CA1174550A - Detergents liquides - Google Patents

Detergents liquides

Info

Publication number: CA1174550A
Authority: CA; Canada
Prior art keywords: composition according; surfactant; weight; phosphonate; alkali metal
Prior art date: 1980-04-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000373269A

Other languages

English (en)

Inventor

Eileen Smith

Dorothy M. Titchener

Doreen A. Timperley

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Solvay Interox Ltd

Original Assignee

Interox Chemicals Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-04-01

Filing date

1981-03-18

Publication date

1984-09-18

1981-03-18 Application filed by Interox Chemicals Ltd filed Critical Interox Chemicals Ltd

1984-09-18 Application granted granted Critical

1984-09-18 Publication of CA1174550A publication Critical patent/CA1174550A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 195
239000003599 detergent Substances 0.000 title claims abstract description 58
239000007788 liquid Substances 0.000 title claims abstract description 27
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 98
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 65
239000004094 surface-active agent Substances 0.000 claims abstract description 54
125000000129 anionic group Chemical group 0.000 claims abstract description 34
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims abstract description 34
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims abstract description 30
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 23
229910021653 sulphate ion Inorganic materials 0.000 claims abstract description 23
229920000388 Polyphosphate Polymers 0.000 claims abstract description 21
239000001205 polyphosphate Substances 0.000 claims abstract description 21
235000011176 polyphosphates Nutrition 0.000 claims abstract description 21
239000003945 anionic surfactant Substances 0.000 claims abstract description 14
239000002736 nonionic surfactant Substances 0.000 claims abstract description 12
150000007942 carboxylates Chemical class 0.000 claims abstract description 9
229940050410 gluconate Drugs 0.000 claims abstract description 9
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims abstract description 6
-1 hydroxyalkyl diphosphonate Chemical compound 0.000 claims description 63
238000005406 washing Methods 0.000 claims description 45
229910052783 alkali metal Inorganic materials 0.000 claims description 34
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
239000003752 hydrotrope Substances 0.000 claims description 21
QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 21
150000001340 alkali metals Chemical class 0.000 claims description 17
239000002671 adjuvant Substances 0.000 claims description 12
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 10
125000003118 aryl group Chemical group 0.000 claims description 10
239000008139 complexing agent Substances 0.000 claims description 9
230000000536 complexating effect Effects 0.000 claims description 8
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 8
238000000034 method Methods 0.000 claims description 8
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 7
235000011180 diphosphates Nutrition 0.000 claims description 7
GWASTCVCPXFIQT-UHFFFAOYSA-N NC1OP(=O)O1 Chemical compound NC1OP(=O)O1 GWASTCVCPXFIQT-UHFFFAOYSA-N 0.000 claims description 6
239000007864 aqueous solution Substances 0.000 claims description 6
BPSYZMLXRKCSJY-UHFFFAOYSA-N 1,3,2-dioxaphosphepan-2-ium 2-oxide Chemical compound O=[P+]1OCCCCO1 BPSYZMLXRKCSJY-UHFFFAOYSA-N 0.000 claims description 5
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims description 5
TWYSBDNLTRUTQT-UHFFFAOYSA-A hexadecapotassium;phosphonato phosphate Chemical group [K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O TWYSBDNLTRUTQT-UHFFFAOYSA-A 0.000 claims description 5
230000008569 process Effects 0.000 claims description 5
230000003019 stabilising effect Effects 0.000 claims description 5
238000010790 dilution Methods 0.000 claims description 4
239000012895 dilution Substances 0.000 claims description 4
238000004900 laundering Methods 0.000 claims description 4
RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 3
RXTCWPTWYYNTOA-UHFFFAOYSA-N O=P1OCCCCCO1 Chemical compound O=P1OCCCCCO1 RXTCWPTWYYNTOA-UHFFFAOYSA-N 0.000 claims description 3
238000009835 boiling Methods 0.000 claims description 3
239000001509 sodium citrate Substances 0.000 claims description 3
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 3
235000015096 spirit Nutrition 0.000 claims description 3
239000003513 alkali Substances 0.000 claims description 2
NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 claims description 2
230000004048 modification Effects 0.000 claims description 2
238000012986 modification Methods 0.000 claims description 2
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 2
125000003916 ethylene diamine group Chemical group 0.000 claims 2
DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 claims 1
239000008240 homogeneous mixture Substances 0.000 claims 1
238000004519 manufacturing process Methods 0.000 claims 1
KQTIIICEAUMSDG-UHFFFAOYSA-N tricarballylic acid Chemical compound OC(=O)CC(C(O)=O)CC(O)=O KQTIIICEAUMSDG-UHFFFAOYSA-N 0.000 claims 1
150000002978 peroxides Chemical class 0.000 abstract description 9
RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 abstract description 5
TTZMPOZCBFTTPR-UHFFFAOYSA-N O=P1OCO1 Chemical compound O=P1OCO1 TTZMPOZCBFTTPR-UHFFFAOYSA-N 0.000 abstract description 4
UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 abstract 1
150000001875 compounds Chemical class 0.000 description 33
244000299461 Theobroma cacao Species 0.000 description 27
235000009470 Theobroma cacao Nutrition 0.000 description 27
239000000243 solution Substances 0.000 description 22
125000004432 carbon atom Chemical group C* 0.000 description 16
239000003381 stabilizer Substances 0.000 description 15
239000002253 acid Substances 0.000 description 13
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
229910052760 oxygen Inorganic materials 0.000 description 11
239000001301 oxygen Substances 0.000 description 11
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
125000000217 alkyl group Chemical group 0.000 description 9
239000007787 solid Substances 0.000 description 9
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
238000004453 electron probe microanalysis Methods 0.000 description 8
150000003138 primary alcohols Chemical class 0.000 description 8
229910052708 sodium Inorganic materials 0.000 description 8
239000011734 sodium Substances 0.000 description 8
239000012141 concentrate Substances 0.000 description 7
KJPHTXTWFHVJIG-UHFFFAOYSA-N n-ethyl-2-[(6-methoxypyridin-3-yl)-(2-methylphenyl)sulfonylamino]-n-(pyridin-3-ylmethyl)acetamide Chemical compound C=1C=C(OC)N=CC=1N(S(=O)(=O)C=1C(=CC=CC=1)C)CC(=O)N(CC)CC1=CC=CN=C1 KJPHTXTWFHVJIG-UHFFFAOYSA-N 0.000 description 7
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
239000007844 bleaching agent Substances 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
239000004744 fabric Substances 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
239000012190 activator Substances 0.000 description 5
238000007046 ethoxylation reaction Methods 0.000 description 5
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
125000003277 amino group Chemical group 0.000 description 4
230000000694 effects Effects 0.000 description 4
230000001771 impaired effect Effects 0.000 description 4
238000010348 incorporation Methods 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 4
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 4
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 3
229910019142 PO4 Inorganic materials 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
239000011575 calcium Substances 0.000 description 3
229910000019 calcium carbonate Inorganic materials 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
238000004090 dissolution Methods 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
230000003993 interaction Effects 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
238000002156 mixing Methods 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
230000003287 optical effect Effects 0.000 description 3
239000010452 phosphate Substances 0.000 description 3
ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
150000003014 phosphoric acid esters Chemical class 0.000 description 3
239000002689 soil Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 2
229920000742 Cotton Polymers 0.000 description 2
244000228957 Ferula foetida Species 0.000 description 2
240000007930 Oxalis acetosella Species 0.000 description 2
235000008098 Oxalis acetosella Nutrition 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
125000003158 alcohol group Chemical group 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
229910052910 alkali metal silicate Inorganic materials 0.000 description 2
150000005215 alkyl ethers Chemical class 0.000 description 2
230000008901 benefit Effects 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
230000000295 complement effect Effects 0.000 description 2
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
238000001035 drying Methods 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
238000005191 phase separation Methods 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920001983 poloxamer Polymers 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Substances 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
235000020095 red wine Nutrition 0.000 description 2
150000003333 secondary alcohols Chemical class 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
239000000344 soap Substances 0.000 description 2
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
239000013042 solid detergent Substances 0.000 description 2
241000894007 species Species 0.000 description 2
PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 2
235000021286 stilbenes Nutrition 0.000 description 2
238000012360 testing method Methods 0.000 description 2
BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
KWMLJOLKUYYJFJ-DVKNGEFBSA-N (2s,3r,4s,5r,6r)-2,3,4,5,6,7-hexahydroxyheptanoic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)C(O)=O KWMLJOLKUYYJFJ-DVKNGEFBSA-N 0.000 description 1
QYAPHLRPFNSDNH-MRFRVZCGSA-N (4s,4as,5as,6s,12ar)-7-chloro-4-(dimethylamino)-1,6,10,11,12a-pentahydroxy-6-methyl-3,12-dioxo-4,4a,5,5a-tetrahydrotetracene-2-carboxamide;hydrochloride Chemical compound Cl.C1=CC(Cl)=C2[C@](O)(C)[C@H]3C[C@H]4[C@H](N(C)C)C(=O)C(C(N)=O)=C(O)[C@@]4(O)C(=O)C3=C(O)C2=C1O QYAPHLRPFNSDNH-MRFRVZCGSA-N 0.000 description 1
CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical compound OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
ZGBKEOLAPVBJFC-DJLDLDEBSA-N 1-[(2r,4s,5r)-5-(hydroxymethyl)-4-methoxyoxolan-2-yl]-5-methylpyrimidine-2,4-dione Chemical compound O1[C@H](CO)[C@@H](OC)C[C@@H]1N1C(=O)NC(=O)C(C)=C1 ZGBKEOLAPVBJFC-DJLDLDEBSA-N 0.000 description 1
QFMDFTQOJHFVNR-UHFFFAOYSA-N 1-[2,2-dichloro-1-(4-ethylphenyl)ethyl]-4-ethylbenzene Chemical compound C1=CC(CC)=CC=C1C(C(Cl)Cl)C1=CC=C(CC)C=C1 QFMDFTQOJHFVNR-UHFFFAOYSA-N 0.000 description 1
NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 description 1
AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
DEQYKFQEQDSGBB-UHFFFAOYSA-N 2-(2-carboxybenzoyl)peroxycarbonylbenzoic acid Chemical compound OC(=O)C1=CC=CC=C1C(=O)OOC(=O)C1=CC=CC=C1C(O)=O DEQYKFQEQDSGBB-UHFFFAOYSA-N 0.000 description 1
IPBNQYLKHUNLQE-UHFFFAOYSA-N 8-anilinonaphthalene-1-sulfonic acid;azane Chemical compound [NH4+].C=12C(S(=O)(=O)[O-])=CC=CC2=CC=CC=1NC1=CC=CC=C1 IPBNQYLKHUNLQE-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
241000331231 Amorphocerini gen. n. 1 DAD-2008 Species 0.000 description 1
KUVYVUQTILBHAB-UHFFFAOYSA-N C=C.[K].[K].[K].[K].[K].[K] Chemical group C=C.[K].[K].[K].[K].[K].[K] KUVYVUQTILBHAB-UHFFFAOYSA-N 0.000 description 1
244000060011 Cocos nucifera Species 0.000 description 1
235000013162 Cocos nucifera Nutrition 0.000 description 1
101710184444 Complexin Proteins 0.000 description 1
RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
206010020400 Hostility Diseases 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
241000257303 Hymenoptera Species 0.000 description 1
KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
229910018828 PO3H2 Inorganic materials 0.000 description 1
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
241000183024 Populus tremula Species 0.000 description 1
241000534944 Thia Species 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000009471 action Effects 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
125000003282 alkyl amino group Chemical group 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000006295 amino methylene group Chemical group [H]N(*)C([H])([H])* 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
101150039027 ampH gene Proteins 0.000 description 1
239000002280 amphoteric surfactant Substances 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
238000004380 ashing Methods 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
150000001721 carbon Chemical group 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
150000004651 carbonic acid esters Chemical class 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
150000001767 cationic compounds Chemical class 0.000 description 1
239000002752 cationic softener Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
NCEXYHBECQHGNR-UHFFFAOYSA-N chembl421 Chemical compound C1=C(O)C(C(=O)O)=CC(N=NC=2C=CC(=CC=2)S(=O)(=O)NC=2N=CC=CC=2)=C1 NCEXYHBECQHGNR-UHFFFAOYSA-N 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
235000019864 coconut oil Nutrition 0.000 description 1
239000003240 coconut oil Substances 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000000332 continued effect Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
230000006735 deficit Effects 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
210000003298 dental enamel Anatomy 0.000 description 1
239000012933 diacyl peroxide Substances 0.000 description 1
229910003460 diamond Inorganic materials 0.000 description 1
239000010432 diamond Substances 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
238000007865 diluting Methods 0.000 description 1
229950010286 diolamine Drugs 0.000 description 1
XQRLCLUYWUNEEH-UHFFFAOYSA-N diphosphonic acid Chemical compound OP(=O)OP(O)=O XQRLCLUYWUNEEH-UHFFFAOYSA-N 0.000 description 1
YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
239000003814 drug Substances 0.000 description 1
239000000975 dye Substances 0.000 description 1
NXMSOLWESKBEJJ-UHFFFAOYSA-N ethyl 2,2-difluoro-3-oxobutanoate Chemical compound CCOC(=O)C(F)(F)C(C)=O NXMSOLWESKBEJJ-UHFFFAOYSA-N 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
239000000835 fiber Substances 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
239000011521 glass Substances 0.000 description 1
239000000174 gluconic acid Substances 0.000 description 1
235000012208 gluconic acid Nutrition 0.000 description 1
239000008233 hard water Substances 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
125000002768 hydroxyalkyl group Chemical group 0.000 description 1
150000002443 hydroxylamines Chemical class 0.000 description 1
JCYWCSGERIELPG-UHFFFAOYSA-N imes Chemical class CC1=CC(C)=CC(C)=C1N1C=CN(C=2C(=CC(C)=CC=2C)C)[C]1 JCYWCSGERIELPG-UHFFFAOYSA-N 0.000 description 1
MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
230000007774 longterm Effects 0.000 description 1
239000000463 material Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000003973 paint Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000002304 perfume Substances 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
NIXKBAZVOQAHGC-UHFFFAOYSA-N phenylmethanesulfonic acid Chemical compound OS(=O)(=O)CC1=CC=CC=C1 NIXKBAZVOQAHGC-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
150000003013 phosphoric acid derivatives Chemical group 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
239000012286 potassium permanganate Substances 0.000 description 1
230000002028 premature Effects 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000000452 restraining effect Effects 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
239000000176 sodium gluconate Substances 0.000 description 1
235000012207 sodium gluconate Nutrition 0.000 description 1
229940005574 sodium gluconate Drugs 0.000 description 1
NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
ZAWGLAXBGYSUHN-UHFFFAOYSA-M sodium;2-[bis(carboxymethyl)amino]acetate Chemical compound [Na+].OC(=O)CN(CC(O)=O)CC([O-])=O ZAWGLAXBGYSUHN-UHFFFAOYSA-M 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000010186 staining Methods 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000003756 stirring Methods 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
230000009044 synergistic interaction Effects 0.000 description 1
239000003760 tallow Substances 0.000 description 1
RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
238000004448 titration Methods 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
MPSJHIAGGNGGEZ-UHFFFAOYSA-K trisodium;2-(carboxylatomethoxy)butanedioate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)COC(C([O-])=O)CC([O-])=O MPSJHIAGGNGGEZ-UHFFFAOYSA-K 0.000 description 1
HERBOKBJKVUALN-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]acetate;hydrate Chemical compound O.[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O HERBOKBJKVUALN-UHFFFAOYSA-K 0.000 description 1
229960004418 trolamine Drugs 0.000 description 1
239000000230 xanthan gum Substances 0.000 description 1
229920001285 xanthan gum Polymers 0.000 description 1
229940082509 xanthan gum Drugs 0.000 description 1
235000010493 xanthan gum Nutrition 0.000 description 1
229910052724 xenon Inorganic materials 0.000 description 1
FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3937—Stabilising agents
- C11D3/394—Organic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CA000373269A 1980-04-01 1981-03-18 Detergents liquides Expired CA1174550A (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
GB8010887		1980-04-01
GB8010885		1980-04-01
GB8010885		1980-04-01
GB8010887		1980-04-01

Publications (1)

Publication Number	Publication Date
CA1174550A true CA1174550A (fr)	1984-09-18

Family

ID=26275047

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000373269A Expired CA1174550A (fr)	1980-04-01	1981-03-18	Detergents liquides

Country Status (7)

Country	Link
EP (1)	EP0037184B1 (fr)
AU (1)	AU544887B2 (fr)
BR (1)	BR8101906A (fr)
CA (1)	CA1174550A (fr)
DE (1)	DE3168426D1 (fr)
ES (1)	ES8405839A1 (fr)
PT (1)	PT72722B (fr)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AR241024A1 (es) *	1981-09-30	1991-04-30	Interox Chemicals Ltd	Composicion de peroxido de hidrogeno acuoso apropiada para dilucion,para formar composiciones detergentes liquidas o composiciones de blanqueo,que consiste esencialmente en (a) de 20 a 35% en peso, en base a la composicion , de peroxido de hidrogeno,(b)
DE3364292D1 (en) *	1982-02-03	1986-08-07	Procter & Gamble	Oxygen-bleach-containing liquid detergent compositions
ZA852197B (en) *	1984-04-06	1986-11-26	Colgate Palmolive Co	Liquid laundry detergent composition containing polyphosphate
US5250212A (en) *	1987-05-27	1993-10-05	The Procter & Gamble Company	Liquid detergent containing solid peroxygen bleach and solvent system comprising water and lower aliphatic monoalcohol
GB8830296D0 (en) *	1988-12-28	1989-02-22	Unilever Plc	Bleaching composition
US5275753A (en) *	1989-01-10	1994-01-04	The Procter & Gamble Company	Stabilized alkaline liquid detergent compositions containing enzyme and peroxygen bleach
GB8904007D0 (en) *	1989-02-22	1989-04-05	Procter & Gamble	Stabilized,bleach containing,liquid detergent compositions
US5160655A (en) *	1989-02-27	1992-11-03	Lever Brothers Company, Division Of Conopco, Inc.	Aqueous structured liquid detergent compositions containing selected peroxygen bleach compounds
DE69033783T2 (de) *	1989-02-27	2002-04-18	Unilever N.V., Rotterdam	Flüssiges Reinigungsmittel
DE4023893A1 (de) *	1990-07-27	1992-01-30	Henkel Kgaa	Bleichendes fluessigwaschmittel
DK0769047T3 (da) *	1994-07-01	1999-09-27	Warwick Int Group	Blegesammensætninger
EP0769046B1 (fr) *	1994-07-01	1998-09-02	Warwick International Group Limited	Compositions de blanchiment
GB9413307D0 (en) *	1994-07-01	1994-08-24	Warwick Int Group	Bleaching compositions
GB9506065D0 (en) *	1995-03-24	1995-05-10	Warwick Int Group	Alkaline isotropic liquid detergent with peroxide
GB9506066D0 (en) *	1995-03-24	1995-05-10	Warwick Int Group	Alkaline isotropic liquid detergent with peroxide
GB9506093D0 (en) *	1995-03-24	1995-05-10	Warwick Int Group	Alkaline isotropic liquid detergent with peroxide
AU5115796A (en) *	1995-03-24	1996-10-16	Warwick International Group Limited	Alkaline isotropic liquid detergent with peroxide
DE69811786T2 (de) *	1997-07-16	2003-10-23	Nagase Chemtex Corp., Osaka	Verwendung von Chelat bildenden Zusammensetzungen zum Reinigen
ES2402725B1 (es) *	2011-10-28	2014-03-11	Betelgeux, S.L.	Detergente líquido para eliminación de biofilms en superficies.

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE795085A (fr) *	1972-03-10	1973-05-29	Benckiser Knapsack Gmbh	Procede de blanchiment de fibres cellulosiques seules ou en melange avec des fibres synthetiques
NL7608266A (nl) *	1975-08-16	1977-02-18	Henkel & Cie Gmbh	Concentraten van microbicide middelen.

1981
- 1981-03-09 DE DE8181300964T patent/DE3168426D1/de not_active Expired
- 1981-03-09 EP EP19810300964 patent/EP0037184B1/fr not_active Expired
- 1981-03-18 CA CA000373269A patent/CA1174550A/fr not_active Expired
- 1981-03-24 PT PT7272281A patent/PT72722B/pt unknown
- 1981-03-26 AU AU68812/81A patent/AU544887B2/en not_active Ceased
- 1981-03-30 BR BR8101906A patent/BR8101906A/pt not_active IP Right Cessation
- 1981-03-31 ES ES500915A patent/ES8405839A1/es not_active Expired

Also Published As

Publication number	Publication date
AU544887B2 (en)	1985-06-20
EP0037184A2 (fr)	1981-10-07
EP0037184B1 (fr)	1985-01-23
ES500915A0 (es)	1984-06-16
ES8405839A1 (es)	1984-06-16
PT72722B (en)	1982-03-24
DE3168426D1 (en)	1985-03-07
PT72722A (en)	1981-04-01
BR8101906A (pt)	1981-10-06
EP0037184A3 (en)	1982-03-17
AU6881281A (en)	1981-10-08

Legal Events

Date	Code	Title	Description
2001-09-18	MKEX	Expiry

Publication	Publication Date	Title
US4525291A (en)	1985-06-25	Liquid detergent compositions
CA1174550A (fr)	1984-09-18	Detergents liquides
US4347149A (en)	1982-08-31	Aqueous bleach compositions
US4316812A (en)	1982-02-23	Detergent composition
US5597790A (en)	1997-01-28	Liquid detergent compositions containing a suspended peroxygen bleach
AU662501B2 (en)	1995-09-07	Liquid detergent compositions containing a suspended peroxygen bleach
EP0598694B1 (fr)	1998-02-04	Compositions stables contenant de sels d'acide persulfurique
AU2007317613B2 (en)	2012-12-06	Liquid detergent formulation with hydrogen peroxide
EP0624640B1 (fr)	2005-01-12	Composition de blanchiment aqueuse, translucide et isotrope
US4783278A (en)	1988-11-08	Concentrated liquid compositions containing a peroxygen compound
US4497725A (en)	1985-02-05	Aqueous bleach compositions
MXPA97002315A (en)	1997-06-01	Compositions liquid detergents containing non-aqueous bleach
DK158521B (da)	1990-05-28	Detergentsammensaetning indeholdende peroxygenblegeforbindelser og blegeaktivatorer af carboxylsyreestertypen
JPH10505365A (ja)	1998-05-26	過酸素漂白組成物
SK115597A3 (en)	1998-06-03	Laundry pretreatment with peroxide bleaches containing chelators for iron, copper or manganese for reduced fabric damage
CA2030098A1 (fr)	1991-05-22	Compositions liquides exemptes de chlore pour lave-vaisselle
GB2072643A (en)	1981-10-07	Aqueous H2O2 bleach compositions
US3708427A (en)	1973-01-02	Washing and cleansing compositions
EP0769047B1 (fr)	1999-03-10	Compositions de blanchiment
US5914304A (en)	1999-06-22	Bleaching compositions
JP4694056B2 (ja)	2011-06-01	２剤型漂白剤
IE904574A1 (en)	1991-06-19	Concentrated aqueous liquid bleach composition
CZ250593A3 (en)	1994-06-15	Liquid detergent composition
HUP9903642A2 (hu)	2000-03-28	Javított fehérítőszer, valamint eljárás szennyeződés eltávolítására textíliából
JPH04285697A (ja)	1992-10-09	非イオン性粉末洗浄剤組成物