CA1199293A - Hydrotraitement bi-etage des petroles lourds, avec recyclage des residus - Google Patents
Hydrotraitement bi-etage des petroles lourds, avec recyclage des residusInfo
- Publication number
- CA1199293A CA1199293A CA000429277A CA429277A CA1199293A CA 1199293 A CA1199293 A CA 1199293A CA 000429277 A CA000429277 A CA 000429277A CA 429277 A CA429277 A CA 429277A CA 1199293 A CA1199293 A CA 1199293A
- Authority
- CA
- Canada
- Prior art keywords
- process according
- boiling above
- effluent
- reaction zone
- hydrogenation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000295 fuel oil Substances 0.000 title abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 53
- 230000008569 process Effects 0.000 claims abstract description 52
- 238000009835 boiling Methods 0.000 claims abstract description 46
- 239000003054 catalyst Substances 0.000 claims abstract description 46
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 44
- 239000007787 solid Substances 0.000 claims abstract description 28
- 239000003245 coal Substances 0.000 claims abstract description 27
- 239000002245 particle Substances 0.000 claims abstract description 27
- 239000007788 liquid Substances 0.000 claims description 41
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 27
- 229910052739 hydrogen Inorganic materials 0.000 claims description 26
- 239000001257 hydrogen Substances 0.000 claims description 26
- 238000006243 chemical reaction Methods 0.000 claims description 21
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
- 238000004064 recycling Methods 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 2
- 239000000306 component Substances 0.000 claims 27
- 229910052593 corundum Inorganic materials 0.000 claims 3
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 3
- 239000002002 slurry Substances 0.000 claims 2
- 239000003921 oil Substances 0.000 abstract description 26
- 229910052751 metal Inorganic materials 0.000 abstract description 11
- 239000002184 metal Substances 0.000 abstract description 11
- 230000003197 catalytic effect Effects 0.000 description 15
- 239000000047 product Substances 0.000 description 13
- 239000012263 liquid product Substances 0.000 description 11
- 239000007789 gas Substances 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 7
- 239000003208 petroleum Substances 0.000 description 6
- 229910052750 molybdenum Inorganic materials 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- -1 metals compounds Chemical class 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- 150000003623 transition metal compounds Chemical class 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000000386 donor Substances 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 239000000852 hydrogen donor Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000004058 oil shale Substances 0.000 description 2
- 239000003079 shale oil Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910001868 water Inorganic materials 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229910021094 Co(NO3)2-6H2O Inorganic materials 0.000 description 1
- 229910018590 Ni(NO3)2-6H2O Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002802 bituminous coal Substances 0.000 description 1
- 239000010882 bottom ash Substances 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical class [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US38933882A | 1982-06-17 | 1982-06-17 | |
| US389,338 | 1982-06-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1199293A true CA1199293A (fr) | 1986-01-14 |
Family
ID=23537846
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000429277A Expired CA1199293A (fr) | 1982-06-17 | 1983-05-31 | Hydrotraitement bi-etage des petroles lourds, avec recyclage des residus |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS596283A (fr) |
| CA (1) | CA1199293A (fr) |
| DE (1) | DE3321690A1 (fr) |
| GB (1) | GB2121817B (fr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3572001D1 (en) * | 1984-01-19 | 1989-09-07 | Ruhrkohle Ag | Hydrogen gas distribution in coal liquefaction plants |
| US4564439A (en) * | 1984-06-29 | 1986-01-14 | Chevron Research Company | Two-stage, close-coupled thermal catalytic hydroconversion process |
| GB2182947B (en) * | 1985-11-19 | 1990-04-04 | Chevron Res | A multi-staged ,close coupled thermal catalytic hydroconversion process |
| AU602150B2 (en) * | 1986-07-03 | 1990-10-04 | Takeda Chemical Industries Ltd. | Bath preparation |
| EP0569092A1 (fr) * | 1992-05-05 | 1993-11-10 | Shell Internationale Researchmaatschappij B.V. | Procédé d'hydrotraitement |
| WO1994022982A1 (fr) * | 1993-04-07 | 1994-10-13 | Union Oil Company Of California | Procede d'hydrocraquage/hydrotraitement integre |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1315559A (en) * | 1970-08-10 | 1973-05-02 | Exxon Research Engineering Co | Hydrocracking process for high end point feeds |
| US4330389A (en) * | 1976-12-27 | 1982-05-18 | Chevron Research Company | Coal liquefaction process |
-
1983
- 1983-05-31 CA CA000429277A patent/CA1199293A/fr not_active Expired
- 1983-06-15 DE DE19833321690 patent/DE3321690A1/de not_active Withdrawn
- 1983-06-16 JP JP10853883A patent/JPS596283A/ja active Pending
- 1983-06-16 GB GB08316435A patent/GB2121817B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB2121817B (en) | 1987-01-21 |
| JPS596283A (ja) | 1984-01-13 |
| GB8316435D0 (en) | 1983-07-20 |
| DE3321690A1 (de) | 1983-12-22 |
| GB2121817A (en) | 1984-01-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4695369A (en) | Catalytic hydroconversion of heavy oil using two metal catalyst | |
| US4376037A (en) | Hydroprocessing of heavy hydrocarbonaceous oils | |
| US4389301A (en) | Two-step hydroprocessing of heavy hydrocarbonaceous oils | |
| US4606809A (en) | Hydroconversion of heavy oils | |
| US11702603B2 (en) | Method for converting feedstocks comprising a hydrocracking step, a precipitation step and a sediment separation step, in order to produce fuel oils | |
| US4079004A (en) | Method for separating undissolved solids from a coal liquefaction product | |
| EP0048098B1 (fr) | Amélioration d'huile résiduelle | |
| US3622498A (en) | Slurry processing for black oil conversion | |
| US4411767A (en) | Integrated process for the solvent refining of coal | |
| US4389303A (en) | Process of converting high-boiling crude oils to equivalent petroleum products | |
| EA011976B1 (ru) | Способ переработки тяжелой нефти с рециркуляцией суспензии активной каталитической композиции | |
| US4379744A (en) | Coal liquefaction process | |
| US4300996A (en) | Three-stage coal liquefaction process | |
| US4081360A (en) | Method for suppressing asphaltene formation during coal liquefaction and separation of solids from the liquid product | |
| US3825488A (en) | Process for hydrorefining a hydrocarbon charge stock | |
| US4659452A (en) | Multi-stage hydrofining process | |
| CA1199293A (fr) | Hydrotraitement bi-etage des petroles lourds, avec recyclage des residus | |
| US4428820A (en) | Coal liquefaction process with controlled recycle of ethyl acetate-insolubles | |
| US4534847A (en) | Process for producing low-sulfur boiler fuel by hydrotreatment of solvent deashed SRC | |
| US4331531A (en) | Three-stage coal liquefaction process | |
| US4325800A (en) | Two-stage coal liquefaction process with interstage guard bed | |
| US4510038A (en) | Coal liquefaction using vacuum distillation and an external residuum feed | |
| JPH0631332B2 (ja) | 重質炭化水素油の水素化処理法 | |
| GB2164055A (en) | Coal liquefaction process | |
| US4264430A (en) | Three-stage coal liquefaction process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |