CA1205937A - Melanges aqueux de resine - Google Patents

Melanges aqueux de resine

Info

Publication number: CA1205937A
Authority: CA; Canada
Prior art keywords: water; weight; percent; emulsion; resin
Prior art date: 1982-02-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000396632A

Other languages

English (en)

Inventor

Frank J. Traver

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

General Electric Co

Original Assignee

General Electric Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-02-19

Filing date

1982-02-19

Publication date

1986-06-10

1982-02-19 Application filed by General Electric Co filed Critical General Electric Co

1982-02-19 Priority to CA000396632A priority Critical patent/CA1205937A/fr

1986-06-10 Application granted granted Critical

1986-06-10 Publication of CA1205937A publication Critical patent/CA1205937A/fr

Status Expired legal-status Critical Current

Links

XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 90
239000000839 emulsion Substances 0.000 title claims abstract description 72
229920005989 resin Polymers 0.000 title claims abstract description 65
239000011347 resin Substances 0.000 title claims abstract description 65
229920001296 polysiloxane Polymers 0.000 claims abstract description 65
229920002050 silicone resin Polymers 0.000 claims abstract description 61
239000000203 mixture Substances 0.000 claims abstract description 57
239000003995 emulsifying agent Substances 0.000 claims abstract description 29
239000007787 solid Substances 0.000 claims abstract description 28
238000000034 method Methods 0.000 claims description 33
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 28
239000001923 methylcellulose Substances 0.000 claims description 20
229960002900 methylcellulose Drugs 0.000 claims description 20
LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical group CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 19
229920000609 methyl cellulose Polymers 0.000 claims description 19
235000010981 methylcellulose Nutrition 0.000 claims description 19
239000003960 organic solvent Substances 0.000 claims description 18
239000000084 colloidal system Substances 0.000 claims description 15
229920002678 cellulose Polymers 0.000 claims description 14
239000001913 cellulose Substances 0.000 claims description 14
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 8
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 8
239000003945 anionic surfactant Substances 0.000 claims description 8
239000003795 chemical substances by application Substances 0.000 claims description 8
238000004945 emulsification Methods 0.000 claims description 8
239000011734 sodium Substances 0.000 claims description 8
229910052708 sodium Inorganic materials 0.000 claims description 8
235000019333 sodium laurylsulphate Nutrition 0.000 claims description 8
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
150000004996 alkyl benzenes Chemical class 0.000 claims description 6
229940077388 benzenesulfonate Drugs 0.000 claims description 6
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 6
229930195733 hydrocarbon Natural products 0.000 claims description 6
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
239000004215 Carbon black (E152) Substances 0.000 claims description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 5
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
230000001804 emulsifying effect Effects 0.000 claims description 5
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
229910052710 silicon Inorganic materials 0.000 claims description 5
239000008096 xylene Substances 0.000 claims description 5
150000002148 esters Chemical class 0.000 claims description 4
239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 4
229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 4
235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 4
UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 4
238000003801 milling Methods 0.000 claims description 4
238000002156 mixing Methods 0.000 claims description 4
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
150000005215 alkyl ethers Chemical class 0.000 claims description 3
125000000217 alkyl group Chemical group 0.000 claims description 3
229940047662 ammonium xylenesulfonate Drugs 0.000 claims description 3
229910052681 coesite Inorganic materials 0.000 claims description 3
229910052906 cristobalite Inorganic materials 0.000 claims description 3
HESSGHHCXGBPAJ-UHFFFAOYSA-N n-[3,5,6-trihydroxy-1-oxo-4-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyhexan-2-yl]acetamide Chemical compound CC(=O)NC(C=O)C(O)C(C(O)CO)OC1OC(CO)C(O)C(O)C1O HESSGHHCXGBPAJ-UHFFFAOYSA-N 0.000 claims description 3
239000011342 resin composition Substances 0.000 claims description 3
239000000377 silicon dioxide Substances 0.000 claims description 3
235000012239 silicon dioxide Nutrition 0.000 claims description 3
229940079842 sodium cumenesulfonate Drugs 0.000 claims description 3
RTVVXRKGQRRXFJ-UHFFFAOYSA-N sodium;2-sulfobutanedioic acid Chemical compound [Na].OC(=O)CC(C(O)=O)S(O)(=O)=O RTVVXRKGQRRXFJ-UHFFFAOYSA-N 0.000 claims description 3
QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 claims description 3
229910052682 stishovite Inorganic materials 0.000 claims description 3
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
229910052905 tridymite Inorganic materials 0.000 claims description 3
229960004418 trolamine Drugs 0.000 claims description 3
239000004711 α-olefin Substances 0.000 claims description 3
OPVLOHUACNWTQT-UHFFFAOYSA-N azane;2-dodecoxyethyl hydrogen sulfate Chemical compound N.CCCCCCCCCCCCOCCOS(O)(=O)=O OPVLOHUACNWTQT-UHFFFAOYSA-N 0.000 claims description 2
229910020381 SiO1.5 Inorganic materials 0.000 claims 4
125000003944 tolyl group Chemical group 0.000 claims 2
FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 claims 1
239000002904 solvent Substances 0.000 abstract description 5
125000000129 anionic group Chemical group 0.000 abstract description 4
239000000243 solution Substances 0.000 description 28
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 21
229920003091 Methocel™ Polymers 0.000 description 16
238000006460 hydrolysis reaction Methods 0.000 description 16
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 15
230000007062 hydrolysis Effects 0.000 description 15
229910000077 silane Inorganic materials 0.000 description 15
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 14
238000000576 coating method Methods 0.000 description 14
239000000047 product Substances 0.000 description 13
239000007864 aqueous solution Substances 0.000 description 9
239000000843 powder Substances 0.000 description 9
239000011248 coating agent Substances 0.000 description 8
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
238000013019 agitation Methods 0.000 description 6
239000005054 phenyltrichlorosilane Substances 0.000 description 6
ORVMIVQULIKXCP-UHFFFAOYSA-N trichloro(phenyl)silane Chemical compound Cl[Si](Cl)(Cl)C1=CC=CC=C1 ORVMIVQULIKXCP-UHFFFAOYSA-N 0.000 description 6
229920003086 cellulose ether Polymers 0.000 description 5
LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 5
238000009472 formulation Methods 0.000 description 5
239000004615 ingredient Substances 0.000 description 5
239000005055 methyl trichlorosilane Substances 0.000 description 5
JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 5
NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 4
239000000470 constituent Substances 0.000 description 4
OSXYHAQZDCICNX-UHFFFAOYSA-N dichloro(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](Cl)(Cl)C1=CC=CC=C1 OSXYHAQZDCICNX-UHFFFAOYSA-N 0.000 description 4
239000006185 dispersion Substances 0.000 description 4
YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 4
239000003973 paint Substances 0.000 description 4
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
239000008199 coating composition Substances 0.000 description 3
239000005457 ice water Substances 0.000 description 3
239000002609 medium Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
229920002153 Hydroxypropyl cellulose Polymers 0.000 description 2
239000005909 Kieselgur Substances 0.000 description 2
229910004738 SiO1 Inorganic materials 0.000 description 2
239000012874 anionic emulsifier Substances 0.000 description 2
239000012461 cellulose resin Substances 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
230000009977 dual effect Effects 0.000 description 2
230000007613 environmental effect Effects 0.000 description 2
238000001914 filtration Methods 0.000 description 2
239000001863 hydroxypropyl cellulose Substances 0.000 description 2
235000010977 hydroxypropyl cellulose Nutrition 0.000 description 2
229940071676 hydroxypropylcellulose Drugs 0.000 description 2
239000010410 layer Substances 0.000 description 2
229940050176 methyl chloride Drugs 0.000 description 2
239000012044 organic layer Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
238000000926 separation method Methods 0.000 description 2
JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 1
DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
101100087530 Caenorhabditis elegans rom-1 gene Proteins 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
229920003108 Methocel™ A4M Polymers 0.000 description 1
101100305983 Mus musculus Rom1 gene Proteins 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229920006321 anionic cellulose Polymers 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
230000002939 deleterious effect Effects 0.000 description 1
KTQYJQFGNYHXMB-UHFFFAOYSA-N dichloro(methyl)silicon Chemical compound C[Si](Cl)Cl KTQYJQFGNYHXMB-UHFFFAOYSA-N 0.000 description 1
229960004132 diethyl ether Drugs 0.000 description 1
MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
229940043264 dodecyl sulfate Drugs 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
229940052303 ethers for general anesthesia Drugs 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
238000000265 homogenisation Methods 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
239000012535 impurity Substances 0.000 description 1
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 1
MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
239000005048 methyldichlorosilane Substances 0.000 description 1
239000011368 organic material Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000002243 precursor Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
238000013341 scale-up Methods 0.000 description 1
SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
125000005372 silanol group Chemical group 0.000 description 1
239000010703 silicon Substances 0.000 description 1
-1 siloxane units Chemical group 0.000 description 1
238000003756 stirring Methods 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA000396632A 1982-02-19 1982-02-19 Melanges aqueux de resine Expired CA1205937A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000396632A CA1205937A (fr)	1982-02-19	1982-02-19	Melanges aqueux de resine

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000396632A CA1205937A (fr)	1982-02-19	1982-02-19	Melanges aqueux de resine

Publications (1)

Publication Number	Publication Date
CA1205937A true CA1205937A (fr)	1986-06-10

Family

ID=4122109

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000396632A Expired CA1205937A (fr)	1982-02-19	1982-02-19	Melanges aqueux de resine

Country Status (1)

Country	Link
CA (1)	CA1205937A (fr)

1982
- 1982-02-19 CA CA000396632A patent/CA1205937A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2003-06-10	MKEX	Expiry

Publication	Publication Date	Title
US4518727A (en)	1985-05-21	Water based resin emulsions
US4529758A (en)	1985-07-16	Water based resin dispersions
US4525502A (en)	1985-06-25	Water based resin emulsions
CA1204896A (fr)	1986-05-20	Enduits faits de silicone et de matiere organique
EP0317057B1 (fr)	1995-11-22	Pocédé de préparation de compositions aqueuses à base d'une silicone et d'un polymère organique
DE69404876T2 (de)	1998-02-26	Verfahren zur Herstellung von, im wesentlichen Silanol-freien Silikonharzpulvern
DE602004001390T2 (de)	2007-06-06	Verfahren zur herstellung von silikonharzemulsionen
EP0640664B1 (fr)	1999-11-03	Compositions d'émulsions de polysiloxanes
US4383062A (en)	1983-05-10	Waterborne coating compositions
JPS58101153A (ja)	1983-06-16	シリコ−ン水性エマルジヨン組成物
JPS62257939A (ja)	1987-11-10	シリコ−ンエラストマ−球状微粉末の製造方法
JPH06184444A (ja)	1994-07-05	低いデュロメータ硬度及び高い引裂強さの鋳型用化合物
JPH03250050A (ja)	1991-11-07	オルガノポリシロキサン系エラストマー粉体およびその製造方法
US20140357773A1 (en)	2014-12-04	Silicone Resin Emulsions
JPH05132622A (ja)	1993-05-28	水性シリコーンエマルジヨン
JPH02187463A (ja)	1990-07-23	室温で固体の高分子量オルガノポリシロキサンの水性乳濁液を製造する方法
AU649735B2 (en)	1994-06-02	Aqueous silicone-organic hybrids
CA1246270A (fr)	1988-12-06	Emulsions de resine a base d'eau
EP0444662B1 (fr)	1994-09-21	Composition de revêtement à base de polysiloxane protégeant contre la corrosion et ayant une durée de travail améliorée
CA1205937A (fr)	1986-06-10	Melanges aqueux de resine
US5045584A (en)	1991-09-03	Polish containing silicone elastomer particles
JP3384827B2 (ja)	2003-03-10	水分散シリコーン樹脂組成物
US6224946B1 (en)	2001-05-01	Suspensions, a process for their preparation, and the use thereof
JPS60252656A (ja)	1985-12-13	水をベースとする樹脂エマルジヨン
GB2085903A (en)	1982-05-06	Water dispersible silicone resins for water based applications