CA1278897C - Curable organopolysiloxane, composition - Google Patents

Curable organopolysiloxane, composition

Info

Publication number: CA1278897C
Authority: CA; Canada
Prior art keywords: weight; polysiloxane; substituted; hydrocarbon group; positive integer
Prior art date: 1985-05-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000508129A

Other languages

English (en)

French (fr)

Inventor

Catherine A. Dittmer

Robert S. Dubrow

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Raychem Corp

Original Assignee

Raychem Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-05-02

Filing date

1986-05-01

Publication date

1991-01-08

1986-05-01 Application filed by Raychem Corp filed Critical Raychem Corp

1991-01-08 Application granted granted Critical

1991-01-08 Publication of CA1278897C publication Critical patent/CA1278897C/en

2008-01-08 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

229920001296 polysiloxane Polymers 0.000 title claims abstract description 99
239000000203 mixture Substances 0.000 title claims abstract description 84
-1 polysiloxane Polymers 0.000 claims abstract description 95
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 72
239000000654 additive Substances 0.000 claims abstract description 55
230000000996 additive effect Effects 0.000 claims abstract description 43
230000035515 penetration Effects 0.000 claims abstract description 34
239000000463 material Substances 0.000 claims abstract description 22
238000000034 method Methods 0.000 claims abstract description 17
238000003847 radiation curing Methods 0.000 claims abstract description 5
239000000126 substance Substances 0.000 claims abstract description 4
125000001183 hydrocarbyl group Chemical group 0.000 claims description 27
238000001723 curing Methods 0.000 claims description 23
238000004132 cross linking Methods 0.000 claims description 15
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 13
125000001931 aliphatic group Chemical group 0.000 claims description 12
239000000758 substrate Substances 0.000 claims description 12
239000003999 initiator Substances 0.000 claims description 11
238000010894 electron beam technology Methods 0.000 claims description 8
150000002978 peroxides Chemical class 0.000 claims description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 16
239000000565 sealant Substances 0.000 abstract description 3
235000013870 dimethyl polysiloxane Nutrition 0.000 description 27
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 23
239000004205 dimethyl polysiloxane Substances 0.000 description 22
235000013350 formula milk Nutrition 0.000 description 18
239000012530 fluid Substances 0.000 description 12
230000005855 radiation Effects 0.000 description 12
229920002554 vinyl polymer Polymers 0.000 description 10
150000001875 compounds Chemical class 0.000 description 9
239000000523 sample Substances 0.000 description 9
230000000052 comparative effect Effects 0.000 description 6
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
239000011243 crosslinked material Substances 0.000 description 4
239000004342 Benzoyl peroxide Substances 0.000 description 3
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
229960003328 benzoyl peroxide Drugs 0.000 description 3
235000019400 benzoyl peroxide Nutrition 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 3
229920005645 diorganopolysiloxane polymer Polymers 0.000 description 2
239000000945 filler Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
HFGHRUCCKVYFKL-UHFFFAOYSA-N 4-ethoxy-2-piperazin-1-yl-7-pyridin-4-yl-5h-pyrimido[5,4-b]indole Chemical compound C1=C2NC=3C(OCC)=NC(N4CCNCC4)=NC=3C2=CC=C1C1=CC=NC=C1 HFGHRUCCKVYFKL-UHFFFAOYSA-N 0.000 description 1
GUTLYIVDDKVIGB-OUBTZVSYSA-N Cobalt-60 Chemical compound [60Co] GUTLYIVDDKVIGB-OUBTZVSYSA-N 0.000 description 1
229910018540 Si C Inorganic materials 0.000 description 1
239000013036 UV Light Stabilizer Substances 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
239000003139 biocide Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
239000003989 dielectric material Substances 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
239000000417 fungicide Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
238000009413 insulation Methods 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
229940038597 peroxide anti-acne preparations for topical use Drugs 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000000049 pigment Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
230000009993 protective function Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000007789 sealing Methods 0.000 description 1
239000003566 sealing material Substances 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
229940024463 silicone emollient and protective product Drugs 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Silicon Polymers (AREA)

CA000508129A 1985-05-02 1986-05-01 Curable organopolysiloxane, composition Expired - Fee Related CA1278897C (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US73040285A	1985-05-02	1985-05-02
US730,402		1985-05-02

Publications (1)

Publication Number	Publication Date
CA1278897C true CA1278897C (en)	1991-01-08

Family

ID=24935194

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000508129A Expired - Fee Related CA1278897C (en)	1985-05-02	1986-05-01	Curable organopolysiloxane, composition

Country Status (14)

Country	Link
EP (1)	EP0203738A3 (da)
JP (1)	JPS61261357A (da)
KR (1)	KR950001850B1 (da)
AU (1)	AU596971B2 (da)
BR (1)	BR8601973A (da)
CA (1)	CA1278897C (da)
DK (1)	DK200086A (da)
ES (1)	ES8801933A1 (da)
FI (1)	FI861829A7 (da)
IL (1)	IL78585A (da)
MX (1)	MX168314B (da)
NO (1)	NO861719L (da)
NZ (1)	NZ215915A (da)
ZA (1)	ZA863317B (da)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS62243621A (ja) *	1986-04-17	1987-10-24	Toray Silicone Co Ltd	シリコ−ンゴム粒状物の製造方法
US4852646A (en) *	1987-06-16	1989-08-01	Raychem Corporation	Thermally conductive gel materials
US4806594A (en) *	1987-06-17	1989-02-21	Union Carbide Corporation	Water curable compositions of silane containing ole36in polymers
JPH04503825A (ja) *	1989-03-01	1992-07-09	レイケム・コーポレイション	オルガノポリシロキサン組成物の硬化法およびそれからなる物品
US5162480A (en) *	1990-12-14	1992-11-10	Union Carbide Chemicals & Plastics Technology Corporation	Self-curing ceramicizable polysiloxanes

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2819236A (en) *	1954-12-23	1958-01-07	Dow Corning	Low durometer siloxane elastomers
GB912259A (en) *	1959-04-22	1962-12-05	Midland Silicones Ltd	Improvements in or relating to the curing of silicones by irradiation
US3660345A (en) *	1968-09-09	1972-05-02	Gen Electric	Organopolysiloxane elastomer compositions
JPS4810633B1 (da) *	1969-04-25	1973-04-05
JPS4810947B1 (da) *	1969-08-15	1973-04-09
JPS5344182B2 (da) *	1975-01-14	1978-11-27
JPS6017428B2 (ja) *	1980-12-08	1985-05-02	信越化学工業株式会社	射出成形用一液型オルガノポリシロキサン組成物
US4355121A (en) *	1981-04-09	1982-10-19	General Electric Company	Heat strength curable silicone rubber compositions
JPS601897B2 (ja) *	1981-11-25	1985-01-18	東芝シリコ−ン株式会社	紫外線による硬化に適したシリコ−ンゴム組成物

1986
- 1986-04-22 NZ NZ215915A patent/NZ215915A/xx unknown
- 1986-04-22 IL IL78585A patent/IL78585A/xx not_active IP Right Cessation
- 1986-04-29 ES ES554512A patent/ES8801933A1/es not_active Expired
- 1986-04-30 NO NO861719A patent/NO861719L/no unknown
- 1986-04-30 FI FI861829A patent/FI861829A7/fi not_active IP Right Cessation
- 1986-05-01 EP EP86303348A patent/EP0203738A3/en not_active Withdrawn
- 1986-05-01 CA CA000508129A patent/CA1278897C/en not_active Expired - Fee Related
- 1986-05-01 DK DK200086A patent/DK200086A/da not_active Application Discontinuation
- 1986-05-02 ZA ZA863317A patent/ZA863317B/xx unknown
- 1986-05-02 BR BR8601973A patent/BR8601973A/pt unknown
- 1986-05-02 MX MX002377A patent/MX168314B/es unknown
- 1986-05-02 JP JP61102964A patent/JPS61261357A/ja active Pending
- 1986-05-02 KR KR1019860003444A patent/KR950001850B1/ko not_active Expired - Fee Related
- 1986-05-02 AU AU57053/86A patent/AU596971B2/en not_active Ceased

Also Published As

Publication number	Publication date
ES8801933A1 (es)	1988-03-16
EP0203738A2 (en)	1986-12-03
DK200086D0 (da)	1986-05-01
KR950001850B1 (ko)	1995-03-04
AU5705386A (en)	1986-11-06
MX168314B (es)	1993-05-18
FI861829L (fi)	1986-11-03
NO861719L (no)	1986-11-03
DK200086A (da)	1986-11-03
FI861829A0 (fi)	1986-04-30
BR8601973A (pt)	1987-01-06
NZ215915A (en)	1989-05-29
ZA863317B (en)	1988-01-27
FI861829A7 (fi)	1986-11-03
ES554512A0 (es)	1988-03-16
IL78585A (en)	1990-06-10
KR860009078A (ko)	1986-12-20
AU596971B2 (en)	1990-05-24
JPS61261357A (ja)	1986-11-19
EP0203738A3 (en)	1988-01-13
IL78585A0 (en)	1986-08-31

Legal Events

Date	Code	Title	Description
1993-07-10	MKLA	Lapsed

Publication	Publication Date	Title
US4777063A (en)	1988-10-11	Curable organopolysiloxane composition
CA1339437C (en)	1997-09-02	Adhesion promoter for uv curable siloxane compositions and compositions containing same
AU603865B2 (en)	1990-11-29	Organopolysiloxane fluids
US3284406A (en)	1966-11-08	Organosiloxane encapsulating resins
CA1080388A (en)	1980-06-24	Self-adhering silicone compositions and preparations thereof
US4108825A (en)	1978-08-22	Flame retardant heat-curable silicone compositions containing ceric hydrate
CA1241785A (en)	1988-09-06	Uv curable silicone block colpolymers
US4340090A (en)	1982-07-20	Silicone compositions for the treatment of glass fibers and methods of treatment
KR900001759A (ko)	1990-02-27	탈착 코딩용 실리콘 조성물
US5188864A (en)	1993-02-23	Adhesion promoter for UV curable siloxane compositions and compositions containing same
US4780486A (en)	1988-10-25	Fast ultraviolet radiation curing silicone composition
US4946874A (en)	1990-08-07	Fast ultraviolet radiation curing silicone composition containing two vinyl polymers
EP0152179A2 (en)	1985-08-21	UV curable silicone rubber compositions
ES480461A1 (es)	1980-08-16	Un procedimiento para la preparacion de una composicion elastomerica de silicona.
EP0305032A2 (en)	1989-03-01	Method for preparing clear polyorganosiloxane elastomers
JPH02227463A (ja)	1990-09-10	オルガノシロキサン組成物，及び硬化エラストマーの圧縮永久歪を改良する方法
CA1096096A (en)	1981-02-17	Siloxane elastomer prepared from mercaptoorganopolysiloxanes
CA1192694A (en)	1985-08-27	High strength curable silicone rubber compositions
US5162389A (en)	1992-11-10	Fast ultraviolet radiation curing silicone composition having a high refractive index
KR840008672A (ko)	1984-12-17	액체 오가노실록산 수지조성물
JPH039954A (ja)	1991-01-17	（メタ）アクリロキシアルケニレン官能性プレポリマーの架橋
CA2037653A1 (en)	1991-09-20	Storage stable one-part organosiloxane compositions
US5124212A (en)	1992-06-23	Articles prepared from fast ultraviolet radiation curing silicone composition
JPS61258838A (ja)	1986-11-17	硬化性ポリシルアリ−レン−ポリシロキサン共重合体
US5169879A (en)	1992-12-08	Fast ultraviolet radiation curing silicone composition