CA1243074A - Composition d'ionomeres mixtes pour cloisons d'accumulateurs - Google Patents

Composition d'ionomeres mixtes pour cloisons d'accumulateurs

Info

Publication number: CA1243074A
Authority: CA; Canada
Prior art keywords: copolymer; acrylic acid; melt index; acid; mole percent
Prior art date: 1982-09-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000541642A

Other languages

English (en)

Inventor

Walter R. Wszolek

Joseph T. Lundquist, Jr.

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

WR Grace and Co

Original Assignee

WR Grace and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-09-02

Filing date

1987-07-08

Publication date

1988-10-11

1982-09-02 Priority claimed from US06/414,004 external-priority patent/US4434215A/en

1987-07-08 Application filed by WR Grace and Co filed Critical WR Grace and Co

1987-07-08 Priority to CA000541642A priority Critical patent/CA1243074A/fr

1988-10-11 Application granted granted Critical

1988-10-11 Publication of CA1243074A publication Critical patent/CA1243074A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 38
229920000554 ionomer Polymers 0.000 title 1
229920001577 copolymer Polymers 0.000 claims abstract description 63
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 44
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 41
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 21
239000005977 Ethylene Substances 0.000 claims abstract description 21
239000000463 material Substances 0.000 claims description 26
239000012528 membrane Substances 0.000 claims description 26
239000002253 acid Substances 0.000 claims description 15
229920000098 polyolefin Polymers 0.000 claims description 15
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 14
-1 alkaline earth metal cation Chemical class 0.000 claims description 14
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 13
239000003513 alkali Substances 0.000 claims description 8
239000011148 porous material Substances 0.000 claims description 8
239000003792 electrolyte Substances 0.000 claims description 7
239000004014 plasticizer Substances 0.000 claims description 7
239000000945 filler Substances 0.000 claims description 6
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
239000002245 particle Substances 0.000 claims description 3
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
238000000034 method Methods 0.000 abstract description 13
239000000155 melt Substances 0.000 abstract description 4
239000008240 homogeneous mixture Substances 0.000 abstract description 2
KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 14
210000001787 dendrite Anatomy 0.000 description 12
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 9
229910052725 zinc Inorganic materials 0.000 description 9
239000011701 zinc Substances 0.000 description 9
230000015572 biosynthetic process Effects 0.000 description 7
229920000642 polymer Polymers 0.000 description 7
230000005764 inhibitory process Effects 0.000 description 6
239000000178 monomer Substances 0.000 description 6
230000035515 penetration Effects 0.000 description 6
239000004698 Polyethylene Substances 0.000 description 5
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
229920000573 polyethylene Polymers 0.000 description 4
238000012545 processing Methods 0.000 description 4
239000000243 solution Substances 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
239000004716 Ethylene/acrylic acid copolymer Substances 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
230000012010 growth Effects 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
239000011159 matrix material Substances 0.000 description 3
QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
230000004580 weight loss Effects 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
239000004743 Polypropylene Substances 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
125000005907 alkyl ester group Chemical group 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
239000002131 composite material Substances 0.000 description 2
230000007547 defect Effects 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 2
230000001747 exhibiting effect Effects 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
229910010272 inorganic material Inorganic materials 0.000 description 2
239000011147 inorganic material Substances 0.000 description 2
239000010954 inorganic particle Substances 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
HTQOEHYNHFXMJJ-UHFFFAOYSA-N oxosilver zinc Chemical compound [Zn].[Ag]=O HTQOEHYNHFXMJJ-UHFFFAOYSA-N 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
239000002243 precursor Substances 0.000 description 2
238000012216 screening Methods 0.000 description 2
238000012360 testing method Methods 0.000 description 2
239000011787 zinc oxide Substances 0.000 description 2
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
229920002799 BoPET Polymers 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
208000032953 Device battery issue Diseases 0.000 description 1
239000004593 Epoxy Chemical class 0.000 description 1
GVGLGOZIDCSQPN-PVHGPHFFSA-N Heroin Chemical compound O([C@H]1[C@H](C=C[C@H]23)OC(C)=O)C4=C5[C@@]12CCN(C)[C@@H]3CC5=CC=C4OC(C)=O GVGLGOZIDCSQPN-PVHGPHFFSA-N 0.000 description 1
239000013032 Hydrocarbon resin Substances 0.000 description 1
239000005041 Mylar™ Substances 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
229920002367 Polyisobutene Polymers 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
239000011149 active material Substances 0.000 description 1
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
238000007605 air drying Methods 0.000 description 1
229910001854 alkali hydroxide Inorganic materials 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
239000010426 asphalt Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000011437 continuous method Methods 0.000 description 1
230000001351 cycling effect Effects 0.000 description 1
230000008021 deposition Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
229960002069 diamorphine Drugs 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
229920006270 hydrocarbon resin Polymers 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
239000003999 initiator Substances 0.000 description 1
230000001788 irregular Effects 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
239000002648 laminated material Substances 0.000 description 1
235000021388 linseed oil Nutrition 0.000 description 1
239000000944 linseed oil Substances 0.000 description 1
239000010687 lubricating oil Substances 0.000 description 1
101150054634 melk gene Proteins 0.000 description 1
150000004702 methyl esters Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
150000002895 organic esters Chemical class 0.000 description 1
239000011368 organic material Substances 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
230000035699 permeability Effects 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
125000005498 phthalate group Chemical class 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
238000003825 pressing Methods 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000010526 radical polymerization reaction Methods 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical class OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
BSWGGJHLVUUXTL-UHFFFAOYSA-N silver zinc Chemical compound [Zn].[Ag] BSWGGJHLVUUXTL-UHFFFAOYSA-N 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
230000008961 swelling Effects 0.000 description 1
150000003505 terpenes Chemical class 0.000 description 1
235000007586 terpenes Nutrition 0.000 description 1
238000012546 transfer Methods 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
238000005303 weighing Methods 0.000 description 1
238000009736 wetting Methods 0.000 description 1
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

Landscapes

Cell Separators (AREA)

CA000541642A 1982-09-02 1987-07-08 Composition d'ionomeres mixtes pour cloisons d'accumulateurs Expired CA1243074A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000541642A CA1243074A (fr)	1982-09-02	1987-07-08	Composition d'ionomeres mixtes pour cloisons d'accumulateurs

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US414,004		1982-09-02
US06/414,004 US4434215A (en)	1982-09-02	1982-09-02	Battery separator
CA000428045A CA1228949A (fr)	1982-09-02	1983-05-12	Composition d'ionomeres pour separateurs d'accumulateurs
CA000541642A CA1243074A (fr)	1982-09-02	1987-07-08	Composition d'ionomeres mixtes pour cloisons d'accumulateurs

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000428045A Division CA1228949A (fr)	1982-09-02	1983-05-12	Composition d'ionomeres pour separateurs d'accumulateurs

Publications (1)

Publication Number	Publication Date
CA1243074A true CA1243074A (fr)	1988-10-11

Family

ID=25670032

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000541642A Expired CA1243074A (fr)	1982-09-02	1987-07-08	Composition d'ionomeres mixtes pour cloisons d'accumulateurs

Country Status (1)

Country	Link
CA (1)	CA1243074A (fr)

1987
- 1987-07-08 CA CA000541642A patent/CA1243074A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2005-10-11	MKEX	Expiry

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