CA1209510A - Methode d'hydrodemetallisation des huiles d'hydrocarbures, tels les redidus du petrole - Google Patents

Methode d'hydrodemetallisation des huiles d'hydrocarbures, tels les redidus du petrole

Info

Publication number: CA1209510A
Authority: CA; Canada
Prior art keywords: catalyst; slurry; predeposited; metals; weight
Prior art date: 1981-12-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000415513A

Other languages

English (en)

Inventor

Alan G. Bridge

David F. Strahorn

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Chevron USA Inc

Original Assignee

Chevron Research and Technology Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-12-29

Filing date

1982-11-15

Publication date

1986-08-12

1982-11-15 Application filed by Chevron Research and Technology Co filed Critical Chevron Research and Technology Co

1986-08-12 Application granted granted Critical

1986-08-12 Publication of CA1209510A publication Critical patent/CA1209510A/fr

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 33
230000008569 process Effects 0.000 title claims abstract description 32
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 23
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 23
239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 21
239000003208 petroleum Substances 0.000 title claims abstract description 15
239000003921 oil Substances 0.000 title abstract description 22
239000003054 catalyst Substances 0.000 claims abstract description 75
229910052751 metal Inorganic materials 0.000 claims abstract description 48
239000002184 metal Substances 0.000 claims abstract description 48
239000002002 slurry Substances 0.000 claims abstract description 30
150000002739 metals Chemical class 0.000 claims abstract description 25
239000001257 hydrogen Substances 0.000 claims abstract description 24
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 24
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 22
239000002245 particle Substances 0.000 claims abstract description 19
238000007324 demetalation reaction Methods 0.000 claims abstract description 12
239000007788 liquid Substances 0.000 claims abstract description 8
239000007787 solid Substances 0.000 claims abstract description 8
238000006243 chemical reaction Methods 0.000 claims description 24
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 22
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 15
239000000463 material Substances 0.000 claims description 13
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
229910052759 nickel Inorganic materials 0.000 claims description 7
238000011068 loading method Methods 0.000 claims description 6
229910052720 vanadium Inorganic materials 0.000 claims description 6
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 5
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
229910052721 tungsten Inorganic materials 0.000 claims description 3
239000010937 tungsten Substances 0.000 claims description 3
229910017052 cobalt Inorganic materials 0.000 claims description 2
239000010941 cobalt Substances 0.000 claims description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
-1 vanadium metals Chemical class 0.000 claims 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 6
229910052717 sulfur Inorganic materials 0.000 abstract description 6
239000011593 sulfur Substances 0.000 abstract description 6
239000000047 product Substances 0.000 description 13
239000003079 shale oil Substances 0.000 description 9
230000000694 effects Effects 0.000 description 8
229940023032 activated charcoal Drugs 0.000 description 7
238000009835 boiling Methods 0.000 description 7
239000000356 contaminant Substances 0.000 description 7
239000010779 crude oil Substances 0.000 description 6
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
229910052785 arsenic Inorganic materials 0.000 description 5
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 5
239000012071 phase Substances 0.000 description 5
229960005349 sulfur Drugs 0.000 description 5
235000001508 sulfur Nutrition 0.000 description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
239000007789 gas Substances 0.000 description 4
238000011084 recovery Methods 0.000 description 4
239000011949 solid catalyst Substances 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 3
238000006477 desulfuration reaction Methods 0.000 description 3
230000023556 desulfurization Effects 0.000 description 3
239000000203 mixture Substances 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000012141 concentrate Substances 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
238000006263 metalation reaction Methods 0.000 description 2
238000002156 mixing Methods 0.000 description 2
125000001741 organic sulfur group Chemical group 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
238000000926 separation method Methods 0.000 description 2
238000005292 vacuum distillation Methods 0.000 description 2
238000012935 Averaging Methods 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
241000038859 Horia Species 0.000 description 1
229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
229910003294 NiMo Inorganic materials 0.000 description 1
KSECJOPEZIAKMU-UHFFFAOYSA-N [S--].[S--].[S--].[S--].[S--].[V+5].[V+5] Chemical compound [S--].[S--].[S--].[S--].[S--].[V+5].[V+5] KSECJOPEZIAKMU-UHFFFAOYSA-N 0.000 description 1
238000010923 batch production Methods 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
229940106265 charcoal Drugs 0.000 description 1
239000000571 coke Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000005202 decontamination Methods 0.000 description 1
230000003588 decontaminative effect Effects 0.000 description 1
230000008021 deposition Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
230000003628 erosive effect Effects 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000002955 isolation Methods 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
239000002674 ointment Substances 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
239000011236 particulate material Substances 0.000 description 1
239000008188 pellet Substances 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000001294 propane Substances 0.000 description 1
238000007670 refining Methods 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
230000003068 static effect Effects 0.000 description 1
239000000725 suspension Substances 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/243—Tubular reactors spirally, concentrically or zigzag wound
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00548—Flow
- B01J2208/00557—Flow controlling the residence time inside the reactor vessel
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA000415513A 1981-12-29 1982-11-15 Methode d'hydrodemetallisation des huiles d'hydrocarbures, tels les redidus du petrole Expired CA1209510A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US33552581A	1981-12-29	1981-12-29
US335,525		1981-12-29

Publications (1)

Publication Number	Publication Date
CA1209510A true CA1209510A (fr)	1986-08-12

Family

ID=23312148

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000415513A Expired CA1209510A (fr)	1981-12-29	1982-11-15	Methode d'hydrodemetallisation des huiles d'hydrocarbures, tels les redidus du petrole

Country Status (5)

Country	Link
JP (1)	JPS58118892A (fr)
CA (1)	CA1209510A (fr)
DE (1)	DE3246680A1 (fr)
GB (1)	GB2112412B (fr)
NL (1)	NL8204949A (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US20040156763A1 (en) *	2001-03-12	2004-08-12	Wood Mark D.	Reactor apparatus and mixing inlet and methods
US7745369B2 (en)	2003-12-19	2010-06-29	Shell Oil Company	Method and catalyst for producing a crude product with minimal hydrogen uptake
US20100098602A1 (en)	2003-12-19	2010-04-22	Opinder Kishan Bhan	Systems, methods, and catalysts for producing a crude product
US8241489B2 (en)	2003-12-19	2012-08-14	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
CN101166808B (zh)	2005-04-11	2013-03-27	国际壳牌研究有限公司	生产具有降低mcr含量的原油产品的方法和催化剂
JP2008536000A (ja)	2005-04-11	2008-09-04	シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ	窒素含有量の少ない原油生成物の製造方法及び触媒
US7749374B2 (en)	2006-10-06	2010-07-06	Shell Oil Company	Methods for producing a crude product

1982
- 1982-11-15 CA CA000415513A patent/CA1209510A/fr not_active Expired
- 1982-12-16 DE DE19823246680 patent/DE3246680A1/de not_active Withdrawn
- 1982-12-21 GB GB08236290A patent/GB2112412B/en not_active Expired
- 1982-12-22 NL NL8204949A patent/NL8204949A/nl not_active Application Discontinuation
- 1982-12-23 JP JP23513282A patent/JPS58118892A/ja active Pending

Also Published As

Publication number	Publication date
GB2112412A (en)	1983-07-20
JPS58118892A (ja)	1983-07-15
GB2112412B (en)	1986-01-22
NL8204949A (nl)	1983-07-18
DE3246680A1 (de)	1983-07-07

Legal Events

Date	Code	Title	Description
2003-08-12	MKEX	Expiry

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WO2013166361A1 (fr)	2013-11-07	Procédé à lit bouillonnant intégré pour une valorisation de pétrole brut total
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KR20190018465A (ko)	2019-02-22	개선된 품질의 진공 잔사 생성물을 생성하기 위해 에뷸레이티드 베드를 업그레이드하기 위한 이원 촉매 시스템
GB2127843A (en)	1984-04-18	Solvent refining of coal
US4888104A (en)	1989-12-19	Catalytic system for the hydroconversion of heavy oils
KR20240095222A (ko)	2024-06-25	청정 액체 연료 수소 운반체 공정
CA1077917A (fr)	1980-05-20	Hydroconversion d'hydrocarbures lourds
US3271302A (en)	1966-09-06	Multiple-stage hydrorefining of petroleum crude oil
US4659452A (en)	1987-04-21	Multi-stage hydrofining process
JPH0762355A (ja)	1995-03-07	炭素質生成を抑制した重質油の水素化処理法
EP4469538A1 (fr)	2024-12-04	Hydrotraitement et hydrocraquage intégrés avec régénération continue de catalyseur d'hydrotraitement