CA1179116A - Composition and process for consolidating soil - Google Patents

Composition and process for consolidating soil

Info

Publication number: CA1179116A
Authority: CA; Canada
Prior art keywords: composition; silicate; percent; sodium; alkali metal
Prior art date: 1981-10-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000408144A

Other languages

English (en)

French (fr)

Inventor

Thomas M. Vickers, Jr.

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Diamond Shamrock Chemicals Co

Original Assignee

Diamond Shamrock Chemicals Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-10-30

Filing date

1982-07-27

Publication date

1984-12-11

1982-07-27 Application filed by Diamond Shamrock Chemicals Co filed Critical Diamond Shamrock Chemicals Co

1984-12-11 Application granted granted Critical

1984-12-11 Publication of CA1179116A publication Critical patent/CA1179116A/en

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 110
239000002689 soil Substances 0.000 title claims abstract description 33
238000000034 method Methods 0.000 title claims abstract description 10
230000008569 process Effects 0.000 title abstract description 4
LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims abstract description 70
229940015043 glyoxal Drugs 0.000 claims abstract description 46
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims abstract description 27
235000010267 sodium hydrogen sulphite Nutrition 0.000 claims abstract description 26
235000010262 sodium metabisulphite Nutrition 0.000 claims abstract description 22
HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims abstract description 21
229910052910 alkali metal silicate Inorganic materials 0.000 claims abstract description 19
229940001584 sodium metabisulfite Drugs 0.000 claims abstract description 17
239000004115 Sodium Silicate Substances 0.000 claims abstract description 16
229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 14
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 14
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 13
239000001110 calcium chloride Substances 0.000 claims abstract description 13
229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 13
150000003839 salts Chemical class 0.000 claims abstract description 13
229910052783 alkali metal Inorganic materials 0.000 claims abstract description 10
150000001340 alkali metals Chemical class 0.000 claims abstract description 10
239000007788 liquid Substances 0.000 claims abstract description 9
229910052751 metal Inorganic materials 0.000 claims abstract description 8
239000002184 metal Substances 0.000 claims abstract description 8
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 28
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 23
230000000087 stabilizing effect Effects 0.000 claims description 14
239000000654 additive Substances 0.000 claims description 12
230000000996 additive effect Effects 0.000 claims description 12
239000000377 silicon dioxide Substances 0.000 claims description 11
235000012239 silicon dioxide Nutrition 0.000 claims description 9
239000007787 solid Substances 0.000 claims description 9
WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 claims description 8
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 5
KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 5
229910000272 alkali metal oxide Inorganic materials 0.000 claims description 3
230000006872 improvement Effects 0.000 claims description 3
229910001948 sodium oxide Inorganic materials 0.000 claims description 3
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims 2
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims 2
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical group [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims 1
229910000365 copper sulfate Inorganic materials 0.000 claims 1
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims 1
229910001388 sodium aluminate Inorganic materials 0.000 claims 1
239000011592 zinc chloride Substances 0.000 claims 1
235000005074 zinc chloride Nutrition 0.000 claims 1
-1 e.g. Inorganic materials 0.000 abstract description 9
239000000499 gel Substances 0.000 description 37
239000000243 solution Substances 0.000 description 26
238000001879 gelation Methods 0.000 description 10
239000003112 inhibitor Substances 0.000 description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
239000000463 material Substances 0.000 description 8
ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 7
229910004879 Na2S2O5 Inorganic materials 0.000 description 7
238000009472 formulation Methods 0.000 description 6
239000011734 sodium Substances 0.000 description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 5
230000002401 inhibitory effect Effects 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
229910021529 ammonia Inorganic materials 0.000 description 4
229910052681 coesite Inorganic materials 0.000 description 4
229910052906 cristobalite Inorganic materials 0.000 description 4
230000006641 stabilisation Effects 0.000 description 4
238000011105 stabilization Methods 0.000 description 4
239000012086 standard solution Substances 0.000 description 4
229910052682 stishovite Inorganic materials 0.000 description 4
238000012360 testing method Methods 0.000 description 4
229910052905 tridymite Inorganic materials 0.000 description 4
RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical compound Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 description 3
239000004576 sand Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
239000004348 Glyceryl diacetate Substances 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
YHFXJKYHUWPWSJ-UHFFFAOYSA-L [Na+].[Na+].OS([O-])=O.OS([O-])=O Chemical compound [Na+].[Na+].OS([O-])=O.OS([O-])=O YHFXJKYHUWPWSJ-UHFFFAOYSA-L 0.000 description 2
150000001408 amides Chemical class 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
239000012530 fluid Substances 0.000 description 2
235000019443 glyceryl diacetate Nutrition 0.000 description 2
239000011440 grout Substances 0.000 description 2
231100001261 hazardous Toxicity 0.000 description 2
238000010348 incorporation Methods 0.000 description 2
238000005259 measurement Methods 0.000 description 2
238000002156 mixing Methods 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Substances 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
235000019351 sodium silicates Nutrition 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
238000004026 adhesive bonding Methods 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
239000002671 adjuvant Substances 0.000 description 1
230000032683 aging Effects 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
239000010425 asbestos Substances 0.000 description 1
239000004566 building material Substances 0.000 description 1
DNSISZSEWVHGLH-UHFFFAOYSA-N butanamide Chemical compound CCCC(N)=O DNSISZSEWVHGLH-UHFFFAOYSA-N 0.000 description 1
229910052792 caesium Inorganic materials 0.000 description 1
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
230000000249 desinfective effect Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000008394 flocculating agent Substances 0.000 description 1
238000009408 flooring Methods 0.000 description 1
239000003517 fume Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
231100000206 health hazard Toxicity 0.000 description 1
230000005764 inhibitory process Effects 0.000 description 1
238000009413 insulation Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
229910052914 metal silicate Inorganic materials 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
230000001473 noxious effect Effects 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
230000035699 permeability Effects 0.000 description 1
239000004848 polyfunctional curative Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
229940080818 propionamide Drugs 0.000 description 1
235000011962 puddings Nutrition 0.000 description 1
239000000376 reactant Substances 0.000 description 1
229910052895 riebeckite Inorganic materials 0.000 description 1
239000011435 rock Substances 0.000 description 1
229910052701 rubidium Inorganic materials 0.000 description 1
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
235000019795 sodium metasilicate Nutrition 0.000 description 1
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
235000010265 sodium sulphite Nutrition 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000004753 textile Substances 0.000 description 1
239000002023 wood Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
- C09K17/42—Inorganic compounds mixed with organic active ingredients, e.g. accelerators
- C09K17/46—Inorganic compounds mixed with organic active ingredients, e.g. accelerators the inorganic compound being a water-soluble silicate
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S106/00—Compositions: coating or plastic
- Y10S106/90—Soil stabilization

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Ceramic Engineering (AREA)
Materials Engineering (AREA)
Structural Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Life Sciences & Earth Sciences (AREA)
General Life Sciences & Earth Sciences (AREA)
Soil Sciences (AREA)
Soil Conditioners And Soil-Stabilizing Materials (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)

CA000408144A 1981-10-30 1982-07-27 Composition and process for consolidating soil Expired CA1179116A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US316,854		1981-10-30
US06/316,854 US4354874A (en)	1981-10-30	1981-10-30	Composition and process for consolidating soil

Publications (1)

Publication Number	Publication Date
CA1179116A true CA1179116A (en)	1984-12-11

Family

ID=23230983

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000408144A Expired CA1179116A (en)	1981-10-30	1982-07-27	Composition and process for consolidating soil

Country Status (3)

Country	Link
US (1)	US4354874A (ja)
JP (1)	JPS5876480A (ja)
CA (1)	CA1179116A (ja)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB2170839A (en) *	1985-02-11	1986-08-13	Labofina Sa	Process for consolidating soils
US5560773A (en) *	1995-06-13	1996-10-01	Fmc Corporation	Penetrating sealant composition
US6152234A (en) *	1998-06-10	2000-11-28	Atlantic Richfield Company	Method for strengthening a subterranean formation
US6156819A (en) *	1998-12-21	2000-12-05	Atlantic Richfield Company	Use of low- and high-molecular-weight polymers in well treatments
US6166103A (en) *	1998-12-21	2000-12-26	Atlantic Richfield Company	Aqueous gelable compositions with delayed gelling times
US6133204A (en) *	1999-02-09	2000-10-17	Atlantic Richfield Company	Use of oil-based gel-breaker/inhibitor compounds with polymer gels in well treatments
US6265355B1 (en)	1999-02-09	2001-07-24	Atlantic Richfield Company	Gel-breaker composition and a method for breaking a gel
GB2405636B (en) *	2003-09-08	2006-07-26	Schlumberger Holdings	Dual function cement additive
US7651294B2 (en) *	2006-04-06	2010-01-26	Team Laboratory Chemical Corporation	Soil stabilization method
CN110563388B (zh) *	2019-09-29	2020-09-01	海南正威实业开发有限公司	一种生态土壤固化剂及其制备方法
JP2022102098A (ja) *	2020-12-25	2022-07-07	デンカ株式会社	地盤注入材

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3028340A (en) *	1956-12-28	1962-04-03	Nobel Bozel	Production of new compositions from glyoxal and alkali metal silicates
US3202214A (en) *	1960-04-18	1965-08-24	Halliburton Co	Preparation and use of sodium silicate gels
US3241990A (en) *	1965-03-10	1966-03-22	Harrison John Gordon	Alkali metal silicate compositions and process of manufacture
US3864137A (en) *	1971-12-31	1975-02-04	Bayer Ag	Hydrogen peroxide blowing agent for silicate foams
US4056937A (en) *	1976-01-08	1977-11-08	Kyokado Engineering Co. Ltd.	Method of consolidating soils
JPS6050742B2 (ja) *	1977-11-08	1985-11-09	大阪曹達株式会社	自己硬化性無機組成物
US4293340A (en) *	1979-11-05	1981-10-06	Diamond Shamrock Corporation	Composition and process for stabilizing soil

1981
- 1981-10-30 US US06/316,854 patent/US4354874A/en not_active Expired - Fee Related
1982
- 1982-07-27 CA CA000408144A patent/CA1179116A/en not_active Expired
- 1982-09-20 JP JP57163779A patent/JPS5876480A/ja active Pending

Also Published As

Publication number	Publication date
US4354874A (en)	1982-10-19
JPS5876480A (ja)	1983-05-09

Legal Events

Date	Code	Title	Description
2001-12-12	MKEC	Expiry (correction)
2002-07-27	MKEX	Expiry

Publication	Publication Date	Title
US4384894A (en)	1983-05-24	Composition and process for modifying gelation of alkali metal silicates
EP0028495B1 (en)	1983-09-28	Composition and process for stabilizing soil
CA1179116A (en)	1984-12-11	Composition and process for consolidating soil
JPH028981B2 (ja)	1990-02-28
CA1176440A (en)	1984-10-23	Controlling the curing time of alkali metal silicates using derivatives of glyoxal
US6916366B2 (en)	2005-07-12	Aqueous composition for rendering a substrate hydrophobic
JPS6128618B2 (ja)	1986-07-01
US4904304A (en)	1990-02-27	Chemical grout for ground injection and method for accretion
US5750053A (en)	1998-05-12	Corrosion inhibitor for reducing corrosion in metallic concrete reinforcements
US3686872A (en)	1972-08-29	Soil grouting process
US4561898A (en)	1985-12-31	Hardener for silicate soil stabilizers
US4697961A (en)	1987-10-06	Process for consolidating soils
US3706581A (en)	1972-12-19	Soil grouting process and composition
SK68499A3 (en)	1999-12-10	Compositions for treating soils, method of preparation and use thereof
EP0078365A1 (en)	1983-05-11	Composition and process for modifying gelation of alkali metal silicates
US3306758A (en)	1967-02-28	Composition and method for stabilizing soil
US3884861A (en)	1975-05-20	Soil grouting process and composition
JP3551688B2 (ja)	2004-08-11	含水土壌用固化材及び含水土壌の固化改良方法
US3087825A (en)	1963-04-30	Corrosion-resistant cementitious mineral building materials and method of productionof the same
JP3072346B2 (ja)	2000-07-31	地盤注入用材料
US3626699A (en)	1971-12-14	Grouting of soils
JP3463505B2 (ja)	2003-11-05	含水土壌用固化材及び含水土壌の固化改良方法
RU2138460C1 (ru)	1999-09-27	Строительная смесь с бактерицидными свойствами
JPS5833277B2 (ja)	1983-07-19	土質の安定化処理方法
FR2612176A1 (fr)	1988-09-16	Melange pour l'obtention de beton chimiquement stable