Expired CA1151726A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000378435A CA1151726A (fr)	1981-05-27	1981-05-27	Electrodes de cellule alcaline et methode de fabrication

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000378435A CA1151726A (fr)	1981-05-27	1981-05-27	Electrodes de cellule alcaline et methode de fabrication

Publications (1)

Publication Number	Publication Date
CA1151726A true CA1151726A (fr)	1983-08-09

Family

ID=4120075

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000378435A Expired CA1151726A (fr)	1981-05-27	1981-05-27	Electrodes de cellule alcaline et methode de fabrication

Country Status (1)

Country	Link
CA (1)	CA1151726A (fr)

1981
- 1981-05-27 CA CA000378435A patent/CA1151726A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2000-08-09	MKEX	Expiry

Publication	Publication Date	Title
EP0758491B1 (fr)	1999-05-12	Piles etanches rechargeables a anodes de zinc sans mercure et leur procede de fabrication
US7169508B2 (en)	2007-01-30	Method of manufacturing anode compositions for use in rechargeable electrochemical cells
EP0882309B1 (fr)	2002-04-24	Anode de zinc pour cellule electrochimique
DE69129483T2 (de)	1998-10-08	Elektrochemische Zellen ohne wesentlichen Quecksilbergehalt
US3956018A (en)	1976-05-11	Primary electric current-producing dry cell using a (CFx)n cathode and an aqueous alkaline electrolyte
DE60038240T2 (de)	2009-02-26	Alkalische zelle mit isolator
DE60007138T2 (de)	2004-09-02	Alkalische zelle mit verbesserte anode
HUT67932A (en)	1995-05-29	Alkaline manganese dioxide cell of low mercury content or withot mercury
WO1997017737A1 (fr)	1997-05-15	Piles alcalines rechargeables contenant des anodes en zinc non additionnees de mercure
KR100441166B1 (ko)	2004-10-02	알카리성 일차전지
EP1988590A1 (fr)	2008-11-05	Pile alcaline
JP5172181B2 (ja)	2013-03-27	亜鉛アルカリ電池
DE2246753B2 (de)	1979-10-11	Galvanisches Element mit sich verbrauchender Zinkelektrode
US3981748A (en)	1976-09-21	Non-aqueous, primary battery having a blended cathode active material
CA1151726A (fr)	1983-08-09	Electrodes de cellule alcaline et methode de fabrication
DE2951520A1 (de)	1980-07-10	Elektrochemische lithium-bleisulfat- primaerzelle
EP1293002B1 (fr)	2005-05-11	Pile electrochimique avec une anode contenant du soufre
GB2118762A (en)	1983-11-02	Electrochemical cell with compacted cathode containing polyolefin powder additive
WO1991015034A1 (fr)	1991-10-03	Electrode en lithium poreux et batterie comportant une telle electrode
JP4265738B2 (ja)	2009-05-20	アルカリ電池
GB2376342A (en)	2002-12-11	Optimised alkaline electrochemical cells
JP2007273406A (ja)	2007-10-18	アルカリ電池
JPH05151957A (ja)	1993-06-18	アルカリ電池
HK1017150B (en)	2002-12-06	Zinc anode for an electrochemical cell
JPH053032A (ja)	1993-01-08	アルカリ電池