CA1170187A - Dentifrice au zeolite synthetique - Google Patents

Dentifrice au zeolite synthetique

Info

Publication number: CA1170187A
Authority: CA; Canada
Prior art keywords: zeolite; dentifrice composition; percent; micron; size
Prior art date: 1980-08-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000377704A

Other languages

English (en)

Inventor

Rimantas Glemza

Chang W. Chi

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

WR Grace and Co

Original Assignee

WR Grace and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-08-21

Filing date

1981-05-15

Publication date

1984-07-03

1981-05-15 Application filed by WR Grace and Co filed Critical WR Grace and Co

1984-07-03 Application granted granted Critical

1984-07-03 Publication of CA1170187A publication Critical patent/CA1170187A/fr

Status Expired legal-status Critical Current

Links

239000010457 zeolite Substances 0.000 title claims abstract description 75
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 59
229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 53
239000000551 dentifrice Substances 0.000 title claims abstract description 47
239000000203 mixture Substances 0.000 claims abstract description 44
239000013078 crystal Substances 0.000 claims abstract description 37
238000005498 polishing Methods 0.000 claims abstract description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
238000005299 abrasion Methods 0.000 claims description 10
239000012065 filter cake Substances 0.000 claims description 10
239000003906 humectant Substances 0.000 claims description 10
210000004268 dentin Anatomy 0.000 claims description 8
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
238000004140 cleaning Methods 0.000 claims description 7
229910052708 sodium Inorganic materials 0.000 claims description 7
239000011734 sodium Substances 0.000 claims description 7
239000007788 liquid Substances 0.000 claims description 6
230000002285 radioactive effect Effects 0.000 claims description 5
JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 claims 1
239000012459 cleaning agent Substances 0.000 abstract description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
239000000606 toothpaste Substances 0.000 description 11
239000002245 particle Substances 0.000 description 10
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
239000003082 abrasive agent Substances 0.000 description 7
239000003795 chemical substances by application Substances 0.000 description 7
239000000796 flavoring agent Substances 0.000 description 7
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
235000019634 flavors Nutrition 0.000 description 6
239000000843 powder Substances 0.000 description 6
239000004094 surface-active agent Substances 0.000 description 6
229940034610 toothpaste Drugs 0.000 description 6
239000004615 ingredient Substances 0.000 description 5
239000006072 paste Substances 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
239000000654 additive Substances 0.000 description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
-1 e.g. Chemical class 0.000 description 4
235000011187 glycerol Nutrition 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
239000004965 Silica aerogel Substances 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
150000001340 alkali metals Chemical class 0.000 description 3
229910000323 aluminium silicate Inorganic materials 0.000 description 3
JUNWLZAGQLJVLR-UHFFFAOYSA-J calcium diphosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])(=O)OP([O-])([O-])=O JUNWLZAGQLJVLR-UHFFFAOYSA-J 0.000 description 3
229940043256 calcium pyrophosphate Drugs 0.000 description 3
239000001768 carboxy methyl cellulose Substances 0.000 description 3
210000003298 dental enamel Anatomy 0.000 description 3
235000019821 dicalcium diphosphate Nutrition 0.000 description 3
238000009826 distribution Methods 0.000 description 3
235000003599 food sweetener Nutrition 0.000 description 3
239000000499 gel Substances 0.000 description 3
238000000034 method Methods 0.000 description 3
239000002808 molecular sieve Substances 0.000 description 3
239000003755 preservative agent Substances 0.000 description 3
230000002335 preservative effect Effects 0.000 description 3
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000000600 sorbitol Substances 0.000 description 3
239000003765 sweetening agent Substances 0.000 description 3
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
239000002202 Polyethylene glycol Substances 0.000 description 2
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
239000003513 alkali Substances 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
150000001342 alkaline earth metals Chemical class 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229910000019 calcium carbonate Inorganic materials 0.000 description 2
239000001506 calcium phosphate Substances 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
239000006071 cream Substances 0.000 description 2
230000006378 damage Effects 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
238000001035 drying Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000003349 gelling agent Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000000017 hydrogel Substances 0.000 description 2
239000003921 oil Substances 0.000 description 2
229920001223 polyethylene glycol Polymers 0.000 description 2
239000011148 porous material Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
239000000047 product Substances 0.000 description 2
CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 2
229940081974 saccharin Drugs 0.000 description 2
235000019204 saccharin Nutrition 0.000 description 2
239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
238000006748 scratching Methods 0.000 description 2
230000002393 scratching effect Effects 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
239000000344 soap Substances 0.000 description 2
WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
235000010234 sodium benzoate Nutrition 0.000 description 2
239000004299 sodium benzoate Substances 0.000 description 2
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 2
235000019333 sodium laurylsulphate Nutrition 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
239000002562 thickening agent Substances 0.000 description 2
UBLAMKHIFZBBSS-UHFFFAOYSA-N 3-Methylbutyl pentanoate Chemical compound CCCCC(=O)OCCC(C)C UBLAMKHIFZBBSS-UHFFFAOYSA-N 0.000 description 1
MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
239000005725 8-Hydroxyquinoline Substances 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
241000206575 Chondrus crispus Species 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
235000019739 Dicalciumphosphate Nutrition 0.000 description 1
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
101000998146 Homo sapiens Interleukin-17A Proteins 0.000 description 1
102100033461 Interleukin-17A Human genes 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
208000027418 Wounds and injury Diseases 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
230000002730 additional effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
150000008051 alkyl sulfates Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000003242 anti bacterial agent Substances 0.000 description 1
230000002882 anti-plaque Effects 0.000 description 1
239000002585 base Substances 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
229910000278 bentonite Inorganic materials 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
235000010216 calcium carbonate Nutrition 0.000 description 1
235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
239000008112 carboxymethyl-cellulose Substances 0.000 description 1
229940105329 carboxymethylcellulose Drugs 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003518 caustics Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
239000003086 colorant Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
NEFBYIFKOOEVPA-UHFFFAOYSA-K dicalcium phosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])([O-])=O NEFBYIFKOOEVPA-UHFFFAOYSA-K 0.000 description 1
229910000390 dicalcium phosphate Inorganic materials 0.000 description 1
229940038472 dicalcium phosphate Drugs 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
150000002222 fluorine compounds Chemical class 0.000 description 1
235000013355 food flavoring agent Nutrition 0.000 description 1
150000002357 guanidines Chemical class 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
208000014674 injury Diseases 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
101150085091 lat-2 gene Proteins 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000003801 milling Methods 0.000 description 1
238000002156 mixing Methods 0.000 description 1
210000000214 mouth Anatomy 0.000 description 1
230000009972 noncorrosive effect Effects 0.000 description 1
229960003540 oxyquinoline Drugs 0.000 description 1
230000000069 prophylactic effect Effects 0.000 description 1
230000001698 pyrogenic effect Effects 0.000 description 1
MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
150000002910 rare earth metals Chemical class 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
239000002002 slurry Substances 0.000 description 1
AQMNWCRSESPIJM-UHFFFAOYSA-M sodium metaphosphate Chemical compound [Na+].[O-]P(=O)=O AQMNWCRSESPIJM-UHFFFAOYSA-M 0.000 description 1
235000019983 sodium metaphosphate Nutrition 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
239000003826 tablet Substances 0.000 description 1
230000008719 thickening Effects 0.000 description 1
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
229940078499 tricalcium phosphate Drugs 0.000 description 1
235000019731 tricalcium phosphate Nutrition 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
WGIWBXUNRXCYRA-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WGIWBXUNRXCYRA-UHFFFAOYSA-H 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1
229920001285 xanthan gum Polymers 0.000 description 1
239000011701 zinc Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011746 zinc citrate Substances 0.000 description 1
229940068475 zinc citrate Drugs 0.000 description 1
235000006076 zinc citrate Nutrition 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof

Landscapes

Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Animal Behavior & Ethology (AREA)
General Health & Medical Sciences (AREA)
Public Health (AREA)
Veterinary Medicine (AREA)
Oral & Maxillofacial Surgery (AREA)
Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Birds (AREA)
Epidemiology (AREA)
Cosmetics (AREA)

CA000377704A 1980-08-21 1981-05-15 Dentifrice au zeolite synthetique Expired CA1170187A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US18021080A	1980-08-21	1980-08-21
US180,210		1980-08-21

Publications (1)

Publication Number	Publication Date
CA1170187A true CA1170187A (fr)	1984-07-03

Family

ID=22659627

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000377704A Expired CA1170187A (fr)	1980-08-21	1981-05-15	Dentifrice au zeolite synthetique

Country Status (10)

Country	Link
JP (1)	JPS5754112A (fr)
AR (1)	AR225684A1 (fr)
AU (1)	AU7351081A (fr)
BE (1)	BE890022A (fr)
BR (1)	BR8103733A (fr)
CA (1)	CA1170187A (fr)
DE (1)	DE3132336A1 (fr)
FR (1)	FR2488794B1 (fr)
GB (1)	GB2082454B (fr)
ZA (1)	ZA813563B (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2540093B1 (fr) *	1983-02-02	1987-01-23	Rhone Poulenc Spec Chim	Procede de preparation d'un silico-aluminate alcalin utilisable dans les compositions dentifrices
US4818518A (en) *	1984-11-16	1989-04-04	Uop	Effervescent dentifrice
US4592855A (en) *	1984-11-16	1986-06-03	Union Carbide Corporation	Effervescent compositions
US4826676A (en) *	1987-06-30	1989-05-02	Uop	Anticariogenic and anticalculus compositions containing zeolitic zinc cations
GB0400447D0 (en) *	2004-01-09	2004-02-11	Glaxo Group Ltd	Dentifrice compositions
GB0400446D0 (en) *	2004-01-09	2004-02-11	Glaxo Group Ltd	Dentifrice compositions
GB0400408D0 (en) *	2004-01-09	2004-02-11	Ineos Silicas Ltd	Dentifrice compositions containing zeolites
GB0400414D0 (en) *	2004-01-09	2004-02-11	Ineos Silicas Ltd	Dental abrasive system

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE378010C (de) *	1922-05-23	1923-07-02	Leonhard Frank Dr	Verfahren zur Herstellung von Zahnreinigungsmitteln
DE2757280A1 (de) *	1977-12-22	1979-07-05	Blendax Werke Schneider Co	Zahnpasta

1981
- 1981-05-15 CA CA000377704A patent/CA1170187A/fr not_active Expired
- 1981-05-27 ZA ZA00813563A patent/ZA813563B/xx unknown
- 1981-06-12 BR BR8103733A patent/BR8103733A/pt unknown
- 1981-06-24 GB GB8119517A patent/GB2082454B/en not_active Expired
- 1981-07-28 AU AU73510/81A patent/AU7351081A/en not_active Abandoned
- 1981-08-03 JP JP56120801A patent/JPS5754112A/ja active Pending
- 1981-08-17 DE DE19813132336 patent/DE3132336A1/de not_active Withdrawn
- 1981-08-18 AR AR286466A patent/AR225684A1/es active
- 1981-08-19 BE BE0/205720A patent/BE890022A/fr not_active IP Right Cessation
- 1981-08-20 FR FR8116021A patent/FR2488794B1/fr not_active Expired

Also Published As

Publication number	Publication date
GB2082454A (en)	1982-03-10
GB2082454B (en)	1984-07-25
DE3132336A1 (de)	1982-08-12
JPS5754112A (fr)	1982-03-31
BE890022A (fr)	1981-12-16
AU7351081A (en)	1982-09-23
FR2488794B1 (fr)	1985-10-04
AR225684A1 (es)	1982-04-15
BR8103733A (pt)	1982-08-24
ZA813563B (en)	1982-06-30
FR2488794A1 (fr)	1982-02-26

Legal Events

Date	Code	Title	Description
2001-07-03	MKEX	Expiry

Publication	Publication Date	Title
US4349533A (en)	1982-09-14	Toothpaste containing pH-adjusted zeolite
US4923684A (en)	1990-05-08	Tripolyphosphate-containing anti-calculus toothpaste
EP0329069B1 (fr)	1992-05-06	Composition orale antitartre
US4130636A (en)	1978-12-19	Dentifrice
US4144322A (en)	1979-03-13	Reduction of abrasiveness in dentrifices
US4244707A (en)	1981-01-13	Abrasive composition for use in toothpaste
US4159280A (en)	1979-06-26	Therapeutic dentifrices in unlined container and methods
PL172151B1 (pl)	1997-08-29	Pasta do zebów PL PL PL PL
JP2003532663A (ja)	2003-11-05	清浄性の高い歯磨き剤
US4174387A (en)	1979-11-13	Reduction of abrasiveness in dentifrices
AU2018344394A1 (en)	2020-04-16	Novel composition
JPH0637381B2 (ja)	1994-05-18	凝集粒子を含有する歯みがき
CN117257656A (zh)	2023-12-22	牙膏组合物
US4060599A (en)	1977-11-29	Dentifrices
CA1329369C (fr)	1994-05-10	Pate dentifrice peu abrasive
US4826676A (en)	1989-05-02	Anticariogenic and anticalculus compositions containing zeolitic zinc cations
PL191433B1 (pl)	2006-05-31	Środek do czyszczenia zębów zawierający połączenie środków polerujących na bazie kwasu krzemowego i tlenku glinowego
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