JPS61213272A - カチオン性電着組成物 - Google Patents

カチオン性電着組成物

Info

Publication number: JPS61213272A
Authority: JP; Japan
Prior art keywords: acid; alkyd; electrodeposition; ethylenically unsaturated; grafting agent
Prior art date: 1983-12-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP5408285A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0586824B2 (fr

Inventor

ジエフレー　エル・アンダーソン

フイリツプ　ジエイ・ルホツフ

ロバート　ビー・エデンボーグ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BARUSUPAA CORP

Original Assignee

BARUSUPAA CORP

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-12-08

Filing date

1985-03-18

Publication date

1986-09-22

1983-12-08 Priority claimed from US06/559,385 external-priority patent/US4511692A/en

1985-03-18 Application filed by BARUSUPAA CORP filed Critical BARUSUPAA CORP

1986-09-22 Publication of JPS61213272A publication Critical patent/JPS61213272A/ja

1993-12-14 Publication of JPH0586824B2 publication Critical patent/JPH0586824B2/ja

Status Granted legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims description 36
238000004070 electrodeposition Methods 0.000 title claims description 27
125000002091 cationic group Chemical group 0.000 title claims description 12
229920000180 alkyd Polymers 0.000 claims description 61
150000004665 fatty acids Chemical class 0.000 claims description 33
235000014113 dietary fatty acids Nutrition 0.000 claims description 32
229930195729 fatty acid Natural products 0.000 claims description 32
239000000194 fatty acid Substances 0.000 claims description 32
239000002253 acid Substances 0.000 claims description 31
239000000178 monomer Substances 0.000 claims description 25
239000003795 chemical substances by application Substances 0.000 claims description 20
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
150000007519 polyprotic acids Polymers 0.000 claims description 13
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 12
150000008064 anhydrides Chemical class 0.000 claims description 11
150000005846 sugar alcohols Polymers 0.000 claims description 11
239000000758 substrate Substances 0.000 claims description 10
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
238000000576 coating method Methods 0.000 claims description 9
239000000463 material Substances 0.000 claims description 9
239000003981 vehicle Substances 0.000 claims description 8
239000011248 coating agent Substances 0.000 claims description 7
239000002904 solvent Substances 0.000 claims description 7
150000007513 acids Chemical class 0.000 claims description 6
239000002274 desiccant Substances 0.000 claims description 6
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 6
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
150000001412 amines Chemical class 0.000 claims description 5
239000012948 isocyanate Substances 0.000 claims description 5
150000002513 isocyanates Chemical class 0.000 claims description 5
238000000034 method Methods 0.000 claims description 5
239000000049 pigment Substances 0.000 claims description 5
125000003277 amino group Chemical group 0.000 claims description 4
239000008199 coating composition Substances 0.000 claims description 4
238000004519 manufacturing process Methods 0.000 claims description 4
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 3
LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 3
BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 3
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
239000011976 maleic acid Substances 0.000 claims description 3
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 3
239000004334 sorbic acid Substances 0.000 claims description 3
235000010199 sorbic acid Nutrition 0.000 claims description 3
229940075582 sorbic acid Drugs 0.000 claims description 3
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 3
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 3
239000007795 chemical reaction product Substances 0.000 claims 5
229920000578 graft copolymer Polymers 0.000 claims 2
RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims 1
125000001931 aliphatic group Chemical group 0.000 claims 1
150000001768 cations Chemical group 0.000 claims 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 27
239000007787 solid Substances 0.000 description 14
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 12
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 11
239000008096 xylene Substances 0.000 description 11
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 10
239000003054 catalyst Substances 0.000 description 10
238000006243 chemical reaction Methods 0.000 description 9
POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 9
239000003973 paint Substances 0.000 description 8
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 7
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 7
JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 6
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 6
238000001723 curing Methods 0.000 description 6
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 6
229920005989 resin Polymers 0.000 description 6
239000011347 resin Substances 0.000 description 6
239000000126 substance Substances 0.000 description 6
XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 5
239000005711 Benzoic acid Substances 0.000 description 5
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 5
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
235000010233 benzoic acid Nutrition 0.000 description 5
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 4
-1 Dimethylaminoethyl Chemical group 0.000 description 4
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
239000012298 atmosphere Substances 0.000 description 4
239000003505 polymerization initiator Substances 0.000 description 4
OZAIFHULBGXAKX-UHFFFAOYSA-N 2,2'-azo-bis-isobutyronitrile Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
239000008367 deionised water Substances 0.000 description 3
229910021641 deionized water Inorganic materials 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
238000001035 drying Methods 0.000 description 3
239000004310 lactic acid Substances 0.000 description 3
235000014655 lactic acid Nutrition 0.000 description 3
238000013035 low temperature curing Methods 0.000 description 3
235000019260 propionic acid Nutrition 0.000 description 3
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 2
FLCAEMBIQVZWIF-UHFFFAOYSA-N 6-(dimethylamino)-2-methylhex-2-enamide Chemical compound CN(C)CCCC=C(C)C(N)=O FLCAEMBIQVZWIF-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
244000068988 Glycine max Species 0.000 description 2
235000010469 Glycine max Nutrition 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
239000001361 adipic acid Substances 0.000 description 2
235000011037 adipic acid Nutrition 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
239000011953 free-radical catalyst Substances 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
230000003301 hydrolyzing effect Effects 0.000 description 2
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
150000007524 organic acids Chemical class 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
229920000768 polyamine Polymers 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000010992 reflux Methods 0.000 description 2
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
239000003784 tall oil Substances 0.000 description 2
UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 2
QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 2
150000004670 unsaturated fatty acids Chemical class 0.000 description 2
235000021122 unsaturated fatty acids Nutrition 0.000 description 2
235000015112 vegetable and seed oil Nutrition 0.000 description 2
239000008158 vegetable oil Substances 0.000 description 2
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NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 1
229940058015 1,3-butylene glycol Drugs 0.000 description 1
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 description 1
SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 1
QHVBLSNVXDSMEB-UHFFFAOYSA-N 2-(diethylamino)ethyl prop-2-enoate Chemical compound CCN(CC)CCOC(=O)C=C QHVBLSNVXDSMEB-UHFFFAOYSA-N 0.000 description 1
DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 description 1
TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
HOSGXJWQVBHGLT-UHFFFAOYSA-N 6-hydroxy-3,4-dihydro-1h-quinolin-2-one Chemical group N1C(=O)CCC2=CC(O)=CC=C21 HOSGXJWQVBHGLT-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
229920000178 Acrylic resin Polymers 0.000 description 1
239000004925 Acrylic resin Substances 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
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LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
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239000005977 Ethylene Substances 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
241000219289 Silene Species 0.000 description 1
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ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
238000012644 addition polymerization Methods 0.000 description 1
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JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
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239000003963 antioxidant agent Substances 0.000 description 1
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IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
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CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
229910052918 calcium silicate Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
239000004359 castor oil Substances 0.000 description 1
235000019438 castor oil Nutrition 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
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VMCSLFBARAKODZ-UHFFFAOYSA-N cyclohexane 2,2,3-tris(hydroxymethyl)butane-1,4-diol Chemical compound C(O)C(C(CO)(CO)CO)CO.C1CCCCC1 VMCSLFBARAKODZ-UHFFFAOYSA-N 0.000 description 1
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238000000354 decomposition reaction Methods 0.000 description 1
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238000010291 electrical method Methods 0.000 description 1
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238000005886 esterification reaction Methods 0.000 description 1
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238000010438 heat treatment Methods 0.000 description 1
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239000002655 kraft paper Substances 0.000 description 1
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239000011572 manganese Substances 0.000 description 1
238000000691 measurement method Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
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150000003839 salts Chemical class 0.000 description 1
239000004576 sand Substances 0.000 description 1
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230000002123 temporal effect Effects 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
239000002383 tung oil Substances 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
229910000165 zinc phosphate Inorganic materials 0.000 description 1

Landscapes

Paints Or Removers (AREA)
Polyesters Or Polycarbonates (AREA)

JP5408285A 1983-12-08 1985-03-18 カチオン性電着組成物 Granted JPS61213272A (ja)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US06/559,385 US4511692A (en)	1983-12-08	1983-12-08	Cationic electrodeposition composition

Publications (2)

Publication Number	Publication Date
JPS61213272A true JPS61213272A (ja)	1986-09-22
JPH0586824B2 JPH0586824B2 (fr)	1993-12-14

Family

ID=24233406

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP5408285A Granted JPS61213272A (ja)	1983-12-08	1985-03-18	カチオン性電着組成物

Country Status (3)

Country	Link
JP (1)	JPS61213272A (fr)
AU (2)	AU4018085A (fr)
CA (1)	CA1253270A (fr)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0104683B1 (fr) *	1982-09-09	1986-09-10	Akzo N.V.	Procédé de revêtement de substrats électriquement conducteurs et une composition aqueuse renfermant un liant cationique

1985
- 1985-03-13 CA CA000476428A patent/CA1253270A/fr not_active Expired
- 1985-03-18 JP JP5408285A patent/JPS61213272A/ja active Granted
- 1985-03-19 AU AU40180/85A patent/AU4018085A/en not_active Abandoned
1989
- 1989-02-17 AU AU30045/89A patent/AU622149B2/en not_active Ceased

Also Published As

Publication number	Publication date
CA1253270A (fr)	1989-04-25
JPH0586824B2 (fr)	1993-12-14
AU4018085A (en)	1986-09-25
AU3004589A (en)	1989-06-29
AU622149B2 (en)	1992-04-02

Publication	Publication Date	Title
US4517322A (en)	1985-05-14	Acrylated alkyd and polyester resins
US4851460A (en)	1989-07-25	Aqueous coating composition, process for its preparation and its use
JP2599938B2 (ja)	1997-04-16	水稀釈可能な自然乾燥ラッカ―結合剤の製造方法
US4273690A (en)	1981-06-16	Coating compositions of an alkyd-acrylic graft copolymer
EP0256521B1 (fr)	1990-11-14	Composition aqueuse de revêtement, sa préparation et son utilisation pour le revêtement de boîtes de conserves
US3804786A (en)	1974-04-16	Water-dispersible cationic polyurethane resins
CA2531324C (fr)	2012-12-18	Peinture a l'eau thermodurcissable et methodes de formation de films de revetement
JPH0449587B2 (fr)	1992-08-11
JPH0127090B2 (fr)	1989-05-26
KR940010968B1 (ko)	1994-11-21	중합체 분산액의 제조방법
JPH10501838A (ja)	1998-02-17	少なくとも３成分からなる被覆材料、その製造方法並びにその使用
JPS6191201A (ja)	1986-05-09	陰極電着による導電性表面のコーティング方法
JPS6086172A (ja)	1985-05-15	被覆組成物及び被覆の製法
JPH0710959B2 (ja)	1995-02-08	水性電着ラツカーコーテイング組成物
JPS60501012A (ja)	1985-07-04	熱硬化可能の結合剤混合物
JPH05125326A (ja)	1993-05-21	水性自然乾燥性コーテイング剤、その製造および使用
US4511692A (en)	1985-04-16	Cationic electrodeposition composition
JPH0247509B2 (fr)	1990-10-19
JPS6351480A (ja)	1988-03-04	非自動架橋型バインダ−組成物
JPH0657817B2 (ja)	1994-08-03	カチオン結合剤を含有する水性コーティング組成物
HK1049018A1 (en)	2003-04-25	Rosin-fatty acid vinylic emulsion compositions
EP0687716B1 (fr)	1998-10-07	Composition de résine dispersable dans l'eau renfermant un microgel anionique et composition de revêtement par électrodéposition en contenant
EP1853642B1 (fr)	2009-12-02	Dispersion d alkyde autoreticulante
JPS61213272A (ja)	1986-09-22	カチオン性電着組成物
JP2912020B2 (ja)	1999-06-28	水性電気コーティング組成物におけるつや消し剤としての架橋不飽和ポリエステル