CA1231612A - Detergents a teneur d'halogene actif stabilise, leur fabrication et leur emploi - Google Patents

Detergents a teneur d'halogene actif stabilise, leur fabrication et leur emploi

Info

Publication number: CA1231612A
Authority: CA; Canada
Prior art keywords: sulfonamide; group; halogen; detergent; water
Prior art date: 1984-06-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000474405A

Other languages

English (en)

Inventor

Anthony J. Bruegge

Denny E. Daugherty

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Chemed Corp

Original Assignee

Chemed Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-06-19

Filing date

1985-02-15

Publication date

1988-01-19

1985-02-15 Application filed by Chemed Corp filed Critical Chemed Corp

1988-01-19 Application granted granted Critical

1988-01-19 Publication of CA1231612A publication Critical patent/CA1231612A/fr

Status Expired legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims abstract description 84
229910052736 halogen Inorganic materials 0.000 title claims abstract description 59
150000002367 halogens Chemical class 0.000 title claims abstract description 55
239000000203 mixture Substances 0.000 title claims abstract description 34
238000000034 method Methods 0.000 title claims abstract description 15
229940124530 sulfonamide Drugs 0.000 claims abstract description 70
150000003456 sulfonamides Chemical class 0.000 claims abstract description 58
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims abstract description 25
239000007864 aqueous solution Substances 0.000 claims abstract description 19
239000013042 solid detergent Substances 0.000 claims abstract description 15
229920000867 polyelectrolyte Polymers 0.000 claims abstract description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 49
239000000243 solution Substances 0.000 claims description 37
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 34
239000000460 chlorine Substances 0.000 claims description 34
229910052801 chlorine Inorganic materials 0.000 claims description 34
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 29
239000007787 solid Substances 0.000 claims description 15
229910000029 sodium carbonate Inorganic materials 0.000 claims description 14
-1 alkylaryl sulfonamides Chemical class 0.000 claims description 13
238000002156 mixing Methods 0.000 claims description 13
229910052739 hydrogen Inorganic materials 0.000 claims description 7
229910021645 metal ion Inorganic materials 0.000 claims description 7
239000003513 alkali Substances 0.000 claims description 6
150000003839 salts Chemical class 0.000 claims description 6
229910019142 PO4 Inorganic materials 0.000 claims description 5
229910001413 alkali metal ion Inorganic materials 0.000 claims description 5
229910001420 alkaline earth metal ion Inorganic materials 0.000 claims description 5
150000007973 cyanuric acids Chemical class 0.000 claims description 5
150000001469 hydantoins Chemical class 0.000 claims description 5
150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 5
125000004422 alkyl sulphonamide group Chemical group 0.000 claims description 4
239000010452 phosphate Substances 0.000 claims description 4
235000021317 phosphate Nutrition 0.000 claims description 4
LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 claims description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
125000000217 alkyl group Chemical group 0.000 claims 4
125000004421 aryl sulphonamide group Chemical group 0.000 claims 4
230000000087 stabilizing effect Effects 0.000 claims 3
229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
150000001342 alkaline earth metals Chemical class 0.000 claims 1
239000013530 defoamer Substances 0.000 claims 1
229910000000 metal hydroxide Inorganic materials 0.000 claims 1
150000004692 metal hydroxides Chemical class 0.000 claims 1
239000002002 slurry Substances 0.000 abstract description 13
230000000694 effects Effects 0.000 abstract description 7
239000000945 filler Substances 0.000 abstract description 3
150000004679 hydroxides Chemical class 0.000 abstract 1
230000002035 prolonged effect Effects 0.000 abstract 1
229960001479 tosylchloramide sodium Drugs 0.000 description 35
VDQQXEISLMTGAB-UHFFFAOYSA-N chloramine T Chemical compound [Na+].CC1=CC=C(S(=O)(=O)[N-]Cl)C=C1 VDQQXEISLMTGAB-UHFFFAOYSA-N 0.000 description 33
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 17
235000019832 sodium triphosphate Nutrition 0.000 description 13
238000004061 bleaching Methods 0.000 description 12
235000017550 sodium carbonate Nutrition 0.000 description 12
241000243251 Hydra Species 0.000 description 11
239000004115 Sodium Silicate Substances 0.000 description 11
QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 11
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 11
229910052911 sodium silicate Inorganic materials 0.000 description 11
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 11
239000005708 Sodium hypochlorite Substances 0.000 description 10
150000001875 compounds Chemical class 0.000 description 10
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 10
239000001488 sodium phosphate Substances 0.000 description 10
235000019795 sodium metasilicate Nutrition 0.000 description 9
239000004744 fabric Substances 0.000 description 8
229910000406 trisodium phosphate Inorganic materials 0.000 description 8
235000019801 trisodium phosphate Nutrition 0.000 description 8
229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 7
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 7
229920000058 polyacrylate Polymers 0.000 description 6
230000006641 stabilisation Effects 0.000 description 6
238000011105 stabilization Methods 0.000 description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
235000011121 sodium hydroxide Nutrition 0.000 description 5
235000019830 sodium polyphosphate Nutrition 0.000 description 5
239000011734 sodium Substances 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
125000000565 sulfonamide group Chemical group 0.000 description 4
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
239000011591 potassium Substances 0.000 description 3
229910052700 potassium Inorganic materials 0.000 description 3
239000004094 surface-active agent Substances 0.000 description 3
238000012360 testing method Methods 0.000 description 3
238000005406 washing Methods 0.000 description 3
YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 2
ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 2
229920000742 Cotton Polymers 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
244000269722 Thea sinensis Species 0.000 description 2
229920000180 alkyd Polymers 0.000 description 2
229910021538 borax Inorganic materials 0.000 description 2
150000004649 carbonic acid derivatives Chemical class 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
229910001919 chlorite Inorganic materials 0.000 description 2
229910052619 chlorite group Inorganic materials 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 description 2
238000010494 dissociation reaction Methods 0.000 description 2
230000005593 dissociations Effects 0.000 description 2
238000009472 formulation Methods 0.000 description 2
239000008233 hard water Substances 0.000 description 2
229940091173 hydantoin Drugs 0.000 description 2
238000006703 hydration reaction Methods 0.000 description 2
238000010348 incorporation Methods 0.000 description 2
229910052816 inorganic phosphate Inorganic materials 0.000 description 2
229920000728 polyester Polymers 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
239000004328 sodium tetraborate Substances 0.000 description 2
235000010339 sodium tetraborate Nutrition 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
238000004448 titration Methods 0.000 description 2
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
OFTZZDZZNXTWFO-UHFFFAOYSA-N 1,3-dichloro-5-ethyl-5-methylimidazolidine-2,4-dione Chemical compound CCC1(C)N(Cl)C(=O)N(Cl)C1=O OFTZZDZZNXTWFO-UHFFFAOYSA-N 0.000 description 1
CTKZXPQQBVOAGH-UHFFFAOYSA-N 1,3-dichloro-5-methyl-5-(2-methylpropyl)imidazolidine-2,4-dione Chemical compound CC(C)CC1(C)N(Cl)C(=O)N(Cl)C1=O CTKZXPQQBVOAGH-UHFFFAOYSA-N 0.000 description 1
SJWDWCUVDYUSCL-UHFFFAOYSA-N 1-bromo-3-chloroimidazolidine-2,4-dione Chemical compound ClN1C(=O)CN(Br)C1=O SJWDWCUVDYUSCL-UHFFFAOYSA-N 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
244000007853 Sarothamnus scoparius Species 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
239000003518 caustics Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
JSYGRUBHOCKMGQ-UHFFFAOYSA-N dichloramine Chemical compound ClNCl JSYGRUBHOCKMGQ-UHFFFAOYSA-N 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
TUCSOESCAKHLJM-UHFFFAOYSA-L dipotassium carbonic acid carbonate Chemical compound [K+].[K+].OC(O)=O.OC(O)=O.[O-]C([O-])=O TUCSOESCAKHLJM-UHFFFAOYSA-L 0.000 description 1
BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
229910000397 disodium phosphate Inorganic materials 0.000 description 1
235000019800 disodium phosphate Nutrition 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000003292 glue Substances 0.000 description 1
150000004688 heptahydrates Chemical class 0.000 description 1
WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 1
230000036571 hydration Effects 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
229940060367 inert ingredients Drugs 0.000 description 1
229910052909 inorganic silicate Inorganic materials 0.000 description 1
239000002563 ionic surfactant Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000006194 liquid suspension Substances 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
LWXVCCOAQYNXNX-UHFFFAOYSA-N lithium hypochlorite Chemical compound [Li+].Cl[O-] LWXVCCOAQYNXNX-UHFFFAOYSA-N 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
150000004689 octahydrates Chemical class 0.000 description 1
239000002245 particle Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
235000011181 potassium carbonates Nutrition 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000010458 rotten stone Substances 0.000 description 1
238000011012 sanitization Methods 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
235000015424 sodium Nutrition 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
229910000162 sodium phosphate Inorganic materials 0.000 description 1
235000011008 sodium phosphates Nutrition 0.000 description 1
229940048086 sodium pyrophosphate Drugs 0.000 description 1
235000019351 sodium silicates Nutrition 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000011550 stock solution Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229950009390 symclosene Drugs 0.000 description 1
238000010998 test method Methods 0.000 description 1
RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
CBNBGETWKBUTEL-UHFFFAOYSA-K tripotassium;phosphate;heptahydrate Chemical compound O.O.O.O.O.O.O.[K+].[K+].[K+].[O-]P([O-])([O-])=O CBNBGETWKBUTEL-UHFFFAOYSA-K 0.000 description 1
KPZYAGQLBFUTMA-UHFFFAOYSA-K tripotassium;phosphate;trihydrate Chemical compound O.O.O.[K+].[K+].[K+].[O-]P([O-])([O-])=O KPZYAGQLBFUTMA-UHFFFAOYSA-K 0.000 description 1
BPFZWBABAJEKEO-UHFFFAOYSA-K trisodium;phosphate;hexahydrate Chemical compound O.O.O.O.O.O.[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O BPFZWBABAJEKEO-UHFFFAOYSA-K 0.000 description 1
GSQTXLAHEVFYSA-UHFFFAOYSA-K trisodium;phosphate;octahydrate Chemical compound O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O GSQTXLAHEVFYSA-UHFFFAOYSA-K 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3951—Bleaching agents combined with specific additives

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CA000474405A 1984-06-19 1985-02-15 Detergents a teneur d'halogene actif stabilise, leur fabrication et leur emploi Expired CA1231612A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US62219984A	1984-06-19	1984-06-19
US622,199		1984-06-19

Publications (1)

Publication Number	Publication Date
CA1231612A true CA1231612A (fr)	1988-01-19

Family

ID=24493276

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000474405A Expired CA1231612A (fr)	1984-06-19	1985-02-15	Detergents a teneur d'halogene actif stabilise, leur fabrication et leur emploi

Country Status (3)

Country	Link
EP (1)	EP0165676A3 (fr)
JP (1)	JPH0742480B2 (fr)
CA (1)	CA1231612A (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5066416A (en) *	1987-08-31	1991-11-19	Olin Corporation	Process for producing moldable detergents having a stable available chlorine concentration
SE465958B (sv) *	1988-09-26	1991-11-25	Sandvik Ab	Dubbelsidigt skaer
NZ237301A (en) *	1990-03-13	1992-09-25	Colgate Palmolive Co	Aqueous automatic dishwasher detergent compositions comprising potassium tripolyphosphate, cross-linked polycarboxylate-type thickener and sodium ions
WO1996027651A1 (fr) *	1995-03-03	1996-09-12	The Procter & Gamble Company	Compositions nettoyantes reduisant les mauvaises odeurs sur la peau
JP2002060798A (ja) *	2000-08-17	2002-02-26	Asahi Denka Kogyo Kk	溶融型固形洗浄剤組成物およびその製造方法
WO2006010421A1 (fr) *	2004-07-27	2006-02-02	Unilever N.V.	Compositions de blanchiment liquides aqueuses

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE437383A (fr) *	1938-12-24
NL203752A (fr) *	1955-01-18
JPS5115038A (ja) *	1974-07-22	1976-02-06	Hironori Hirai	Oopunendoseiboki

1985
- 1985-02-15 CA CA000474405A patent/CA1231612A/fr not_active Expired
- 1985-04-26 EP EP85302981A patent/EP0165676A3/fr not_active Withdrawn
- 1985-06-18 JP JP60132889A patent/JPH0742480B2/ja not_active Expired - Lifetime

Also Published As

Publication number	Publication date
JPS6114299A (ja)	1986-01-22
EP0165676A2 (fr)	1985-12-27
EP0165676A3 (fr)	1987-08-19
JPH0742480B2 (ja)	1995-05-10

Legal Events

Date	Code	Title	Description
2005-02-15	MKEX	Expiry

Publication	Publication Date	Title
US4681696A (en)	1987-07-21	Solid stabilized active halogen-containing detergent compositions and methods
US4289640A (en)	1981-09-15	Cleaning compositions
EP1056828B1 (fr)	2007-07-18	Composition de blanchiment au chlore acide stabilisee et procede d'utilisation
CA1095802A (fr)	1981-02-17	Nettoyant
EP0178893B1 (fr)	1992-01-22	Compositions détergentes solides
US3306858A (en)	1967-02-28	Process for the preparation of storage stable detergent composition
US5057236A (en)	1991-10-15	Surfactant ion pair fluorescent whitener compositions
US4992195A (en)	1991-02-12	Dishwashing composition
US5981461A (en)	1999-11-09	Cleaning compositions containing a halogen bleaching agent and a sulfosuccinate salt
CA2007380C (fr)	1997-03-04	Detergent liquide contenant une enzyme et un systeme de stabilisation
JP2562064B2 (ja)	1996-12-11	漂白組成物
CA1231612A (fr)	1988-01-19	Detergents a teneur d'halogene actif stabilise, leur fabrication et leur emploi
CA1337146C (fr)	1995-10-03	Solubilisation d'un azurant dans l'hypochlorite liquide
JPH0640709A (ja)	1994-02-15	安定な過炭酸ソーダ及びその製造法並びに安定な過炭酸ソーダを含有する漂白洗浄剤組成物
EP0121286B1 (fr)	1989-07-19	Agent de nettoyage à base de chlore actif et de composés alcalins
US3303104A (en)	1967-02-07	Compositions containing discoloration inhibitors
JP2869310B2 (ja)	1999-03-10	安定な過炭酸ソーダ及びその製造方法並びに安定な過炭酸ソーダを含有してなる漂白洗浄剤組成物
EP0368100A2 (fr)	1990-05-16	Composition particulaire contenant un agent de blanchiment et un éclaircissant optique, et son procédé de préparation
US5066416A (en)	1991-11-19	Process for producing moldable detergents having a stable available chlorine concentration
JPH04363400A (ja)	1992-12-16	非イオン性粉末洗浄剤組成物
JP2559062B2 (ja)	1996-11-27	着色剤含有水性アルカリ金属亜塩素酸塩組成物
CA1046388A (fr)	1979-01-16	Prevention de decoloration, solutions caustiques contaminees par le nickel
US3578600A (en)	1971-05-11	Stabilization of n-chloro-imides
US4973424A (en)	1990-11-27	Bleaching and sanitizing compositions
JP2003073693A (ja)	2003-03-12	溶融型固形洗浄剤組成物及びその製造方法