CA1165303A - Charbon de bois impregne pour separer les molecules radioactives des gaz - Google Patents
Charbon de bois impregne pour separer les molecules radioactives des gazInfo
- Publication number
- CA1165303A CA1165303A CA000370072A CA370072A CA1165303A CA 1165303 A CA1165303 A CA 1165303A CA 000370072 A CA000370072 A CA 000370072A CA 370072 A CA370072 A CA 370072A CA 1165303 A CA1165303 A CA 1165303A
- Authority
- CA
- Canada
- Prior art keywords
- charcoal
- adsorbent
- octane
- diazabicyclo
- impregnated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003610 charcoal Substances 0.000 title claims abstract description 49
- 230000002285 radioactive effect Effects 0.000 title claims abstract description 16
- 239000007789 gas Substances 0.000 title claims description 18
- 239000003463 adsorbent Substances 0.000 claims abstract description 28
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical class C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 238000005507 spraying Methods 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 11
- 125000001424 substituent group Chemical group 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 229940106265 charcoal Drugs 0.000 description 44
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 15
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 10
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 150000001350 alkyl halides Chemical class 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 150000003512 tertiary amines Chemical class 0.000 description 3
- FTTATHOUSOIFOQ-UHFFFAOYSA-N 1,2,3,4,6,7,8,8a-octahydropyrrolo[1,2-a]pyrazine Chemical compound C1NCCN2CCCC21 FTTATHOUSOIFOQ-UHFFFAOYSA-N 0.000 description 2
- 210000001736 capillary Anatomy 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000006199 nebulizer Substances 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 239000002594 sorbent Substances 0.000 description 2
- RVNSAAIWCWTCTJ-ZPQYLTHOSA-N (2s,3s,4r)-2-(1,2-dihydroxyethyl)pyrrolidine-3,4-diol Chemical compound OCC(O)[C@@H]1NC[C@@H](O)[C@H]1O RVNSAAIWCWTCTJ-ZPQYLTHOSA-N 0.000 description 1
- PNDPGZBMCMUPRI-HVTJNCQCSA-N 10043-66-0 Chemical compound [131I][131I] PNDPGZBMCMUPRI-HVTJNCQCSA-N 0.000 description 1
- QXKMWFFBWDHDCB-UHFFFAOYSA-N 3-methyl-1,4-diazabicyclo[2.2.2]octane Chemical compound C1CN2C(C)CN1CC2 QXKMWFFBWDHDCB-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/02—Treating gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3204—Inorganic carriers, supports or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3244—Non-macromolecular compounds
- B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
- B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
- B01J20/3255—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such comprising a cyclic structure containing at least one of the heteroatoms nitrogen, oxygen or sulfur, e.g. heterocyclic or heteroaromatic structures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3287—Layers in the form of a liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4812—Sorbents characterised by the starting material used for their preparation the starting material being of organic character
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4812—Sorbents characterised by the starting material used for their preparation the starting material being of organic character
- B01J2220/485—Plants or land vegetals, e.g. cereals, wheat, corn, rice, sphagnum, peat moss
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
- B01J2220/56—Use in the form of a bed
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11855480A | 1980-02-04 | 1980-02-04 | |
| US118,554 | 1980-02-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1165303A true CA1165303A (fr) | 1984-04-10 |
Family
ID=22379326
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000370072A Expired CA1165303A (fr) | 1980-02-04 | 1981-02-04 | Charbon de bois impregne pour separer les molecules radioactives des gaz |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0045318A1 (fr) |
| CA (1) | CA1165303A (fr) |
| WO (1) | WO1981002256A1 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4531953A (en) * | 1983-06-21 | 1985-07-30 | Calgon Corporation | Sublimation of amine compounds on activated carbon pore surfaces |
| CA2015810A1 (fr) * | 1990-05-01 | 1991-11-01 | Septimus H. Liang | Sublimation de composes amines sur du charbon active sous pression reduite |
| US6767860B2 (en) | 2001-05-10 | 2004-07-27 | 3M Innovative Properties Company | Sublimation of solid organic compounds onto substrate surfaces in the presence of a fluid impregnant |
| JP5781279B2 (ja) * | 2010-06-15 | 2015-09-16 | 三菱重工業株式会社 | 放射性ヨウ素の吸着材及び放射性ヨウ素の除去装置 |
| JP6848539B2 (ja) * | 2016-03-09 | 2021-03-24 | 東ソー株式会社 | 水酸基を含有する環状アミン化合物が固定化された担持物 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US411833A (en) * | 1889-10-01 | Electric motor | ||
| US2818323A (en) * | 1953-10-07 | 1957-12-31 | Universal Oil Prod Co | Purification of gases with an amine impregnated solid absorbent |
| US3015368A (en) * | 1960-03-16 | 1962-01-02 | Socony Mobil Oil Co Inc | Treatment of desiccants |
| US3112320A (en) * | 1961-08-02 | 1963-11-26 | Air Prod & Chem | Stabilized triethylene diamine |
| US3297701A (en) * | 1962-03-23 | 1967-01-10 | Jefferson Chem Co Inc | Synthesis of diazabicyclo-(2, 2, 2)-octane and derivatives |
| US3325547A (en) * | 1963-10-21 | 1967-06-13 | Jefferson Chem Co Inc | Stabilization of polyoxyalkylene compounds |
| GB1123821A (en) * | 1965-01-22 | 1968-08-14 | Atomic Energy Authority Uk | Improvements in or relating to fission product trapping systems |
| GB1124116A (en) * | 1965-07-28 | 1968-08-21 | Atomic Energy Authority Uk | Improvements in or relating to charcoal for use in trapping systems |
| US3491031A (en) * | 1966-11-18 | 1970-01-20 | Calgon C0Rp | Reactivation of monoethanolamine impregnated activated carbon |
| US4040802A (en) * | 1975-04-22 | 1977-08-09 | Deitz Victor R | Activation of water soluble amines by halogens for trapping methyl radioactive iodine from air streams |
| US4204980A (en) * | 1976-01-08 | 1980-05-27 | American Air Filter Company, Inc. | Method and composition for removing iodine from gases |
| US4016242A (en) * | 1976-02-26 | 1977-04-05 | The United States Of America As Represented By The United States Energy Research And Development Administration | Salts of the iodine oxyacids in the impregnation of adsorbent charcoal for trapping radioactive methyliodide |
-
1981
- 1981-02-03 WO PCT/US1981/000144 patent/WO1981002256A1/fr not_active Ceased
- 1981-02-03 EP EP19810900607 patent/EP0045318A1/fr not_active Withdrawn
- 1981-02-04 CA CA000370072A patent/CA1165303A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0045318A1 (fr) | 1982-02-10 |
| WO1981002256A1 (fr) | 1981-08-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5738790A (en) | Composite membranes for solid phase extractions and reactions | |
| US4040802A (en) | Activation of water soluble amines by halogens for trapping methyl radioactive iodine from air streams | |
| EP1121968A2 (fr) | Filtre chimique et méthode pour sa production | |
| EP2514526B1 (fr) | Catalyseur de combustion d'hydrogène et son procédé de production et procédé de combustion d'hydrogène | |
| US4111833A (en) | Activated carbon material | |
| KR0155342B1 (ko) | 가열공기로 teda 증기를 발생하여 유동층흡착탑에서 teda 첨착활성탄 제조방법과 그 장치 | |
| CA2011500C (fr) | Methode d'essai utilisant l'eau deuteree | |
| US5145820A (en) | Reduced pressure sublimation of amine compounds on activated carbons | |
| JPS598419B2 (ja) | 単体ヨウ素または有機ヨウ素化合物の吸着材 | |
| CA1129837A (fr) | Absorbant de produit de fission, impregne de quinuclidine | |
| KR101972312B1 (ko) | 금속 첨착 활성탄 흡착제 및 이의 제조 방법 | |
| WO1981002256A1 (fr) | Charbon impregne pour extraire des molecules radioactives d'un gaz | |
| RU2036698C1 (ru) | Адсорбирующий фильтрующий материал, способ его получения и способ очистки газов от радиоактивных веществ | |
| KR102140913B1 (ko) | 방사성 요오드 화합물 흡착제 | |
| Underhill et al. | Impregnated charcoal for removing radioactive molecules from gases | |
| GB2327048A (en) | Adsorbent zeolite composition | |
| JP4471421B2 (ja) | ホルムアルデヒド吸着組成物 | |
| JPH0310061B2 (fr) | ||
| Kulyukhin et al. | Removal of volatile radioactive iodine compounds from water vapor–air medium | |
| JPS6147595A (ja) | ヨウ素除去方法 | |
| RU2141376C1 (ru) | Углеродсодержащий сорбент и способ его получения | |
| JPS5811038A (ja) | 有機溶剤蒸気の吸着剤 | |
| RU2673678C1 (ru) | Способ приготовления твердого гранулированного реактива для получения газообразного радиоактивного метилиодида | |
| Mikheev et al. | Sorption of CH3131I from steam-gas phase on modified Ag-containing zeolites | |
| JPS63283645A (ja) | 空気浄化剤 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |