CA1244305A - Composante de carbone-graphite pour cellule electrochimique; procede pour obtenir la composante - Google Patents
Composante de carbone-graphite pour cellule electrochimique; procede pour obtenir la composanteInfo
- Publication number
- CA1244305A CA1244305A CA000512660A CA512660A CA1244305A CA 1244305 A CA1244305 A CA 1244305A CA 000512660 A CA000512660 A CA 000512660A CA 512660 A CA512660 A CA 512660A CA 1244305 A CA1244305 A CA 1244305A
- Authority
- CA
- Canada
- Prior art keywords
- cellulose fibers
- resin
- pore size
- controlled pore
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910002804 graphite Inorganic materials 0.000 title claims abstract description 31
- 239000010439 graphite Substances 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 26
- 239000011148 porous material Substances 0.000 claims abstract description 73
- 229920005989 resin Polymers 0.000 claims abstract description 66
- 239000011347 resin Substances 0.000 claims abstract description 66
- 229920003043 Cellulose fiber Polymers 0.000 claims abstract description 64
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 63
- 239000000446 fuel Substances 0.000 claims abstract description 38
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 34
- 239000002243 precursor Substances 0.000 claims abstract description 34
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 229920002678 cellulose Polymers 0.000 claims abstract description 9
- 239000001913 cellulose Substances 0.000 claims abstract description 9
- 238000000151 deposition Methods 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims description 24
- 229920001187 thermosetting polymer Polymers 0.000 claims description 21
- 238000010438 heat treatment Methods 0.000 claims description 20
- 239000003054 catalyst Substances 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 18
- 239000000835 fiber Substances 0.000 claims description 16
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 11
- 229920001568 phenolic resin Polymers 0.000 claims description 11
- 239000005011 phenolic resin Substances 0.000 claims description 11
- 239000002002 slurry Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 239000000725 suspension Substances 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 210000004027 cell Anatomy 0.000 description 49
- 239000003792 electrolyte Substances 0.000 description 39
- 239000000758 substrate Substances 0.000 description 22
- 239000007789 gas Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
- 239000012535 impurity Substances 0.000 description 9
- 239000007800 oxidant agent Substances 0.000 description 8
- 230000001590 oxidative effect Effects 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000003763 carbonization Methods 0.000 description 6
- 239000002826 coolant Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 238000007789 sealing Methods 0.000 description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 210000001724 microfibril Anatomy 0.000 description 4
- 230000002093 peripheral effect Effects 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000004917 carbon fiber Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000003487 electrochemical reaction Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002918 waste heat Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000007567 mass-production technique Methods 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Chemical compound CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 229940099990 ogen Drugs 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000002470 thermal conductor Substances 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
- C04B35/83—Carbon fibres in a carbon matrix
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/96—Carbon-based electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0289—Means for holding the electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Electrochemistry (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
- Ceramic Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75171385A | 1985-07-02 | 1985-07-02 | |
| US751,713 | 1985-07-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1244305A true CA1244305A (fr) | 1988-11-08 |
Family
ID=25023165
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000512660A Expired CA1244305A (fr) | 1985-07-02 | 1986-06-27 | Composante de carbone-graphite pour cellule electrochimique; procede pour obtenir la composante |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS627617A (fr) |
| CA (1) | CA1244305A (fr) |
| DE (1) | DE3621936A1 (fr) |
| FR (1) | FR2584535A1 (fr) |
| GB (1) | GB2177387B (fr) |
| NL (1) | NL8601505A (fr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4670300A (en) * | 1985-07-03 | 1987-06-02 | International Fuel Cells Corporation | Carbon-graphite component for an electrochemical cell and method for making the component |
| JPH0311556A (ja) * | 1989-06-07 | 1991-01-18 | Fuji Electric Co Ltd | 燃料電池の電解質リザーバ構造 |
| US5300124A (en) * | 1993-03-31 | 1994-04-05 | International Fuel Cells Corporation | Method for forming a laminated electrolyte reservoir plate |
| US5558955A (en) * | 1994-10-07 | 1996-09-24 | International Fuel Cells Corporation | Cathode reactant flow field component for a fuel cell stack |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB642744A (en) * | 1947-08-08 | 1950-09-13 | India Rubber Gutta Percha & Te | Improvements in or relating to porous pots for primary electric cells |
| US3174895A (en) * | 1960-09-07 | 1965-03-23 | Union Carbide Corp | Graphite cloth laminates |
| GB1069625A (en) * | 1962-12-04 | 1967-05-24 | Borden Chemical Company U K Lt | Improvements in or relating to the manufacture of synthetic resin articles reinforced with fibrous material |
| GB1092271A (en) * | 1963-05-22 | 1967-11-22 | Eisler Paul | Improvements relating to electrode structures for electrochemical systems |
| GB1075226A (en) * | 1964-12-03 | 1967-07-12 | Ship Carbon Company Of Great B | Resin carbonisation |
| FR1493696A (fr) * | 1966-07-20 | 1967-09-01 | Lorraine Carbone | Procédé de fabrication de stratifiés en textiles de carbone et de graphite |
| US3539446A (en) * | 1967-12-29 | 1970-11-10 | Rochester Paper Co | Oil filter paper including phenolic resin and chrome oxide and method for making same |
| DE2104680A1 (de) * | 1971-02-02 | 1972-08-10 | Sigri Elektrographit Gmbh | Verfahren zur Herstellung von Kohlenstoffkörpern |
| FR2143654B1 (fr) * | 1971-06-26 | 1974-07-26 | Sigri Elektrographit Gmbh | |
| US4041116A (en) * | 1973-05-15 | 1977-08-09 | Great Lakes Carbon Corporation | Method for the manufacture of carbon-carbon composites |
| JPS5318603B2 (fr) * | 1973-07-10 | 1978-06-16 | ||
| GB1421672A (en) * | 1973-08-24 | 1976-01-21 | Atomic Energy Authority Uk | Carbon composites |
| US4064207A (en) * | 1976-02-02 | 1977-12-20 | United Technologies Corporation | Fibrillar carbon fuel cell electrode substrates and method of manufacture |
| GB1522280A (en) * | 1976-06-01 | 1978-08-23 | Hollingsworth & Vose Co | Filter medium and method of making same |
| JPS5354193A (en) * | 1976-10-28 | 1978-05-17 | Philips Nv | Manufacture of carbon materials |
| DE2828918C2 (de) * | 1977-07-16 | 1982-07-15 | Aisin Chemical Co. Ltd., Kariya, Aichi | Verfahren zur Herstellung eines Reibungsmaterials auf Papierbasis |
| US4360485A (en) * | 1980-08-25 | 1982-11-23 | United Technologies Corporation | Method for making improved separator plates for electrochemical cells |
| JPS60122711A (ja) * | 1983-12-08 | 1985-07-01 | Oji Paper Co Ltd | 多孔質炭素板の製造方法 |
| JPS60189168A (ja) * | 1984-03-06 | 1985-09-26 | Toshiba Corp | 燃料電池電極用多孔質板 |
| JPS60231470A (ja) * | 1984-04-16 | 1985-11-18 | 昭和電工株式会社 | 緻密な炭素材の製造法 |
-
1986
- 1986-06-09 GB GB8613977A patent/GB2177387B/en not_active Expired
- 1986-06-10 NL NL8601505A patent/NL8601505A/nl not_active Application Discontinuation
- 1986-06-24 JP JP61149334A patent/JPS627617A/ja active Pending
- 1986-06-27 CA CA000512660A patent/CA1244305A/fr not_active Expired
- 1986-06-30 FR FR8609457A patent/FR2584535A1/fr not_active Withdrawn
- 1986-06-30 DE DE19863621936 patent/DE3621936A1/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| DE3621936A1 (de) | 1987-01-08 |
| GB8613977D0 (en) | 1986-07-16 |
| GB2177387A (en) | 1987-01-21 |
| FR2584535A1 (fr) | 1987-01-09 |
| JPS627617A (ja) | 1987-01-14 |
| NL8601505A (nl) | 1987-02-02 |
| GB2177387B (en) | 1989-07-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |