CA1217482A - Polysaccharides alcoylsulfones; melanges de mortier et de beton qui en renfermant - Google Patents

Polysaccharides alcoylsulfones; melanges de mortier et de beton qui en renfermant

Info

Publication number: CA1217482A
Authority: CA; Canada
Prior art keywords: degree; alkylsulfonated; sulfonation; polysaccharide; mortar
Prior art date: 1983-03-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000448712A

Other languages

English (en)

Inventor

Benito Casu

Fabio Tegiacchi

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Grace Italiana SpA

Original Assignee

Grace Italiana SpA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-03-03

Filing date

1984-03-02

Publication date

1987-02-03

1984-03-02 Application filed by Grace Italiana SpA filed Critical Grace Italiana SpA

1987-02-03 Application granted granted Critical

1987-02-03 Publication of CA1217482A publication Critical patent/CA1217482A/fr

Status Expired legal-status Critical Current

Links

239000004570 mortar (masonry) Substances 0.000 title claims abstract description 29
239000004567 concrete Substances 0.000 title claims abstract description 23
150000004676 glycans Chemical class 0.000 title claims abstract description 22
239000005017 polysaccharide Substances 0.000 title claims abstract description 22
229920001282 polysaccharide Polymers 0.000 title claims abstract description 21
238000000034 method Methods 0.000 claims abstract description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 40
239000003795 chemical substances by application Substances 0.000 claims description 34
229920002472 Starch Polymers 0.000 claims description 33
235000019698 starch Nutrition 0.000 claims description 32
239000000203 mixture Substances 0.000 claims description 29
239000008107 starch Substances 0.000 claims description 28
238000006277 sulfonation reaction Methods 0.000 claims description 24
239000011230 binding agent Substances 0.000 claims description 15
238000006116 polymerization reaction Methods 0.000 claims description 10
229920002488 Hemicellulose Polymers 0.000 claims description 7
LHORZPMPPHTXFQ-UHFFFAOYSA-N 1-chloroethanesulfonic acid Chemical compound CC(Cl)S(O)(=O)=O LHORZPMPPHTXFQ-UHFFFAOYSA-N 0.000 claims description 5
235000013379 molasses Nutrition 0.000 claims description 4
239000002023 wood Substances 0.000 claims description 4
125000000217 alkyl group Chemical group 0.000 claims description 3
150000004804 polysaccharides Polymers 0.000 claims description 2
239000011396 hydraulic cement Substances 0.000 claims 2
239000004568 cement Substances 0.000 description 15
230000000694 effects Effects 0.000 description 15
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
239000000463 material Substances 0.000 description 8
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
238000012360 testing method Methods 0.000 description 6
-1 sulfoalkyl polysaccharides Chemical class 0.000 description 5
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
150000001412 amines Chemical class 0.000 description 4
239000004033 plastic Substances 0.000 description 4
229920000417 polynaphthalene Polymers 0.000 description 4
FSSPGSAQUIYDCN-UHFFFAOYSA-N 1,3-Propane sultone Chemical compound O=S1(=O)CCCO1 FSSPGSAQUIYDCN-UHFFFAOYSA-N 0.000 description 3
MCXZBEZHTYZNRE-UHFFFAOYSA-N 1-chloropropane-1-sulfonic acid Chemical compound CCC(Cl)S(O)(=O)=O MCXZBEZHTYZNRE-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
239000000654 additive Substances 0.000 description 3
150000001768 cations Chemical class 0.000 description 3
238000000227 grinding Methods 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
238000003756 stirring Methods 0.000 description 3
238000006467 substitution reaction Methods 0.000 description 3
FXKMTSIKHBYZSZ-UHFFFAOYSA-N 2-chloroethanesulfonic acid Chemical compound OS(=O)(=O)CCCl FXKMTSIKHBYZSZ-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
238000005481 NMR spectroscopy Methods 0.000 description 2
239000011575 calcium Substances 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
229920002678 cellulose Polymers 0.000 description 2
239000001913 cellulose Substances 0.000 description 2
229920002301 cellulose acetate Polymers 0.000 description 2
NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
239000012528 membrane Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
OGNVQLDIPUXYDH-ZPKKHLQPSA-N (2R,3R,4S)-3-(2-methylpropanoylamino)-4-(4-phenyltriazol-1-yl)-2-[(1R,2R)-1,2,3-trihydroxypropyl]-3,4-dihydro-2H-pyran-6-carboxylic acid Chemical compound CC(C)C(=O)N[C@H]1[C@H]([C@H](O)[C@H](O)CO)OC(C(O)=O)=C[C@@H]1N1N=NC(C=2C=CC=CC=2)=C1 OGNVQLDIPUXYDH-ZPKKHLQPSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
239000004640 Melamine resin Substances 0.000 description 1
229920000877 Melamine resin Polymers 0.000 description 1
229920000881 Modified starch Polymers 0.000 description 1
239000004368 Modified starch Substances 0.000 description 1
239000011398 Portland cement Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
229920002253 Tannate Polymers 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000011400 blast furnace cement Substances 0.000 description 1
230000000740 bleeding effect Effects 0.000 description 1
150000001720 carbohydrates Chemical class 0.000 description 1
235000014633 carbohydrates Nutrition 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000000875 corresponding effect Effects 0.000 description 1
229960003750 ethyl chloride Drugs 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000010881 fly ash Substances 0.000 description 1
239000008103 glucose Substances 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
235000019426 modified starch Nutrition 0.000 description 1
239000012452 mother liquor Substances 0.000 description 1
PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
239000011178 precast concrete Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
238000005204 segregation Methods 0.000 description 1
239000002893 slag Substances 0.000 description 1
239000000176 sodium gluconate Substances 0.000 description 1
235000012207 sodium gluconate Nutrition 0.000 description 1
229940005574 sodium gluconate Drugs 0.000 description 1
239000007858 starting material Substances 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
235000020357 syrup Nutrition 0.000 description 1
239000006188 syrup Substances 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/08—Ethers
- C08B31/12—Ethers having alkyl or cycloalkyl radicals substituted by heteroatoms, e.g. hydroxyalkyl or carboxyalkyl starch
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/16—Sulfur-containing compounds
- C04B24/161—Macromolecular compounds comprising sulfonate or sulfate groups
- C04B24/168—Polysaccharide derivatives, e.g. starch sulfate
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B11/00—Preparation of cellulose ethers
- C08B11/02—Alkyl or cycloalkyl ethers
- C08B11/04—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals
- C08B11/10—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals substituted with acid radicals

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Life Sciences & Earth Sciences (AREA)
Ceramic Engineering (AREA)
Biochemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Structural Engineering (AREA)
Curing Cements, Concrete, And Artificial Stone (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)

CA000448712A 1983-03-03 1984-03-02 Polysaccharides alcoylsulfones; melanges de mortier et de beton qui en renfermant Expired CA1217482A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
IT19879/83A IT1161592B (it)	1983-03-03	1983-03-03	Polisaccaridi alchilsolfonati ad attivita' fluidificante e matle e calcestruzzi contenenti detti polisaccaridi
IT19879A/83		1983-03-03

Publications (1)

Publication Number	Publication Date
CA1217482A true CA1217482A (fr)	1987-02-03

Family

ID=11162016

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000448712A Expired CA1217482A (fr)	1983-03-03	1984-03-02	Polysaccharides alcoylsulfones; melanges de mortier et de beton qui en renfermant

Country Status (10)

Country	Link
US (1)	USH493H (fr)
BE (1)	BE899046A (fr)
CA (1)	CA1217482A (fr)
CH (1)	CH659241A5 (fr)
DE (1)	DE3406745A1 (fr)
FR (1)	FR2541990A1 (fr)
GB (1)	GB2138014B (fr)
IT (1)	IT1161592B (fr)
NL (1)	NL8400642A (fr)
SE (1)	SE8401151L (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5986087A (en) *	1995-05-24	1999-11-16	Dystar Textilfarben Gmbh & Co. Deutschland Kg	Sulfonation of regenerated cellulose with sulfonated polymers and use of the thus modified fibres

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4203530A1 (de) *	1992-02-07	1993-08-12	Wolff Walsrode Ag	Verwendung von wasserloeslichen sulfoalkylderivaten der cellulose in gips- und zementhaltigen massen
DE4203529A1 (de) *	1992-02-07	1993-08-12	Wolff Walsrode Ag	Wasserloesliche sulfoalkylhydroxyalkylderivate der cellulose und deren verwendung in gips- und zementhaltigen massen
TR27111A (tr) *	1992-06-06	1994-11-09	Hoechst Ag	Sulfoakil grubu ihtiva eden alkilhidroksialkil selüloz eterleri.
US5591844A (en) *	1992-06-06	1997-01-07	Hoechst Aktiengesellschaft	Alkyl hydroxyalkyl cellulose ethers containing sulfoalkyl groups
US5573589A (en) *	1993-03-10	1996-11-12	Sandoz Ltd.	Cement compositions containing a sulfated polysaccharide and method
US5575840A (en) *	1993-10-29	1996-11-19	National Starch And Chemical Investment Holding Corporation	Cement mortar systems using blends of polysaccharides and cold-water-soluble, unmodified starches
DE19543304B4 (de) *	1995-11-21	2005-06-09	Skw Bauchemie Gmbh	Zusatzmittel für wasserhaltige Baustoffmischungen und dessen Verwendung
WO1998023647A1 (fr) *	1996-11-27	1998-06-04	Kao Corporation	Derives polysaccharidiques et compositions hydrauliques
IT1291309B1 (it) *	1997-05-06	1999-01-07	F B C Future Biolog Chemicals	Fluidificanti cementizi a base di amidi solfati
DE10209812A1 (de)	2001-03-22	2002-09-26	Degussa Construction Chem Gmbh	Verwendung von wasserlöslichen Polysaccharid-Derivaten als Dispergiermittel für mineralische Bindemittelsuspensionen
BRPI0417144B1 (pt) *	2003-12-01	2017-03-28	Gcp Applied Tech Inc	método para modificar uma composição cimentosa

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2429211A (en)	1944-02-07	1947-10-21	Andes Ralph Verne	High-temperature cement modifier
US2583657A (en)	1949-07-11	1952-01-29	Phillips Petroleum Co	Low water-loss cement and process of making
US2562148A (en)	1949-07-11	1951-07-24	Phillips Petroleum Co	Low water-loss cement slurry
US2896715A (en)	1952-05-05	1959-07-28	Phillips Petroleum Co	Hydraulic cements
US2795508A (en)	1952-08-22	1957-06-11	Phillips Petroleum Co	Sulfoalkyl cellulose ethers and their salts as hydraulic natural cement set retarders
US2820788A (en)	1955-02-24	1958-01-21	Du Pont	Process for preparing sodium sulfomethylcellulose
US2891057A (en)	1956-11-09	1959-06-16	Mo Och Domsjoe Ab	Methods of making cellulose ethers
US3332791A (en) *	1964-05-12	1967-07-25	Rayonier Inc	Process for producing portland cement compositions
US3530112A (en)	1967-07-24	1970-09-22	Itt Rayonier Inc	Process for preparing dispersants useful in hydraulic cement slurries
JPS6018615B2 (ja)	1976-03-10	1985-05-11	花王株式会社	水硬性セメント組成物

1983
- 1983-03-03 IT IT19879/83A patent/IT1161592B/it active
1984
- 1984-02-01 US US06/575,733 patent/USH493H/en not_active Abandoned
- 1984-02-24 DE DE19843406745 patent/DE3406745A1/de not_active Withdrawn
- 1984-02-29 NL NL8400642A patent/NL8400642A/nl not_active Application Discontinuation
- 1984-02-29 FR FR8403166A patent/FR2541990A1/fr not_active Withdrawn
- 1984-03-01 GB GB08405407A patent/GB2138014B/en not_active Expired
- 1984-03-01 SE SE8401151A patent/SE8401151L/ not_active Application Discontinuation
- 1984-03-01 BE BE212480A patent/BE899046A/fr unknown
- 1984-03-02 CA CA000448712A patent/CA1217482A/fr not_active Expired
- 1984-03-02 CH CH1020/84A patent/CH659241A5/de not_active IP Right Cessation

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5986087A (en) *	1995-05-24	1999-11-16	Dystar Textilfarben Gmbh & Co. Deutschland Kg	Sulfonation of regenerated cellulose with sulfonated polymers and use of the thus modified fibres

Also Published As

Publication number	Publication date
GB2138014A (en)	1984-10-17
BE899046A (fr)	1984-07-02
IT1161592B (it)	1987-03-18
SE8401151L (sv)	1984-09-04
NL8400642A (nl)	1984-10-01
SE8401151D0 (sv)	1984-03-01
CH659241A5 (de)	1987-01-15
IT8319879A1 (it)	1984-09-03
FR2541990A1 (fr)	1984-09-07
USH493H (en)	1988-07-05
DE3406745A1 (de)	1984-09-06
GB2138014B (en)	1986-04-09
GB8405407D0 (en)	1984-04-04
IT8319879A0 (it)	1983-03-03

Legal Events

Date	Code	Title	Description
2004-03-02	MKEX	Expiry

Publication	Publication Date	Title
EP0077129B1 (fr)	1986-01-15	Additif pour mélanges de ciment hydraulique
US4818288A (en)	1989-04-04	Dispersant for concrete mixtures of high salt content
EP0101723B1 (fr)	1986-11-26	Procede d'amelioration de melanges de ciment hydraulique
CA1217482A (fr)	1987-02-03	Polysaccharides alcoylsulfones; melanges de mortier et de beton qui en renfermant
US20050241540A1 (en)	2005-11-03	Cement-based plasters using water retention agents prepared from raw cotton linters
JPS6018615B2 (ja)	1985-05-11	水硬性セメント組成物
US20050241543A1 (en)	2005-11-03	Cement-based systems using plastification/extrusion auxiliaries prepared from raw cotton linters
US20050241542A1 (en)	2005-11-03	Cement-based systems using water retention agents prepared from raw cotton linters
JPH0328147A (ja)	1991-02-06	コンクリート組成物中の空気連行を調節する方法
JPS6246946A (ja)	1987-02-28	水溶性のナフタリンスルホン酸―ホルムアルデヒド縮合生成物の塩を無機結合剤の混和剤として使用する方法
EP0855995A2 (fr)	1998-08-05	Adjuvants du beton a base de lignine sulfomethylolatee
NO861593L (no)	1986-10-27	Vanlig blanding egnet for fremstilling av fluid betongvelling.
CA1226429A (fr)	1987-09-08	Adjuvants antireducteurs de filtrat pour ciments hydrauliques de garnissage des forages
CN109503788B (zh)	2021-06-15	一种石膏用磺化三聚氰胺减水剂的合成方法
JPS6339906A (ja)	1988-02-20	セメント添加剤
CN109306021B (zh)	2020-10-09	一种淀粉硫酸酯缓凝高效减水剂及其制备方法
CN112851183B (zh)	2022-07-01	一种适用于降低大体积混凝土水化热的外加剂及其制备方法
JP3192464B2 (ja)	2001-07-30	セメント混和剤
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CN115838443B (zh)	2024-03-22	一种磺化瓜尔胶醚及其制备方法和应用
CA1162951A (fr)	1984-02-28	Superplasticiseur pour ciment
CN111548072A (zh)	2020-08-18	一种高强高性能混凝土及其制备方法
CN119875007B (zh)	2025-06-10	一种用于高温下的湿拌砂浆保水剂及其制备方法和应用
JPS6215500B2 (fr)	1987-04-08
JPH03141142A (ja)	1991-06-17	セメント用減水剤

CA1217482A - Polysaccharides alcoylsulfones; melanges de mortier et de beton qui en renfermant - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (2)

Publications (1)

Family

ID=11162016

Family Applications (1)

Country Status (10)

Cited By (1)

Families Citing this family (11)

Family Cites Families (10)

Cited By (1)

Also Published As

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