CA1167200A - Procede de polymerisation du propylene - Google Patents

Procede de polymerisation du propylene

Info

Publication number: CA1167200A
Authority: CA; Canada
Prior art keywords: electron donor; catalyst; propylene; process according; titanium
Prior art date: 1979-07-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000355674A

Other languages

English (en)

Inventor

Edward A. Zukowski

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

El Paso Polyolefins Co

Original Assignee

El Paso Polyolefins Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-07-09

Filing date

1980-07-08

Publication date

1984-05-08

1980-07-08 Application filed by El Paso Polyolefins Co filed Critical El Paso Polyolefins Co

1984-05-08 Application granted granted Critical

1984-05-08 Publication of CA1167200A publication Critical patent/CA1167200A/fr

Status Expired legal-status Critical Current

Links

QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 31
238000006116 polymerization reaction Methods 0.000 title claims abstract description 30
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title claims abstract description 28
239000003054 catalyst Substances 0.000 claims abstract description 60
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 25
239000005977 Ethylene Substances 0.000 claims abstract description 25
239000011777 magnesium Substances 0.000 claims abstract description 12
229910052749 magnesium Inorganic materials 0.000 claims abstract description 12
239000007791 liquid phase Substances 0.000 claims abstract description 5
235000001055 magnesium Nutrition 0.000 claims abstract 5
229940091250 magnesium supplement Drugs 0.000 claims abstract 5
238000000034 method Methods 0.000 claims description 32
230000008569 process Effects 0.000 claims description 30
239000000306 component Substances 0.000 claims description 27
239000010936 titanium Substances 0.000 claims description 20
229910052719 titanium Inorganic materials 0.000 claims description 17
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 16
150000001875 compounds Chemical class 0.000 claims description 16
239000000203 mixture Substances 0.000 claims description 14
229910052782 aluminium Inorganic materials 0.000 claims description 13
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 12
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 11
238000006243 chemical reaction Methods 0.000 claims description 10
150000002148 esters Chemical class 0.000 claims description 10
230000006872 improvement Effects 0.000 claims description 7
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical group CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims description 6
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 5
239000002253 acid Substances 0.000 claims description 4
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
229910052751 metal Inorganic materials 0.000 claims description 4
239000002184 metal Substances 0.000 claims description 4
125000000217 alkyl group Chemical group 0.000 claims description 3
150000004985 diamines Chemical class 0.000 claims description 3
QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical group COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 2
230000003197 catalytic effect Effects 0.000 claims description 2
238000010924 continuous production Methods 0.000 claims description 2
229920000768 polyamine Polymers 0.000 claims description 2
230000000379 polymerizing effect Effects 0.000 claims description 2
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical group [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims 2
150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
235000011147 magnesium chloride Nutrition 0.000 claims 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims 1
-1 mag-nesium halide Chemical class 0.000 abstract description 7
229940095050 propylene Drugs 0.000 description 19
229920000642 polymer Polymers 0.000 description 18
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
235000010210 aluminium Nutrition 0.000 description 8
238000002474 experimental method Methods 0.000 description 7
239000007788 liquid Substances 0.000 description 7
239000000178 monomer Substances 0.000 description 7
230000000694 effects Effects 0.000 description 6
239000002002 slurry Substances 0.000 description 6
239000007787 solid Substances 0.000 description 6
239000003039 volatile agent Substances 0.000 description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 3
150000004820 halides Chemical class 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
229910010061 TiC13 Inorganic materials 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
239000002585 base Substances 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
238000010348 incorporation Methods 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
239000003607 modifier Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
PIPWSBOFSUJCCO-UHFFFAOYSA-N 2,2-dimethylpiperazine Chemical compound CC1(C)CNCCN1 PIPWSBOFSUJCCO-UHFFFAOYSA-N 0.000 description 1
ZEYHEAKUIGZSGI-UHFFFAOYSA-N 4-methoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C=C1 ZEYHEAKUIGZSGI-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
239000004264 Petrolatum Substances 0.000 description 1
241000950638 Symphysodon discus Species 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
WPFRLQWLYOFXMF-UHFFFAOYSA-K aluminum titanium(4+) trichloride Chemical compound [Al+3].[Cl-].[Cl-].[Cl-].[Ti+4] WPFRLQWLYOFXMF-UHFFFAOYSA-K 0.000 description 1
KSKPGAGLAZXNEO-UHFFFAOYSA-H aluminum;titanium(3+);hexachloride Chemical compound [Al+3].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Ti+3] KSKPGAGLAZXNEO-UHFFFAOYSA-H 0.000 description 1
230000008901 benefit Effects 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
238000000071 blow moulding Methods 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000003426 co-catalyst Substances 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
HHEIMYAXCOIQCJ-UHFFFAOYSA-N ethyl 2,2-dimethylpropanoate Chemical compound CCOC(=O)C(C)(C)C HHEIMYAXCOIQCJ-UHFFFAOYSA-N 0.000 description 1
RETLCWPMLJPOTP-UHFFFAOYSA-N ethyl 2-chlorobenzoate Chemical compound CCOC(=O)C1=CC=CC=C1Cl RETLCWPMLJPOTP-UHFFFAOYSA-N 0.000 description 1
SOUAXOGPALPTTC-UHFFFAOYSA-N ethyl 2-methylbenzoate Chemical compound CCOC(=O)C1=CC=CC=C1C SOUAXOGPALPTTC-UHFFFAOYSA-N 0.000 description 1
LMXMLKHKWPCFTG-UHFFFAOYSA-N ethyl 4-butoxybenzoate Chemical compound CCCCOC1=CC=C(C(=O)OCC)C=C1 LMXMLKHKWPCFTG-UHFFFAOYSA-N 0.000 description 1
229940093499 ethyl acetate Drugs 0.000 description 1
235000019439 ethyl acetate Nutrition 0.000 description 1
JJOYCHKVKWDMEA-UHFFFAOYSA-N ethyl cyclohexanecarboxylate Chemical compound CCOC(=O)C1CCCCC1 JJOYCHKVKWDMEA-UHFFFAOYSA-N 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
HOQADATXFBOEGG-UHFFFAOYSA-N isofenphos Chemical compound CCOP(=S)(NC(C)C)OC1=CC=CC=C1C(=O)OC(C)C HOQADATXFBOEGG-UHFFFAOYSA-N 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
235000010446 mineral oil Nutrition 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000002895 organic esters Chemical class 0.000 description 1
229920006280 packaging film Polymers 0.000 description 1
239000012785 packaging film Substances 0.000 description 1
229940066842 petrolatum Drugs 0.000 description 1
235000019271 petrolatum Nutrition 0.000 description 1
150000003018 phosphorus compounds Chemical class 0.000 description 1
XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
229920001384 propylene homopolymer Polymers 0.000 description 1
238000010926 purge Methods 0.000 description 1
SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
AJSTXXYNEIHPMD-UHFFFAOYSA-N triethyl borate Chemical compound CCOB(OCC)OCC AJSTXXYNEIHPMD-UHFFFAOYSA-N 0.000 description 1
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CA000355674A 1979-07-09 1980-07-08 Procede de polymerisation du propylene Expired CA1167200A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US5593379A	1979-07-09	1979-07-09
US55,933		1979-07-09

Publications (1)

Publication Number	Publication Date
CA1167200A true CA1167200A (fr)	1984-05-08

Family

ID=22001092

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000355674A Expired CA1167200A (fr)	1979-07-09	1980-07-08	Procede de polymerisation du propylene

Country Status (10)

Country	Link
JP (1)	JPS6021685B2 (fr)
BR (1)	BR8004219A (fr)
CA (1)	CA1167200A (fr)
DE (1)	DE3026010C2 (fr)
DK (1)	DK293580A (fr)
FR (1)	FR2460967A1 (fr)
MX (1)	MX153604A (fr)
NO (1)	NO157458C (fr)
SE (1)	SE8005027L (fr)
ZA (1)	ZA802449B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
KR100398270B1 (ko) *	2000-07-12	2003-09-19	최용식	모터펌프를 이용한 헤어세팅장치
CN100551762C (zh)	2003-11-20	2009-10-21	国立大学法人东京工业大学	履带、履带单元以及用于制造履带的方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1477315A (fr) *	1965-05-28	1967-04-14	Rexall Drug Chemical	Procédé perfectionné de polymérisation du propylène
IT1005486B (it) *	1974-02-15	1976-08-20	Montedison Spa	Gomme termoplastiche e processo per la loro preparazione
IT1054410B (it) *	1975-11-21	1981-11-10	Mitsui Petrochemical Ind	Catalizzatori per la polimerizzazione delle alfa olefine
JPS591406B2 (ja) *	1976-08-09	1984-01-12	昭和電工株式会社	改良されたオレフイン系重合体を製造する方法
JPS5840564B2 (ja) *	1976-06-24	1983-09-06	昭和電工株式会社	オレフイン重合体の製造方法

1980
- 1980-04-23 ZA ZA00802449A patent/ZA802449B/xx unknown
- 1980-05-14 NO NO801444A patent/NO157458C/no unknown
- 1980-06-03 FR FR8012315A patent/FR2460967A1/fr active Pending
- 1980-06-18 MX MX182812A patent/MX153604A/es unknown
- 1980-06-26 JP JP55086003A patent/JPS6021685B2/ja not_active Expired
- 1980-07-08 DK DK293580A patent/DK293580A/da not_active Application Discontinuation
- 1980-07-08 SE SE8005027A patent/SE8005027L/xx not_active Application Discontinuation
- 1980-07-08 CA CA000355674A patent/CA1167200A/fr not_active Expired
- 1980-07-08 BR BR8004219A patent/BR8004219A/pt unknown
- 1980-07-09 DE DE3026010A patent/DE3026010C2/de not_active Expired

Also Published As

Publication number	Publication date
NO157458C (no)	1988-03-23
DE3026010C2 (de)	1985-01-31
DE3026010A1 (de)	1981-01-15
SE8005027L (sv)	1981-01-10
ZA802449B (en)	1981-04-29
BR8004219A (pt)	1981-01-21
NO801444L (no)	1981-01-12
MX153604A (es)	1986-12-03
JPS6021685B2 (ja)	1985-05-29
JPS5614508A (en)	1981-02-12
FR2460967A1 (fr)	1981-01-30
NO157458B (no)	1987-12-14
DK293580A (da)	1981-01-10

Legal Events

Date	Code	Title	Description
2001-05-08	MKEX	Expiry

Publication	Publication Date	Title
CA1263371A (fr)	1989-11-28	CATALYSEUR SUR SUPPORT POUR LA POLYMERISATION .alpha.-OLEFINES, OBTENU DANS DES CONDITIONS DE PREPOLYMERISATION COMPLETE
US4894424A (en)	1990-01-16	Polymerisation of olefins using modified ziegler-natta catalyst
NO175314B (no)	1994-06-20	Katalysatorsystem for polymerisasjon av olefiner, fremstilling av en prokatalysator og anvendelse av systemet ved polymerisasjon av etylen
EP0576411B1 (fr)	1999-03-17	Système catalytique amélioré pour la polymérisation d'oléfines
AU731769B2 (en)	2001-04-05	Process for making propylene homo or copolymers
CA1170245A (fr)	1984-07-03	Solide a teneur de magnesium
EP0133783B1 (fr)	1989-04-26	Catalyseur supporté pour la polymérisation de l'éthylène à température élevée
US4351930A (en)	1982-09-28	Propylene copolymerization process and product
US4308357A (en)	1981-12-29	Block copolymerization process and product
US4276191A (en)	1981-06-30	Catalyst and process for polymerization of alpha-olefins
US3676414A (en)	1972-07-11	Process for polymerizing {60 -olefins
CA1167200A (fr)	1984-05-08	Procede de polymerisation du propylene
GB2103628A (en)	1983-02-23	Block copolymerization process
US4081589A (en)	1978-03-28	Elimination of fibrous polymers
US4416799A (en)	1983-11-22	Catalytic component for polymerizing α-olefin and method for homo- or co-polymerization of α-olefin
CA2053645C (fr)	2002-10-15	Catalyseur de polymerisation d'olefines
JPH08504446A (ja)	1996-05-14	α−オレフィンの重合方法
US4342856A (en)	1982-08-03	Propylene polymerization process and product
US4020264A (en)	1977-04-26	Crystalline polyolefins and production thereof
US4154702A (en)	1979-05-15	Polyolefin catalyst
EP0576413B1 (fr)	1999-01-13	Donneurs d'électrons pour la polymérisation améliorée d'oléfines
CA1219997A (fr)	1987-03-31	Polymerisation d'une olefine
US4222895A (en)	1980-09-16	Polyolefin catalyst
US4981928A (en)	1991-01-01	Supported polyolefin catalyst for polymerization of ethylene under high temperatures
US4197387A (en)	1980-04-08	Polyolefin catalyst