CA2596421C - Procede de fabrication et d'utilisation de materiau argileux anionique - Google Patents

Procede de fabrication et d'utilisation de materiau argileux anionique Download PDF

Info

Publication number: CA2596421C
Authority: CA; Canada
Prior art keywords: compound; hydrotalcite; htl; compounds; applicant
Prior art date: 1997-10-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA2596421A

Other languages

English (en)

Other versions

CA2596421A1 (fr

Inventor

Albert A. Vierheilig

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Johnson Matthey Process Technologies Inc

Original Assignee

Intercat Savannah Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-10-20

Filing date

1998-09-15

Publication date

2012-08-07

1997-10-20 Priority claimed from US08/955,017 external-priority patent/US6028023A/en

1998-09-15 Application filed by Intercat Savannah Inc filed Critical Intercat Savannah Inc

1999-04-29 Publication of CA2596421A1 publication Critical patent/CA2596421A1/fr

2012-08-07 Application granted granted Critical

2012-08-07 Publication of CA2596421C publication Critical patent/CA2596421C/fr

2018-09-15 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 101
230000008569 process Effects 0.000 title claims abstract description 56
125000000129 anionic group Chemical group 0.000 title abstract description 60
239000004927 clay Substances 0.000 title abstract description 50
239000000463 material Substances 0.000 title description 81
150000001875 compounds Chemical class 0.000 claims abstract description 325
GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 78
229910001701 hydrotalcite Inorganic materials 0.000 claims description 76
229960001545 hydrotalcite Drugs 0.000 claims description 76
239000011777 magnesium Substances 0.000 claims description 49
239000007800 oxidant agent Substances 0.000 claims description 33
229910052749 magnesium Inorganic materials 0.000 claims description 31
239000000203 mixture Substances 0.000 claims description 31
239000002245 particle Substances 0.000 claims description 31
238000002441 X-ray diffraction Methods 0.000 claims description 29
239000011230 binding agent Substances 0.000 claims description 28
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 26
229910052782 aluminium Inorganic materials 0.000 claims description 26
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 25
-1 compound of claim 1 Chemical compound 0.000 claims description 25
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 25
238000006243 chemical reaction Methods 0.000 claims description 24
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 23
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 23
239000011541 reaction mixture Substances 0.000 claims description 22
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 20
230000000887 hydrating effect Effects 0.000 claims description 16
229910052720 vanadium Inorganic materials 0.000 claims description 15
229910052742 iron Inorganic materials 0.000 claims description 14
229910052684 Cerium Inorganic materials 0.000 claims description 13
229910052759 nickel Inorganic materials 0.000 claims description 13
229910052697 platinum Inorganic materials 0.000 claims description 13
229910052804 chromium Inorganic materials 0.000 claims description 12
239000011651 chromium Substances 0.000 claims description 12
239000008188 pellet Substances 0.000 claims description 12
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 11
229910052802 copper Inorganic materials 0.000 claims description 11
239000010949 copper Substances 0.000 claims description 11
229910052750 molybdenum Inorganic materials 0.000 claims description 11
239000011733 molybdenum Substances 0.000 claims description 11
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 11
229910052721 tungsten Inorganic materials 0.000 claims description 11
239000010937 tungsten Substances 0.000 claims description 11
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 10
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 10
229910052770 Uranium Inorganic materials 0.000 claims description 10
229910052769 Ytterbium Inorganic materials 0.000 claims description 10
229910017052 cobalt Inorganic materials 0.000 claims description 10
239000010941 cobalt Substances 0.000 claims description 10
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 10
229910052741 iridium Inorganic materials 0.000 claims description 10
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 10
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 10
229910052763 palladium Inorganic materials 0.000 claims description 10
229910052703 rhodium Inorganic materials 0.000 claims description 10
239000010948 rhodium Substances 0.000 claims description 10
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 10
NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 10
239000013078 crystal Substances 0.000 claims description 9
230000032683 aging Effects 0.000 claims description 7
239000011159 matrix material Substances 0.000 claims description 6
239000013626 chemical specie Substances 0.000 claims description 3
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims 8
JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims 8
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 8
230000003247 decreasing effect Effects 0.000 claims 4
229910020489 SiO3 Inorganic materials 0.000 claims 1
229910001914 chlorine tetroxide Inorganic materials 0.000 claims 1
229910052740 iodine Inorganic materials 0.000 claims 1
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims 1
239000003054 catalyst Substances 0.000 description 69
239000002594 sorbent Substances 0.000 description 52
229910052570 clay Inorganic materials 0.000 description 48
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 47
239000012071 phase Substances 0.000 description 44
238000001994 activation Methods 0.000 description 40
238000010438 heat treatment Methods 0.000 description 39
239000000047 product Substances 0.000 description 35
229910052596 spinel Inorganic materials 0.000 description 35
230000015572 biosynthetic process Effects 0.000 description 33
239000002243 precursor Substances 0.000 description 33
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 32
239000011029 spinel Substances 0.000 description 31
239000002002 slurry Substances 0.000 description 26
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 25
239000000395 magnesium oxide Substances 0.000 description 24
230000004913 activation Effects 0.000 description 21
229910052751 metal Inorganic materials 0.000 description 20
239000002184 metal Substances 0.000 description 20
238000003786 synthesis reaction Methods 0.000 description 16
238000009740 moulding (composite fabrication) Methods 0.000 description 15
230000003647 oxidation Effects 0.000 description 15
238000007254 oxidation reaction Methods 0.000 description 15
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 14
230000036571 hydration Effects 0.000 description 14
238000006703 hydration reaction Methods 0.000 description 14
241000894007 species Species 0.000 description 14
150000001450 anions Chemical class 0.000 description 13
239000003795 chemical substances by application Substances 0.000 description 13
239000004615 ingredient Substances 0.000 description 13
239000004215 Carbon black (E152) Substances 0.000 description 11
239000007795 chemical reaction product Substances 0.000 description 11
230000000694 effects Effects 0.000 description 11
229930195733 hydrocarbon Natural products 0.000 description 11
150000002430 hydrocarbons Chemical class 0.000 description 11
238000001354 calcination Methods 0.000 description 10
230000003197 catalytic effect Effects 0.000 description 10
239000010410 layer Substances 0.000 description 10
238000004519 manufacturing process Methods 0.000 description 10
238000005336 cracking Methods 0.000 description 9
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 9
239000000347 magnesium hydroxide Substances 0.000 description 9
229910001862 magnesium hydroxide Inorganic materials 0.000 description 9
235000012254 magnesium hydroxide Nutrition 0.000 description 9
230000001590 oxidative effect Effects 0.000 description 9
239000007858 starting material Substances 0.000 description 9
239000000654 additive Substances 0.000 description 8
150000001768 cations Chemical class 0.000 description 8
229910000000 metal hydroxide Inorganic materials 0.000 description 8
150000004692 metal hydroxides Chemical class 0.000 description 8
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
230000000996 additive effect Effects 0.000 description 7
229910000422 cerium(IV) oxide Inorganic materials 0.000 description 7
238000001035 drying Methods 0.000 description 7
150000002739 metals Chemical class 0.000 description 7
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 7
238000000354 decomposition reaction Methods 0.000 description 6
230000006870 function Effects 0.000 description 6
150000002500 ions Chemical group 0.000 description 6
239000002244 precipitate Substances 0.000 description 6
238000012360 testing method Methods 0.000 description 6
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 5
239000011229 interlayer Substances 0.000 description 5
238000005342 ion exchange Methods 0.000 description 5
230000000704 physical effect Effects 0.000 description 5
239000006104 solid solution Substances 0.000 description 5
239000000126 substance Substances 0.000 description 5
229910052717 sulfur Inorganic materials 0.000 description 5
239000011593 sulfur Substances 0.000 description 5
238000005979 thermal decomposition reaction Methods 0.000 description 5
238000002411 thermogravimetry Methods 0.000 description 5
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
229910026161 MgAl2O4 Inorganic materials 0.000 description 4
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
239000002734 clay mineral Substances 0.000 description 4
239000012530 fluid Substances 0.000 description 4
230000014509 gene expression Effects 0.000 description 4
239000007787 solid Substances 0.000 description 4
239000000243 solution Substances 0.000 description 4
238000001179 sorption measurement Methods 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
239000002250 absorbent Substances 0.000 description 3
230000002745 absorbent Effects 0.000 description 3
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 3
238000005349 anion exchange Methods 0.000 description 3
239000011324 bead Substances 0.000 description 3
229910052599 brucite Inorganic materials 0.000 description 3
XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 3
239000000969 carrier Substances 0.000 description 3
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 3
239000003814 drug Substances 0.000 description 3
239000007789 gas Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
230000006872 improvement Effects 0.000 description 3
229910052500 inorganic mineral Inorganic materials 0.000 description 3
229910044991 metal oxide Inorganic materials 0.000 description 3
239000011707 mineral Substances 0.000 description 3
230000007935 neutral effect Effects 0.000 description 3
239000003208 petroleum Substances 0.000 description 3
239000011148 porous material Substances 0.000 description 3
229910052725 zinc Inorganic materials 0.000 description 3
239000011701 zinc Substances 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
229910020068 MgAl Inorganic materials 0.000 description 2
229910003112 MgO-Al2O3 Inorganic materials 0.000 description 2
229910002651 NO3 Inorganic materials 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
239000004902 Softening Agent Substances 0.000 description 2
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000011149 active material Substances 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 2
RJZNFXWQRHAVBP-UHFFFAOYSA-I aluminum;magnesium;pentahydroxide Chemical class [OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Al+3] RJZNFXWQRHAVBP-UHFFFAOYSA-I 0.000 description 2
230000027455 binding Effects 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 2
239000000378 calcium silicate Substances 0.000 description 2
229910052918 calcium silicate Inorganic materials 0.000 description 2
229910002092 carbon dioxide Inorganic materials 0.000 description 2
150000004649 carbonic acid derivatives Chemical class 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 2
PPQREHKVAOVYBT-UHFFFAOYSA-H dialuminum;tricarbonate Chemical compound [Al+3].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O PPQREHKVAOVYBT-UHFFFAOYSA-H 0.000 description 2
229940079593 drug Drugs 0.000 description 2
238000009472 formulation Methods 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
229910001425 magnesium ion Inorganic materials 0.000 description 2
YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
239000000391 magnesium silicate Substances 0.000 description 2
229910052919 magnesium silicate Inorganic materials 0.000 description 2
235000019792 magnesium silicate Nutrition 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
239000011572 manganese Substances 0.000 description 2
229910021645 metal ion Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
235000010755 mineral Nutrition 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
239000010452 phosphate Substances 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
230000009467 reduction Effects 0.000 description 2
230000000630 rising effect Effects 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000007921 spray Substances 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
230000035882 stress Effects 0.000 description 2
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
229910052815 sulfur oxide Inorganic materials 0.000 description 2
DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 2
BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
OZXIZRZFGJZWBF-UHFFFAOYSA-N 1,3,5-trimethyl-2-(2,4,6-trimethylphenoxy)benzene Chemical compound CC1=CC(C)=CC(C)=C1OC1=C(C)C=C(C)C=C1C OZXIZRZFGJZWBF-UHFFFAOYSA-N 0.000 description 1
LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 description 1
RRKXGHIWLJDUIU-UHFFFAOYSA-N 5-bromo-8-chloroisoquinoline Chemical compound C1=NC=C2C(Cl)=CC=C(Br)C2=C1 RRKXGHIWLJDUIU-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
229910000505 Al2TiO5 Inorganic materials 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
239000005909 Kieselgur Substances 0.000 description 1
241001175904 Labeo bata Species 0.000 description 1
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
229910020038 Mg6Al2 Inorganic materials 0.000 description 1
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
GANNOFFDYMSBSZ-UHFFFAOYSA-N [AlH3].[Mg] Chemical class [AlH3].[Mg] GANNOFFDYMSBSZ-UHFFFAOYSA-N 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 description 1
238000005882 aldol condensation reaction Methods 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
MJWPFSQVORELDX-UHFFFAOYSA-K aluminium formate Chemical compound [Al+3].[O-]C=O.[O-]C=O.[O-]C=O MJWPFSQVORELDX-UHFFFAOYSA-K 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
229940009827 aluminum acetate Drugs 0.000 description 1
229940118662 aluminum carbonate Drugs 0.000 description 1
GSWGDDYIUCWADU-UHFFFAOYSA-N aluminum magnesium oxygen(2-) Chemical compound [O--].[Mg++].[Al+3] GSWGDDYIUCWADU-UHFFFAOYSA-N 0.000 description 1
OPXQHAWRSLHWOQ-UHFFFAOYSA-I aluminum magnesium pentahydroxide hydrate Chemical class O.[OH-].[OH-].[OH-].[OH-].[OH-].[Mg++].[Al+3] OPXQHAWRSLHWOQ-UHFFFAOYSA-I 0.000 description 1
QANIADJLTJYOFI-UHFFFAOYSA-K aluminum;magnesium;carbonate;hydroxide;hydrate Chemical class O.[OH-].[Mg+2].[Al+3].[O-]C([O-])=O QANIADJLTJYOFI-UHFFFAOYSA-K 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
150000001449 anionic compounds Chemical class 0.000 description 1
229940069428 antacid Drugs 0.000 description 1
239000003159 antacid agent Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000003190 augmentative effect Effects 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
239000002585 base Substances 0.000 description 1
239000005385 borate glass Substances 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
238000004523 catalytic cracking Methods 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000002447 crystallographic data Methods 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
238000001514 detection method Methods 0.000 description 1
238000010586 diagram Methods 0.000 description 1
IQDXNHZDRQHKEF-UHFFFAOYSA-N dialuminum;dicalcium;dioxido(oxo)silane Chemical compound [Al+3].[Al+3].[Ca+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O IQDXNHZDRQHKEF-UHFFFAOYSA-N 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
UYXQSEVJEOMGFV-UHFFFAOYSA-N ethaneperoxoic acid;magnesium Chemical compound [Mg].CC(=O)OO UYXQSEVJEOMGFV-UHFFFAOYSA-N 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
239000000499 gel Substances 0.000 description 1
230000008570 general process Effects 0.000 description 1
239000008187 granular material Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
239000012073 inactive phase Substances 0.000 description 1
239000013067 intermediate product Substances 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
238000006317 isomerization reaction Methods 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
230000002045 lasting effect Effects 0.000 description 1
239000007788 liquid Substances 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
150000002681 magnesium compounds Chemical class 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
GMDNUWQNDQDBNQ-UHFFFAOYSA-L magnesium;diformate Chemical compound [Mg+2].[O-]C=O.[O-]C=O GMDNUWQNDQDBNQ-UHFFFAOYSA-L 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
SHOJXDKTYKFBRD-UHFFFAOYSA-N mesityl oxide Natural products CC(C)=CC(C)=O SHOJXDKTYKFBRD-UHFFFAOYSA-N 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229930014626 natural product Natural products 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000000634 powder X-ray diffraction Methods 0.000 description 1
230000002028 premature Effects 0.000 description 1
AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
150000002910 rare earth metals Chemical class 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000007670 refining Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
238000009877 rendering Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000005368 silicate glass Substances 0.000 description 1
239000012265 solid product Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
238000007669 thermal treatment Methods 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
238000011282 treatment Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1
229910009112 xH2O Inorganic materials 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Landscapes

Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Catalysts (AREA)

CA2596421A 1997-10-20 1998-09-15 Procede de fabrication et d'utilisation de materiau argileux anionique Expired - Lifetime CA2596421C (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US08/955,017 US6028023A (en)	1997-10-20	1997-10-20	Process for making, and use of, anionic clay materials
US955,017		1997-10-20
CA002308748A CA2308748C (fr)	1997-10-20	1998-09-15	Procede de fabrication et d'utilisation de materiau argileux anionique

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CA002308748A Division CA2308748C (fr)	1997-10-20	1998-09-15	Procede de fabrication et d'utilisation de materiau argileux anionique

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CA2596421A1 CA2596421A1 (fr)	1999-04-29
CA2596421C true CA2596421C (fr)	2012-08-07

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CN116586028B (zh) *	2023-05-04	2024-07-16	生态环境部南京环境科学研究所	一种Fe3+-Ti4+-Zr4+-LDH型吸附剂的制备方法及应用
CN117205939A (zh) *	2023-08-08	2023-12-12	北京万邦达环保技术股份有限公司	一种多金属臭氧催化剂及其制备系统和方法

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