CA1227501A - Process for the conversion of olefinic compounds into high viscosity lubes - Google Patents

Process for the conversion of olefinic compounds into high viscosity lubes

Info

Publication number: CA1227501A
Authority: CA; Canada
Prior art keywords: stage; zsm; conversion; process according; zeolite
Prior art date: 1983-09-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000462275A

Other languages

English (en)

French (fr)

Inventor

Ralph M. Dessau

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-09-19

Filing date

1984-08-31

Publication date

1987-09-29

1984-08-31 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1987-09-29 Application granted granted Critical

1987-09-29 Publication of CA1227501A publication Critical patent/CA1227501A/en

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 45
238000006243 chemical reaction Methods 0.000 title claims abstract description 39
150000001875 compounds Chemical class 0.000 title claims abstract description 4
150000001336 alkenes Chemical class 0.000 claims abstract description 28
239000003054 catalyst Substances 0.000 claims abstract description 27
230000003197 catalytic effect Effects 0.000 claims abstract description 3
239000010457 zeolite Substances 0.000 claims description 40
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 31
229910021536 Zeolite Inorganic materials 0.000 claims description 28
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
239000000203 mixture Substances 0.000 claims description 11
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 8
239000000377 silicon dioxide Substances 0.000 claims description 7
239000013078 crystal Substances 0.000 claims description 6
229930195733 hydrocarbon Natural products 0.000 claims description 6
150000002430 hydrocarbons Chemical class 0.000 claims description 6
239000010687 lubricating oil Substances 0.000 claims description 3
239000000314 lubricant Substances 0.000 claims description 2
238000007792 addition Methods 0.000 claims 1
239000007788 liquid Substances 0.000 abstract description 5
238000002441 X-ray diffraction Methods 0.000 description 7
239000011159 matrix material Substances 0.000 description 6
238000001354 calcination Methods 0.000 description 5
239000000047 product Substances 0.000 description 5
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000000463 material Substances 0.000 description 4
150000001340 alkali metals Chemical group 0.000 description 3
229910000323 aluminium silicate Inorganic materials 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
238000005342 ion exchange Methods 0.000 description 3
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
235000012211 aluminium silicate Nutrition 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
239000002585 base Substances 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
150000002892 organic cations Chemical class 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
239000005995 Aluminium silicate Substances 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
238000010306 acid treatment Methods 0.000 description 1
HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical group O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
238000005899 aromatization reaction Methods 0.000 description 1
LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
238000007385 chemical modification Methods 0.000 description 1
239000004927 clay Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
229910001649 dickite Inorganic materials 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
239000000499 gel Substances 0.000 description 1
229910052621 halloysite Inorganic materials 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
-1 i.e. Substances 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052622 kaolinite Inorganic materials 0.000 description 1
239000011707 mineral Substances 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
150000002910 rare earth metals Chemical class 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000001603 reducing effect Effects 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
238000007669 thermal treatment Methods 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
- C10G50/02—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation of hydrocarbon oils for lubricating purposes

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

CA000462275A 1983-09-19 1984-08-31 Process for the conversion of olefinic compounds into high viscosity lubes Expired CA1227501A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US53372283A	1983-09-19	1983-09-19
US533,722		1983-09-19

Publications (1)

Publication Number	Publication Date
CA1227501A true CA1227501A (en)	1987-09-29

Family

ID=24127185

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000462275A Expired CA1227501A (en)	1983-09-19	1984-08-31	Process for the conversion of olefinic compounds into high viscosity lubes

Country Status (7)

Country	Link
EP (1)	EP0135385B1 (de)
JP (1)	JPS6088090A (de)
AU (1)	AU571575B2 (de)
BR (1)	BR8404675A (de)
CA (1)	CA1227501A (de)
NZ (1)	NZ209388A (de)
ZA (1)	ZA847384B (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4520221A (en) *	1984-04-09	1985-05-28	Mobil Oil Corporation	Process of making high VI lubes
US4891457A (en) *	1985-09-13	1990-01-02	Hartley Owen	Multistage process for converting olefins to heavier hydrocarbons
LU86280A1 (fr) *	1986-01-29	1987-09-03	Labofina Sa	Procede de production d'essence
US5112519A (en) *	1989-06-05	1992-05-12	Mobil Oil Corporation	Process for production of biodegradable surfactants and compositions thereof
CN110605139A (zh) *	2019-09-21	2019-12-24	合肥神舟催化净化器股份有限公司	一种稳定性高的汽车尾气净化催化剂的制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3827968A (en) *	1973-01-11	1974-08-06	Mobil Oil Corp	Aromatization process
US4150062A (en) *	1976-12-20	1979-04-17	Mobil Oil Corporation	Light olefin processing
US4227992A (en) *	1979-05-24	1980-10-14	Mobil Oil Corporation	Process for separating ethylene from light olefin mixtures while producing both gasoline and fuel oil
US4211640A (en) *	1979-05-24	1980-07-08	Mobil Oil Corporation	Process for the treatment of olefinic gasoline
US4414423A (en) *	1981-09-25	1983-11-08	Chevron Research Company	Multistep oligomerization process
EP0089795B1 (de) *	1982-03-18	1987-03-25	Mobil Oil Corporation	Verfahren zur Umwandlung von Olefinen zu Schmiermitteln mit hohem Viskositätsindex
ZA831922B (en) *	1982-03-19	1984-11-28	Mobil Oil Corp	Process for converting olefins to high viscosity index lubricants using large crystal zeolites

1984
- 1984-08-30 NZ NZ209388A patent/NZ209388A/en unknown
- 1984-08-31 CA CA000462275A patent/CA1227501A/en not_active Expired
- 1984-09-04 EP EP84306041A patent/EP0135385B1/en not_active Expired
- 1984-09-11 AU AU32910/84A patent/AU571575B2/en not_active Ceased
- 1984-09-18 BR BR8404675A patent/BR8404675A/pt unknown
- 1984-09-19 JP JP59194935A patent/JPS6088090A/ja active Pending
- 1984-09-19 ZA ZA847384A patent/ZA847384B/xx unknown

Also Published As

Publication number	Publication date
JPS6088090A (ja)	1985-05-17
EP0135385A3 (de)	1986-03-12
AU571575B2 (en)	1988-04-21
BR8404675A (pt)	1985-08-13
EP0135385B1 (en)	1989-10-11
EP0135385A2 (de)	1985-03-27
ZA847384B (en)	1986-05-28
AU3291084A (en)	1985-03-28
NZ209388A (en)	1987-02-20

Legal Events

Date	Code	Title	Description
2004-09-29	MKEX	Expiry

Publication	Publication Date	Title
US4594146A (en)	1986-06-10	Conversion with zeolite catalysts prepared by steam treatment
CA1207734A (en)	1986-07-15	Active zeolite catalysts of improved stability
EP0095303B1 (de)	1986-04-30	Katalytisches Entparaffinerungsverfahren
US5171916A (en)	1992-12-15	Light cycle oil conversion
CA1144951A (en)	1983-04-19	Oligomerization of olefins
CA1262363A (en)	1989-10-17	Aromatization reactions with zeolites
US4520221A (en)	1985-05-28	Process of making high VI lubes
US4851602A (en)	1989-07-25	Alkanes and alkenes conversion to high octane gasoline
US4501926A (en)	1985-02-26	Catalytic dewaxing process with zeolite beta
US4547613A (en)	1985-10-15	Process for converting olefins to high viscosity index lubricants
US4282085A (en)	1981-08-04	Petroleum distillate upgrading process
US4377469A (en)	1983-03-22	Maintaining catalytic activity of sodium aluminosilicates
US5554274A (en)	1996-09-10	Manufacture of improved catalyst
AU6160100A (en)	2001-02-13	Process for preparing a lubricating base oil
US5234875A (en)	1993-08-10	Coke-selectivated porous acidic crystalline catalyst, its preparation, and use in olefin oligomerization
US4868146A (en)	1989-09-19	Zeolite catalyst composition and synthesis method
AU6087594A (en)	1995-08-01	A catalytic cracking process
CA1181355A (en)	1985-01-22	Method for enhancing catalytic activity
US5000840A (en)	1991-03-19	Catalytic dewaxing lubricating oil stock derived from oligomerized olefin
US5250484A (en)	1993-10-05	Surface modified porous acidic crystalline catalyst
US4448673A (en)	1984-05-15	Aging resistance shape selective catalyst with enhanced activity
NZ210604A (en)	1988-02-29	Two-stage, two-catalyst process for synthesising lubricating oils
AU618026B2 (en)	1991-12-12	Crystalline zeolite containing intermetallic component and use as catalyst in hydrocarbon conversions
US4547609A (en)	1985-10-15	Multi-stage process for the conversion of olefins into high viscosity lubricants
US4483760A (en)	1984-11-20	Process for dewaxing middle distillates