CA1153020A - Produits hypostyle en argile a couches intercalaires - Google Patents

Produits hypostyle en argile a couches intercalaires

Info

Publication number: CA1153020A
Authority: CA; Canada
Prior art keywords: interlayered; clay; calcined; smectite; base
Prior art date: 1979-09-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000359406A

Other languages

English (en)

Inventor

David E.W. Vaughan

Roger J. Lussier

John S. Magee, Jr.

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

WR Grace and Co

Original Assignee

WR Grace and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-09-04

Filing date

1980-09-02

Publication date

1983-08-30

1979-09-04 Priority claimed from US06/071,957 external-priority patent/US4248739A/en

1979-10-01 Priority claimed from US06/080,959 external-priority patent/US4271043A/en

1980-09-02 Application filed by WR Grace and Co filed Critical WR Grace and Co

1983-08-30 Application granted granted Critical

1983-08-30 Publication of CA1153020A publication Critical patent/CA1153020A/fr

Status Expired legal-status Critical Current

Links

239000004927 clay Substances 0.000 title claims abstract description 62
238000005342 ion exchange Methods 0.000 claims abstract description 22
229920000642 polymer Polymers 0.000 claims abstract description 14
229910021647 smectite Inorganic materials 0.000 claims abstract description 14
238000001354 calcination Methods 0.000 claims abstract description 9
150000004696 coordination complex Chemical class 0.000 claims abstract description 9
239000000440 bentonite Substances 0.000 claims abstract description 6
229910000278 bentonite Inorganic materials 0.000 claims abstract description 6
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 6
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 5
239000000047 product Substances 0.000 claims description 35
239000002585 base Substances 0.000 claims description 25
238000000034 method Methods 0.000 claims description 21
229910001868 water Inorganic materials 0.000 claims description 20
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 13
238000006243 chemical reaction Methods 0.000 claims description 13
239000003054 catalyst Substances 0.000 claims description 11
239000000203 mixture Substances 0.000 claims description 8
-1 cationic hydroxy metal complex Chemical class 0.000 claims description 7
239000011148 porous material Substances 0.000 claims description 7
229910052751 metal Inorganic materials 0.000 claims description 6
239000002184 metal Substances 0.000 claims description 6
229910052901 montmorillonite Inorganic materials 0.000 claims description 5
239000002594 sorbent Substances 0.000 claims description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
150000003754 zirconium Chemical class 0.000 claims description 4
239000004215 Carbon black (E152) Substances 0.000 claims description 3
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 3
229930195733 hydrocarbon Natural products 0.000 claims description 3
150000002430 hydrocarbons Chemical class 0.000 claims description 3
229910052783 alkali metal Inorganic materials 0.000 claims description 2
150000001340 alkali metals Chemical class 0.000 claims description 2
150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
238000007334 copolymerization reaction Methods 0.000 claims description 2
KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 2
229910000271 hectorite Inorganic materials 0.000 claims description 2
230000000737 periodic effect Effects 0.000 claims description 2
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
RKFMOTBTFHXWCM-UHFFFAOYSA-M [AlH2]O Chemical compound [AlH2]O RKFMOTBTFHXWCM-UHFFFAOYSA-M 0.000 claims 1
235000011162 ammonium carbonates Nutrition 0.000 claims 1
235000011114 ammonium hydroxide Nutrition 0.000 claims 1
125000002091 cationic group Chemical group 0.000 claims 1
239000003795 chemical substances by application Substances 0.000 claims 1
238000004519 manufacturing process Methods 0.000 claims 1
229910021645 metal ion Inorganic materials 0.000 claims 1
239000000908 ammonium hydroxide Substances 0.000 abstract description 3
150000002500 ions Chemical class 0.000 description 15
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 13
229910052782 aluminium Inorganic materials 0.000 description 13
235000010210 aluminium Nutrition 0.000 description 13
239000000243 solution Substances 0.000 description 11
239000007864 aqueous solution Substances 0.000 description 10
239000000376 reactant Substances 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
150000001768 cations Chemical class 0.000 description 5
230000003138 coordinated effect Effects 0.000 description 5
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
230000001965 increasing effect Effects 0.000 description 4
239000010410 layer Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
238000004523 catalytic cracking Methods 0.000 description 3
239000011229 interlayer Substances 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
229910000069 nitrogen hydride Inorganic materials 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
229910000027 potassium carbonate Inorganic materials 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
229910017974 NH40H Inorganic materials 0.000 description 2
238000010669 acid-base reaction Methods 0.000 description 2
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
239000012298 atmosphere Substances 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
239000002734 clay mineral Substances 0.000 description 2
239000007789 gas Substances 0.000 description 2
150000004679 hydroxides Chemical class 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
229910052809 inorganic oxide Inorganic materials 0.000 description 2
230000005012 migration Effects 0.000 description 2
238000013508 migration Methods 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
230000008569 process Effects 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000002002 slurry Substances 0.000 description 2
235000011121 sodium hydroxide Nutrition 0.000 description 2
229910052726 zirconium Inorganic materials 0.000 description 2
206010001497 Agitation Diseases 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
101100491995 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) aro-1 gene Proteins 0.000 description 1
101100216944 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) aro-2 gene Proteins 0.000 description 1
229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
229910020489 SiO3 Inorganic materials 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
238000013019 agitation Methods 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910001854 alkali hydroxide Inorganic materials 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
229940024545 aluminum hydroxide Drugs 0.000 description 1
WWHZEXDIQCJXSV-UHFFFAOYSA-N aluminum;trihypochlorite Chemical compound [Al+3].Cl[O-].Cl[O-].Cl[O-] WWHZEXDIQCJXSV-UHFFFAOYSA-N 0.000 description 1
229910021538 borax Inorganic materials 0.000 description 1
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
239000004327 boric acid Substances 0.000 description 1
VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
230000008859 change Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
239000002274 desiccant Substances 0.000 description 1
239000003599 detergent Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000012065 filter cake Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
230000003993 interaction Effects 0.000 description 1
238000006317 isomerization reaction Methods 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
229910052573 porcelain Inorganic materials 0.000 description 1
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
235000011118 potassium hydroxide Nutrition 0.000 description 1
229910001414 potassium ion Inorganic materials 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000002407 reforming Methods 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
239000007921 spray Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/049—Pillared clays
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/28—Selection of materials for use as drying agents
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Analytical Chemistry (AREA)
Dispersion Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Geochemistry & Mineralogy (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Catalysts (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)

CA000359406A 1979-09-04 1980-09-02 Produits hypostyle en argile a couches intercalaires Expired CA1153020A (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US06/071,957 US4248739A (en)	1979-09-04	1979-09-04	Stabilized pillared interlayered clays
US71,957		1979-09-04
US06/080,959 US4271043A (en)	1979-09-04	1979-10-01	Pillared interlayered clay products
US80,959		1979-10-01

Publications (1)

Publication Number	Publication Date
CA1153020A true CA1153020A (fr)	1983-08-30

Family

ID=26752864

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000359406A Expired CA1153020A (fr)	1979-09-04	1980-09-02	Produits hypostyle en argile a couches intercalaires

Country Status (1)

Country	Link
CA (1)	CA1153020A (fr)

1980
- 1980-09-02 CA CA000359406A patent/CA1153020A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2000-08-30	MKEX	Expiry

Publication	Publication Date	Title
US4271043A (en)	1981-06-02	Pillared interlayered clay products
US4248739A (en)	1981-02-03	Stabilized pillared interlayered clays
EP1027151B1 (fr)	2008-05-07	Procede de fabrication et d'utilisation de materiau argileux anionique
EP0197012B1 (fr)	1989-11-15	Classe de produits du type tamis moléculaires constitués d'argiles interlamellaires pontés possédant une structure minérale régulière interstratifiée
US4176090A (en)	1979-11-27	Pillared interlayered clay materials useful as catalysts and sorbents
Occelli	1986	New routes to the preparation of pillared montmorillonite catalysts
US4629712A (en)	1986-12-16	Delaminated clay materials
Malherbe et al.	1997	Use of organic media to modify the surface and porosity properties of hydrotalcite-like compounds
Wright et al.	1972	Catalysis by layer lattice silicates. I. The structure and thermal modification of a synthetic ammonium dioctahedral clay
EP0139291A2 (fr)	1985-05-02	Méthode de craquage d'huile résiduelle
CA1106346A (fr)	1981-08-04	Produits d'argile a intercouches et a structure en colonnes, servant de catalyseurs et de sorbants
Tomlinson	1998	Characterization of pillared layered structures
US4968652A (en)	1990-11-06	Pillared layered silicate compositions containing pillars of silica and metal oxide and their preparation
Miehé-Brendlé et al.	1997	Zr-exchanged and pillared beidellite: preparation and characterization by chemical analysis, XRD and Zr K EXAFS
US5200378A (en)	1993-04-06	Pillaring of layered compounds
CA1153020A (fr)	1983-08-30	Produits hypostyle en argile a couches intercalaires
US5017537A (en)	1991-05-21	Pillaring of layered compounds
Tsai et al.	1994	Pillared titanates: titanium oxide of high surface area and porosity
Clearfield	1996	Preparation of pillared clays and their catalytic properties
CA2596421C (fr)	2012-08-07	Procede de fabrication et d'utilisation de materiau argileux anionique
KR100424880B1 (ko)	2004-03-27	제올라이트의 이온교환방법
Clearfield et al.	1994	Alteration of Alumina Pillared Clays for Enhanced Catalytic Activity
Clearfield et al.	1991	New porous materials from layered compounds
Pinnavaia et al.	1992	Molecular Engineering of Layered Structures II. Synthetic Approaches to Some New Pillared Derivatives
Beyer et al.	1995	Substituting Fe for Al in the Al130407+ Keggin ion was attempted and the incorpo