CA1259845A - Elements photographiques d'inversion contenant des emulsions a grains tabulaires - Google Patents

Elements photographiques d'inversion contenant des emulsions a grains tabulaires

Info

Publication number: CA1259845A
Authority: CA; Canada
Prior art keywords: silver; grains; forming; reversal; less
Prior art date: 1985-02-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000493002A

Other languages

English (en)

Inventor

Allan F. Sowinski

David C. Shuman

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eastman Kodak Co

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-02-04

Filing date

1985-10-15

Publication date

1989-09-26

1985-10-15 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1989-09-26 Application granted granted Critical

1989-09-26 Publication of CA1259845A publication Critical patent/CA1259845A/fr

Status Expired legal-status Critical Current

Links

239000000839 emulsion Substances 0.000 title claims abstract description 139
229910052709 silver Inorganic materials 0.000 claims abstract description 89
239000004332 silver Substances 0.000 claims abstract description 89
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 69
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims abstract description 17
JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 claims abstract description 14
229910021612 Silver iodide Inorganic materials 0.000 claims abstract description 14
229940045105 silver iodide Drugs 0.000 claims abstract description 14
239000000203 mixture Substances 0.000 claims abstract description 7
239000000975 dye Substances 0.000 claims description 34
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 19
ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 claims description 18
230000005855 radiation Effects 0.000 claims description 16
ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 claims description 16
238000003384 imaging method Methods 0.000 claims description 8
AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 claims description 6
239000001043 yellow dye Substances 0.000 claims description 6
RHUVFRWZKMEWNS-UHFFFAOYSA-M silver thiocyanate Chemical compound [Ag+].[S-]C#N RHUVFRWZKMEWNS-UHFFFAOYSA-M 0.000 claims description 5
229910021607 Silver chloride Inorganic materials 0.000 claims description 2
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 2
-1 Silver halide Chemical class 0.000 abstract description 26
239000010410 layer Substances 0.000 description 101
108010010803 Gelatin Proteins 0.000 description 17
239000008273 gelatin Substances 0.000 description 17
229920000159 gelatin Polymers 0.000 description 17
235000019322 gelatine Nutrition 0.000 description 17
235000011852 gelatine desserts Nutrition 0.000 description 17
238000002156 mixing Methods 0.000 description 16
150000002500 ions Chemical class 0.000 description 14
230000001965 increasing effect Effects 0.000 description 11
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 10
239000011248 coating agent Substances 0.000 description 9
238000000576 coating method Methods 0.000 description 9
238000000034 method Methods 0.000 description 8
230000008901 benefit Effects 0.000 description 7
150000003378 silver Chemical class 0.000 description 7
CBEQRNSPHCCXSH-UHFFFAOYSA-N iodine monobromide Chemical compound IBr CBEQRNSPHCCXSH-UHFFFAOYSA-N 0.000 description 6
AGOYDEPGAOXOCK-KCBOHYOISA-N clarithromycin Chemical compound O([C@@H]1[C@@H](C)C(=O)O[C@@H]([C@@]([C@H](O)[C@@H](C)C(=O)[C@H](C)C[C@](C)([C@H](O[C@H]2[C@@H]([C@H](C[C@@H](C)O2)N(C)C)O)[C@H]1C)OC)(C)O)CC)[C@H]1C[C@@](C)(OC)[C@@H](O)[C@H](C)O1 AGOYDEPGAOXOCK-KCBOHYOISA-N 0.000 description 5
238000011161 development Methods 0.000 description 5
238000012545 processing Methods 0.000 description 5
230000006870 function Effects 0.000 description 4
239000011229 interlayer Substances 0.000 description 4
230000008569 process Effects 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
230000007423 decrease Effects 0.000 description 3
230000003247 decreasing effect Effects 0.000 description 3
239000004848 polyfunctional curative Substances 0.000 description 3
238000011160 research Methods 0.000 description 3
230000003595 spectral effect Effects 0.000 description 3
IJHIIHORMWQZRQ-UHFFFAOYSA-N 1-(ethenylsulfonylmethylsulfonyl)ethene Chemical compound C=CS(=O)(=O)CS(=O)(=O)C=C IJHIIHORMWQZRQ-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
239000006096 absorbing agent Substances 0.000 description 2
238000004061 bleaching Methods 0.000 description 2
239000003638 chemical reducing agent Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000000084 colloidal system Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
230000002708 enhancing effect Effects 0.000 description 2
230000001747 exhibiting effect Effects 0.000 description 2
230000006872 improvement Effects 0.000 description 2
239000000463 material Substances 0.000 description 2
239000006224 matting agent Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
238000011282 treatment Methods 0.000 description 2
OPFTUNCRGUEPRZ-UHFFFAOYSA-N (+)-beta-Elemen Natural products CC(=C)C1CCC(C)(C=C)C(C(C)=C)C1 OPFTUNCRGUEPRZ-UHFFFAOYSA-N 0.000 description 1
OPFTUNCRGUEPRZ-QLFBSQMISA-N (-)-beta-elemene Chemical compound CC(=C)[C@@H]1CC[C@@](C)(C=C)[C@H](C(C)=C)C1 OPFTUNCRGUEPRZ-QLFBSQMISA-N 0.000 description 1
CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
241000736839 Chara Species 0.000 description 1
241001125671 Eretmochelys imbricata Species 0.000 description 1
241000483002 Euproctis similis Species 0.000 description 1
241001527806 Iti Species 0.000 description 1
AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
235000018734 Sambucus australis Nutrition 0.000 description 1
244000180577 Sambucus australis Species 0.000 description 1
206010070834 Sensitisation Diseases 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical class [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 1
125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
230000003190 augmentative effect Effects 0.000 description 1
125000000043 benzamido group Chemical group [H]N([*])C(=O)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
RLDQYSHDFVSAPL-UHFFFAOYSA-L calcium;dithiocyanate Chemical compound [Ca+2].[S-]C#N.[S-]C#N RLDQYSHDFVSAPL-UHFFFAOYSA-L 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
229920002301 cellulose acetate Polymers 0.000 description 1
239000003086 colorant Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000000586 desensitisation Methods 0.000 description 1
238000010586 diagram Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
KOWWOODYPWDWOJ-LVBPXUMQSA-N elatine Chemical compound C([C@]12CN(C3[C@@]45OCO[C@]44[C@H]6[C@@H](OC)[C@@H]([C@H](C4)OC)C[C@H]6[C@@]3([C@@H]1[C@@H]5OC)[C@@H](OC)CC2)CC)OC(=O)C1=CC=CC=C1N1C(=O)CC(C)C1=O KOWWOODYPWDWOJ-LVBPXUMQSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000010946 fine silver Substances 0.000 description 1
239000000499 gel Substances 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
239000010931 gold Substances 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
125000005928 isopropyloxycarbonyl group Chemical group [H]C([H])([H])C([H])(OC(*)=O)C([H])([H])[H] 0.000 description 1
JCCNYMKQOSZNPW-UHFFFAOYSA-N loratadine Chemical compound C1CN(C(=O)OCC)CCC1=C1C2=NC=CC=C2CCC2=CC(Cl)=CC=C21 JCCNYMKQOSZNPW-UHFFFAOYSA-N 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
SVIFGEVWHFNGCZ-UHFFFAOYSA-N n-[2-[di(propan-2-yl)amino]ethyl]-2-(2-oxopyrrolidin-1-yl)acetamide;hydron;chloride Chemical compound Cl.CC(C)N(C(C)C)CCNC(=O)CN1CCCC1=O SVIFGEVWHFNGCZ-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229960001679 octinoxate Drugs 0.000 description 1
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920000139 polyethylene terephthalate Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000002516 radical scavenger Substances 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
230000008313 sensitization Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
101150019895 thiE gene Proteins 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/0051—Tabular grain emulsions

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Silver Salt Photography Or Processing Solution Therefor (AREA)

CA000493002A 1985-02-04 1985-10-15 Elements photographiques d'inversion contenant des emulsions a grains tabulaires Expired CA1259845A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US69805385A	1985-02-04	1985-02-04
US698,053		1985-02-04

Publications (1)

Publication Number	Publication Date
CA1259845A true CA1259845A (fr)	1989-09-26

Family

ID=24803736

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000493002A Expired CA1259845A (fr)	1985-02-04	1985-10-15	Elements photographiques d'inversion contenant des emulsions a grains tabulaires

Country Status (5)

Country	Link
EP (1)	EP0190625B1 (fr)
JP (1)	JPH07111551B2 (fr)
AT (1)	ATE63009T1 (fr)
CA (1)	CA1259845A (fr)
DE (1)	DE3678848D1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1213381B (it) *	1986-11-13	1989-12-20	Minnesota Mining And Manufaftu	Procedimento ed elemento per ottenere un'immagine fotografica.
DE3873473T2 (de) *	1987-10-16	1993-04-01	Fuji Photo Film Co Ltd	Photographische silberhalogenidemulsion.
US4865964A (en) *	1988-03-25	1989-09-12	Eastman Kodak Company	Blended emulsions exhibiting improved speed-granularity relationship
US5300413A (en) *	1992-11-27	1994-04-05	Eastman Kodak Company	Photoelectric elements for producing spectral image records retrievable by scanning
US5391468A (en) *	1993-10-29	1995-02-21	Eastman Kodak Company	Reversal photographic elements containing tabular grain emulsions
EP0718676A1 (fr) *	1994-12-22	1996-06-26	Eastman Kodak Company	Eléments photographiques pour tirage contenant des émulsions à rapidité élevée et densités minimales contrÔlées

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3598597A (en) *	1967-05-24	1971-08-10	Gaf Corp	Speed and contrast of a silver halide photographic emulsion obtained by addition of silver chloride emuldion to silver bromide emulsion
JPS5816048A (ja) *	1981-07-22	1983-01-29	Res Inst Electric Magnetic Alloys	耐食性の優れた高透磁率非晶質合金およびその製造方法
JPS58111936A (ja) *	1981-11-12	1983-07-04	イ−ストマン・コダツク・カンパニ−	放射線感応性乳剤およびその製法
CH653150A5 (fr) *	1981-11-12	1985-12-13	Eastman Kodak Co	Produits photographiques positifs-directs.
US4439520A (en) *	1981-11-12	1984-03-27	Eastman Kodak Company	Sensitized high aspect ratio silver halide emulsions and photographic elements
BE894966A (fr) *	1981-11-12	1983-05-09	Eastman Kodak Co	Produit radiographique
JPS59121039A (ja) *	1982-12-27	1984-07-12	Fuji Photo Film Co Ltd	ハロゲン化銀写真感光材料
JPS6012540A (ja) *	1983-07-01	1985-01-22	Konishiroku Photo Ind Co Ltd	リツプマン型ハロゲン化銀写真感光材料

1985
- 1985-10-15 CA CA000493002A patent/CA1259845A/fr not_active Expired
1986
- 1986-01-24 DE DE8686100953T patent/DE3678848D1/de not_active Expired - Fee Related
- 1986-01-24 AT AT86100953T patent/ATE63009T1/de not_active IP Right Cessation
- 1986-01-24 EP EP86100953A patent/EP0190625B1/fr not_active Expired - Lifetime
- 1986-02-04 JP JP61021341A patent/JPH07111551B2/ja not_active Expired - Fee Related

Also Published As

Publication number	Publication date
DE3678848D1 (de)	1991-05-29
EP0190625A2 (fr)	1986-08-13
ATE63009T1 (de)	1991-05-15
JPS61246746A (ja)	1986-11-04
EP0190625B1 (fr)	1991-04-24
JPH07111551B2 (ja)	1995-11-29
EP0190625A3 (en)	1988-07-27

Legal Events

Date	Code	Title	Description
2006-09-26	MKEX	Expiry

Publication	Publication Date	Title
US4656122A (en)	1987-04-07	Reversal photographic elements containing tabular grain emulsions
JPS63220238A (ja)	1988-09-13	ハロゲン化銀乳剤及びそれを用いた写真感光材料
EP0163283B1 (fr)	1987-12-02	Elément photographique ayant un voile dû au colorant sensibilisateur réduit
AU771218B2 (en)	2004-03-18	High contrast visually adaptive radiographic film and imaging assembly
EP0334320B1 (fr)	1992-08-26	Mélange d'émulsions avec une relation sensibilité-granularité modifiée
CA1312767C (fr)	1993-01-19	Methode et element pour obtenir une image photographique
EP1130463B1 (fr)	2004-12-15	Film radiographique avec contraste visuellement adaptable, pouvant être rapidement traité et directement visualisable
EP1203983A1 (fr)	2002-05-08	Film radiographique visuellement adaptable à haut contraste et assemblage pour l'enregistrement et la formation d'images pour l'imagerie orthopédique
JPH05150413A (ja)	1993-06-18	多色写真要素
EP0190625B1 (fr)	1991-04-24	Eléments photographiques inversibles contenant des émulsions à grains tabulaires
US5637447A (en)	1997-06-10	Films for reproducing digitally stored medical diagnostic images
JPH06301130A (ja)	1994-10-28	フィルムおよびカメラ
US6361918B1 (en)	2002-03-26	High speed radiographic film and imaging assembly
US5824459A (en)	1998-10-20	Symmetrical thoracic cavity imaging radiographic element
US5932401A (en)	1999-08-03	Reversal photographic elements comprising an additional layer containing an imaging emulsion and a non-imaging emulsion
US5672467A (en)	1997-09-30	Higher speed color photographic element and a method for high speed imaging
EP0547983B1 (fr)	1995-10-04	Elément photographique inversible et procédé de traitement de celui-ci
US5716774A (en)	1998-02-10	Radiographic elements containing ultrathin tabular grain emulsions
US5391468A (en)	1995-02-21	Reversal photographic elements containing tabular grain emulsions
JPH07306491A (ja)	1995-11-21	写真要素
JP2811305B2 (ja)	1998-10-15	鮮鋭性及び粒状性の改良されたハロゲン化銀写真感光材料
US6358661B1 (en)	2002-03-19	Visually adaptive radiographic film and imaging assembly
JPS61141440A (ja)	1986-06-28	ハロゲン化銀写真感光材料
JPH08211575A (ja)	1996-08-20	カラーリバーサル要素及びその処理方法
JPH09114039A (ja)	1997-05-02	カラーハロゲン化銀写真要素