CA1253270A - Composition d'electrodeposition cationique - Google Patents

Composition d'electrodeposition cationique

Info

Publication number: CA1253270A
Authority: CA; Canada
Prior art keywords: alkyd; acid; composition; electrodeposition; ethylenically unsaturated
Prior art date: 1983-12-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000476428A

Other languages

English (en)

Inventor

Jeffrey L. Anderson

Robert B. Edenborg

Philip J. Ruhoff

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Valspar Corp

Original Assignee

Valspar Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-12-08

Filing date

1985-03-13

Publication date

1989-04-25

1983-12-08 Priority claimed from US06/559,385 external-priority patent/US4511692A/en

1985-03-13 Application filed by Valspar Corp filed Critical Valspar Corp

1989-04-25 Application granted granted Critical

1989-04-25 Publication of CA1253270A publication Critical patent/CA1253270A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 40
238000004070 electrodeposition Methods 0.000 title claims abstract description 33
125000002091 cationic group Chemical group 0.000 title claims abstract description 12
229920000180 alkyd Polymers 0.000 claims abstract description 68
239000000178 monomer Substances 0.000 claims abstract description 26
150000001412 amines Chemical class 0.000 claims abstract description 10
239000003973 paint Substances 0.000 claims abstract description 9
239000002904 solvent Substances 0.000 claims abstract description 8
239000000049 pigment Substances 0.000 claims abstract description 5
239000007795 chemical reaction product Substances 0.000 claims abstract 5
150000004665 fatty acids Chemical class 0.000 claims description 34
235000014113 dietary fatty acids Nutrition 0.000 claims description 33
239000000194 fatty acid Substances 0.000 claims description 33
229930195729 fatty acid Natural products 0.000 claims description 33
239000002253 acid Substances 0.000 claims description 27
239000003795 chemical substances by application Substances 0.000 claims description 21
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
150000007519 polyprotic acids Polymers 0.000 claims description 13
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
238000000576 coating method Methods 0.000 claims description 11
QQVIHTHCMHWDBS-UHFFFAOYSA-N perisophthalic acid Natural products OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 11
150000005846 sugar alcohols Polymers 0.000 claims description 11
239000011248 coating agent Substances 0.000 claims description 9
150000008064 anhydrides Chemical class 0.000 claims description 6
238000000034 method Methods 0.000 claims description 6
125000003277 amino group Chemical group 0.000 claims description 5
239000012948 isocyanate Substances 0.000 claims description 5
150000002513 isocyanates Chemical class 0.000 claims description 5
230000008569 process Effects 0.000 claims description 4
IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical class OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 claims description 3
239000008199 coating composition Substances 0.000 claims description 2
229920000578 graft copolymer Polymers 0.000 claims 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 2
239000000047 product Substances 0.000 claims 1
WSWCOQWTEOXDQX-MQQKCMAXSA-N sorbic acid group Chemical group C(\C=C\C=C\C)(=O)O WSWCOQWTEOXDQX-MQQKCMAXSA-N 0.000 claims 1
230000001590 oxidative effect Effects 0.000 abstract description 3
125000005313 fatty acid group Chemical group 0.000 abstract 1
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 39
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 16
239000007787 solid Substances 0.000 description 16
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 14
239000008096 xylene Substances 0.000 description 14
239000003054 catalyst Substances 0.000 description 13
POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 13
238000006243 chemical reaction Methods 0.000 description 11
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 10
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 10
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 8
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 7
238000002360 preparation method Methods 0.000 description 7
OZAIFHULBGXAKX-UHFFFAOYSA-N 2,2'-azo-bis-isobutyronitrile Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 6
JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 6
POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 6
229920005989 resin Polymers 0.000 description 6
239000011347 resin Substances 0.000 description 6
XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 5
239000005711 Benzoic acid Substances 0.000 description 5
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
235000010233 benzoic acid Nutrition 0.000 description 5
239000000463 material Substances 0.000 description 5
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 5
239000003505 polymerization initiator Substances 0.000 description 5
239000003981 vehicle Substances 0.000 description 5
239000012298 atmosphere Substances 0.000 description 4
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
-1 trimthylolpropane Chemical compound 0.000 description 4
BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 description 3
238000001723 curing Methods 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
230000004927 fusion Effects 0.000 description 3
238000013035 low temperature curing Methods 0.000 description 3
238000007747 plating Methods 0.000 description 3
235000010199 sorbic acid Nutrition 0.000 description 3
239000000758 substrate Substances 0.000 description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
229920002554 vinyl polymer Polymers 0.000 description 3
PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
244000068988 Glycine max Species 0.000 description 2
235000010469 Glycine max Nutrition 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
238000000151 deposition Methods 0.000 description 2
230000008021 deposition Effects 0.000 description 2
SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 2
238000001035 drying Methods 0.000 description 2
BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 2
239000011953 free-radical catalyst Substances 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
230000003301 hydrolyzing effect Effects 0.000 description 2
239000003999 initiator Substances 0.000 description 2
LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical class OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
239000004310 lactic acid Substances 0.000 description 2
235000014655 lactic acid Nutrition 0.000 description 2
235000020778 linoleic acid Nutrition 0.000 description 2
OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
RBQRWNWVPQDTJJ-UHFFFAOYSA-N methacryloyloxyethyl isocyanate Chemical compound CC(=C)C(=O)OCCN=C=O RBQRWNWVPQDTJJ-UHFFFAOYSA-N 0.000 description 2
238000002156 mixing Methods 0.000 description 2
GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 2
WHIVNJATOVLWBW-UHFFFAOYSA-N n-butan-2-ylidenehydroxylamine Chemical compound CCC(C)=NO WHIVNJATOVLWBW-UHFFFAOYSA-N 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
150000007524 organic acids Chemical class 0.000 description 2
229920000768 polyamine Polymers 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
235000019260 propionic acid Nutrition 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
238000010992 reflux Methods 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
239000004334 sorbic acid Substances 0.000 description 2
229940075582 sorbic acid Drugs 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000003784 tall oil Substances 0.000 description 2
UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 2
235000021122 unsaturated fatty acids Nutrition 0.000 description 2
150000004670 unsaturated fatty acids Chemical class 0.000 description 2
235000015112 vegetable and seed oil Nutrition 0.000 description 2
239000008158 vegetable oil Substances 0.000 description 2
235000013311 vegetables Nutrition 0.000 description 2
SZCWBURCISJFEZ-UHFFFAOYSA-N (3-hydroxy-2,2-dimethylpropyl) 3-hydroxy-2,2-dimethylpropanoate Chemical compound OCC(C)(C)COC(=O)C(C)(C)CO SZCWBURCISJFEZ-UHFFFAOYSA-N 0.000 description 1
229940058015 1,3-butylene glycol Drugs 0.000 description 1
PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 1
SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 1
QHVBLSNVXDSMEB-UHFFFAOYSA-N 2-(diethylamino)ethyl prop-2-enoate Chemical compound CCN(CC)CCOC(=O)C=C QHVBLSNVXDSMEB-UHFFFAOYSA-N 0.000 description 1
DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
VYZKQGGPNIFCLD-UHFFFAOYSA-N 3,3-dimethylhexane-2,2-diol Chemical compound CCCC(C)(C)C(C)(O)O VYZKQGGPNIFCLD-UHFFFAOYSA-N 0.000 description 1
FLCAEMBIQVZWIF-UHFFFAOYSA-N 6-(dimethylamino)-2-methylhex-2-enamide Chemical compound CN(C)CCCC=C(C)C(N)=O FLCAEMBIQVZWIF-UHFFFAOYSA-N 0.000 description 1
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240000002834 Paulownia tomentosa Species 0.000 description 1
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ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 1
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125000000217 alkyl group Chemical group 0.000 description 1
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239000003963 antioxidant agent Substances 0.000 description 1
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235000019437 butane-1,3-diol Nutrition 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
239000004359 castor oil Substances 0.000 description 1
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238000001816 cooling Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
VMCSLFBARAKODZ-UHFFFAOYSA-N cyclohexane 2,2,3-tris(hydroxymethyl)butane-1,4-diol Chemical compound C(O)C(C(CO)(CO)CO)CO.C1CCCCC1 VMCSLFBARAKODZ-UHFFFAOYSA-N 0.000 description 1
QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical class OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
239000012975 dibutyltin dilaurate Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
230000032050 esterification Effects 0.000 description 1
238000005886 esterification reaction Methods 0.000 description 1
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239000007789 gas Substances 0.000 description 1
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238000010438 heat treatment Methods 0.000 description 1
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238000005086 pumping Methods 0.000 description 1
230000036647 reaction Effects 0.000 description 1
239000004576 sand Substances 0.000 description 1
150000003398 sorbic acids Chemical class 0.000 description 1
150000003504 terephthalic acids Chemical class 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
229910000165 zinc phosphate Inorganic materials 0.000 description 1

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CA000476428A 1983-12-08 1985-03-13 Composition d'electrodeposition cationique Expired CA1253270A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US06/559,385 US4511692A (en)	1983-12-08	1983-12-08	Cationic electrodeposition composition

Publications (1)

Publication Number	Publication Date
CA1253270A true CA1253270A (fr)	1989-04-25

Family

ID=24233406

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000476428A Expired CA1253270A (fr)	1983-12-08	1985-03-13	Composition d'electrodeposition cationique

Country Status (3)

Country	Link
JP (1)	JPS61213272A (fr)
AU (2)	AU4018085A (fr)
CA (1)	CA1253270A (fr)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0104683B1 (fr) *	1982-09-09	1986-09-10	Akzo N.V.	Procédé de revêtement de substrats électriquement conducteurs et une composition aqueuse renfermant un liant cationique

1985
- 1985-03-13 CA CA000476428A patent/CA1253270A/fr not_active Expired
- 1985-03-18 JP JP5408285A patent/JPS61213272A/ja active Granted
- 1985-03-19 AU AU40180/85A patent/AU4018085A/en not_active Abandoned
1989
- 1989-02-17 AU AU30045/89A patent/AU622149B2/en not_active Ceased

Also Published As

Publication number	Publication date
JPH0586824B2 (fr)	1993-12-14
AU4018085A (en)	1986-09-25
AU3004589A (en)	1989-06-29
AU622149B2 (en)	1992-04-02
JPS61213272A (ja)	1986-09-22

Legal Events

Date	Code	Title	Description
2006-04-25	MKEX	Expiry

Publication	Publication Date	Title
CA1141062A (fr)	1983-02-08	Compositions de revetement, a base de copolymere de greffe alkyd-acrylique
EP0256521B1 (fr)	1990-11-14	Composition aqueuse de revêtement, sa préparation et son utilisation pour le revêtement de boîtes de conserves
CA2359205C (fr)	2005-07-26	Materiau de revetement ou composition d'encre
JP2599938B2 (ja)	1997-04-16	水稀釈可能な自然乾燥ラッカ―結合剤の製造方法
US4849480A (en)	1989-07-18	Crosslinked polymer microparticle
JPWO2000044840A1 (ja)	2002-05-21	塗料又はインキ組成物
US4511692A (en)	1985-04-16	Cationic electrodeposition composition
CA1253270A (fr)	1989-04-25	Composition d'electrodeposition cationique
US3668098A (en)	1972-06-06	Coating compositions
US5929161A (en)	1999-07-27	Cationic polyurethane-based polymer dispersions
EP0687716B1 (fr)	1998-10-07	Composition de résine dispersable dans l'eau renfermant un microgel anionique et composition de revêtement par électrodéposition en contenant
JP2912020B2 (ja)	1999-06-28	水性電気コーティング組成物におけるつや消し剤としての架橋不飽和ポリエステル
US4108750A (en)	1978-08-22	Method for electrodeposition
CN112724326B (zh)	2023-02-03	超支化水性丙烯酸改性醇酸树脂的制备方法及其工业面漆
EP0211625B1 (fr)	1989-12-27	Composition résineuse pour couches supérieures
US4692483A (en)	1987-09-08	Water-based paint composition
JP2513161B2 (ja)	1996-07-03	低温乾燥塗料用樹脂組成物
US3702288A (en)	1972-11-07	Process for finishing metal substrates by electrodepositing a primer composition and applying an acrylic organosol coating composition
JPH11171953A (ja)	1999-06-29	水希釈可能な樹脂、その製造方法およびその用法
JP2004043524A (ja)	2004-02-12	水性中塗り塗料組成物及び複層塗膜の形成方法
US4914139A (en)	1990-04-03	Modified alkyd cationic electrodeposition compositions for producing chip-resistant films
US3493483A (en)	1970-02-03	Electrodeposition method at high voltage
AU605037B2 (en)	1991-01-03	Cathodic electrodeposition paint composition
JPS61247768A (ja)	1986-11-05	常温乾燥性にすぐれた水性塗料組成物
JPS62273268A (ja)	1987-11-27	水希釈性の熱硬化性バインダ−の製造法