CA1274234A - Lacis de files de carbone active - Google Patents

Lacis de files de carbone active

Info

Publication number: CA1274234A
Authority: CA; Canada
Prior art keywords: yarn; yarns; activated carbon; oxidized; fold
Prior art date: 1985-01-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000499726A

Other languages

English (en)

Inventor

Ward Charles Stevens

Robert Domenico Giglia

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Wyeth Holdings LLC

Original Assignee

American Cyanamid Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-01-18

Filing date

1986-01-16

Publication date

1990-09-18

1986-01-16 Application filed by American Cyanamid Co filed Critical American Cyanamid Co

1990-09-18 Application granted granted Critical

1990-09-18 Publication of CA1274234A publication Critical patent/CA1274234A/fr

Status Expired - Fee Related legal-status Critical Current

Links

OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 181
229910052799 carbon Inorganic materials 0.000 claims abstract description 29
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 25
238000000034 method Methods 0.000 claims description 50
230000001590 oxidative effect Effects 0.000 claims description 15
238000004519 manufacturing process Methods 0.000 claims description 10
238000001994 activation Methods 0.000 abstract description 37
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 48
239000007789 gas Substances 0.000 description 46
239000000835 fiber Substances 0.000 description 26
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 24
230000004913 activation Effects 0.000 description 21
229950005499 carbon tetrachloride Drugs 0.000 description 21
239000002243 precursor Substances 0.000 description 15
229910002092 carbon dioxide Inorganic materials 0.000 description 13
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 11
239000001569 carbon dioxide Substances 0.000 description 8
239000004744 fabric Substances 0.000 description 8
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
230000003647 oxidation Effects 0.000 description 8
238000007254 oxidation reaction Methods 0.000 description 8
229920000049 Carbon (fiber) Polymers 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 7
229920001577 copolymer Polymers 0.000 description 7
-1 poly(p-phenylene terephthalamide) Polymers 0.000 description 7
238000001179 sorption measurement Methods 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
229920002239 polyacrylonitrile Polymers 0.000 description 6
239000010453 quartz Substances 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
239000002253 acid Substances 0.000 description 5
230000003213 activating effect Effects 0.000 description 5
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
238000010924 continuous production Methods 0.000 description 5
239000000203 mixture Substances 0.000 description 5
229910052760 oxygen Inorganic materials 0.000 description 5
239000001301 oxygen Substances 0.000 description 5
229920000642 polymer Polymers 0.000 description 5
238000009941 weaving Methods 0.000 description 5
238000010586 diagram Methods 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
230000000704 physical effect Effects 0.000 description 4
238000012545 processing Methods 0.000 description 4
238000009987 spinning Methods 0.000 description 4
238000012360 testing method Methods 0.000 description 4
238000005406 washing Methods 0.000 description 4
229920013683 Celanese Polymers 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
239000000047 product Substances 0.000 description 3
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
229920002972 Acrylic fiber Polymers 0.000 description 2
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
238000005299 abrasion Methods 0.000 description 2
125000005907 alkyl ester group Chemical group 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
239000004760 aramid Substances 0.000 description 2
229920003235 aromatic polyamide Polymers 0.000 description 2
229910021538 borax Chemical class 0.000 description 2
238000009954 braiding Methods 0.000 description 2
239000004917 carbon fiber Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
229910001873 dinitrogen Inorganic materials 0.000 description 2
239000005337 ground glass Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
NQBKFULMFQMZBE-UHFFFAOYSA-N n-bz-3-benzanthronylpyrazolanthron Chemical compound C12=CC=CC(C(=O)C=3C4=CC=CC=3)=C2C4=NN1C1=CC=C2C3=C1C1=CC=CC=C1C(=O)C3=CC=C2 NQBKFULMFQMZBE-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
239000005297 pyrex Substances 0.000 description 2
238000003908 quality control method Methods 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
239000004328 sodium tetraborate Chemical class 0.000 description 2
235000010339 sodium tetraborate Nutrition 0.000 description 2
230000003068 static effect Effects 0.000 description 2
239000000126 substance Substances 0.000 description 2
229920001059 synthetic polymer Polymers 0.000 description 2
239000003440 toxic substance Substances 0.000 description 2
229910001868 water Inorganic materials 0.000 description 2
238000002166 wet spinning Methods 0.000 description 2
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
POTYORUTRLSAGZ-UHFFFAOYSA-N (3-chloro-2-hydroxypropyl) prop-2-enoate Chemical compound ClCC(O)COC(=O)C=C POTYORUTRLSAGZ-UHFFFAOYSA-N 0.000 description 1
KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
FCYVWWWTHPPJII-UHFFFAOYSA-N 2-methylidenepropanedinitrile Chemical compound N#CC(=C)C#N FCYVWWWTHPPJII-UHFFFAOYSA-N 0.000 description 1
XEEYSDHEOQHCDA-UHFFFAOYSA-N 2-methylprop-2-ene-1-sulfonic acid Chemical compound CC(=C)CS(O)(=O)=O XEEYSDHEOQHCDA-UHFFFAOYSA-N 0.000 description 1
XRASRVJYOMVDNP-UHFFFAOYSA-N 4-(7-azabicyclo[4.1.0]hepta-1,3,5-triene-7-carbonyl)benzamide Chemical compound C1=CC(C(=O)N)=CC=C1C(=O)N1C2=CC=CC=C21 XRASRVJYOMVDNP-UHFFFAOYSA-N 0.000 description 1
239000007991 ACES buffer Substances 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
229920000271 Kevlar® Polymers 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
MOMWFXLCFJOAFX-UHFFFAOYSA-N OOOOOOOO Chemical compound OOOOOOOO MOMWFXLCFJOAFX-UHFFFAOYSA-N 0.000 description 1
YAVWDJDEOLOYQO-UHFFFAOYSA-N OOOOOOOOOO Chemical compound OOOOOOOOOO YAVWDJDEOLOYQO-UHFFFAOYSA-N 0.000 description 1
ZQTQPYJGMWHXMO-UHFFFAOYSA-N OOOOOOOOOOOOOOOOO Chemical compound OOOOOOOOOOOOOOOOO ZQTQPYJGMWHXMO-UHFFFAOYSA-N 0.000 description 1
FYKAKDPHDGCKTF-UHFFFAOYSA-N OOOOOOOOOOOOOOOOOOO Chemical compound OOOOOOOOOOOOOOOOOOO FYKAKDPHDGCKTF-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical class [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
125000005396 acrylic acid ester group Chemical group 0.000 description 1
229920006231 aramid fiber Polymers 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
230000005587 bubbling Effects 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
238000003763 carbonization Methods 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
231100000481 chemical toxicant Toxicity 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
239000011280 coal tar Substances 0.000 description 1
238000004581 coalescence Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000002844 continuous effect Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000000578 dry spinning Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
229910001867 inorganic solvent Inorganic materials 0.000 description 1
239000003049 inorganic solvent Substances 0.000 description 1
230000002452 interceptive effect Effects 0.000 description 1
150000002506 iron compounds Chemical class 0.000 description 1
239000004761 kevlar Substances 0.000 description 1
238000009940 knitting Methods 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
229920006286 oxidized acrylic fiber Polymers 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
239000005011 phenolic resin Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
229920003366 poly(p-phenylene terephthalamide) Polymers 0.000 description 1
229920002480 polybenzimidazole Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
238000005070 sampling Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
238000009864 tensile test Methods 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
238000013519 translation Methods 0.000 description 1
229940007392 tylan Drugs 0.000 description 1
WBPYTXDJUQJLPQ-VMXQISHHSA-N tylosin Chemical compound O([C@@H]1[C@@H](C)O[C@H]([C@@H]([C@H]1N(C)C)O)O[C@@H]1[C@@H](C)[C@H](O)CC(=O)O[C@@H]([C@H](/C=C(\C)/C=C/C(=O)[C@H](C)C[C@@H]1CC=O)CO[C@H]1[C@@H]([C@H](OC)[C@H](O)[C@@H](C)O1)OC)CC)[C@H]1C[C@@](C)(O)[C@@H](O)[C@H](C)O1 WBPYTXDJUQJLPQ-VMXQISHHSA-N 0.000 description 1
235000019375 tylosin Nutrition 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
238000005303 weighing Methods 0.000 description 1
230000004584 weight gain Effects 0.000 description 1
235000019786 weight gain Nutrition 0.000 description 1
235000005074 zinc chloride Nutrition 0.000 description 1
239000011592 zinc chloride Substances 0.000 description 1

Landscapes

Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

CA000499726A 1985-01-18 1986-01-16 Lacis de files de carbone active Expired - Fee Related CA1274234A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US69296085A	1985-01-18	1985-01-18
US692,960		1985-01-18

Publications (1)

Publication Number	Publication Date
CA1274234A true CA1274234A (fr)	1990-09-18

Family

ID=24782767

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000499726A Expired - Fee Related CA1274234A (fr)	1985-01-18	1986-01-16	Lacis de files de carbone active

Country Status (1)

Country	Link
CA (1)	CA1274234A (fr)

1986
- 1986-01-16 CA CA000499726A patent/CA1274234A/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
2004-09-20	MKLA	Lapsed

Publication	Publication Date	Title
US3529934A (en)	1970-09-22	Process for the preparation of carbon fibers
US5356707A (en)	1994-10-18	Non-linear carbonaceous fiber
US4520623A (en)	1985-06-04	Activated carbon fiber spun yarn
EP0451263B1 (fr)	1995-11-08	Fibre carbonee lineaire a capacite d'allongement amelioree
US3723607A (en)	1973-03-27	Surface modification of carbon fibers
US3818082A (en)	1974-06-18	Process for the production of carbonaceous tapes
US4073869A (en)	1978-02-14	Internal chemical modification of carbon fibers to yield a product of reduced electrical conductivity
EP0057492B1 (fr)	1987-04-29	Procédé pour la modification superficielle de fibres de carbone
JPH09228171A (ja)	1997-09-02	高耐熱混紡糸
US3723150A (en)	1973-03-27	Surface modification of carbon fibers
CA1274234A (fr)	1990-09-18	Lacis de files de carbone active
US4237108A (en)	1980-12-02	Process for producing carbon fabric
US6156287A (en)	2000-12-05	Method for preparing pan-based activated carbon fabrics
JP2004003043A (ja)	2004-01-08	耐炎化繊維材料、炭素繊維材料、黒鉛繊維材料及びそれらの製造方法
US3723605A (en)	1973-03-27	Process for the production of a continuous length of graphitic fibrous material
US4112059A (en)	1978-09-05	Process for the production of carbon filaments utilizing an acrylic precursor
EP0378381A2 (fr)	1990-07-18	Fibres de carbone chargées de métaux
EP0189134A2 (fr)	1986-07-30	Tissu tricoté chaîne contenant comme trame des fils en carbone activés
JP2002220726A (ja)	2002-08-09	炭素繊維前駆体糸条の製造方法
WO1987002391A1 (fr)	1987-04-23	Procede de production de fibres de carbone
US3926228A (en)	1975-12-16	Carbonaceous tapes
JP2535124B2 (ja)	1996-09-18	Ｐｖｃ／塩素化ｐｖｃ混合物系繊維およびこれから得られた繊維糸
JPS6250574B2 (fr)	1987-10-26
JPS6142006B2 (fr)	1986-09-18
US3650668A (en)	1972-03-21	Thermally stabilized acrylic fibers produced by sulfation and heating in an oxygen-containing atmosphere