CA1246923A - Self-fixing imaging film containing reductant precursor - Google Patents

Self-fixing imaging film containing reductant precursor

Info

Publication number: CA1246923A
Authority: CA; Canada
Prior art keywords: film; tellurium; recited; reductant; imaging
Prior art date: 1982-07-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000432727A

Other languages

English (en)

French (fr)

Inventor

Terry T. Yu

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Energy Conversion Devices Inc

Original Assignee

Energy Conversion Devices Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-07-26

Filing date

1983-07-19

Publication date

1988-12-20

1983-07-19 Application filed by Energy Conversion Devices Inc filed Critical Energy Conversion Devices Inc

1988-12-20 Application granted granted Critical

1988-12-20 Publication of CA1246923A publication Critical patent/CA1246923A/en

Status Expired legal-status Critical Current

Links

238000003384 imaging method Methods 0.000 title claims abstract description 91
239000003638 chemical reducing agent Substances 0.000 title claims description 129
239000002243 precursor Substances 0.000 title claims description 88
239000000203 mixture Substances 0.000 claims abstract description 67
229910052714 tellurium Inorganic materials 0.000 claims abstract description 55
238000011161 development Methods 0.000 claims abstract description 26
150000001875 compounds Chemical class 0.000 claims description 67
-1 hydroxyalkyl-benzyl Chemical group 0.000 claims description 44
238000009740 moulding (composite fabrication) Methods 0.000 claims description 43
150000003498 tellurium compounds Chemical class 0.000 claims description 40
150000002009 diols Chemical class 0.000 claims description 38
PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 38
238000000034 method Methods 0.000 claims description 36
239000001257 hydrogen Substances 0.000 claims description 31
229910052739 hydrogen Inorganic materials 0.000 claims description 31
239000011159 matrix material Substances 0.000 claims description 26
230000018109 developmental process Effects 0.000 claims description 25
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 19
125000000217 alkyl group Chemical group 0.000 claims description 17
238000006243 chemical reaction Methods 0.000 claims description 11
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150000002367 halogens Chemical class 0.000 claims description 11
239000000758 substrate Substances 0.000 claims description 11
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
150000002430 hydrocarbons Chemical class 0.000 claims description 9
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125000003118 aryl group Chemical group 0.000 claims description 7
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238000010438 heat treatment Methods 0.000 claims description 7
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PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
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239000005864 Sulphur Chemical group 0.000 claims 1
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239000010408 film Substances 0.000 description 105
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239000000460 chlorine Substances 0.000 description 10
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235000019441 ethanol Nutrition 0.000 description 10
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239000000852 hydrogen donor Substances 0.000 description 9
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230000015572 biosynthetic process Effects 0.000 description 8
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GFCBQNWHJNGVSP-UHFFFAOYSA-N 2,3-di(propan-2-yloxy)naphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(OC(C)C)=C(OC(C)C)C(=O)C2=C1 GFCBQNWHJNGVSP-UHFFFAOYSA-N 0.000 description 4
SVPKNMBRVBMTLB-UHFFFAOYSA-N 2,3-dichloronaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(Cl)=C(Cl)C(=O)C2=C1 SVPKNMBRVBMTLB-UHFFFAOYSA-N 0.000 description 4
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RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
239000004480 active ingredient Substances 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
150000001412 amines Chemical class 0.000 description 4
150000004982 aromatic amines Chemical class 0.000 description 4
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 4
239000006227 byproduct Substances 0.000 description 4
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QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
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ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
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125000002837 carbocyclic group Chemical group 0.000 description 1
150000001721 carbon Chemical group 0.000 description 1
CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
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238000007278 cyanoethylation reaction Methods 0.000 description 1
150000001923 cyclic compounds Chemical class 0.000 description 1
150000001925 cycloalkenes Chemical class 0.000 description 1
ZXIJMRYMVAMXQP-UHFFFAOYSA-N cycloheptene Chemical compound C1CCC=CCC1 ZXIJMRYMVAMXQP-UHFFFAOYSA-N 0.000 description 1
KTPDXWCNXXKNBQ-UHFFFAOYSA-N cyclohexane;formaldehyde Chemical compound O=C.C1CCCCC1 KTPDXWCNXXKNBQ-UHFFFAOYSA-N 0.000 description 1
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HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
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WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
239000000386 donor Substances 0.000 description 1
238000010981 drying operation Methods 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
239000003822 epoxy resin Substances 0.000 description 1
229960004756 ethanol Drugs 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
229920001249 ethyl cellulose Polymers 0.000 description 1
235000019325 ethyl cellulose Nutrition 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
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239000000194 fatty acid Substances 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
235000001727 glucose Nutrition 0.000 description 1
239000008103 glucose Substances 0.000 description 1
PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
125000004970 halomethyl group Chemical group 0.000 description 1
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
231100001261 hazardous Toxicity 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
150000002391 heterocyclic compounds Chemical class 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
125000004356 hydroxy functional group Chemical group O* 0.000 description 1
239000001863 hydroxypropyl cellulose Substances 0.000 description 1
235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
238000010952 in-situ formation Methods 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
230000000415 inactivating effect Effects 0.000 description 1
150000007529 inorganic bases Chemical class 0.000 description 1
150000002484 inorganic compounds Chemical class 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
125000002346 iodo group Chemical group I* 0.000 description 1
WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 1
125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 1
JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
239000010410 layer Substances 0.000 description 1
208000013469 light sensitivity Diseases 0.000 description 1
125000005647 linker group Chemical group 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium;hydroxide;hydrate Chemical compound [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
235000010981 methylcellulose Nutrition 0.000 description 1
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
FEMOMIGRRWSMCU-UHFFFAOYSA-N ninhydrin Chemical compound C1=CC=C2C(=O)C(O)(O)C(=O)C2=C1 FEMOMIGRRWSMCU-UHFFFAOYSA-N 0.000 description 1
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
230000006911 nucleation Effects 0.000 description 1
238000010899 nucleation Methods 0.000 description 1
229920001778 nylon Polymers 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
125000005429 oxyalkyl group Chemical group 0.000 description 1
239000002245 particle Substances 0.000 description 1
RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
NFBAXHOPROOJAW-UHFFFAOYSA-N phenindione Chemical compound O=C1C2=CC=CC=C2C(=O)C1C1=CC=CC=C1 NFBAXHOPROOJAW-UHFFFAOYSA-N 0.000 description 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
238000007540 photo-reduction reaction Methods 0.000 description 1
239000003504 photosensitizing agent Substances 0.000 description 1
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
229920002239 polyacrylonitrile Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229940057847 polyethylene glycol 600 Drugs 0.000 description 1
229920000139 polyethylene terephthalate Polymers 0.000 description 1
229920001721 polyimide Polymers 0.000 description 1
239000004926 polymethyl methacrylate Substances 0.000 description 1
229920006324 polyoxymethylene Polymers 0.000 description 1
229920005606 polypropylene copolymer Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920000909 polytetrahydrofuran Polymers 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000005033 polyvinylidene chloride Substances 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
229910052573 porcelain Inorganic materials 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
OGHBATFHNDZKSO-UHFFFAOYSA-N propan-2-olate Chemical compound CC(C)[O-] OGHBATFHNDZKSO-UHFFFAOYSA-N 0.000 description 1
WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
230000027756 respiratory electron transport chain Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
BHRZNVHARXXAHW-UHFFFAOYSA-N sec-butylamine Chemical compound CCC(C)N BHRZNVHARXXAHW-UHFFFAOYSA-N 0.000 description 1
230000001235 sensitizing effect Effects 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
AQRYNYUOKMNDDV-UHFFFAOYSA-M silver behenate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O AQRYNYUOKMNDDV-UHFFFAOYSA-M 0.000 description 1
WBQTXTBONIWRGK-UHFFFAOYSA-N sodium;propan-2-olate Chemical compound [Na+].CC(C)[O-] WBQTXTBONIWRGK-UHFFFAOYSA-N 0.000 description 1
239000006104 solid solution Substances 0.000 description 1
229940035044 sorbitan monolaurate Drugs 0.000 description 1
239000001593 sorbitan monooleate Substances 0.000 description 1
235000011069 sorbitan monooleate Nutrition 0.000 description 1
229940035049 sorbitan monooleate Drugs 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000011115 styrene butadiene Substances 0.000 description 1
238000000859 sublimation Methods 0.000 description 1
230000008022 sublimation Effects 0.000 description 1
239000000725 suspension Substances 0.000 description 1
SWLJJEFSPJCUBD-UHFFFAOYSA-N tellurium tetrachloride Chemical compound Cl[Te](Cl)(Cl)Cl SWLJJEFSPJCUBD-UHFFFAOYSA-N 0.000 description 1
YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 1
239000010409 thin film Substances 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 1
230000007704 transition Effects 0.000 description 1
229940086542 triethylamine Drugs 0.000 description 1
YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
229910052724 xenon Inorganic materials 0.000 description 1
FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/72—Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705
- G03C1/73—Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705 containing organic compounds
- G03C1/734—Tellurium or selenium compounds

Landscapes

Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Chemical & Material Sciences (AREA)
Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Manufacturing Of Magnetic Record Carriers (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Thin Magnetic Films (AREA)
Detergent Compositions (AREA)
Polymerisation Methods In General (AREA)
Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)

CA000432727A 1982-07-26 1983-07-19 Self-fixing imaging film containing reductant precursor Expired CA1246923A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US40212082A	1982-07-26	1982-07-26
US402,120		1982-07-26

Publications (1)

Publication Number	Publication Date
CA1246923A true CA1246923A (en)	1988-12-20

Family

ID=23590609

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000432727A Expired CA1246923A (en)	1982-07-26	1983-07-19	Self-fixing imaging film containing reductant precursor

Country Status (6)

Country	Link
EP (1)	EP0100126B1 (de)
JP (1)	JPS5952242A (de)
AT (1)	ATE39029T1 (de)
AU (1)	AU1698483A (de)
CA (1)	CA1246923A (de)
DE (1)	DE3378596D1 (de)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4460678A (en) *	1982-06-28	1984-07-17	Energy Conversion Devices, Inc.	Tellurium imaging composition including improved reductant precursor and method

1983
- 1983-07-19 AU AU16984/83A patent/AU1698483A/en not_active Abandoned
- 1983-07-19 CA CA000432727A patent/CA1246923A/en not_active Expired
- 1983-07-20 AT AT83201076T patent/ATE39029T1/de not_active IP Right Cessation
- 1983-07-20 EP EP83201076A patent/EP0100126B1/de not_active Expired
- 1983-07-20 DE DE8383201076T patent/DE3378596D1/de not_active Expired
- 1983-07-26 JP JP58136686A patent/JPS5952242A/ja active Pending

Also Published As

Publication number	Publication date
EP0100126A2 (de)	1984-02-08
DE3378596D1 (en)	1989-01-05
AU1698483A (en)	1985-01-24
ATE39029T1 (de)	1988-12-15
JPS5952242A (ja)	1984-03-26
EP0100126B1 (de)	1988-11-30
EP0100126A3 (en)	1985-01-23

Legal Events

Date	Code	Title	Description
2005-12-20	MKEX	Expiry

Publication	Publication Date	Title
US3617288A (en)	1971-11-02	Propenone sensitizers for the photolysis of organic halogen compounds
US5153104A (en)	1992-10-06	Thermally developable light-sensitive layers containing photobleachable sensitizers
US5153105A (en)	1992-10-06	Thermally developable light sensitive imageable layers containing photobleachable dyes
US5055373A (en)	1991-10-08	Multicolor recording material
US3640718A (en)	1972-02-08	Spectral sentization of photosensitive compositions
JPH07128785A (ja)	1995-05-19	画像形成材料及び画像形成方法
CA1039553A (en)	1978-10-03	Photothermographic compositions, element and process
GB1580073A (en)	1980-11-26	Sensitive thermographic and photothermographic tellurium compound containing materials
CA1158912A (en)	1983-12-20	Tellurium imaging composition including a n-amido substituted pyrazo containing masked reducing agent
US4340662A (en)	1982-07-20	Tellurium imaging composition
CA1148013A (en)	1983-06-14	Tellurium imaging composition including a glycerol ether or glycerol thioether derivative as source of labile hydrogen for a reductant precursor
US3615478A (en)	1971-10-26	Method of fixing photographic material containing a free radial producing compound
CA1253513A (en)	1989-05-02	Tellurium imaging composition including improved reductant precursor and method
CA1068149A (en)	1979-12-18	Imaging and recording of information using an organo-tellurium compound
CA1246923A (en)	1988-12-20	Self-fixing imaging film containing reductant precursor
US3753395A (en)	1973-08-21	Photo-thermographic recording process with 5-pyrazolane
CA1241562A (en)	1988-09-06	Tellurium imaging composition including alcohol
US4451556A (en)	1984-05-29	Tellurium imaging composition including base
US3095303A (en)	1963-06-25	Styryl dye base composition and photographic processes for producing lithographic surfaces photoresists and prints therewith
US4130426A (en)	1978-12-19	Heat developable light-sensitive diazotype materials and process of use
US4698184A (en)	1987-10-06	Tellurium imaging composition including improved reductant precursor and method
US4184874A (en)	1980-01-22	Photosensitive composition containing chelate compound
US4535055A (en)	1985-08-13	Self-fixing imaging film containing reductant precursor
US4532078A (en)	1985-07-30	Reductant precursor for tellurium imaging compositions
US4448877A (en)	1984-05-15	Tellurium imaging composition including water