CA1281226C - Emulsions et elements photographiques contenant des grains d'halogenure d'argent cristallins a faces tetrahexahedrales - Google Patents

Emulsions et elements photographiques contenant des grains d'halogenure d'argent cristallins a faces tetrahexahedrales

Info

Publication number: CA1281226C
Authority: CA; Canada
Prior art keywords: silver halide; cubic; grains; crystal faces; none
Prior art date: 1985-09-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000515749A

Other languages

English (en)

Inventor

Joe Edward Maskasky

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eastman Kodak Co

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-09-03

Filing date

1986-08-12

Publication date

1991-03-12

1986-07-03 Priority claimed from US06/881,769 external-priority patent/US4680255A/en

1986-08-12 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1991-03-12 Application granted granted Critical

1991-03-12 Publication of CA1281226C publication Critical patent/CA1281226C/fr

2008-03-12 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000013078 crystal Substances 0.000 title claims abstract description 217
229910052709 silver Inorganic materials 0.000 title claims abstract description 162
239000004332 silver Substances 0.000 title claims abstract description 162
-1 silver halide Chemical class 0.000 title claims abstract description 156
239000000839 emulsion Substances 0.000 title claims abstract description 103
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 33
230000005855 radiation Effects 0.000 claims abstract description 17
239000003607 modifier Substances 0.000 claims description 52
239000000975 dye Substances 0.000 claims description 34
ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 claims description 16
125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 claims description 10
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 8
229910021607 Silver chloride Inorganic materials 0.000 claims description 6
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 6
LZNNZDYSCWXPKW-UHFFFAOYSA-N 4-[4-oxo-2-sulfanylidene-5-[2-[3-(3-sulfopropyl)-1,3-thiazolidin-2-ylidene]ethylidene]-1,3-thiazolidin-3-yl]butanoic acid Chemical compound O=C1N(CCCC(=O)O)C(=S)SC1=CC=C1N(CCCS(O)(=O)=O)CCS1 LZNNZDYSCWXPKW-UHFFFAOYSA-N 0.000 claims 1
CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims 1
150000004820 halides Chemical class 0.000 abstract description 11
238000000034 method Methods 0.000 description 39
239000010410 layer Substances 0.000 description 21
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 20
150000002500 ions Chemical class 0.000 description 19
QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical compound Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 description 17
230000003595 spectral effect Effects 0.000 description 16
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 14
238000001556 precipitation Methods 0.000 description 14
231100000202 sensitizing Toxicity 0.000 description 12
230000001235 sensitizing effect Effects 0.000 description 12
230000008021 deposition Effects 0.000 description 11
239000000203 mixture Substances 0.000 description 10
KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical compound O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 9
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 9
238000001179 sorption measurement Methods 0.000 description 9
238000002360 preparation method Methods 0.000 description 8
239000013598 vector Substances 0.000 description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
229910052799 carbon Inorganic materials 0.000 description 6
238000010586 diagram Methods 0.000 description 6
238000000635 electron micrograph Methods 0.000 description 6
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 6
238000005259 measurement Methods 0.000 description 6
238000011160 research Methods 0.000 description 6
159000000000 sodium salts Chemical class 0.000 description 6
108010010803 Gelatin Proteins 0.000 description 5
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 5
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 5
229910052794 bromium Inorganic materials 0.000 description 5
239000008273 gelatin Substances 0.000 description 5
229920000159 gelatin Polymers 0.000 description 5
235000019322 gelatine Nutrition 0.000 description 5
235000011852 gelatine desserts Nutrition 0.000 description 5
238000003384 imaging method Methods 0.000 description 5
239000011734 sodium Substances 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
239000000084 colloidal system Substances 0.000 description 4
238000010894 electron beam technology Methods 0.000 description 4
239000000463 material Substances 0.000 description 4
238000011179 visual inspection Methods 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
229910002651 NO3 Inorganic materials 0.000 description 3
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 3
238000013459 approach Methods 0.000 description 3
210000000988 bone and bone Anatomy 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
238000011161 development Methods 0.000 description 3
230000018109 developmental process Effects 0.000 description 3
238000002050 diffraction method Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000001493 electron microscopy Methods 0.000 description 3
230000006870 function Effects 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
230000003993 interaction Effects 0.000 description 3
230000001788 irregular Effects 0.000 description 3
238000012545 processing Methods 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
238000001228 spectrum Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
PSLYVIQYHWPRAS-UHFFFAOYSA-N 2-sulfanyl-1H-tetrazol-5-one Chemical compound SN1N=NC(N1)=O PSLYVIQYHWPRAS-UHFFFAOYSA-N 0.000 description 2
UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical compound O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 2
KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
238000001016 Ostwald ripening Methods 0.000 description 2
NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
206010070834 Sensitisation Diseases 0.000 description 2
241000212342 Sium Species 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
ISAKRJDGNUQOIC-UHFFFAOYSA-N Uracil Chemical compound O=C1C=CNC(=O)N1 ISAKRJDGNUQOIC-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
229910052921 ammonium sulfate Inorganic materials 0.000 description 2
230000008901 benefit Effects 0.000 description 2
229940006460 bromide ion Drugs 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
KOWWOODYPWDWOJ-LVBPXUMQSA-N elatine Chemical compound C([C@]12CN(C3[C@@]45OCO[C@]44[C@H]6[C@@H](OC)[C@@H]([C@H](C4)OC)C[C@H]6[C@@]3([C@@H]1[C@@H]5OC)[C@@H](OC)CC2)CC)OC(=O)C1=CC=CC=C1N1C(=O)CC(C)C1=O KOWWOODYPWDWOJ-LVBPXUMQSA-N 0.000 description 2
210000003608 fece Anatomy 0.000 description 2
238000011835 investigation Methods 0.000 description 2
XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 2
229940006461 iodide ion Drugs 0.000 description 2
238000001000 micrograph Methods 0.000 description 2
238000013508 migration Methods 0.000 description 2
230000005012 migration Effects 0.000 description 2
238000002156 mixing Methods 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
239000012071 phase Substances 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
230000008569 process Effects 0.000 description 2
235000018102 proteins Nutrition 0.000 description 2
108090000623 proteins and genes Proteins 0.000 description 2
102000004169 proteins and genes Human genes 0.000 description 2
230000009467 reduction Effects 0.000 description 2
230000005070 ripening Effects 0.000 description 2
230000035945 sensitivity Effects 0.000 description 2
230000008313 sensitization Effects 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
125000004434 sulfur atom Chemical group 0.000 description 2
150000003852 triazoles Chemical class 0.000 description 2
UDATXMIGEVPXTR-UHFFFAOYSA-N 1,2,4-triazolidine-3,5-dione Chemical compound O=C1NNC(=O)N1 UDATXMIGEVPXTR-UHFFFAOYSA-N 0.000 description 1
KANAPVJGZDNSCZ-UHFFFAOYSA-N 1,2-benzothiazole 1-oxide Chemical compound C1=CC=C2S(=O)N=CC2=C1 KANAPVJGZDNSCZ-UHFFFAOYSA-N 0.000 description 1
QLDQYRDCPNBPII-UHFFFAOYSA-N 1,2-benzoxazol-3-one Chemical compound C1=CC=C2C(O)=NOC2=C1 QLDQYRDCPNBPII-UHFFFAOYSA-N 0.000 description 1
NPZTUJOABDZTLV-UHFFFAOYSA-N 1,2-dihydrobenzotriazol-4-one Chemical compound O=C1C=CC=C2NNN=C12 NPZTUJOABDZTLV-UHFFFAOYSA-N 0.000 description 1
OXFSTTJBVAAALW-UHFFFAOYSA-N 1,3-dihydroimidazole-2-thione Chemical compound SC1=NC=CN1 OXFSTTJBVAAALW-UHFFFAOYSA-N 0.000 description 1
SEARPMOICNRYEK-UHFFFAOYSA-N 1-(disulfanyl)hexane Chemical compound CCCCCCSS SEARPMOICNRYEK-UHFFFAOYSA-N 0.000 description 1
WJYTUEDMQDYMFC-UHFFFAOYSA-N 1-oxacyclooctadec-2-en-4-one Chemical compound C1(C=COCCCCCCCCCCCCCC1)=O WJYTUEDMQDYMFC-UHFFFAOYSA-N 0.000 description 1
FHTDDANQIMVWKZ-UHFFFAOYSA-N 1h-pyridine-4-thione Chemical compound SC1=CC=NC=C1 FHTDDANQIMVWKZ-UHFFFAOYSA-N 0.000 description 1
JGRMXPSUZIYDRR-UHFFFAOYSA-N 2-(4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl)acetic acid Chemical compound OC(=O)CN1C(=O)CSC1=S JGRMXPSUZIYDRR-UHFFFAOYSA-N 0.000 description 1
ORLTWSXWDJXSLB-UHFFFAOYSA-N 2-[5-(anilinomethylidene)-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]ethanesulfonic acid Chemical compound O=C1N(CCS(=O)(=O)O)C(=S)SC1=CNC1=CC=CC=C1 ORLTWSXWDJXSLB-UHFFFAOYSA-N 0.000 description 1
NVTTXBSQOZAGQD-UHFFFAOYSA-N 2-[5-[2-(3-ethyl-1,3-benzoxazol-2-ylidene)ethylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]propanoic acid Chemical compound O1C2=CC=CC=C2N(CC)C1=CC=C1SC(=S)N(C(C)C(O)=O)C1=O NVTTXBSQOZAGQD-UHFFFAOYSA-N 0.000 description 1
JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
RKRXTVLCZDPERO-UHFFFAOYSA-N 2-methyl-6-nitro-1h-benzimidazole Chemical compound C1=C([N+]([O-])=O)C=C2NC(C)=NC2=C1 RKRXTVLCZDPERO-UHFFFAOYSA-N 0.000 description 1
XLUWNAXYGUQQJL-UHFFFAOYSA-N 2h-1,3,4-oxadiazol-5-one Chemical compound O=C1OCN=N1 XLUWNAXYGUQQJL-UHFFFAOYSA-N 0.000 description 1
TZFOEYRGARRRGO-UHFFFAOYSA-N 2h-triazole-4,5-dicarboxylic acid Chemical compound OC(=O)C1=NNN=C1C(O)=O TZFOEYRGARRRGO-UHFFFAOYSA-N 0.000 description 1
OKDGPOCKHMGDQY-UHFFFAOYSA-N 3,4-dihydropyrrol-2-one Chemical compound O=C1CCC=N1 OKDGPOCKHMGDQY-UHFFFAOYSA-N 0.000 description 1
UKJRKKQWBUZLPP-UHFFFAOYSA-N 3-methyl-1,3-benzothiazol-3-ium Chemical compound C1=CC=C2[N+](C)=CSC2=C1 UKJRKKQWBUZLPP-UHFFFAOYSA-N 0.000 description 1
HMYWZHOIHLAJTH-UHFFFAOYSA-N 4-ethyl-4-methyl-5-sulfanylideneimidazolidin-2-one Chemical compound CCC1(C)NC(=O)NC1=S HMYWZHOIHLAJTH-UHFFFAOYSA-N 0.000 description 1
ADPKXPIDMSMDQP-UHFFFAOYSA-N 5-(1,3-dithiolan-2-ylidene)-3-ethyl-2-sulfanylidene-1,3-thiazolidin-4-one Chemical compound O=C1N(CC)C(=S)SC1=C1SCCS1 ADPKXPIDMSMDQP-UHFFFAOYSA-N 0.000 description 1
INVVMIXYILXINW-UHFFFAOYSA-N 5-methyl-1h-[1,2,4]triazolo[1,5-a]pyrimidin-7-one Chemical compound CC1=CC(=O)N2NC=NC2=N1 INVVMIXYILXINW-UHFFFAOYSA-N 0.000 description 1
YPXQSGWOGQPLQO-UHFFFAOYSA-N 5-nitro-1,3-dihydrobenzimidazole-2-thione Chemical compound [O-][N+](=O)C1=CC=C2N=C(S)NC2=C1 YPXQSGWOGQPLQO-UHFFFAOYSA-N 0.000 description 1
WSGURAYTCUVDQL-UHFFFAOYSA-N 5-nitro-1h-indazole Chemical compound [O-][N+](=O)C1=CC=C2NN=CC2=C1 WSGURAYTCUVDQL-UHFFFAOYSA-N 0.000 description 1
ODPOAESBSUKMHD-UHFFFAOYSA-L 6,7-dihydrodipyrido[1,2-b:1',2'-e]pyrazine-5,8-diium;dibromide Chemical compound [Br-].[Br-].C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 ODPOAESBSUKMHD-UHFFFAOYSA-L 0.000 description 1
PBADSWFRDNMCQD-UHFFFAOYSA-N 6-bromo-5-methyl-1h-[1,2,4]triazolo[1,5-a]pyrimidin-7-one Chemical compound O=C1C(Br)=C(C)N=C2N=CNN21 PBADSWFRDNMCQD-UHFFFAOYSA-N 0.000 description 1
RDDFONIJRJHLCM-UHFFFAOYSA-N 7-methoxy-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidine Chemical compound COC1=CC(C)=NC2=NC=NN12 RDDFONIJRJHLCM-UHFFFAOYSA-N 0.000 description 1
102000009027 Albumins Human genes 0.000 description 1
108010088751 Albumins Proteins 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
241000283690 Bos taurus Species 0.000 description 1
102100025597 Caspase-4 Human genes 0.000 description 1
WROIFJAIALUVMP-UHFFFAOYSA-N ClC=1C(C=2C(NNN2)=CC1[N+](=O)[O-])=O Chemical compound ClC=1C(C=2C(NNN2)=CC1[N+](=O)[O-])=O WROIFJAIALUVMP-UHFFFAOYSA-N 0.000 description 1
102000008186 Collagen Human genes 0.000 description 1
108010035532 Collagen Proteins 0.000 description 1
241000518994 Conta Species 0.000 description 1
102100034032 Cytohesin-3 Human genes 0.000 description 1
229940090898 Desensitizer Drugs 0.000 description 1
239000005630 Diquat Substances 0.000 description 1
101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 1
241001464057 Electroma Species 0.000 description 1
PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 description 1
229920000084 Gum arabic Polymers 0.000 description 1
101100273284 Homo sapiens CASP4 gene Proteins 0.000 description 1
101000870123 Homo sapiens Cytohesin-3 Proteins 0.000 description 1
101000823778 Homo sapiens Y-box-binding protein 2 Proteins 0.000 description 1
241000271915 Hydrophis Species 0.000 description 1
206010022528 Interactions Diseases 0.000 description 1
FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 description 1
229920000877 Melamine resin Polymers 0.000 description 1
101100412856 Mus musculus Rhod gene Proteins 0.000 description 1
BBLAVAZGWSWRMD-UHFFFAOYSA-N OC=1N2C(=NN=C2N=C(C1)C)SC Chemical compound OC=1N2C(=NN=C2N=C(C1)C)SC BBLAVAZGWSWRMD-UHFFFAOYSA-N 0.000 description 1
241001163743 Perlodes Species 0.000 description 1
BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
241000978776 Senegalia senegal Species 0.000 description 1
229910021612 Silver iodide Inorganic materials 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
101150052863 THY1 gene Proteins 0.000 description 1
101100242191 Tetraodon nigroviridis rho gene Proteins 0.000 description 1
241001061127 Thione Species 0.000 description 1
102100022222 Y-box-binding protein 2 Human genes 0.000 description 1
229920002494 Zein Polymers 0.000 description 1
239000011358 absorbing material Substances 0.000 description 1
239000000205 acacia gum Substances 0.000 description 1
235000010489 acacia gum Nutrition 0.000 description 1
239000000370 acceptor Substances 0.000 description 1
230000009471 action Effects 0.000 description 1
238000007259 addition reaction Methods 0.000 description 1
239000003513 alkali Substances 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
210000003423 ankle Anatomy 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
238000000149 argon plasma sintering Methods 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
239000002585 base Substances 0.000 description 1
235000021028 berry Nutrition 0.000 description 1
239000000298 carbocyanine Substances 0.000 description 1
239000005018 casein Substances 0.000 description 1
BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
235000021240 caseins Nutrition 0.000 description 1
229910052798 chalcogen Inorganic materials 0.000 description 1
150000001787 chalcogens Chemical class 0.000 description 1
LSWDNLDYKNRURG-UHFFFAOYSA-N chembl1548097 Chemical compound N1=C(C)C=C(O)N2N=NN=C21 LSWDNLDYKNRURG-UHFFFAOYSA-N 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
230000001427 coherent effect Effects 0.000 description 1
229920001436 collagen Polymers 0.000 description 1
229940000425 combination drug Drugs 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000012866 crystallographic experiment Methods 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
MPLIZXMCHYSZBR-UHFFFAOYSA-N ethyl 5-methyl-2-methylsulfanyl-7-oxo-[1,2,4]triazolo[1,5-a]pyrimidine-4-carboxylate Chemical compound CCOC(=O)N1C(C)=CC(=O)N2N=C(SC)N=C12 MPLIZXMCHYSZBR-UHFFFAOYSA-N 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000000499 gel Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000004676 glycans Chemical class 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
239000010931 gold Substances 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Inorganic materials Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
238000007689 inspection Methods 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
230000000873 masking effect Effects 0.000 description 1
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
QLNWXBAGRTUKKI-UHFFFAOYSA-N metacetamol Chemical compound CC(=O)NC1=CC=CC(O)=C1 QLNWXBAGRTUKKI-UHFFFAOYSA-N 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229930182817 methionine Natural products 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000013081 microcrystal Substances 0.000 description 1
210000004088 microvessel Anatomy 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 1
SCWKACOBHZIKDI-UHFFFAOYSA-N n-[3-(5-sulfanylidene-2h-tetrazol-1-yl)phenyl]acetamide Chemical compound CC(=O)NC1=CC=CC(N2C(N=NN2)=S)=C1 SCWKACOBHZIKDI-UHFFFAOYSA-N 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229910000510 noble metal Inorganic materials 0.000 description 1
230000006911 nucleation Effects 0.000 description 1
238000010899 nucleation Methods 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000001814 pectin Substances 0.000 description 1
235000010987 pectin Nutrition 0.000 description 1
229920001277 pectin Polymers 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
WHMDPDGBKYUEMW-UHFFFAOYSA-N pyridine-2-thiol Chemical compound SC1=CC=CC=N1 WHMDPDGBKYUEMW-UHFFFAOYSA-N 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000002310 reflectometry Methods 0.000 description 1
239000000837 restrainer Substances 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
230000000979 retarding effect Effects 0.000 description 1
IOVGROKTTNBUGK-SJCJKPOMSA-N ritodrine Chemical compound N([C@@H](C)[C@H](O)C=1C=CC(O)=CC=1)CCC1=CC=C(O)C=C1 IOVGROKTTNBUGK-SJCJKPOMSA-N 0.000 description 1
238000012216 screening Methods 0.000 description 1
229910052711 selenium Inorganic materials 0.000 description 1
239000011669 selenium Substances 0.000 description 1
ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
229940045105 silver iodide Drugs 0.000 description 1
239000002356 single layer Substances 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
125000006850 spacer group Chemical group 0.000 description 1
238000003756 stirring Methods 0.000 description 1
125000005504 styryl group Chemical group 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
239000013589 supplement Substances 0.000 description 1
238000006557 surface reaction Methods 0.000 description 1
YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
229940086542 triethylamine Drugs 0.000 description 1
229940035893 uracil Drugs 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000001043 yellow dye Substances 0.000 description 1
239000005019 zein Substances 0.000 description 1
229940093612 zein Drugs 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/04—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
- G03C1/047—Proteins, e.g. gelatine derivatives; Hydrolysis or extraction products of proteins
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/0051—Tabular grain emulsions
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/07—Substances influencing grain growth during silver salt formation
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/0051—Tabular grain emulsions
- G03C2001/0055—Aspect ratio of tabular grains in general; High aspect ratio; Intermediate aspect ratio; Low aspect ratio
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G03C2001/03511—Bromide content
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C2200/00—Details
- G03C2200/03—111 crystal face

Landscapes

Chemical & Material Sciences (AREA)
Physics & Mathematics (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
General Physics & Mathematics (AREA)
Spectroscopy & Molecular Physics (AREA)
Crystallography & Structural Chemistry (AREA)
Silver Salt Photography Or Processing Solution Therefor (AREA)

CA000515749A 1985-09-03 1986-08-12 Emulsions et elements photographiques contenant des grains d'halogenure d'argent cristallins a faces tetrahexahedrales Expired - Fee Related CA1281226C (fr)

Applications Claiming Priority (8)

Application Number	Priority Date	Filing Date	Title
US77222885A	1985-09-03	1985-09-03
US772,228		1985-09-03
US81113285A	1985-12-19	1985-12-19
US81113385A	1985-12-19	1985-12-19
US811,132		1985-12-19
US811,133		1985-12-19
US881,769		1986-07-03
US06/881,769 US4680255A (en)	1985-09-03	1986-07-03	Emulsions and photographic elements containing silver halide grains having tetrahexahedral crystal faces

Publications (1)

Publication Number	Publication Date
CA1281226C true CA1281226C (fr)	1991-03-12

Family

ID=27505722

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000515749A Expired - Fee Related CA1281226C (fr)	1985-09-03	1986-08-12	Emulsions et elements photographiques contenant des grains d'halogenure d'argent cristallins a faces tetrahexahedrales

Country Status (3)

Country	Link
EP (1)	EP0213963B1 (fr)
CA (1)	CA1281226C (fr)
DE (1)	DE3680608D1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3582707D1 (de) *	1984-07-28	1991-06-06	Konishiroku Photo Ind	Silberhalogenidkoerner, ihre herstellung und lichtempfindliches photographisches material, das diese enthaelt.

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4183756A (en) *	1978-05-03	1980-01-15	Eastman Kodak Company	Pre-precipitation spectral sensitizing dye addition process
US4225666A (en) *	1979-02-02	1980-09-30	Eastman Kodak Company	Silver halide precipitation and methine dye spectral sensitization process and products thereof

1986
- 1986-08-12 CA CA000515749A patent/CA1281226C/fr not_active Expired - Fee Related
- 1986-09-03 EP EP19860306828 patent/EP0213963B1/fr not_active Expired
- 1986-09-03 DE DE8686306828T patent/DE3680608D1/de not_active Expired - Fee Related

Also Published As

Publication number	Publication date
EP0213963B1 (fr)	1991-07-31
DE3680608D1 (de)	1991-09-05
EP0213963A3 (en)	1988-11-30
EP0213963A2 (fr)	1987-03-11

Legal Events

Date	Code	Title	Description
1996-09-12	MKLA	Lapsed

Publication	Publication Date	Title
CA1175694A (fr)	1984-10-09	Elements photographiques predurcis comprenant des grains tabulaires d'halogenure d'argent
DE3241645C2 (de)	1997-04-17	Strahlungsempfindliche photographische Silberhalogenidemulsion und Verfahren zur Herstellung derselben
US3655394A (en)	1972-04-11	Preparation of silver halide grains
US4643966A (en)	1987-02-17	Emulsions and photographic elements containing ruffled silver halide grains
EP0178097B1 (fr)	1991-03-20	Emulsion photographique à l'halogénure d'argent sensible à la lumière
US4035185A (en)	1977-07-12	Blended internal latent image emulsions, elements including such emulsions and processes for their preparation and use
DE69625315T2 (de)	2003-08-21	Strahlungsempfindliche Halogenidemulsionen und Verfahren zu ihrer Herstellung
EP0566079A2 (fr)	1993-10-20	Dispersions aqueuses de particules solides de dichalcogénures pour émulsions et revêtements photographiques
EP0566074A2 (fr)	1993-10-20	Emulsions photographiques à l'halogénure d'argent en présence de dichalcogénures organiques
US4724200A (en)	1988-02-09	Emulsions and photographic elements containing silver halide grains having icositetrahedral crystal faces
CA1281226C (fr)	1991-03-12	Emulsions et elements photographiques contenant des grains d'halogenure d'argent cristallins a faces tetrahexahedrales
US4680256A (en)	1987-07-14	Emulsions and photographic elements containing silver halide grains having trisoctahedra crystal faces
US4680254A (en)	1987-07-14	Emulsions and photographic elements containing silver halide grains having hexoctamedral crystal faces
CA1281224C (fr)	1991-03-12	Emulsions et elements photographiques contenant des grains cristallins d'halogenure d'argent a faces trioctahedrales
US4680255A (en)	1987-07-14	Emulsions and photographic elements containing silver halide grains having tetrahexahedral crystal faces
EP0195622A2 (fr)	1986-09-24	Agents azolium hydrolysés pour augmenter la sensibilité et inhiber le voile en photographie à l'halogénure d'argent
EP0269404B1 (fr)	1992-08-26	Matériau photographique à l'halogénure d'argent sensible à la lumière
EP0233396B1 (fr)	1991-07-31	Emulsions photographiques à l'halogénure d'argent avec des grains à faces
CA1280312C (fr)	1991-02-19	Emulsions et elements photographiques contenant des grains d'halogenure d'argent ruches
CA1281225C (fr)	1991-03-12	Emulsions et elements photographiques a grains d'halogenure d'argent cristallins a faces hexaoctahedrales
JPH08339047A (ja)	1996-12-24	写真要素
EP0328391A2 (fr)	1989-08-16	Stabilisateurs pour émulsions photographiques
CA1060698A (fr)	1979-08-21	Elements a emulsions fusionnees a image latente interne et methodes d'utilisation et de fabrication
EP0766130B1 (fr)	1999-12-08	Matériau photographique à couche d'émulsion à l'halogénure d'argent sensibilisée à la lumière rouge ayant une sensibilité à la chaleur améliorée
EP0766131B1 (fr)	1999-12-08	Matériau photographique à couche d'émulsion à l'halogénure d'argent sensibilisée à la lumière rouge ayant une sensibilité à la chaleur améliorée